ES2147742T3 - Utilizacion de la energia del gas quemado para vaporizar agente reductor acuoso para la reduccion del nox en el gas quemado. - Google Patents
Utilizacion de la energia del gas quemado para vaporizar agente reductor acuoso para la reduccion del nox en el gas quemado.Info
- Publication number
- ES2147742T3 ES2147742T3 ES93305391T ES93305391T ES2147742T3 ES 2147742 T3 ES2147742 T3 ES 2147742T3 ES 93305391 T ES93305391 T ES 93305391T ES 93305391 T ES93305391 T ES 93305391T ES 2147742 T3 ES2147742 T3 ES 2147742T3
- Authority
- ES
- Spain
- Prior art keywords
- burned gas
- nox
- combustion gas
- reduction
- energy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/30—Controlling by gas-analysis apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8631—Processes characterised by a specific device
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Chimneys And Flues (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
UN METODO PARA VAPORIZAR UN AGENTE DE REDUCCION ACUOSA PARA REDUCIR NOX EN GAS DE COMBUSTION EN UN SISTEMA DE COMBUSTION. UN INTERCAMBIADOR DE CALOR ESTA DISPUESTO EN LA TRAYECTORIA DE GAS DE COMBUSTION DE MANERA QUE EL CALOR DEL GAS DE COMBUSTION CALIENTE UN MEDIO DE TRANSFERENCIA DE CALOR, PREFERENTEMENTE AIRE AMBIENTE. EL AIRE CALENTADO PASA A UN RECIPIENTE VAPORIZADOR DONDE SE VAPORIZA UN AGENTE DE REDUCCION ACUOSA, PREFERENTEMENTE AMONIACO ACUOSO. EL AMONIACO VAPORIZADO ES INYECTADO DENTRO DE LA TRAYECTORIA DE GAS DE COMBUSTION DONDE ES EFECTIVO PARA REDUCIR NOX. SE PRESENTAN TAMBIEN ALGUNOS ASPECTOS DE UN SISTEMA DE CONTROL AUTOMATICO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/923,718 US5296206A (en) | 1992-07-31 | 1992-07-31 | Using flue gas energy to vaporize aqueous reducing agent for reduction of NOx in flue gas |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2147742T3 true ES2147742T3 (es) | 2000-10-01 |
Family
ID=25449160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES93305391T Expired - Lifetime ES2147742T3 (es) | 1992-07-31 | 1993-07-09 | Utilizacion de la energia del gas quemado para vaporizar agente reductor acuoso para la reduccion del nox en el gas quemado. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5296206A (es) |
EP (1) | EP0583878B1 (es) |
JP (1) | JPH084712B2 (es) |
KR (1) | KR100259104B1 (es) |
CN (1) | CN1036247C (es) |
CA (1) | CA2099521C (es) |
ES (1) | ES2147742T3 (es) |
MX (1) | MX9304556A (es) |
PT (1) | PT583878E (es) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4301760A1 (de) * | 1993-01-23 | 1994-08-11 | Rothemuehle Brandt Kritzler | Verfahren und Vorrichtung für einen Regenerativ-Wärmetauscher zur Behandlung schadstoffhaltiger Abgase |
JPH0796141A (ja) * | 1993-09-30 | 1995-04-11 | Hitachi Zosen Corp | 脱硝装置におけるアンモニア供給方法 |
US5738024A (en) * | 1996-04-19 | 1998-04-14 | Winegar; Phillip | Catalytic reduction apparatus for NOX reduction |
DE19719998C2 (de) | 1997-05-13 | 2003-10-30 | Daimler Chrysler Ag | Verfahren und Vorrichtung zur Stickoxidreduktion im Abgas einer Verbrennungseinrichtung |
DE19750138A1 (de) * | 1997-11-12 | 1999-05-27 | Siemens Ag | Einrichtung zum Einbringen eines flüssigen Reduktionsmittels in eine Abgas-Reinigungsanlage |
WO1999058230A1 (de) * | 1998-05-11 | 1999-11-18 | Siemens Aktiengesellschaft | Verfahren und vorrichtung zur selektiven katalytischen reduktion von stickoxiden in einem sauerstoffhaltigen gasförmigen medium |
US6273120B1 (en) | 1998-11-12 | 2001-08-14 | Siemens Aktiengesellschaft | Device for introducing a liquid reducing agent into an exhaust gas purification system |
US5943865A (en) * | 1998-12-03 | 1999-08-31 | Cohen; Mitchell B. | Reheating flue gas for selective catalytic systems |
US6315969B1 (en) | 2000-02-18 | 2001-11-13 | Mitsubishi Heavy Industries America, Inc. | Gas re-circulation selective catalytic reduction system with heat trace |
