ES2162300T3 - Catalizador de oxidacion y un procedimiento para la obtencion de epoxidos a partir de olefinas, hidrogeno y oxigeno con empleo del catalizador de oxidacion. - Google Patents
Catalizador de oxidacion y un procedimiento para la obtencion de epoxidos a partir de olefinas, hidrogeno y oxigeno con empleo del catalizador de oxidacion.Info
- Publication number
- ES2162300T3 ES2162300T3 ES97925025T ES97925025T ES2162300T3 ES 2162300 T3 ES2162300 T3 ES 2162300T3 ES 97925025 T ES97925025 T ES 97925025T ES 97925025 T ES97925025 T ES 97925025T ES 2162300 T3 ES2162300 T3 ES 2162300T3
- Authority
- ES
- Spain
- Prior art keywords
- oxidation catalyst
- olefins
- oxygen
- hydrogen
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 230000003647 oxidation Effects 0.000 title abstract 5
- 238000007254 oxidation reaction Methods 0.000 title abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000001301 oxygen Substances 0.000 title abstract 2
- 229910052760 oxygen Inorganic materials 0.000 title abstract 2
- 150000002118 epoxides Chemical class 0.000 title 1
- -1 PALADY Chemical compound 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
CATALIZADOR DE OXIDACION A BASE DE SILICALITAS DE TITANIO O VANADIO CON ESTRUCTURA ZEOLITICA Y CON UN CONTENIDO DE 0,01 HASTA 30 % EN PESO DE UNO O VARIOS METALES NOBLES DEL GRUPO DE RUTENIO, RODIO, PALADIO, OSMIO, IRIDIO, PLATINO RENIO, ORO Y PLATA, CARACTERIZADO PORQUE EL CATALIZADOR DE OXIDACION SE FORMA MEDIANTE UN PROCEDIMIENTO DE CONFIGURACION SOLIDA. ESTE CATALIZADOR DE OXIDACION SE UTILIZA PARA LA OBTENCION DE OXIDOS, EN PARTICULAR OXIDO DE PROPILENO A PARTIR DE OLEFINAS, HIDROGENO Y OXIGENO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19623609A DE19623609A1 (de) | 1996-06-13 | 1996-06-13 | Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2162300T3 true ES2162300T3 (es) | 2001-12-16 |
Family
ID=7796861
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97925025T Expired - Lifetime ES2162300T3 (es) | 1996-06-13 | 1997-05-30 | Catalizador de oxidacion y un procedimiento para la obtencion de epoxidos a partir de olefinas, hidrogeno y oxigeno con empleo del catalizador de oxidacion. |
Country Status (12)
Country | Link |
---|---|
US (1) | US6008389A (es) |
EP (1) | EP0904151B1 (es) |
JP (1) | JP2000511818A (es) |
KR (1) | KR20000016574A (es) |
CN (1) | CN1103634C (es) |
AU (1) | AU3030997A (es) |
BR (1) | BR9709702A (es) |
CA (1) | CA2256383A1 (es) |
DE (2) | DE19623609A1 (es) |
ES (1) | ES2162300T3 (es) |
MX (1) | MX202663B (es) |
WO (1) | WO1997047386A1 (es) |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2156391T3 (es) * | 1996-07-01 | 2001-06-16 | Dow Chemical Co | Proceso para la oxidacion directa de olefinas a oxidos de olefinas. |
DE19723751A1 (de) * | 1997-06-06 | 1998-12-10 | Basf Ag | Formkörper und Verfahren zu dessen Herstellung |
US6562986B2 (en) | 1997-06-30 | 2003-05-13 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
US6323351B1 (en) | 1997-06-30 | 2001-11-27 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
