ES2082792T3 - Monoepoxidacion selectiva de estireno, analogos de estireno y derivados de estireno para el oxido correspondiente con oxigeno molecular. - Google Patents
Monoepoxidacion selectiva de estireno, analogos de estireno y derivados de estireno para el oxido correspondiente con oxigeno molecular.Info
- Publication number
- ES2082792T3 ES2082792T3 ES89912939T ES89912939T ES2082792T3 ES 2082792 T3 ES2082792 T3 ES 2082792T3 ES 89912939 T ES89912939 T ES 89912939T ES 89912939 T ES89912939 T ES 89912939T ES 2082792 T3 ES2082792 T3 ES 2082792T3
- Authority
- ES
- Spain
- Prior art keywords
- styrene
- analogs
- derivatives
- molecular oxygen
- oxide corresponding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/302—Basic shape of the elements
- B01J2219/30215—Toroid or ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/304—Composition or microstructure of the elements
- B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procedimiento para la monoepoxidación selectiva de compuestos aril-vinílicos que tienen la estructura: **fórmula** en la que Ar es fenilo; fenilo substituido con metilo, metoxi, halógeno, vinilo o fenilo; naftilo; o piridilo; y cada R se selecciona independientemente de hidrógeno y alquilo que tiene en el intervalo de 1 hasta 20 átomos de carbono, con la condición de que no haya átomos de hidrógeno alílicos a un doble enlace en dicha estructura; comprendiendo dicho procedimiento poner en contacto dicho compuesto aril-vinílico con una cantidad suficiente de un gas que contiene oxígeno a findemantenerla relación molar de compuesto aril-vinílico a oxígeno en el intervalo de 0,01 hasta 30, en presencia de un catalizador que contiene plata que contiene en el intervalo de 0,01 a 2% en peso, basado en el peso total de catalizador, incluyendo soporte, de al menos un promotor seleccionado de: nitrato de rubidio, acetato de rubidio, cloruro de rubidio, bromuro de rubidio, cloruro de cesio, bromuro decesio, nitrato de cesio, óxido de cesio e hidróxido de cesio; en el que dicho contacto se lleva a cabo a una presión en el intervalo de 10,13 kPa a 10,130 MPa (0,1 hasta 100 atmósferas), a una temperatura en el intervalo de 100 hasta 325º C, durante un tiempo suficiente para obtener conversiones de compuesto aril-vinílico en el intervalo de 0,5 hasta 75%.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US27033288A | 1988-11-14 | 1988-11-14 | |
US07/394,023 US5145968A (en) | 1988-11-14 | 1989-08-15 | Selective monoepoxidation of styrene, styrene analogs, and styrene derivatives to the corresponding oxide with molecular oxygen |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2082792T3 true ES2082792T3 (es) | 1996-04-01 |
Family
ID=26954218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES89912939T Expired - Lifetime ES2082792T3 (es) | 1988-11-14 | 1989-11-13 | Monoepoxidacion selectiva de estireno, analogos de estireno y derivados de estireno para el oxido correspondiente con oxigeno molecular. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5145968A (es) |
EP (2) | EP0369902A1 (es) |
JP (1) | JP2997039B2 (es) |
AT (1) | ATE133946T1 (es) |
CA (1) | CA2002242C (es) |
DE (1) | DE68925645T2 (es) |
ES (1) | ES2082792T3 (es) |
WO (1) | WO1990005726A1 (es) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5138077A (en) * | 1991-07-29 | 1992-08-11 | Eastman Kodak Company | Selective epoxidation of diolefins and aryl olefins |
DE69426321T2 (de) * | 1993-08-06 | 2001-04-05 | Sumitomo Chemical Co | Verfahren zur Herstellung von Olefinoxiden |
US5908942A (en) * | 1995-09-15 | 1999-06-01 | Eastman Chemical Company | Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions |
AU736456B2 (en) * | 1996-07-11 | 2001-07-26 | Dow Chemical Company, The | Process for the direct oxidation of olefins to olefin oxides |
