ES2173660T3 - Aditivos para mejorar la reversibilidad de un electrodo de carbono de un generador electroquimico secundario de iones de litio. - Google Patents

Aditivos para mejorar la reversibilidad de un electrodo de carbono de un generador electroquimico secundario de iones de litio.

Info

Publication number
ES2173660T3
ES2173660T3 ES98963594T ES98963594T ES2173660T3 ES 2173660 T3 ES2173660 T3 ES 2173660T3 ES 98963594 T ES98963594 T ES 98963594T ES 98963594 T ES98963594 T ES 98963594T ES 2173660 T3 ES2173660 T3 ES 2173660T3
Authority
ES
Spain
Prior art keywords
carbon electrode
reversibility
additives
improve
electrochemical generator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98963594T
Other languages
English (en)
Inventor
Denis Billaud
Abdelaziz Naji
Patrick Willmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National dEtudes Spatiales CNES
Original Assignee
Centre National dEtudes Spatiales CNES
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National dEtudes Spatiales CNES filed Critical Centre National dEtudes Spatiales CNES
Application granted granted Critical
Publication of ES2173660T3 publication Critical patent/ES2173660T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H01M6/168—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by additives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)

Abstract

Procedimiento para mejorar la reversibilidad de la intercalación de litio en un electrodo de carbono de un generador electroquímico de iones de litio, que utiliza un electrolito que comprende carbonato de propileno, según el cual se forma por vía electroquímica, durante la primera utilización del generador, una película de pasivación sobre la superficie del electrodo de carbono esencialmente a partir de un compuesto orgánico escogido entre los ésteres -halogenados cíclicos de fórmula (II) **fórmula** en la que X representa un halógeno como Cl, Br o I, y n es un número entero de 1 a 3, pudiendo estar sustituidos uno o varios de los grupos CH2 con grupos metilo, etilo, propilo o butilo.
ES98963594T 1997-12-23 1998-12-22 Aditivos para mejorar la reversibilidad de un electrodo de carbono de un generador electroquimico secundario de iones de litio. Expired - Lifetime ES2173660T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9716355A FR2772990B1 (fr) 1997-12-23 1997-12-23 Additifs pour ameliorer la reversibilite d'une electrode de carbone d'un generateur electrochimique secondaire a ions lithium

Publications (1)

Publication Number Publication Date
ES2173660T3 true ES2173660T3 (es) 2002-10-16

Family

ID=9514997

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98963594T Expired - Lifetime ES2173660T3 (es) 1997-12-23 1998-12-22 Aditivos para mejorar la reversibilidad de un electrodo de carbono de un generador electroquimico secundario de iones de litio.

Country Status (6)

Country Link
US (1) US6489063B1 (es)
EP (1) EP1042839B1 (es)
DE (1) DE69804141T2 (es)
ES (1) ES2173660T3 (es)
FR (1) FR2772990B1 (es)
WO (1) WO1999034468A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1764852A1 (en) 2005-09-16 2007-03-21 Sanyo Component Europe GmbH Method of manufacturing a lithium battery
US8993177B2 (en) * 2009-12-04 2015-03-31 Envia Systems, Inc. Lithium ion battery with high voltage electrolytes and additives
US10411299B2 (en) 2013-08-02 2019-09-10 Zenlabs Energy, Inc. Electrolytes for stable cycling of high capacity lithium based batteries

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2082817A5 (en) * 1970-03-27 1971-12-10 Accumulateurs Fixes Non aqs electrolyte - of potassium aluminium chloride lithium aluminium chloride in methylchloroformate,for electrochemical
JPH0711966B2 (ja) * 1986-03-17 1995-02-08 三洋電機株式会社 非水電解液電池
JP2582893B2 (ja) * 1989-03-31 1997-02-19 日立マクセル株式会社 有機電解液電池
JPH07192762A (ja) * 1993-12-24 1995-07-28 Sony Corp 非水電解液二次電池
US5529859A (en) * 1994-04-15 1996-06-25 National Research Council Of Canada Elecrolyte for a secondary cell
CA2153478C (en) * 1994-07-07 1999-03-09 Keiichi Yokoyama Non-aqueous electrolytic solutions and non-aqueous electrolyte cells comprising the same
JPH08298134A (ja) * 1995-04-25 1996-11-12 Sony Corp 非水電解液
JPH09147865A (ja) * 1995-11-27 1997-06-06 Sanyo Electric Co Ltd リチウム二次電池
JP3639376B2 (ja) * 1996-03-15 2005-04-20 日立マクセル株式会社 有機電解液二次電池
JPH09320633A (ja) * 1996-05-28 1997-12-12 Hitachi Maxell Ltd 非水二次電池
JPH105582A (ja) 1996-06-21 1998-01-13 Nippon Shokubai Co Ltd 吸液性樹脂およびその製造方法
JPH1055822A (ja) * 1996-08-08 1998-02-24 Hitachi Ltd リチウム２次電池及び電源装置
JPH10189008A (ja) * 1996-12-27 1998-07-21 Sanyo Electric Co Ltd リチウム電池

Also Published As

Publication number Publication date
FR2772990A1 (fr) 1999-06-25
EP1042839A1 (fr) 2000-10-11
US6489063B1 (en) 2002-12-03
EP1042839B1 (fr) 2002-03-06
DE69804141D1 (de) 2002-04-11
WO1999034468A1 (fr) 1999-07-08
DE69804141T2 (de) 2002-09-26
FR2772990B1 (fr) 2000-03-03

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