BE1011577A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur. |
DE19804709A1 (de) | 1998-02-06 | 1999-08-12 | Bayer Ag | Verfahren zur katalytischen Direktoxidation ungesättigter Kohlenwasserstoffe in der Gasphase |
CN100334079C (zh) * | 1998-04-15 | 2007-08-29 | 陶氏环球技术公司 | 将烯烃直接氧化成烯烃氧化物的方法 |
US6005123A (en) * | 1998-04-16 | 1999-12-21 | Arco Chemical Technology, L.P. | Epoxidation process |
DE19835481A1 (de) | 1998-08-07 | 2000-02-17 | Bayer Ag | Verfahren zur Oxidation von Kohlenwasserstoffen |
DE19857137A1 (de) | 1998-12-11 | 2000-06-15 | Bayer Ag | Integriertes Verfahren zur Herstellung von Epoxiden aus Olefinen |
CN1172921C (zh) | 1998-12-16 | 2004-10-27 | 陶氏环球技术公司 | 将烯烃直接氧化成烯烃氧化物的方法 |
ATE259258T1 (de) | 1999-04-08 | 2004-02-15 | Dow Global Technologies Inc | Verfahren für die oxidierung von olefinen zu olefinoxiden unter verwendung eines oxidierten gold-katalysators |
US6821923B1 (en) | 1999-04-08 | 2004-11-23 | Dow Global Technologies Inc. | Method of preparing a catalyst containing gold and titanium |
DE19920753A1 (de) | 1999-04-23 | 2000-10-26 | Bayer Ag | Verfahren zur Herstellung von amorphen, edelmetallhaltigen Titan-Silizium-Mischoxiden |
DE19939416A1 (de) | 1999-08-20 | 2001-02-22 | Basf Ag | Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs |
CA2712321C (en) | 1999-10-21 | 2013-07-30 | Technolas Gmbh Ophthalmologische Systeme | Iris recognition and tracking for optical treatment |
MXPA02006936A (es) * | 2000-02-22 | 2003-01-28 | Arco Chem Tech | Proceso de epoxidacion directa utilizando composicion de catalizador mejorado. |
EP1138386A1 (de) * | 2000-03-29 | 2001-10-04 | Degussa AG | Verfahren zur Herstellung eines Titansilicalitformkörpers |
EP1138387A1 (de) * | 2000-03-29 | 2001-10-04 | Degussa AG | Verfahren zur Herstellung eines Titansilicalitformkörpers |
US6337412B1 (en) | 2000-04-25 | 2002-01-08 | Chemical Research & Licensing Company | Three stage propylene oxide process |
US6194591B1 (en) * | 2000-04-27 | 2001-02-27 | Arco Chemical Technology, L.P. | Aqueous epoxidation process using modified titanium zeolite |
MY131860A (en) * | 2000-06-21 | 2007-09-28 | Shell Int Research | Process for preparation of catalyst and use there of |
US6307073B1 (en) * | 2000-07-25 | 2001-10-23 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
US6281369B1 (en) | 2000-12-07 | 2001-08-28 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
US6310224B1 (en) | 2001-01-19 | 2001-10-30 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
JP3747239B2 (ja) * | 2001-02-28 | 2006-02-22 | 独立行政法人産業技術総合研究所 | プロピレンオキシドの製造方法 |
EP1249275B1 (de) * | 2001-04-14 | 2007-07-11 | Umicore AG & Co. KG | Katalysator und Verfahren zur Entfernung von Kohlenmonoxid aus einem Reformatgas, und Verfahren zur Herstellung des Katalysators |
EP1453605B1 (en) | 2001-08-01 | 2006-03-22 | Dow Global Technologies Inc. | Method of increasing the lifetime of a hydro-oxidation catalyst |
US6441204B1 (en) * | 2001-10-19 | 2002-08-27 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
