ES2157930T3 - Copolimeros de 1-buteno/propileno amorfos de alta resistencia a la traccion. - Google Patents
Copolimeros de 1-buteno/propileno amorfos de alta resistencia a la traccion.Info
- Publication number
- ES2157930T3 ES2157930T3 ES93922144T ES93922144T ES2157930T3 ES 2157930 T3 ES2157930 T3 ES 2157930T3 ES 93922144 T ES93922144 T ES 93922144T ES 93922144 T ES93922144 T ES 93922144T ES 2157930 T3 ES2157930 T3 ES 2157930T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- molar ratio
- propylene
- alkyl
- butene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
Abstract
UN PROCESO PARA LA PRODUCCION DE COPOLIMEROS DE PROPILENO/1-BUTENO QUE COMPRENDE: HACER REACCIONAR PROPILENO Y MONOMEROS 1-BUTENO EN PRESENCIA DE UN SISTEMA CATALIZADOR QUE COMPRENDE: (A) UN COMPONENTE CATALIZADOR SOPORTADO EN SOLIDO QUE SE PREPARA POR EL METODO QUE COMPRENDE: (I) CO-TRITURAR BASE DE SOPORTE DE HALURO DE MAGNESIO Y TRIHALURO DE ALUMINIO EN UNA PROPORCION MOLAR DE 8:0,5 DE 8:3 EN AUSENCIA DE DONANTE DE ELECTRONES AÑADIDOS; Y (II) CO-TRITURAR ENTONCES EL PRODUCTO DEL PASO (I) EN AUSENCIA DE DONANTE DE ELECTRONES AÑADIDOS CON SUFICIENTE TETRAHALURO DE TITANIO PARA PROPORCIONAR UNA RELACION MOLAR DE HALURO DE MAGNESIO RESPECTO A TETRAHALURO DE TITANIO DE 8:0,1 A 8:10; (B) UN COCATALIZADOR DE TRIALQUILALUMINIO, QUE TIENE DE 1 A 9 ATOMOS DE CARBONO EN CADA GRUPO ALQUILO EN UNA CANTIDAD TAL QUE LA RELACION AL/TI ESTA ENTRE 50:1 Y 500:1; (C) UN COMPONENTE ALCOXI SILANO DE LA FORMULA RNSI(OR'')4-N DONDE N = 1-3, R = ARILO O ALQUILO Y R'' = ALQUILO C1-3 EN UNA CANTIDAD SUFICIENTE TAL QUE LA RELACION MOLAR DE CO-CATALIZADOR DE ORGANOALUMINIO RESPECTO A ALCOXI SILANO ESTA EN EL MARGEN DE 20:1 A 45:1. ESTANDO CARACTERIZADO DICHO COPOLIMERO POR UN CONTENIDO DE PROPILENO DE 25 A 50 % DE PESO, UN CONTENIDO 1-BUTENO DE 50 A 75 % DE PESO Y UNA RESISTENCIA A LA TENSION DE AL MENOS 300 PSIG.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/941,916 US5302675A (en) | 1992-09-08 | 1992-09-08 | High tensile strength amorphous 1-butene/propylene copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2157930T3 true ES2157930T3 (es) | 2001-09-01 |
Family
ID=25477292
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES93922144T Expired - Lifetime ES2157930T3 (es) | 1992-09-08 | 1993-09-08 | Copolimeros de 1-buteno/propileno amorfos de alta resistencia a la traccion. |
Country Status (10)
Country | Link |
---|---|
US (1) | US5302675A (es) |
EP (1) | EP0660847B1 (es) |
JP (2) | JP3513518B2 (es) |
KR (1) | KR950703010A (es) |
AT (1) | ATE201702T1 (es) |
AU (1) | AU664318B2 (es) |
DE (1) | DE69330279T2 (es) |
ES (1) | ES2157930T3 (es) |
FI (1) | FI111375B (es) |
WO (1) | WO1994005711A1 (es) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5714554A (en) * | 1992-09-08 | 1998-02-03 | Rexene Corporation | High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers |
US5693729A (en) * | 1993-08-27 | 1997-12-02 | Showa Denko K.K. | Catalyst for polymerization of olefin and process for the preparation of olefin polymer |
US5880241A (en) * | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
