HUP0003699A2 - Hordozós késői átmenetifém katalizátorrendszerek - Google Patents

Hordozós késői átmenetifém katalizátorrendszerek

Info

Publication number
HUP0003699A2
HUP0003699A2 HU0003699A HUP0003699A HUP0003699A2 HU P0003699 A2 HUP0003699 A2 HU P0003699A2 HU 0003699 A HU0003699 A HU 0003699A HU P0003699 A HUP0003699 A HU P0003699A HU P0003699 A2 HUP0003699 A2 HU P0003699A2
Authority
HU
Hungary
Prior art keywords
transition metal
phase polymerization
late transition
metal catalyst
catalyst systems
Prior art date
Application number
HU0003699A
Other languages
English (en)
Inventor
Jo Ann Marie Canich
David Edward Gindelberger
Phillip T. Matsunaga
Kevin Richard Squire
George Alan Vaughan
Original Assignee
Exxon Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc. filed Critical Exxon Chemical Patents Inc.
Publication of HUP0003699A2 publication Critical patent/HUP0003699A2/hu
Publication of HUP0003699A3 publication Critical patent/HUP0003699A3/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

A találmány szilárd hordozón immobilizált késői átmenetifém-katalizátor rendszerekre vonatkozik, valamint ezek alkalmazásáraheterogén fázisú polimerizációs eljárásokban, különösen olefinmonomerek gázfázisú polimerizálásában. A találmány szerinti előnyöskésői átmenetifém-katalizátorrendszer kétfogú ligandumszerkezettelstabilizált, 9., 10. vagy 11. csoportba tartozó fémkomplexettartalmaz, amely szilárd, pórusos fém- vagy metalloid-oxidrészecskékből álló hordozón van immobilizálva, a hordozó előnyösenszilícium-dioxidot tartalmaz. Az olefin monomerek gázfázisúpolimerizációját úgy hajtják végre, hogy egy vagy több olefintgázfázisú polimerizáció körülményei között a fentikatalizátorrendszerrel érintkeztetnek. Ó
HU0003699A 1996-06-17 1997-06-17 Supported late transition metal catalyst systems HUP0003699A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2009596P 1996-06-17 1996-06-17

Publications (2)

Publication Number Publication Date
HUP0003699A2 true HUP0003699A2 (hu) 2001-02-28
HUP0003699A3 HUP0003699A3 (en) 2008-09-29

Family

ID=21796718

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0003699A HUP0003699A3 (en) 1996-06-17 1997-06-17 Supported late transition metal catalyst systems

Country Status (9)

Country Link
EP (2) EP1287891A3 (hu)
JP (1) JP4359658B2 (hu)
CN (1) CN1128818C (hu)
AU (1) AU721921B2 (hu)
CA (1) CA2257796C (hu)
DE (1) DE69718642T2 (hu)
ES (1) ES2191184T3 (hu)
HU (1) HUP0003699A3 (hu)
WO (1) WO1997048736A1 (hu)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6812184B1 (en) 1996-06-17 2004-11-02 Exxonmobil Chemical Patents Inc. Supported late transition metal catalyst systems
US6194341B1 (en) 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
BR9710881A (pt) * 1996-07-23 1999-09-08 Du Pont Processo para a polimerização de olefinas e composto.
US6103658A (en) * 1997-03-10 2000-08-15 Eastman Chemical Company Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom
US6660677B1 (en) 1997-03-10 2003-12-09 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
US6822062B2 (en) 1997-03-10 2004-11-23 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
US6200925B1 (en) 1997-03-13 2001-03-13 Eastman Chemical Company Catalyst compositions for the polymerization of olefins
US6245871B1 (en) 1997-04-18 2001-06-12 Eastman Chemical Company Group 8-10 transition metal olefin polymerization catalysts
RU2000119136A (ru) * 1997-12-19 2002-08-10 Филлипс Петролеум Компани (US) Катализаторы на основе диимина никеля с метилалюмоксаном в качестве сокатализатора, способ полимеризации олефинов в присутствии этого катализатора и получаемые полимеры
US6511936B1 (en) 1998-02-12 2003-01-28 University Of Delaware Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins
WO1999048930A1 (fr) * 1998-03-20 1999-09-30 Idemitsu Petrochemical Co., Ltd. Catalyseurs permettant la production de polymeres olefiniques et procede de production de ces polymeres olefiniques
US6117959A (en) 1998-09-02 2000-09-12 Eastman Chemical Company Polyolefin catalysts
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
WO2000032642A1 (fr) * 1998-12-02 2000-06-08 Idemitsu Petrochemical Co., Ltd. Catalyseur pour la polymerisation d'olefines et procede de production d'un polymere d'olefines a l'aide de ce catalyseur
US6350832B1 (en) * 1998-12-09 2002-02-26 The B. F. Goodrich Company Mold addition polymerization of norbornene-type monomers using group 10 metal complexes
KR100368184B1 (ko) 1998-12-11 2003-01-30 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 올레핀의 중합 방법
WO2000050470A2 (en) 1999-02-22 2000-08-31 Eastman Chemical Company Catalysts containing n-pyrrolyl substituted nitrogen donors
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
US6620896B1 (en) 1999-02-23 2003-09-16 Eastman Chemical Company Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom
KR20010102542A (ko) 1999-03-09 2001-11-15 간디 지오프레이 에이치. 올레핀의 다단계 (공)중합 방법
US6197715B1 (en) 1999-03-23 2001-03-06 Cryovac, Inc. Supported catalysts and olefin polymerization processes utilizing same
US6197714B1 (en) 1999-03-23 2001-03-06 Cryovac, Inc. Supported catalysts and olefin polymerization processes utilizing same
US6506704B1 (en) * 1999-03-23 2003-01-14 Cryovac, Inc. Olefin polymerization catalysts and processes for making and using same
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6281303B1 (en) 1999-07-27 2001-08-28 Eastman Chemical Company Olefin oligomerization and polymerization catalysts
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6300439B1 (en) * 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
GB0003356D0 (en) * 2000-02-14 2000-04-05 Bp Chem Int Ltd Catalyst preparation method
US7056996B2 (en) 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
US6579823B2 (en) 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
ES2208247T3 (es) 2000-03-13 2004-06-16 Repsol Quimica S.A. Complejo de diimina bidentados de niquel y paladio y catalizadores de polimerizacion obtenidos a partir de los mismos.
ES2228436T3 (es) * 2000-03-13 2005-04-16 Repsol Quimica S.A. Compuestos diimino.
US6501000B1 (en) 2000-04-04 2002-12-31 Exxonmobil Research And Engineering Company Late transition metal catalyst complexes and oligomers therefrom
US6689928B2 (en) 2000-04-04 2004-02-10 Exxonmobil Research And Engineering Company Transition metal complexes and oligomers therefrom
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
EP1379560A1 (en) * 2001-04-17 2004-01-14 E.I. Du Pont De Nemours And Company Olefin polymerization catalyst
CN1160381C (zh) 2001-09-27 2004-08-04 中国石油化工股份有限公司 含双席夫碱配体的烯烃聚合催化剂及制备方法与应用
US6730757B2 (en) 2002-03-08 2004-05-04 Exxonmobil Research And Engineering Company Sulfur-containing and sulfur-nitrogen-containing catalysts for polymerization of olefins and polar monomers
US7247687B2 (en) 2002-07-17 2007-07-24 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin polymerization and oligomerization
EP1493755A1 (en) 2003-06-30 2005-01-05 Henkel KGaA Zero valent metal initiated gas-phase deposition polymerization (GDP)
EP2045273A1 (en) 2007-10-01 2009-04-08 Total Petrochemicals Research Feluy Patent Dept. Method for Supplying Granulated Material to a Polymerisation Reactor
KR101663184B1 (ko) 2009-12-15 2016-10-06 삼성전자주식회사 하이브리드 다공성 물질 및 그의 제조방법
KR101321028B1 (ko) 2010-08-16 2013-10-25 주식회사 엘지화학 후기 전이금속 화합물을 포함하는 담지 촉매 및 이를 이용한 올레핀계 중합체의 제조방법
CN113278098B (zh) * 2021-06-08 2023-03-14 钦州东辰材料科技有限公司 一种复合载体负载的聚烯烃催化剂及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686159A (en) * 1969-12-19 1972-08-22 Shell Oil Co Ethylene polymerization
US3759889A (en) * 1970-01-15 1973-09-18 Shell Oil Co Ethylene polymerization in the presence of complex nickel catalysts containing a glycolic acid thioglycolic or thiolactic acid ligand
US4716205A (en) * 1985-10-15 1987-12-29 E. I. Du Pont De Nemours And Company Nickel-catalyzed polymerization of ethylene
US5055552A (en) * 1989-06-14 1991-10-08 Shell Oil Company Polymerization of co/olefin with phosphorus bidentate ligand-solid support reaction product
US5227464A (en) * 1991-03-21 1993-07-13 Shell Oil Company Gas phase polymerization of co/olefin with particular catalyst support
US5237047A (en) * 1991-05-01 1993-08-17 Shell Oil Company Polymerization of co/olefin wth catalyst chemically bound to particles of support
US5504049A (en) * 1992-07-01 1996-04-02 Exxon Chemical Patents Inc. Transition metal olefin polymerization catalysts
WO1998056832A1 (en) * 1997-06-09 1998-12-17 E.I. Du Pont De Nemours And Company Polymerization of olefins

Also Published As

Publication number Publication date
EP1287891A3 (en) 2003-11-26
JP2002500681A (ja) 2002-01-08
JP4359658B2 (ja) 2009-11-04
DE69718642T2 (de) 2003-11-13
CA2257796A1 (en) 1997-12-24
ES2191184T3 (es) 2003-09-01
CN1225645A (zh) 1999-08-11
AU3396297A (en) 1998-01-07
EP0907665A1 (en) 1999-04-14
EP0907665B1 (en) 2003-01-22
AU721921B2 (en) 2000-07-20
CN1128818C (zh) 2003-11-26
EP1287891A2 (en) 2003-03-05
HUP0003699A3 (en) 2008-09-29
DE69718642D1 (de) 2003-02-27
WO1997048736A1 (en) 1997-12-24
CA2257796C (en) 2006-01-24

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FA9A Lapse of provisional patent protection due to relinquishment or protection considered relinquished