US6323351B1 (en) | 1997-06-30 | 2001-11-27 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
CN1116107C (zh) * | 1997-06-30 | 2003-07-30 | 陶氏环球技术公司 | 烯烃直接氧化成烯化氧的方法 |
US6562986B2 (en) | 1997-06-30 | 2003-05-13 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
US5945550A (en) * | 1998-07-24 | 1999-08-31 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
US6646142B1 (en) | 1998-12-16 | 2003-11-11 | Dow Global Technologies Inc. | Process for the direct oxidation of olefins to olefin oxides |
US6821923B1 (en) * | 1999-04-08 | 2004-11-23 | Dow Global Technologies Inc. | Method of preparing a catalyst containing gold and titanium |
US6172245B1 (en) | 1999-12-16 | 2001-01-09 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
US6388106B1 (en) | 2001-05-24 | 2002-05-14 | Eastman Chemical Company | Selective epoxidation of conjugated diolefins |
JP2004340880A (ja) * | 2003-05-19 | 2004-12-02 | Soatec Inc | レーザ測定装置 |
US7235676B2 (en) * | 2004-03-31 | 2007-06-26 | Council Of Scientific & Industrial Research | Catalytic process for the preparation of epoxides from alkenes |
US7345182B2 (en) * | 2005-12-27 | 2008-03-18 | Central Salt And Marine Chemicals Research Institute | Catalytic epoxidation of styrene with molecular oxygen using metal ion exchanged zeolites |
JP5006855B2 (ja) * | 2008-09-24 | 2012-08-22 | 本田技研工業株式会社 | 排ガス浄化触媒及びこれを用いた排ガス浄化フィルタ |
CN103204830B (zh) * | 2012-01-13 | 2015-09-23 | 中国石油化工股份有限公司 | 一种催化氧化苯乙烯的方法 |
WO2018140466A1 (en) * | 2017-01-24 | 2018-08-02 | Lyondell Chemical Technology, L.P. | Liquid phase selective oxidation to epoxides with molecular oxygen |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2404438A (en) * | 1943-09-07 | 1946-07-23 | Shell Dev | Process for the manufacture of olefin oxides |
US2992238A (en) * | 1959-03-20 | 1961-07-11 | Dow Chemical Co | Vapor phase preparation of styrene oxide |
JPS5425011B2 (es) * | 1971-10-05 | 1979-08-24 | ||
JPS525586A (en) * | 1975-07-02 | 1977-01-17 | Yoshizaki Kozo | Thermoelectric couple holder |
US4760042A (en) * | 1982-03-24 | 1988-07-26 | Scientific Design Company, Inc. | Process for preparing an alkali metal-promoted silver catalyst |
US4894467A (en) * | 1986-10-16 | 1990-01-16 | The Standard Oil Company | Vapor phase oxidation or styrene to styrene oxide |
US4845253A (en) * | 1987-11-23 | 1989-07-04 | The Dow Chemical Company | Silver-based catalyst for vapor phase oxidation of olefins to epoxides |
US4950773A (en) * | 1988-01-28 | 1990-08-21 | Eastman Kodak Company | Selective epoxidation of olefins |
-
1989
- 1989-08-15 US US07/394,023 patent/US5145968A/en not_active Expired - Fee Related
- 1989-11-06 CA CA002002242A patent/CA2002242C/en not_active Expired - Fee Related
- 1989-11-13 DE DE68925645T patent/DE68925645T2/de not_active Expired - Fee Related
- 1989-11-13 EP EP89420435A patent/EP0369902A1/en active Pending
- 1989-11-13 AT AT89912939T patent/ATE133946T1/de not_active IP Right Cessation
- 1989-11-13 ES ES89912939T patent/ES2082792T3/es not_active Expired - Lifetime
- 1989-11-13 JP JP2500457A patent/JP2997039B2/ja not_active Expired - Fee Related
- 1989-11-13 WO PCT/US1989/005219 patent/WO1990005726A1/en active IP Right Grant
- 1989-11-13 EP EP89912939A patent/EP0442947B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE68925645D1 (de) | 1996-03-21 |
JP2997039B2 (ja) | 2000-01-11 |
CA2002242C (en) | 2000-09-05 |
EP0442947A1 (en) | 1991-08-28 |
CA2002242A1 (en) | 1990-05-14 |
DE68925645T2 (de) | 1996-06-20 |
EP0442947B1 (en) | 1996-02-07 |
EP0369902A1 (en) | 1990-05-23 |
ATE133946T1 (de) | 1996-02-15 |
WO1990005726A1 (en) | 1990-05-31 |
JPH04501564A (ja) | 1992-03-19 |
US5145968A (en) | 1992-09-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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