US6498259B1 (en) * | 2001-10-19 | 2002-12-24 | Arco Chemical Technology L.P. | Direct epoxidation process using a mixed catalyst system |
US6403815B1 (en) * | 2001-11-29 | 2002-06-11 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
US20030119658A1 (en) * | 2001-12-21 | 2003-06-26 | Conocophillips Company | Recovery of rhenium from a spent catalyst via sublimation |
DE10233382A1 (de) | 2002-07-23 | 2004-01-29 | Basf Ag | Verfahren zur kontinuierlich betriebenen Reindestillation des bei der koppel-produktfreien Synthese von Propylenoxid anfallenden 1.2-Propylenglykols |
DE10233387A1 (de) | 2002-07-23 | 2004-02-12 | Basf Ag | Verfahren zur kontinuierlich betriebenen Reindestillation von Oxiranen, speziell von Propylenoxid |
DE10233388A1 (de) | 2002-07-23 | 2004-02-12 | Basf Ag | Verfahren zur kontinuierlich betriebenen Reindestillation des bei der koppel-produktfreien Propylenoxidsynthese verwendeten Lösungsmittels Methanol unter gleichzeitiger Abtrennung der Methoxypropanole und der Schwersieder |
US20030111171A1 (en) * | 2002-09-09 | 2003-06-19 | Casey Paul Karol | Poly(trimethylene) terephthalate texile staple production |
US6960671B2 (en) | 2002-09-20 | 2005-11-01 | Arco Chemical Technology, L.P. | Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein |
US20040124140A1 (en) * | 2002-12-30 | 2004-07-01 | Sawyer Gary A. | In situ filtration draught tube reactor system |
DE10320635A1 (de) * | 2003-05-08 | 2004-11-18 | Basf Ag | Verfahren zur Herstellung von Propylenoxid |
DE10321876A1 (de) * | 2003-05-15 | 2004-12-02 | Bayer Materialscience Ag | Katalysator |
US6884898B1 (en) | 2003-12-08 | 2005-04-26 | Arco Chemical Technology, L.P. | Propylene oxide process |
US6867312B1 (en) | 2004-03-17 | 2005-03-15 | Arco Chemical Technology, L.P. | Propylene oxide process |
US7786318B2 (en) * | 2005-04-12 | 2010-08-31 | Lyondell Chemical Technology, L.P. | Catalyst preparation |
CN101296915A (zh) * | 2005-10-25 | 2008-10-29 | 堪萨斯大学 | 用于将烯烃选择性氧化为环氧化物的方法 |
JP5179882B2 (ja) * | 2006-01-31 | 2013-04-10 | 旭化成ケミカルズ株式会社 | 芳香族炭化水素化合物製造用触媒 |
US7238817B1 (en) * | 2006-02-22 | 2007-07-03 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
BRPI0716682A2 (pt) * | 2006-11-17 | 2013-09-24 | Dow Global Technologies Inc | "composiÇço de catalisador, processo para preparar um àxido de olefina e composiÇço de precursor de catalisador." |
US7563740B2 (en) * | 2006-12-19 | 2009-07-21 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
JP5336468B2 (ja) * | 2007-04-05 | 2013-11-06 | ダウ グローバル テクノロジーズ エルエルシー | オレフィンオキシド生成物流れの分離と統合されたヒドロ酸化法 |
CN101284232B (zh) * | 2007-04-13 | 2013-01-16 | 微宏动力系统(湖州)有限公司 | 甲烷溴氧化制溴甲烷及其转化制碳氢化合物的催化剂 |
KR100918105B1 (ko) * | 2008-03-27 | 2009-09-22 | 한국화학연구원 | 피셔-트롭쉬 합성용 코발트/지르코늄-인/실리카 촉매와이의 제조방법 |
CN102441430B (zh) | 2010-10-11 | 2013-06-12 | 中国石油化工股份有限公司 | 一种催化剂及其制备方法和环氧化烯烃的方法 |
DE102011101877A1 (de) * | 2011-05-18 | 2012-11-22 | Süd-Chemie AG | Niedertemperatur-Oxidationskatalysator mit besonders ausgeprägten hydrophoben Eigenschaften für die Oxidation organischer Schadstoffe |
