ES2051994T3 - Epoxidacion selectiva de olefinas. - Google Patents
Epoxidacion selectiva de olefinas.Info
- Publication number
- ES2051994T3 ES2051994T3 ES89300776T ES89300776T ES2051994T3 ES 2051994 T3 ES2051994 T3 ES 2051994T3 ES 89300776 T ES89300776 T ES 89300776T ES 89300776 T ES89300776 T ES 89300776T ES 2051994 T3 ES2051994 T3 ES 2051994T3
- Authority
- ES
- Spain
- Prior art keywords
- olefins
- selective epoxidation
- epoxidation
- selective
- contacted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCESO PARA LA EPOXIDACION SELECTIVA DE OLEFINAS QUE NO TIENEN H ALILICOS. TALES OLEFINAS SE PONEN EN CONTACTO CON UN GAS QUE CONTIENE O EN PRESENCIA DE UN CATALIZADOR DE PLATA Y UN HALURO ORGANICO EN CONDICIONES DE REACCION DEFINIDAS, DANDO LUGAR A LA PRODUCCION SELECTIVA DE EPOXIDOS CON BUEN RENDIMIENTO.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/149,297 US4897498A (en) | 1988-01-28 | 1988-01-28 | Selective monoepoxidation of olefins |
US07/292,589 US4950773A (en) | 1988-01-28 | 1988-12-30 | Selective epoxidation of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2051994T3 true ES2051994T3 (es) | 1994-07-01 |
Family
ID=26846613
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES89300776T Expired - Lifetime ES2051994T3 (es) | 1988-01-28 | 1989-01-27 | Epoxidacion selectiva de olefinas. |
Country Status (12)
Country | Link |
---|---|
US (1) | US4950773A (es) |
EP (2) | EP0326392B1 (es) |
JP (1) | JP2854059B2 (es) |
KR (1) | KR960011382B1 (es) |
CN (1) | CN1023225C (es) |
AT (1) | ATE102615T1 (es) |
AU (1) | AU618792B2 (es) |
BR (1) | BR8907211A (es) |
CA (1) | CA1338268C (es) |
DE (1) | DE68913563T2 (es) |
ES (1) | ES2051994T3 (es) |
WO (1) | WO1989007101A1 (es) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5145968A (en) * | 1988-11-14 | 1992-09-08 | Eastman Kodak Company | Selective monoepoxidation of styrene, styrene analogs, and styrene derivatives to the corresponding oxide with molecular oxygen |
WO1990011279A1 (en) * | 1989-03-20 | 1990-10-04 | Eastman Kodak Company | Selective epoxidation of bicyclic olefins |
US5138077A (en) * | 1991-07-29 | 1992-08-11 | Eastman Kodak Company | Selective epoxidation of diolefins and aryl olefins |
US5117012A (en) * | 1991-10-07 | 1992-05-26 | Eastman Kodak Company | Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation effluents |
US5155242A (en) * | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
US5326873A (en) * | 1992-06-05 | 1994-07-05 | Eastman Kodak Company | Palladium catalyzed addition of amines to 3,4-epoxy-1-butene |
DE4241942A1 (de) * | 1992-12-11 | 1994-06-16 | Basf Ag | Verfahren zur Herstellung von 3,4-Epoxy-1-buten |
US5418202A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
DE4422671A1 (de) | 1994-06-30 | 1996-01-04 | Basf Ag | Verfahren zur Herstellung von 2,5-Dihydrofuran |
DE4424219A1 (de) | 1994-07-09 | 1996-01-11 | Basf Ag | Verfahren zur Herstellung von 2,5-Dihydrofuran |
US5466832A (en) * | 1995-02-13 | 1995-11-14 | Eastman Chemical Company | Process for the manufacture of 2,5-dihydrofurans from γ, δ-epoxybutenes |
US5908942A (en) * | 1995-09-15 | 1999-06-01 | Eastman Chemical Company | Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions |
US5780657A (en) * | 1997-06-23 | 1998-07-14 | Arco Chemical Technology, L.P. | Propylene epoxidation using chloride-containing silver catalysts |
US6562986B2 (en) | 1997-06-30 | 2003-05-13 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
US6323351B1 (en) * | 1997-06-30 | 2001-11-27 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
US5973209A (en) * | 1997-07-11 | 1999-10-26 | The Nutrasweet Company | Method for preparing 3, 3-dimethybutyraldehyde |
US5756779A (en) * | 1997-09-29 | 1998-05-26 | Eastman Chemical Company | Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation effluents |
US6222058B1 (en) | 1998-03-30 | 2001-04-24 | Eastman Chemical Company | Process for the manufacture of cyclopropanecarbonitrile |
US5945550A (en) * | 1998-07-24 | 1999-08-31 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
US6455713B1 (en) | 1998-09-14 | 2002-09-24 | Eastman Chemical Company | Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene |
ES2190280T3 (es) | 1998-12-16 | 2003-07-16 | Dow Global Technologies Inc | Procedimiento para la oxidacion directa de olefinas a oxidos de olefina. |
US6018061A (en) * | 1999-05-05 | 2000-01-25 | Eastman Chemical Company | Process for recovering 3,4-epoxy-1-butene |
US6610878B1 (en) | 1999-05-10 | 2003-08-26 | Eastman Chemical Company | Poly(3-cyclopropyl-3-hydroxypropionate) and processes for its preparation and derivatives thereof |
EP1086743B1 (en) | 1999-09-21 | 2006-08-16 | Nippon Shokubai Co., Ltd. | Catalyst for production of epoxides and methods for production thereof and epoxides |
US6172245B1 (en) | 1999-12-16 | 2001-01-09 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
US7678343B2 (en) | 1999-12-24 | 2010-03-16 | Ineos Vinyls Uk Ltd. | Metallic monolith catalyst support for selective gas phase reactions in tubular fixed bed reactors |
JP3825217B2 (ja) * | 1999-12-28 | 2006-09-27 | 株式会社日本触媒 | 酸化エチレンの製造方法 |
US6270739B1 (en) | 2000-06-16 | 2001-08-07 | Eastman Chemical Company | Process for the removal of carbon dioxide from 3,4-epoxy-1-butene process recycle streams |
US6353140B1 (en) | 2000-10-19 | 2002-03-05 | Eastman Chemical Company | Process for the purification of cyclopropanecarboxaldehyde |
US6388106B1 (en) | 2001-05-24 | 2002-05-14 | Eastman Chemical Company | Selective epoxidation of conjugated diolefins |
US6500970B1 (en) | 2001-07-20 | 2002-12-31 | Eastman Chemical Company | Recovery and purification of 3,4-epoxy-1-butene using high-boiling solvents |
US6596882B2 (en) | 2001-07-20 | 2003-07-22 | Eastman Chemical Company | Recovery and purification of 3,4-epoxy-1-butene using water-miscible solvents |
US6395913B1 (en) | 2001-07-20 | 2002-05-28 | Eastman Chemical Company | Recovery and purification of 3,4-epoxy-1-butene |
US7193094B2 (en) * | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
US6582565B1 (en) | 2002-01-17 | 2003-06-24 | Eastman Chemical Company | Recovery of 3,4-epoxy-1-butene by extractive distillation |
DE60332457D1 (de) | 2002-06-28 | 2010-06-17 | Shell Int Research | Verfahren zur verbesserung der selektivität eines katalysators und verfahren zum epoxidieren eines olefins |
CN100376561C (zh) * | 2002-06-28 | 2008-03-26 | 国际壳牌研究有限公司 | 环氧化方法的开车方法、烯烃环氧化的催化剂和方法 |
CA2494767C (en) | 2002-06-28 | 2012-07-17 | John Robert Lockemeyer | A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin |
DE10231976A1 (de) * | 2002-07-15 | 2004-01-29 | Basf Ag | Strukturierte Katalysator-Schüttung |
DE10300526A1 (de) * | 2003-01-09 | 2004-07-22 | Hte Ag The High Throughput Experimentation Company | Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen |
JP4572551B2 (ja) * | 2003-03-25 | 2010-11-04 | 住友化学株式会社 | 酸化オレフィンの製造法 |
CA2520776C (en) * | 2003-04-01 | 2012-05-08 | Shell Internationale Research Maatschappij B.V. | An olefin epoxidation process and a catalyst for use in the process |
US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
DE502004010465D1 (de) | 2003-08-06 | 2010-01-14 | Basf Se | Verfahren zum betreiben einer kontinuierlichen heterogen katalysierten gasphasen-partialoxidation wenigstens einer organischen verbindung |
JP2005200323A (ja) * | 2004-01-14 | 2005-07-28 | Mitsubishi Chemicals Corp | 3,4−ジアセトキシ−1−ブテン及びそれを用いた誘導体の製造方法 |
DE102004025445A1 (de) | 2004-05-19 | 2005-02-10 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation wenigstens einer organischen Verbindung |
CN101040051B (zh) * | 2004-10-14 | 2012-02-01 | 住友化学株式会社 | 生产2-羟基-4-(甲硫基)丁酸的方法 |
US7439389B2 (en) | 2005-03-01 | 2008-10-21 | Basf Aktiengesellschaft | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
DE102006000996A1 (de) | 2006-01-05 | 2007-07-12 | Basf Ag | Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung |
EP1734030A1 (de) | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
DE102007004961A1 (de) | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist |
DE102007017080A1 (de) | 2007-04-10 | 2008-10-16 | Basf Se | Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres |
CN103599798B (zh) | 2007-05-09 | 2015-11-18 | 国际壳牌研究有限公司 | 环氧化催化剂及其制备方法和生产环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺的方法 |
DE102007028332A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst |
DE102007028333A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors |
DE102008018968A1 (de) | 2008-04-16 | 2009-10-22 | Ticona Gmbh | Polyoxymethylen-Formmassen und Formkörper und deren Verwendung |
KR101629038B1 (ko) | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
CN102056909B (zh) | 2008-05-07 | 2014-03-05 | 国际壳牌研究有限公司 | 环氧化工艺的开车方法及环氧乙烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法 |
US8840976B2 (en) | 2010-10-14 | 2014-09-23 | Ticona Llc | VOC or compressed gas containment device made from a polyoxymethylene polymer |
EP2505609B1 (en) | 2011-04-01 | 2015-01-21 | Ticona GmbH | High impact resistant polyoxymethylene for extrusion blow molding |
JP2013028591A (ja) | 2011-06-21 | 2013-02-07 | Sumitomo Chemical Co Ltd | アミノアルコール化合物の製造方法 |
JP2013028590A (ja) | 2011-06-21 | 2013-02-07 | Sumitomo Chemical Co Ltd | アミノアルコール化合物の製造方法 |
WO2013101624A1 (en) | 2011-12-30 | 2013-07-04 | Ticona Llc | Printable molded articles made from a polyoxymethylene polymer composition |
US9745467B2 (en) | 2012-12-27 | 2017-08-29 | Ticona, Llc | Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light |
CN104888855B (zh) * | 2015-04-03 | 2017-03-01 | 江南大学 | 一种用于烯烃环氧化反应的乙酰丙酮氧钼固体催化剂及其制备方法 |
BR112019011162B1 (pt) | 2016-12-02 | 2022-08-16 | Shell Internationale Research Maatschappij B.V. | Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno |
CN108283943B (zh) * | 2017-01-10 | 2021-07-02 | 中国石油化工股份有限公司 | 氧化铝载体及其制备方法、乙烯环氧化反应用银催化剂及乙烯环氧化制备环氧乙烷的方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA488990A (en) * | 1952-12-23 | J. Carlson George | Process for forming ethylene oxide | |
US2279470A (en) * | 1938-04-12 | 1942-04-14 | Carbide & Carbon Chem Corp | Process of making olefin oxides |
US2404438A (en) * | 1943-09-07 | 1946-07-23 | Shell Dev | Process for the manufacture of olefin oxides |
US2709173A (en) * | 1950-01-09 | 1955-05-24 | California Research Corp | Oxidation of olefins and catalyst therefor |
GB1327497A (en) * | 1972-05-25 | 1973-08-22 | Bp Chem Int Ltd | Propylene oxide |
DE2967112D1 (en) * | 1978-02-10 | 1984-08-23 | Ici Plc | Production of olefine oxides |
DE2936036A1 (de) * | 1979-09-06 | 1981-04-02 | EC Erdölchemie GmbH, 5000 Köln | Verfahren zur herstellung von ethylenoxid |
US4760042A (en) * | 1982-03-24 | 1988-07-26 | Scientific Design Company, Inc. | Process for preparing an alkali metal-promoted silver catalyst |
GB8611121D0 (en) * | 1986-05-07 | 1986-06-11 | Shell Int Research | Silver catalyst |
-
1988
- 1988-12-30 US US07/292,589 patent/US4950773A/en not_active Expired - Lifetime
-
1989
- 1989-01-20 CA CA000588759A patent/CA1338268C/en not_active Expired - Fee Related
- 1989-01-27 WO PCT/US1989/000341 patent/WO1989007101A1/en not_active Application Discontinuation
- 1989-01-27 JP JP1502490A patent/JP2854059B2/ja not_active Expired - Fee Related
- 1989-01-27 KR KR1019890701791A patent/KR960011382B1/ko not_active IP Right Cessation
- 1989-01-27 ES ES89300776T patent/ES2051994T3/es not_active Expired - Lifetime
- 1989-01-27 BR BR898907211A patent/BR8907211A/pt not_active IP Right Cessation
- 1989-01-27 AT AT89300776T patent/ATE102615T1/de not_active IP Right Cessation
- 1989-01-27 EP EP89300776A patent/EP0326392B1/en not_active Expired - Lifetime
- 1989-01-27 EP EP89902677A patent/EP0397793A1/en active Pending
- 1989-01-27 AU AU31825/89A patent/AU618792B2/en not_active Ceased
- 1989-01-27 DE DE68913563T patent/DE68913563T2/de not_active Expired - Fee Related
- 1989-01-28 CN CN89101635A patent/CN1023225C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR960011382B1 (ko) | 1996-08-22 |
AU3182589A (en) | 1989-08-25 |
ATE102615T1 (de) | 1994-03-15 |
WO1989007101A1 (en) | 1989-08-10 |
US4950773A (en) | 1990-08-21 |
CA1338268C (en) | 1996-04-23 |
JPH03502330A (ja) | 1991-05-30 |
CN1036012A (zh) | 1989-10-04 |
BR8907211A (pt) | 1991-03-05 |
EP0397793A1 (en) | 1990-11-22 |
AU618792B2 (en) | 1992-01-09 |
DE68913563D1 (de) | 1994-04-14 |
EP0326392A1 (en) | 1989-08-02 |
EP0326392B1 (en) | 1994-03-09 |
KR900700473A (ko) | 1990-08-13 |
DE68913563T2 (de) | 1994-09-29 |
CN1023225C (zh) | 1993-12-22 |
JP2854059B2 (ja) | 1999-02-03 |
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