DE68913563D1 - Selektive Epoxidation von Olefinen. - Google Patents
Selektive Epoxidation von Olefinen.Info
- Publication number
- DE68913563D1 DE68913563D1 DE89300776T DE68913563T DE68913563D1 DE 68913563 D1 DE68913563 D1 DE 68913563D1 DE 89300776 T DE89300776 T DE 89300776T DE 68913563 T DE68913563 T DE 68913563T DE 68913563 D1 DE68913563 D1 DE 68913563D1
- Authority
- DE
- Germany
- Prior art keywords
- olefins
- selective epoxidation
- epoxidation
- selective
- contacted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/149,297 US4897498A (en) | 1988-01-28 | 1988-01-28 | Selective monoepoxidation of olefins |
US07/292,589 US4950773A (en) | 1988-01-28 | 1988-12-30 | Selective epoxidation of olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
DE68913563D1 true DE68913563D1 (de) | 1994-04-14 |
DE68913563T2 DE68913563T2 (de) | 1994-09-29 |
Family
ID=26846613
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE68913563T Expired - Fee Related DE68913563T2 (de) | 1988-01-28 | 1989-01-27 | Selektive Epoxidation von Olefinen. |
Country Status (12)
Country | Link |
---|---|
US (1) | US4950773A (de) |
EP (2) | EP0397793A1 (de) |
JP (1) | JP2854059B2 (de) |
KR (1) | KR960011382B1 (de) |
CN (1) | CN1023225C (de) |
AT (1) | ATE102615T1 (de) |
AU (1) | AU618792B2 (de) |
BR (1) | BR8907211A (de) |
CA (1) | CA1338268C (de) |
DE (1) | DE68913563T2 (de) |
ES (1) | ES2051994T3 (de) |
WO (1) | WO1989007101A1 (de) |
Families Citing this family (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5145968A (en) * | 1988-11-14 | 1992-09-08 | Eastman Kodak Company | Selective monoepoxidation of styrene, styrene analogs, and styrene derivatives to the corresponding oxide with molecular oxygen |
WO1990011279A1 (en) * | 1989-03-20 | 1990-10-04 | Eastman Kodak Company | Selective epoxidation of bicyclic olefins |
US5138077A (en) * | 1991-07-29 | 1992-08-11 | Eastman Kodak Company | Selective epoxidation of diolefins and aryl olefins |
US5117012A (en) * | 1991-10-07 | 1992-05-26 | Eastman Kodak Company | Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation effluents |
US5155242A (en) * | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
US5326873A (en) * | 1992-06-05 | 1994-07-05 | Eastman Kodak Company | Palladium catalyzed addition of amines to 3,4-epoxy-1-butene |
DE4241942A1 (de) * | 1992-12-11 | 1994-06-16 | Basf Ag | Verfahren zur Herstellung von 3,4-Epoxy-1-buten |
US5418202A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
DE4422671A1 (de) | 1994-06-30 | 1996-01-04 | Basf Ag | Verfahren zur Herstellung von 2,5-Dihydrofuran |
DE4424219A1 (de) | 1994-07-09 | 1996-01-11 | Basf Ag | Verfahren zur Herstellung von 2,5-Dihydrofuran |
US5466832A (en) * | 1995-02-13 | 1995-11-14 | Eastman Chemical Company | Process for the manufacture of 2,5-dihydrofurans from γ, δ-epoxybutenes |
US5908942A (en) * | 1995-09-15 | 1999-06-01 | Eastman Chemical Company | Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions |
US5780657A (en) * | 1997-06-23 | 1998-07-14 | Arco Chemical Technology, L.P. | Propylene epoxidation using chloride-containing silver catalysts |
US6323351B1 (en) * | 1997-06-30 | 2001-11-27 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
US6562986B2 (en) | 1997-06-30 | 2003-05-13 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
US5973209A (en) * | 1997-07-11 | 1999-10-26 | The Nutrasweet Company | Method for preparing 3, 3-dimethybutyraldehyde |
US5756779A (en) * | 1997-09-29 | 1998-05-26 | Eastman Chemical Company | Recovery of 3,4-epoxy-1-butene from 1,3-butadiene oxidation effluents |
US6222058B1 (en) | 1998-03-30 | 2001-04-24 | Eastman Chemical Company | Process for the manufacture of cyclopropanecarbonitrile |
US5945550A (en) * | 1998-07-24 | 1999-08-31 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
US6455713B1 (en) | 1998-09-14 | 2002-09-24 | Eastman Chemical Company | Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene |
CN1172921C (zh) | 1998-12-16 | 2004-10-27 | 陶氏环球技术公司 | 将烯烃直接氧化成烯烃氧化物的方法 |
US6018061A (en) * | 1999-05-05 | 2000-01-25 | Eastman Chemical Company | Process for recovering 3,4-epoxy-1-butene |