KR100607538B1 (ko) * | 1999-04-20 | 2006-08-02 | 삼성토탈 주식회사 | 열접착성 필름용 프로필렌-에틸렌-부텐-1 공중합체 및 이를 포함하는 수지조성물 |
US8178636B2 (en) * | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
US20060089617A1 (en) * | 2004-10-21 | 2006-04-27 | Adherent Laboratories, Inc. | Disposable article tab attachment adhesive |
US8048054B2 (en) * | 2004-10-21 | 2011-11-01 | Adherent Laboratories, Inc. | Disposable article tab attachment adhesive |
BR112013004339B1 (pt) * | 2010-08-26 | 2020-03-10 | Henkel IP & Holding GmbH | Adesivo fundido a quente de poli-alfa-olefina amorfa e artigo compreendendo o mesmo |
US9469791B2 (en) | 2011-04-28 | 2016-10-18 | Adherent Laboratories, Inc. | Polyolefin based hot melt adhesive composition |
BR112013033142A2 (pt) | 2011-06-27 | 2017-01-24 | Fuller H B Co | polímeros de propileno alfa-olefina, composições adesivas termofundidas que incluem polímeros de propileno-alfa-olefina e artigos que incluem os mesmos |
WO2013003197A1 (en) | 2011-06-27 | 2013-01-03 | H.B. Fuller Company | Free radical initiator modified hot melt adhesive composition including functionalized polyethylene and propylene-alpha-olefin polymer |
US8865824B2 (en) | 2012-09-19 | 2014-10-21 | IFS Industries Inc. | Hot melt adhesive |
US9241843B2 (en) | 2012-09-19 | 2016-01-26 | The Procter & Gamble Company | Article with tackifier-free adhesive |
US9593235B2 (en) | 2013-02-15 | 2017-03-14 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
US9267060B2 (en) | 2013-02-15 | 2016-02-23 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
US10639210B2 (en) | 2013-12-19 | 2020-05-05 | The Procter & Gamble Company | Article with tackifier-free adhesive |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US9382351B2 (en) | 2014-02-07 | 2016-07-05 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
CN103951898B (zh) * | 2014-04-12 | 2016-02-17 | 青岛科技大学 | 聚1-丁烯/1-丁烯-丙烯共聚物釜内合金及其制备方法 |
US10160888B2 (en) | 2015-09-30 | 2018-12-25 | RexTac LLC. | Propylene-based amorphous poly-alpha-olefins (APAOs) formulated with hexene-1 monomer containing amorphous poly-alpha-olefins for use in hot melt adhesives |
US20170292047A1 (en) | 2016-04-12 | 2017-10-12 | Rextac Llc | Hexene-1 Containing Amorphous Polyalphaolefins For Improved Hot Melt Adhesives |
US10752815B2 (en) | 2016-04-12 | 2020-08-25 | Rextac Llc | Low molecular weight butene-1-co-hexene-1 amorphous poly alpha olefins for hot-melt adhesives with enhanced properties |
KR101924121B1 (ko) | 2016-11-28 | 2019-02-22 | 주식회사 일렘테크놀러지 | 저온-고신율 특성을 가지는 1-부텐계 공중합체 및 이의 제조방법 |
US11021636B2 (en) | 2018-04-20 | 2021-06-01 | The Procter & Gamble Company | Adhesive composition for absorbent articles |
WO2019204545A1 (en) | 2018-04-20 | 2019-10-24 | The Procter & Gamble Company | Absorbent article comprising an adhesive composition |
JP2021518869A (ja) | 2018-04-20 | 2021-08-05 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 吸収性物品用接着剤組成物 |
CN112041408A (zh) * | 2018-04-20 | 2020-12-04 | 宝洁公司 | 用于吸收制品的粘合剂组合物 |
EP3781105A1 (en) | 2018-04-20 | 2021-02-24 | The Procter & Gamble Company | Absorbent article comprising an adhesive composition |
US11707548B2 (en) | 2018-10-09 | 2023-07-25 | The Procter & Gamble Company | Absorbent article comprising a lotion resistant polymeric filler composition |