KR102305167B1 (ko) * | 2013-10-23 | 2021-09-29 | 바스프 에스이 | 소수성 제올라이트 물질의 성형물 및 이의 제조 방법 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4686029A (en) * | 1985-12-06 | 1987-08-11 | Union Carbide Corporation | Dewaxing catalysts and processes employing titanoaluminosilicate molecular sieves |
IT1222868B (it) * | 1987-10-12 | 1990-09-12 | Montedipe Spa | Metodo per la preparazione di titanio silicaliti |
DK717188A (da) * | 1987-12-29 | 1989-06-30 | Mobil Oil Corp | Titanosilicat samt anvendelse af dette ved fremstilling af aromatiske carbonhydrider |
US4828812A (en) * | 1987-12-29 | 1989-05-09 | Mobil Oil Corporation | Titanosilicates of enhanced ion exchange capacity and their preparation |
US5244650A (en) * | 1989-06-29 | 1993-09-14 | Engelhard Corporation | Large-pored molecular sieves with charged octahedral titanium and charged tetrahedral aluminum sites |
JP3044836B2 (ja) * | 1991-05-28 | 2000-05-22 | 東ソー株式会社 | プロピレンオキシドの製法 |
DE69426321T2 (de) * | 1993-08-06 | 2001-04-05 | Sumitomo Chemical Co., Ltd. | Verfahren zur Herstellung von Olefinoxiden |
DE4425672A1 (de) * | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
DE4435239A1 (de) * | 1994-10-04 | 1996-04-11 | Basf Ag | Verfahren zur Herstellung von Hydroxylaminen aus Ammoniak oder den entsprechenden Aminen, Wasserstoff und Sauerstoff |
-
1996
- 1996-06-13 DE DE19623609A patent/DE19623609A1/de not_active Withdrawn
-
1997
- 1997-05-30 WO PCT/EP1997/002821 patent/WO1997047386A1/de not_active Application Discontinuation
- 1997-05-30 ES ES97925025T patent/ES2162300T3/es not_active Expired - Lifetime
- 1997-05-30 BR BR9709702A patent/BR9709702A/pt not_active Application Discontinuation
- 1997-05-30 CN CN97195498A patent/CN1103634C/zh not_active Expired - Lifetime
- 1997-05-30 JP JP10501133A patent/JP2000511818A/ja active Pending
- 1997-05-30 EP EP97925025A patent/EP0904151B1/de not_active Revoked
- 1997-05-30 CA CA002256383A patent/CA2256383A1/en not_active Abandoned
- 1997-05-30 DE DE59704251T patent/DE59704251D1/de not_active Revoked
- 1997-05-30 KR KR1019980710169A patent/KR20000016574A/ko not_active Application Discontinuation
- 1997-05-30 AU AU30309/97A patent/AU3030997A/en not_active Abandoned
- 1997-05-30 US US09/147,383 patent/US6008389A/en not_active Expired - Lifetime
-
1998
- 1998-12-07 MX MX9810300A patent/MX202663B/es unknown
Also Published As
Publication number | Publication date |
---|---|
AU3030997A (en) | 1998-01-07 |
MX9810300A (en) | 1999-04-30 |
US6008389A (en) | 1999-12-28 |
JP2000511818A (ja) | 2000-09-12 |
CN1103634C (zh) | 2003-03-26 |
CN1222096A (zh) | 1999-07-07 |
DE59704251D1 (de) | 2001-09-13 |
KR20000016574A (ko) | 2000-03-25 |
MX202663B (en) | 2001-06-26 |
CA2256383A1 (en) | 1997-12-18 |
EP0904151B1 (de) | 2001-08-08 |
DE19623609A1 (de) | 1997-12-18 |
EP0904151A1 (de) | 1999-03-31 |
BR9709702A (pt) | 1999-08-10 |
WO1997047386A1 (de) | 1997-12-18 |
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