ES2148667T3 - Procedimiento para la carbonilacion de butadieno o un derivado de butadieno. - Google Patents
Procedimiento para la carbonilacion de butadieno o un derivado de butadieno.Info
- Publication number
- ES2148667T3 ES2148667T3 ES96200391T ES96200391T ES2148667T3 ES 2148667 T3 ES2148667 T3 ES 2148667T3 ES 96200391 T ES96200391 T ES 96200391T ES 96200391 T ES96200391 T ES 96200391T ES 2148667 T3 ES2148667 T3 ES 2148667T3
- Authority
- ES
- Spain
- Prior art keywords
- butadien
- derivative
- carbonilation
- procedure
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title abstract 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
SE DESCRIBE UN PROCEDIMIENTO PARA LA CARBONILACION DE BUTADIENO O DE UN DERIVADO DE BUTADIENO EN PRESENCIA DE MONOXIDO DE CARBONO Y DE UN ALCOHOL O AGUA Y UN SISTEMA CATALIZADOR QUE CONTIENE PALADIO, UN ACIDO CARBOXILICO Y UN LIGANDO DE FOSFINA MONODENTADO, EN DONDE LAS CANTIDADES DE REACTIVOS DURANTE EL PROCEDIMIENTO DE CARBONILACION SON TALES QUE LA RELACION MOLAR DE BUTADIENO O DE DERIVADO DE BUTADIENO RESPECTO AL PALADIO DE LA MEZCLA DE REACCION SEA INFERIOR A 70:1, LA RELACION MOLAR DE ACIDO CARBOXILICO A PALADIO SEA MAYOR DE 10:1 Y LA RELACION MOLAR DE ALCOHOL O AGUA A BUTADIENO O DERIVADO DE BUTADIENO SEA INFERIOR A 2:1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39331395A | 1995-02-22 | 1995-02-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2148667T3 true ES2148667T3 (es) | 2000-10-16 |
Family
ID=23554187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96200391T Expired - Lifetime ES2148667T3 (es) | 1995-02-22 | 1996-02-16 | Procedimiento para la carbonilacion de butadieno o un derivado de butadieno. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5672732A (es) |
| EP (1) | EP0728732B1 (es) |
| JP (1) | JPH08245510A (es) |
| KR (1) | KR960031420A (es) |
| CN (1) | CN1070169C (es) |
| CA (1) | CA2169892A1 (es) |
| DE (1) | DE69608587T2 (es) |
| ES (1) | ES2148667T3 (es) |
| SG (1) | SG44551A1 (es) |
| TW (1) | TW336223B (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5886236A (en) * | 1997-04-15 | 1999-03-23 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing aldehyde acid salts |
| US5962680A (en) * | 1997-04-15 | 1999-10-05 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for producing epsilon caprolactams |
| US5925754A (en) * | 1997-04-15 | 1999-07-20 | Union Carbide Chemicals & Plastics Technology Corporation | Epsilon caprolactam compositions |
| US5962732A (en) * | 1998-12-17 | 1999-10-05 | E. I. Du Pont De Nemours And Company | Process for the preparation of 3-pentenoic acid from butadiene using a nickel catalyst |
| TW524801B (en) * | 1999-03-22 | 2003-03-21 | Shell Int Research | Process for the carbonylation of conjugated dienes |
| EP1118607A1 (en) * | 2000-01-19 | 2001-07-25 | Dsm N.V. | Process for the carbonylation of butadiene and/or at least one butadiene derivative |
| EP1223155A1 (en) * | 2001-01-15 | 2002-07-17 | Dsm N.V. | Process for the preparation of a caprolactam precursor from butadiene |
| EP2922813B1 (en) | 2012-11-23 | 2016-10-12 | Firmenich SA | Hydrocarbonylation or methoxycarbonylation of 1,3-diene derivatives with palladium complex |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4124617A (en) * | 1977-06-28 | 1978-11-07 | Texaco Development Corporation | Process for preparing unsaturated aliphatic esters from aliphatic dienes |
| US4172087A (en) * | 1978-02-13 | 1979-10-23 | Texaco Development Corporation | Process for preparing unsaturated aliphatic esters from aliphatic dienes |
| GB8432376D0 (en) * | 1984-12-21 | 1985-02-06 | Shell Int Research | Carbonylation of acetylenically unsaturated compounds |
| GB8501919D0 (en) * | 1985-01-25 | 1985-02-27 | Shell Int Research | Carbonylation of allenically unsaturated compounds |
| KR880007427A (ko) * | 1986-12-05 | 1988-08-27 | 오노 알버어스 | 공역 디엔의 카르보닐화 방법 및 이를 위한 촉매 시스템 |
| KR880007418A (ko) * | 1986-12-10 | 1988-08-27 | 오노 알버어스 | 공역 디엔의 선택적 카르보닐화 방법 및 이를 위한 유기 질소-함유 열기를 갖지 않는 촉매 시스템 |
| GB8711524D0 (en) * | 1987-05-15 | 1987-06-17 | Shell Int Research | Carboxylic acids |
| US5103043A (en) * | 1989-03-03 | 1992-04-07 | Shell Oil Company | Carbonylation catalyst system |
| KR0148012B1 (ko) * | 1989-03-03 | 1998-08-17 | 오노 알버어스 | 신규한 포스핀으로 구성되는 촉매시스템 및 이를 이용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화방법 |
| US5026901A (en) * | 1990-03-29 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Palladium catalyzed carboalkoxylation of butadiene |
| GB9026211D0 (en) * | 1990-12-03 | 1991-01-16 | Shell Int Research | Carbonylation process |
| EP0577205B1 (en) * | 1992-06-29 | 1997-10-08 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of conjugated dienes |
| US5292944A (en) * | 1993-06-29 | 1994-03-08 | E. I. Du Pont De Nemours And Company | Process for the preparation of adipic acid or pentenoic acid |
-
1996
- 1996-02-12 KR KR1019960003273A patent/KR960031420A/ko not_active Withdrawn
- 1996-02-16 DE DE69608587T patent/DE69608587T2/de not_active Expired - Fee Related
- 1996-02-16 EP EP96200391A patent/EP0728732B1/en not_active Expired - Lifetime
- 1996-02-16 SG SG1996002086A patent/SG44551A1/en unknown
- 1996-02-16 ES ES96200391T patent/ES2148667T3/es not_active Expired - Lifetime
- 1996-02-17 TW TW085102037A patent/TW336223B/zh active
- 1996-02-17 CN CN96105591A patent/CN1070169C/zh not_active Expired - Fee Related
- 1996-02-20 CA CA002169892A patent/CA2169892A1/en not_active Abandoned
- 1996-02-22 JP JP8035015A patent/JPH08245510A/ja active Pending
- 1996-02-22 US US08/605,590 patent/US5672732A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR960031420A (ko) | 1996-09-17 |
| DE69608587D1 (de) | 2000-07-06 |
| US5672732A (en) | 1997-09-30 |
| EP0728732A1 (en) | 1996-08-28 |
| CA2169892A1 (en) | 1996-08-23 |
| DE69608587T2 (de) | 2001-02-15 |
| SG44551A1 (en) | 1999-06-22 |
| TW336223B (en) | 1998-07-11 |
| CN1070169C (zh) | 2001-08-29 |
| EP0728732B1 (en) | 2000-05-31 |
| JPH08245510A (ja) | 1996-09-24 |
| CN1138021A (zh) | 1996-12-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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