EP3892246A1 (en) | 2020-04-08 | 2021-10-13 | The Procter & Gamble Company | Method for applying a polymeric composition and absorbent articles comprising such composition |
CN115322275A (zh) * | 2022-03-07 | 2022-11-11 | 陕西延长中煤榆林能源化工有限公司 | 一种丙烯/1-丁烯共聚聚丙烯树脂的工业化生产方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3923758A (en) * | 1973-07-02 | 1975-12-02 | Eastman Kodak Co | Substantially hexane soluble propylene/butene-1 copolymer containing 30 to 75 weight percent butene-1 |
JPS5379984A (en) * | 1976-12-24 | 1978-07-14 | Mitsui Petrochem Ind Ltd | Copolymer and production |
US4347158A (en) * | 1980-05-02 | 1982-08-31 | Dart Industries, Inc. | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4451688A (en) * | 1981-12-03 | 1984-05-29 | Nippon Oil Company, Limited | Process for preparing polyolefins |
JPS6038414A (ja) * | 1983-08-12 | 1985-02-28 | Mitsui Petrochem Ind Ltd | 熱可塑性樹脂共重合体 |
US4847340A (en) * | 1986-06-30 | 1989-07-11 | Rexene Products Company | Novel propylene polymerization process |
US4736002A (en) * | 1986-06-30 | 1988-04-05 | El Paso Products Company | Novel propylene polymerization process |
US4859757A (en) * | 1986-06-30 | 1989-08-22 | Rexene Products Company | Novel propylene polymers |
CA1308857C (en) * | 1988-03-30 | 1992-10-13 | Brian J. Pellon | Propylene copolymerization process |
JP2854886B2 (ja) * | 1989-08-10 | 1999-02-10 | 三井化学株式会社 | プロピレンとブテンの共重合体 |
-
1992
- 1992-09-08 US US07/941,916 patent/US5302675A/en not_active Expired - Lifetime
-
1993
- 1993-09-08 DE DE69330279T patent/DE69330279T2/de not_active Expired - Lifetime
- 1993-09-08 ES ES93922144T patent/ES2157930T3/es not_active Expired - Lifetime
- 1993-09-08 KR KR1019950700896A patent/KR950703010A/ko active IP Right Grant
- 1993-09-08 AU AU51251/93A patent/AU664318B2/en not_active Ceased
- 1993-09-08 WO PCT/US1993/008222 patent/WO1994005711A1/en active IP Right Grant
- 1993-09-08 AT AT93922144T patent/ATE201702T1/de active
- 1993-09-08 JP JP50741094A patent/JP3513518B2/ja not_active Expired - Fee Related
- 1993-09-08 EP EP93922144A patent/EP0660847B1/en not_active Expired - Lifetime
-
1995
- 1995-03-07 FI FI951042A patent/FI111375B/fi not_active IP Right Cessation
-
2003
- 2003-07-11 JP JP2003273493A patent/JP3640024B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5302675A (en) | 1994-04-12 |
JP3640024B2 (ja) | 2005-04-20 |
FI951042A0 (fi) | 1995-03-07 |
KR950703010A (ko) | 1995-08-23 |
AU5125193A (en) | 1994-03-29 |
EP0660847A4 (en) | 1995-05-09 |
JPH08501337A (ja) | 1996-02-13 |
DE69330279D1 (de) | 2001-07-05 |
ATE201702T1 (de) | 2001-06-15 |
FI951042A (fi) | 1995-03-07 |
WO1994005711A1 (en) | 1994-03-17 |
JP2004002882A (ja) | 2004-01-08 |
JP3513518B2 (ja) | 2004-03-31 |
DE69330279T2 (de) | 2001-10-31 |
AU664318B2 (en) | 1995-11-09 |
EP0660847A1 (en) | 1995-07-05 |
EP0660847B1 (en) | 2001-05-30 |
FI111375B (fi) | 2003-07-15 |
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Legal Events
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FG2A | Definitive protection |
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