DE69217392D1 - Epoxidation mittels thalium-aktivierten silberkatalysatoren - Google Patents

Epoxidation mittels thalium-aktivierten silberkatalysatoren

Info

Publication number
DE69217392D1
DE69217392D1 DE69217392T DE69217392T DE69217392D1 DE 69217392 D1 DE69217392 D1 DE 69217392D1 DE 69217392 T DE69217392 T DE 69217392T DE 69217392 T DE69217392 T DE 69217392T DE 69217392 D1 DE69217392 D1 DE 69217392D1
Authority
DE
Germany
Prior art keywords
epoxidation
thalium
silver catalysts
activated silver
activated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69217392T
Other languages
English (en)
Other versions
DE69217392T2 (de
Inventor
John Monnier
Peter Muehlbauer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Publication of DE69217392D1 publication Critical patent/DE69217392D1/de
Application granted granted Critical
Publication of DE69217392T2 publication Critical patent/DE69217392T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69217392T 1991-07-29 1992-07-23 Epoxidation mittels thalium-aktivierten silberkatalysatoren Expired - Fee Related DE69217392T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/737,287 US5138077A (en) 1991-07-29 1991-07-29 Selective epoxidation of diolefins and aryl olefins
PCT/US1992/006093 WO1993003024A1 (en) 1991-07-29 1992-07-23 Epoxidation using thallium promoted silver catalysts

Publications (2)

Publication Number Publication Date
DE69217392D1 true DE69217392D1 (de) 1997-03-20
DE69217392T2 DE69217392T2 (de) 1997-05-22

Family

ID=24963306

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69217392T Expired - Fee Related DE69217392T2 (de) 1991-07-29 1992-07-23 Epoxidation mittels thalium-aktivierten silberkatalysatoren

Country Status (10)

Country Link
US (1) US5138077A (de)
EP (1) EP0641332B1 (de)
JP (1) JP3210337B2 (de)
KR (1) KR100200315B1 (de)
AT (1) ATE148695T1 (de)
CA (1) CA2114138C (de)
DE (1) DE69217392T2 (de)
ES (1) ES2097344T3 (de)
GR (1) GR3023126T3 (de)
WO (1) WO1993003024A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5362890A (en) * 1993-10-04 1994-11-08 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
US5908942A (en) * 1995-09-15 1999-06-01 Eastman Chemical Company Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions
US5945550A (en) * 1998-07-24 1999-08-31 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
EP1086743B1 (de) * 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Katalysator für die Herstellung von Epoxiden und Verfahren für die Bereitung derselben und die Herstellung von Epoxiden
US6172245B1 (en) 1999-12-16 2001-01-09 Eastman Chemical Company Gas phase process for the epoxidation of non-allylic olefins
US6270739B1 (en) 2000-06-16 2001-08-07 Eastman Chemical Company Process for the removal of carbon dioxide from 3,4-epoxy-1-butene process recycle streams
US6388106B1 (en) 2001-05-24 2002-05-14 Eastman Chemical Company Selective epoxidation of conjugated diolefins
JP4572551B2 (ja) * 2003-03-25 2010-11-04 住友化学株式会社 酸化オレフィンの製造法
FR2880345A1 (fr) * 2004-12-30 2006-07-07 Adisseo Ireland Ltd Synthese et applications de l'acide 2-oxo-4-methylthiobutyrique, ses tels et ses derives