US6610878B1 (en) | 1999-05-10 | 2003-08-26 | Eastman Chemical Company | Poly(3-cyclopropyl-3-hydroxypropionate) and processes for its preparation and derivatives thereof |
EP1086743B1 (de) | 1999-09-21 | 2006-08-16 | Nippon Shokubai Co., Ltd. | Katalysator für die Herstellung von Epoxiden und Verfahren für die Bereitung derselben und die Herstellung von Epoxiden |
US6172245B1 (en) | 1999-12-16 | 2001-01-09 | Eastman Chemical Company | Gas phase process for the epoxidation of non-allylic olefins |
US7678343B2 (en) | 1999-12-24 | 2010-03-16 | Ineos Vinyls Uk Ltd. | Metallic monolith catalyst support for selective gas phase reactions in tubular fixed bed reactors |
JP3825217B2 (ja) * | 1999-12-28 | 2006-09-27 | 株式会社日本触媒 | 酸化エチレンの製造方法 |
US6270739B1 (en) | 2000-06-16 | 2001-08-07 | Eastman Chemical Company | Process for the removal of carbon dioxide from 3,4-epoxy-1-butene process recycle streams |
US6353140B1 (en) | 2000-10-19 | 2002-03-05 | Eastman Chemical Company | Process for the purification of cyclopropanecarboxaldehyde |
US6388106B1 (en) * | 2001-05-24 | 2002-05-14 | Eastman Chemical Company | Selective epoxidation of conjugated diolefins |
US6596882B2 (en) | 2001-07-20 | 2003-07-22 | Eastman Chemical Company | Recovery and purification of 3,4-epoxy-1-butene using water-miscible solvents |
US6395913B1 (en) | 2001-07-20 | 2002-05-28 | Eastman Chemical Company | Recovery and purification of 3,4-epoxy-1-butene |
US6500970B1 (en) | 2001-07-20 | 2002-12-31 | Eastman Chemical Company | Recovery and purification of 3,4-epoxy-1-butene using high-boiling solvents |
US7193094B2 (en) * | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
US6582565B1 (en) | 2002-01-17 | 2003-06-24 | Eastman Chemical Company | Recovery of 3,4-epoxy-1-butene by extractive distillation |
CN100512966C (zh) | 2002-06-28 | 2009-07-15 | 国际壳牌研究有限公司 | 提高催化剂选择性的方法和烯烃环氧化方法 |
BRPI0312010B1 (pt) | 2002-06-28 | 2017-11-28 | Shell Internationale Research Maatschappij B.V | Method for detaining an epoxidation process and a process for the epoxidation of an olefine |
AU2003243758A1 (en) * | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin |
DE10231976A1 (de) | 2002-07-15 | 2004-01-29 | Basf Ag | Strukturierte Katalysator-Schüttung |
DE10300526A1 (de) * | 2003-01-09 | 2004-07-22 | Hte Ag The High Throughput Experimentation Company | Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen |
JP4572551B2 (ja) * | 2003-03-25 | 2010-11-04 | 住友化学株式会社 | 酸化オレフィンの製造法 |
EP1613428B1 (de) * | 2003-04-01 | 2007-10-31 | Shell Internationale Research Maatschappij B.V. | Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren |
US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
BRPI0413297B1 (pt) | 2003-08-06 | 2014-01-21 | Processo para operar uma oxidação parcial contínua em fase gasosa catalisada de maneira heterogênea de pelo menos um composto orgânico | |
JP2005200323A (ja) * | 2004-01-14 | 2005-07-28 | Mitsubishi Chemicals Corp | 3,4−ジアセトキシ−1−ブテン及びそれを用いた誘導体の製造方法 |
DE102004025445A1 (de) | 2004-05-19 | 2005-02-10 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation wenigstens einer organischen Verbindung |
CN101040051B (zh) * | 2004-10-14 | 2012-02-01 | 住友化学株式会社 | 生产2-羟基-4-(甲硫基)丁酸的方法 |
US7439389B2 (en) | 2005-03-01 | 2008-10-21 | Basf Aktiengesellschaft | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
DE102006000996A1 (de) | 2006-01-05 | 2007-07-12 | Basf Ag | Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung |
EP1734030A1 (de) | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
DE102007004961A1 (de) | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist |
DE102007017080A1 (de) | 2007-04-10 | 2008-10-16 | Basf Se | Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres |
US10532989B2 (en) | 2007-05-09 | 2020-01-14 | Shell Oil Company | Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
DE102007028333A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors |
DE102007028332A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst |
DE102008018968A1 (de) | 2008-04-16 | 2009-10-22 | Ticona Gmbh | Polyoxymethylen-Formmassen und Formkörper und deren Verwendung |
EP2297124B1 (de) | 2008-05-07 | 2013-08-21 | Shell Internationale Research Maatschappij B.V. | Verfahren zum einleiten eines epoxidierungsverfahrens, verfahren zur herstellung von ethylenoxid, einem 1,2-diol, einem 1,2-diolether, einem 1,2-carbonat oder einem alkanolamin |
CN102066348B (zh) | 2008-05-07 | 2013-09-25 | 国际壳牌研究有限公司 | 环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或链烷醇胺的制备方法 |
US8840976B2 (en) | 2010-10-14 | 2014-09-23 | Ticona Llc | VOC or compressed gas containment device made from a polyoxymethylene polymer |
EP2505609B1 (de) | 2011-04-01 | 2015-01-21 | Ticona GmbH | Polyoxymethylen mit hoher schlagfestigkeit für extrusionsblasformung |
JP2013028591A (ja) | 2011-06-21 | 2013-02-07 | Sumitomo Chemical Co Ltd | アミノアルコール化合物の製造方法 |
JP2013028590A (ja) | 2011-06-21 | 2013-02-07 | Sumitomo Chemical Co Ltd | アミノアルコール化合物の製造方法 |
WO2013101624A1 (en) | 2011-12-30 | 2013-07-04 | Ticona Llc | Printable molded articles made from a polyoxymethylene polymer composition |
US9745467B2 (en) | 2012-12-27 | 2017-08-29 | Ticona, Llc | Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light |
CN104888855B (zh) * | 2015-04-03 | 2017-03-01 | 江南大学 | 一种用于烯烃环氧化反应的乙酰丙酮氧钼固体催化剂及其制备方法 |
TWI774707B (zh) | 2016-12-02 | 2022-08-21 | 荷蘭商蜆殼國際研究所 | 用於調節乙烯環氧化催化劑之方法及用於製造環氧乙烷之相關方法 |
CN108283943B (zh) * | 2017-01-10 | 2021-07-02 | 中国石油化工股份有限公司 | 氧化铝载体及其制备方法、乙烯环氧化反应用银催化剂及乙烯环氧化制备环氧乙烷的方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA488990A (en) * | 1952-12-23 | J. Carlson George | Process for forming ethylene oxide | |
US2279470A (en) * | 1938-04-12 | 1942-04-14 | Carbide & Carbon Chem Corp | Process of making olefin oxides |
US2404438A (en) * | 1943-09-07 | 1946-07-23 | Shell Dev | Process for the manufacture of olefin oxides |
US2709173A (en) * | 1950-01-09 | 1955-05-24 | California Research Corp | Oxidation of olefins and catalyst therefor |
GB1327497A (en) * | 1972-05-25 | 1973-08-22 | Bp Chem Int Ltd | Propylene oxide |
EP0003642B1 (de) * | 1978-02-10 | 1984-07-18 | Imperial Chemical Industries Plc | Herstellung von Olefinoxyden |
DE2936036A1 (de) * | 1979-09-06 | 1981-04-02 | EC Erdölchemie GmbH, 5000 Köln | Verfahren zur herstellung von ethylenoxid |
US4760042A (en) * | 1982-03-24 | 1988-07-26 | Scientific Design Company, Inc. | Process for preparing an alkali metal-promoted silver catalyst |
GB8611121D0 (en) * | 1986-05-07 | 1986-06-11 | Shell Int Research | Silver catalyst |
-
1988
- 1988-12-30 US US07/292,589 patent/US4950773A/en not_active Expired - Lifetime
-
1989
- 1989-01-20 CA CA000588759A patent/CA1338268C/en not_active Expired - Fee Related
- 1989-01-27 DE DE68913563T patent/DE68913563T2/de not_active Expired - Fee Related
- 1989-01-27 ES ES89300776T patent/ES2051994T3/es not_active Expired - Lifetime
- 1989-01-27 WO PCT/US1989/000341 patent/WO1989007101A1/en not_active Application Discontinuation
- 1989-01-27 JP JP1502490A patent/JP2854059B2/ja not_active Expired - Fee Related
- 1989-01-27 AU AU31825/89A patent/AU618792B2/en not_active Ceased
- 1989-01-27 AT AT89300776T patent/ATE102615T1/de not_active IP Right Cessation
- 1989-01-27 EP EP89902677A patent/EP0397793A1/de active Pending
- 1989-01-27 EP EP89300776A patent/EP0326392B1/de not_active Expired - Lifetime
- 1989-01-27 BR BR898907211A patent/BR8907211A/pt not_active IP Right Cessation
- 1989-01-27 KR KR1019890701791A patent/KR960011382B1/ko not_active IP Right Cessation
- 1989-01-28 CN CN89101635A patent/CN1023225C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ATE102615T1 (de) | 1994-03-15 |
EP0397793A1 (de) | 1990-11-22 |
JP2854059B2 (ja) | 1999-02-03 |
EP0326392B1 (de) | 1994-03-09 |
AU3182589A (en) | 1989-08-25 |
AU618792B2 (en) | 1992-01-09 |
CA1338268C (en) | 1996-04-23 |
BR8907211A (pt) | 1991-03-05 |
CN1036012A (zh) | 1989-10-04 |
CN1023225C (zh) | 1993-12-22 |
US4950773A (en) | 1990-08-21 |
EP0326392A1 (de) | 1989-08-02 |
DE68913563T2 (de) | 1994-09-29 |
WO1989007101A1 (en) | 1989-08-10 |
KR900700473A (ko) | 1990-08-13 |
ES2051994T3 (es) | 1994-07-01 |
KR960011382B1 (ko) | 1996-08-22 |
JPH03502330A (ja) | 1991-05-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: EASTMAN CHEMICAL CO., KINGSPORT, TENN., US |
|
8339 | Ceased/non-payment of the annual fee |