US20020044886A1 (en) * | 2000-10-16 | 2002-04-18 | William Larco | Vaporization system having blower positioned in reduced temperature zone |
EP1339479B1 (en) * | 2000-12-01 | 2007-03-07 | Fuel Tech, Inc. | SELECTIVE CATALYTIC REDUCTION OF NOx, ENABLED BY SIDE STREAM UREA DECOMPOSITION |
WO2002062704A2 (en) * | 2001-02-08 | 2002-08-15 | The Chemithon Corporation | Method for quantitative production of gaseous ammonia |
US6706246B2 (en) | 2001-02-26 | 2004-03-16 | Abb Lummus Global Inc. | System and method for the selective catalytic reduction of nitrogen oxide in a gas stream |
US6960329B2 (en) | 2002-03-12 | 2005-11-01 | Foster Wheeler Energy Corporation | Method and apparatus for removing mercury species from hot flue gas |
AU2003299644A1 (en) * | 2002-12-17 | 2004-07-22 | Clean Diesel Technologies, Inc. | Nox control for ic engines |
US20040197251A1 (en) * | 2003-04-07 | 2004-10-07 | Glex, Inc. | Vaporization having fast start up |
US7069715B1 (en) * | 2003-10-07 | 2006-07-04 | Express Integrated Technologies Llc | Method and apparatus for the pre-heating of vaporization chamber |
US20090004083A1 (en) * | 2003-12-17 | 2009-01-01 | Valentine James M | NOx control for IC engines |
US7588440B2 (en) * | 2005-04-13 | 2009-09-15 | Babcock & Wilcox Power Generation Group, Inc. | Carrier air heating system for SCR |
DE102006023147A1 (de) * | 2006-05-16 | 2008-01-10 | Emitec Gesellschaft Für Emissionstechnologie Mbh | Verfahren und Vorrichtung zum Bereitstellen eines gasförmigen Stoffgemisches |
US8899020B2 (en) | 2006-08-21 | 2014-12-02 | Southwest Research Institute | Apparatus and method for assisting selective catalytic reduction |
US8047145B2 (en) * | 2007-02-20 | 2011-11-01 | Hitachi Power Systems America, Ltd | Ammonia vaporization system using non-flue gas intermediate heat transfer medium |
US7985280B2 (en) * | 2007-02-20 | 2011-07-26 | Hitachi Power Systems America, Ltd. | Separation of aqueous ammonia components for NOx reduction |
US7874140B2 (en) * | 2007-06-08 | 2011-01-25 | Foster Wheeler North America Corp. | Method of and power plant for generating power by oxyfuel combustion |
US8145044B1 (en) | 2008-06-11 | 2012-03-27 | Honeywell International Inc. | Air ammonia heater and vaporization chamber system |
US7638107B1 (en) | 2008-06-11 | 2009-12-29 | Callidus Technologies, LLC | Multi-bed selective catalytic reduction system |
US20100175366A1 (en) * | 2009-01-09 | 2010-07-15 | General Electric Company | Ammonia injection system for peaker cycle |
CN101890279B (zh) * | 2010-03-10 | 2013-03-13 | 张作保 | 一种高效氨法脱硝工艺及其装置 |
US20120012298A1 (en) * | 2010-07-18 | 2012-01-19 | Taylor Scott A | Method and Appratus for Heating an Aqueous Mixture to Vaporization |
US8361422B2 (en) * | 2010-08-19 | 2013-01-29 | Dow Global Technologies Llc | Method and devices for heating urea-containing materials in vehicle emission control system |
JP2014500942A (ja) | 2010-11-12 | 2014-01-16 | キャボット コーポレイション | 排ガスの焼却におけるNOx排出を低減する方法および装置 |
US8591849B2 (en) | 2012-04-16 | 2013-11-26 | Combustion Components Associates, Inc. | On demand generation of ammonia for small industrial and commercial boilers |
US8815197B2 (en) | 2012-10-05 | 2014-08-26 | Peerless Mfg. Co. | Method for urea decomposition and ammonia feed to a selective catalytic reduction system |
US9593609B2 (en) | 2012-10-05 | 2017-03-14 | Peerless Mfg. Co. | System and method for urea decomposition to ammonia in a side stream for selective catalytic reduction |
US9746177B2 (en) | 2012-11-12 | 2017-08-29 | Peerless Mfg. Co. | Urea decomposition and improved SCR NOx reduction on industrial and small utility boilers |
KR102115054B1 (ko) * | 2015-06-16 | 2020-05-26 | 현대중공업파워시스템 주식회사 | 복합 화력발전 시스템 |
US20170356319A1 (en) * | 2016-06-09 | 2017-12-14 | General Electric Company | Exhaust Gas Heat Exchange for Ammonia Evaporation Using a Heat Pipe |
KR102362761B1 (ko) * | 2017-11-22 | 2022-02-15 | 씨에스케이(주) | 가스 처리 장치 |
US11255242B2 (en) | 2018-02-27 | 2022-02-22 | Exxonmobil Chemical Patents Inc. | System and process for delivering controlled quantities of ammonia to ammonia-consuming devices |
CN109012152A (zh) * | 2018-07-30 | 2018-12-18 | 芜湖凯奥尔环保科技有限公司 | 一种脱硝废水废气净化系统 |
CN109464892A (zh) * | 2018-12-28 | 2019-03-15 | 启明星宇节能科技股份有限公司 | 脱硝自动化控制系统 |
CN111558286A (zh) * | 2020-05-12 | 2020-08-21 | 江苏峰峰鸿运环保科技发展有限公司 | 一种sncr-scr联合脱硝方法及装置 |
US11906248B2 (en) * | 2021-07-13 | 2024-02-20 | Pts Power Inc. | Exhaust gas path heat energy utilization system and method |
JP2023016065A (ja) * | 2021-07-21 | 2023-02-02 | 三菱重工業株式会社 | アンモニア燃料供給ユニット、発電プラント、及びボイラの運転方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3897539A (en) * | 1971-10-31 | 1975-07-29 | Inst Gas Technology | Tail gas nitrogen oxide abatement process |
US3900554A (en) * | 1973-03-16 | 1975-08-19 | Exxon Research Engineering Co | Method for the reduction of the concentration of no in combustion effluents using ammonia |
JPS5499771A (en) * | 1978-01-24 | 1979-08-06 | Mitsubishi Heavy Ind Ltd | Controlling method for ammonia injection at dry process exhaust gas dieitration method |
EP0278241B1 (de) * | 1987-02-11 | 1992-07-08 | Deutsche Babcock Anlagen Gmbh | Verfahren zum Einmischen von Ammoniak in einen Rauchgasstrom |
DE3739162A1 (de) * | 1987-11-19 | 1989-06-01 | Krupp Koppers Gmbh | Verfahren zum entfernen von sauren komponenten und stickoxiden aus den abgasen industrieller feuerungsanlagen |
JPH0286813A (ja) * | 1988-09-22 | 1990-03-27 | Mitsubishi Heavy Ind Ltd | 排煙脱硝装置 |
US5047220A (en) * | 1989-03-27 | 1991-09-10 | Foster Wheeler Energy Corporation | Catalytic denitrification control process and system for combustion flue gases |
JPH0386212A (ja) * | 1989-08-30 | 1991-04-11 | Mitsubishi Heavy Ind Ltd | 排ガスの脱硝方法 |
US5024171A (en) * | 1990-03-19 | 1991-06-18 | Wahlco, Inc. | Reduction of acidic emissions from combustion of sulfur-laden fuels |
DE4010566A1 (de) * | 1990-04-02 | 1991-10-10 | Krc Umwelttechnik Gmbh | Verfahren zur abscheidung von kohlenstoffhaltigen und/oder stickoxidhaltigen schadstoffen in rauchgasen |
US5020457A (en) * | 1990-06-22 | 1991-06-04 | The United States Of America As Represented By The United States Department Of Energy | Destruction of acid gas emissions |
US5098680A (en) * | 1990-10-15 | 1992-03-24 | Exxon Research & Engineering Company | Aqueous ammonia injection scheme |
JP3100191B2 (ja) * | 1991-09-02 | 2000-10-16 | 三菱重工業株式会社 | 排煙脱硝装置 |
US5237939A (en) * | 1992-08-20 | 1993-08-24 | Wahlco Environmental Systems, Inc. | Method and apparatus for reducing NOx emissions |
-
1992
- 1992-07-31 US US07/923,718 patent/US5296206A/en not_active Expired - Lifetime
-
1993
- 1993-07-02 CA CA002099521A patent/CA2099521C/en not_active Expired - Lifetime
- 1993-07-09 ES ES93305391T patent/ES2147742T3/es not_active Expired - Lifetime
- 1993-07-09 EP EP93305391A patent/EP0583878B1/en not_active Expired - Lifetime
- 1993-07-09 PT PT93305391T patent/PT583878E/pt unknown
- 1993-07-19 KR KR1019930013527A patent/KR100259104B1/ko not_active IP Right Cessation
- 1993-07-27 JP JP5185168A patent/JPH084712B2/ja not_active Expired - Lifetime
- 1993-07-28 MX MX9304556A patent/MX9304556A/es not_active IP Right Cessation
- 1993-07-30 CN CN93109100A patent/CN1036247C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH06154552A (ja) | 1994-06-03 |
CN1036247C (zh) | 1997-10-29 |
KR100259104B1 (ko) | 2000-06-15 |
US5296206A (en) | 1994-03-22 |
CN1083740A (zh) | 1994-03-16 |
PT583878E (pt) | 2000-08-31 |
CA2099521C (en) | 2004-03-30 |
EP0583878B1 (en) | 2000-05-03 |
CA2099521A1 (en) | 1994-02-01 |
MX9304556A (es) | 1994-02-28 |
EP0583878A1 (en) | 1994-02-23 |
JPH084712B2 (ja) | 1996-01-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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