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5136245B2 (de) * 1973-09-07 1976-10-07
JPS5946229B2 (ja) * 1975-08-21 1984-11-10 株式会社日本触媒 酸化エチレンの製造方法
JPS5929293B2 (ja) * 1977-07-01 1984-07-19 株式会社日本触媒 酸化エチレン製造用銀担持触媒の製造方法
US4169099A (en) * 1978-05-25 1979-09-25 Halcon Research And Development Corporation Catalyst and process for producing ethylene oxide
US4267073A (en) * 1978-06-19 1981-05-12 Shell Oil Company Ethylene oxide catalyst
JPS5844021B2 (ja) * 1978-11-01 1983-09-30 東レ株式会社 酸化エチレン製造用触媒組成物
JPS57107240A (en) * 1980-12-26 1982-07-03 Nippon Shokubai Kagaku Kogyo Co Ltd Production of silver catalyst for producing ethylene oxide
AU586048B2 (en) * 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
US4950773A (en) * 1988-01-28 1990-08-21 Eastman Kodak Company Selective epoxidation of olefins
US4897498A (en) * 1988-01-28 1990-01-30 Eastman Kodak Company Selective monoepoxidation of olefins
US5145968A (en) * 1988-11-14 1992-09-08 Eastman Kodak Company Selective monoepoxidation of styrene, styrene analogs, and styrene derivatives to the corresponding oxide with molecular oxygen
CA2045396A1 (en) * 1989-03-20 1990-09-21 John R. Monnier Selective epoxidation of bicyclic olefins
US5112795A (en) * 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same

Also Published As

Publication number Publication date
ATE148695T1 (de) 1997-02-15
JPH07501318A (ja) 1995-02-09
CA2114138A1 (en) 1993-02-18
GR3023126T3 (en) 1997-07-30
ES2097344T3 (es) 1997-04-01
KR100200315B1 (ko) 1999-06-15
EP0641332B1 (de) 1997-02-05
DE69217392T2 (de) 1997-05-22
US5138077A (en) 1992-08-11
EP0641332A1 (de) 1995-03-08
CA2114138C (en) 1997-03-25
JP3210337B2 (ja) 2001-09-17
KR940702492A (ko) 1994-08-20
WO1993003024A1 (en) 1993-02-18

Similar Documents

Publication Publication Date Title
ES2051994T3 (es) Epoxidacion selectiva de olefinas.
DE69004446T2 (de) Katalysator für Olefinpolymerisation.
MX164798B (es) Procedimiento de sintesis directa para organohalohidrosilanos
MY104723A (en) Selective epoxidation of olefins.
ATE223755T1 (de) Herstellung von olefinen
IN192066B (de)
IT1269931B (it) Componenti e catalizzatori per la polimerizzazione di olefine
ES2113374T3 (es) Catalizadores quirales y reacciones de epoxidacion catalizadas por los mismos.
DE69217392T2 (de) Epoxidation mittels thalium-aktivierten silberkatalysatoren
ES2082792T3 (es) Monoepoxidacion selectiva de estireno, analogos de estireno y derivados de estireno para el oxido correspondiente con oxigeno molecular.
ES2094371T3 (es) Recuperacion de 3,4-epoxi-1-buteno a partir de efluentes de oxidacion de 1,3-butadieno.
IT1298337B1 (it) Procedimento per la preparazione di epossidi olefinici.
DE69016559D1 (de) Epoxydierungsverfahren.
IT8322387A0 (it) Procedimento di sintesi di mercaptani a partire da olefine edi idrogeno solfurato, tramite catalisi eterogenea.
DE69311750D1 (de) Heterogener Katalysator für die Herstellung von alternierenden Kohlenmonoxid-Olefin-Copolymeren
DE3465463D1 (en) Process for the valence-isomerisation of olefins
ES8504651A1 (es) Un procedimiento para convertir un hidrocarburo inferior saturado y monosustituido en un hidrocarburo dihalogenado saturado
KR900011694A (ko) 과할로겐화된 에탄 유도체의 선택적 촉매 수소화 반응
NO872191D0 (no) Fremgangsmaate for fremstilling av etere ved anvendelse av lagdelte eller soeyleformede leirekatalysatorer.
ATE32884T1 (de) Herstellung von nitroverbindungen durch dampfphasennitrierung von olefinen.
ES2058906T3 (es) Preparacion de aldehidos.
UA16082A1 (uk) Каталізатор для окислеhhя метаhолу в метилформіат і спосіб його одержаhhя
SU1329601A1 (ru) Способ получения каталитического комплекса для алкилирования бензола этиленом

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee