MX9304556A - Metodo para evaporar un agente reductor acuoso, para reducir el nox en los gases de combustion, en un sistema de combustion. - Google Patents
Metodo para evaporar un agente reductor acuoso, para reducir el nox en los gases de combustion, en un sistema de combustion.Info
- Publication number
- MX9304556A MX9304556A MX9304556A MX9304556A MX9304556A MX 9304556 A MX9304556 A MX 9304556A MX 9304556 A MX9304556 A MX 9304556A MX 9304556 A MX9304556 A MX 9304556A MX 9304556 A MX9304556 A MX 9304556A
- Authority
- MX
- Mexico
- Prior art keywords
- reducing agent
- combustion gases
- combustion
- reduce nox
- evaporate
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/30—Controlling by gas-analysis apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8631—Processes characterised by a specific device
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Chimneys And Flues (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Esta invención se refiere a un método para evaporar un agente reductor acuoso, para reducir el NOx en los gases de la cobustión, en un sistema de combustión. Se colocan intercambiadores de calor en la trayectoria de los gases de la combustión, de modo que el calor de los gases de la combustión caliente el medio de transferencia de calor, preferiblemente el aire del medio ambiente. El aire caliente se hace pasar a un recipiente evaporador en donde él mismo evapora un agente reductor acuoso, preferiblemente amoníaco acuoso. El amoníaco evaporado es inyectado en la trayectoria de los gases de la combustión, en donde él mismo es efectivo para reducir el NOx. También se describen algunos aspectos de un sistema de control automático.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/923,718 US5296206A (en) | 1992-07-31 | 1992-07-31 | Using flue gas energy to vaporize aqueous reducing agent for reduction of NOx in flue gas |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9304556A true MX9304556A (es) | 1994-02-28 |
Family
ID=25449160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9304556A MX9304556A (es) | 1992-07-31 | 1993-07-28 | Metodo para evaporar un agente reductor acuoso, para reducir el nox en los gases de combustion, en un sistema de combustion. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5296206A (es) |
EP (1) | EP0583878B1 (es) |
JP (1) | JPH084712B2 (es) |
KR (1) | KR100259104B1 (es) |
CN (1) | CN1036247C (es) |
CA (1) | CA2099521C (es) |
ES (1) | ES2147742T3 (es) |
MX (1) | MX9304556A (es) |
PT (1) | PT583878E (es) |
Families Citing this family (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4301760A1 (de) * | 1993-01-23 | 1994-08-11 | Rothemuehle Brandt Kritzler | Verfahren und Vorrichtung für einen Regenerativ-Wärmetauscher zur Behandlung schadstoffhaltiger Abgase |
JPH0796141A (ja) * | 1993-09-30 | 1995-04-11 | Hitachi Zosen Corp | 脱硝装置におけるアンモニア供給方法 |
US5738024A (en) * | 1996-04-19 | 1998-04-14 | Winegar; Phillip | Catalytic reduction apparatus for NOX reduction |
DE19719998C2 (de) | 1997-05-13 | 2003-10-30 | Daimler Chrysler Ag | Verfahren und Vorrichtung zur Stickoxidreduktion im Abgas einer Verbrennungseinrichtung |
DE19750138A1 (de) * | 1997-11-12 | 1999-05-27 | Siemens Ag | Einrichtung zum Einbringen eines flüssigen Reduktionsmittels in eine Abgas-Reinigungsanlage |
ATE246535T1 (de) | 1998-05-11 | 2003-08-15 | Siemens Ag | Verfahren und vorrichtung zur selektiven katalytischen reduktion von stickoxiden in einem sauerstoffhaltigen gasförmigen medium |
US6273120B1 (en) | 1998-11-12 | 2001-08-14 | Siemens Aktiengesellschaft | Device for introducing a liquid reducing agent into an exhaust gas purification system |
US5943865A (en) * | 1998-12-03 | 1999-08-31 | Cohen; Mitchell B. | Reheating flue gas for selective catalytic systems |
US6315969B1 (en) | 2000-02-18 | 2001-11-13 | Mitsubishi Heavy Industries America, Inc. | Gas re-circulation selective catalytic reduction system with heat trace |
US20020044886A1 (en) * | 2000-10-16 | 2002-04-18 | William Larco | Vaporization system having blower positioned in reduced temperature zone |
AU2002228791A1 (en) * | 2000-12-01 | 2002-06-11 | Fuel Tech. Inc. | Selective catalytic reduction of no, enabled by side stream urea decomposition |
AU2002238089A1 (en) * | 2001-02-08 | 2002-08-19 | The Chemithon Corporation | Method for quantitative production of gaseous ammonia |
US6706246B2 (en) | 2001-02-26 | 2004-03-16 | Abb Lummus Global Inc. | System and method for the selective catalytic reduction of nitrogen oxide in a gas stream |
US6960329B2 (en) | 2002-03-12 | 2005-11-01 | Foster Wheeler Energy Corporation | Method and apparatus for removing mercury species from hot flue gas |
WO2004058641A1 (en) * | 2002-12-17 | 2004-07-15 | Clean Diesel Technologies, Inc. | Nox control for ic engines |
US20040197251A1 (en) * | 2003-04-07 | 2004-10-07 | Glex, Inc. | Vaporization having fast start up |
US7069715B1 (en) * | 2003-10-07 | 2006-07-04 | Express Integrated Technologies Llc | Method and apparatus for the pre-heating of vaporization chamber |
US20090004083A1 (en) * | 2003-12-17 | 2009-01-01 | Valentine James M | NOx control for IC engines |
US7588440B2 (en) * | 2005-04-13 | 2009-09-15 | Babcock & Wilcox Power Generation Group, Inc. | Carrier air heating system for SCR |
DE102006023147A1 (de) * | 2006-05-16 | 2008-01-10 | Emitec Gesellschaft Für Emissionstechnologie Mbh | Verfahren und Vorrichtung zum Bereitstellen eines gasförmigen Stoffgemisches |
US8899020B2 (en) | 2006-08-21 | 2014-12-02 | Southwest Research Institute | Apparatus and method for assisting selective catalytic reduction |
US7985280B2 (en) * | 2007-02-20 | 2011-07-26 | Hitachi Power Systems America, Ltd. | Separation of aqueous ammonia components for NOx reduction |
US8047145B2 (en) * | 2007-02-20 | 2011-11-01 | Hitachi Power Systems America, Ltd | Ammonia vaporization system using non-flue gas intermediate heat transfer medium |
US7874140B2 (en) * | 2007-06-08 | 2011-01-25 | Foster Wheeler North America Corp. | Method of and power plant for generating power by oxyfuel combustion |
US8145044B1 (en) | 2008-06-11 | 2012-03-27 | Honeywell International Inc. | Air ammonia heater and vaporization chamber system |
US7638107B1 (en) | 2008-06-11 | 2009-12-29 | Callidus Technologies, LLC | Multi-bed selective catalytic reduction system |
US20100175366A1 (en) * | 2009-01-09 | 2010-07-15 | General Electric Company | Ammonia injection system for peaker cycle |
CN101890279B (zh) * | 2010-03-10 | 2013-03-13 | 张作保 | 一种高效氨法脱硝工艺及其装置 |
US20120012298A1 (en) * | 2010-07-18 | 2012-01-19 | Taylor Scott A | Method and Appratus for Heating an Aqueous Mixture to Vaporization |
US8361422B2 (en) * | 2010-08-19 | 2013-01-29 | Dow Global Technologies Llc | Method and devices for heating urea-containing materials in vehicle emission control system |
BR112013011849B1 (pt) * | 2010-11-12 | 2020-10-20 | Cabot Corporation | método e aparelho para reduzir as emissões de nox na incineração de gás residual |
US8591849B2 (en) | 2012-04-16 | 2013-11-26 | Combustion Components Associates, Inc. | On demand generation of ammonia for small industrial and commercial boilers |
US8815197B2 (en) | 2012-10-05 | 2014-08-26 | Peerless Mfg. Co. | Method for urea decomposition and ammonia feed to a selective catalytic reduction system |
US9593609B2 (en) | 2012-10-05 | 2017-03-14 | Peerless Mfg. Co. | System and method for urea decomposition to ammonia in a side stream for selective catalytic reduction |
US9746177B2 (en) | 2012-11-12 | 2017-08-29 | Peerless Mfg. Co. | Urea decomposition and improved SCR NOx reduction on industrial and small utility boilers |
KR102115054B1 (ko) * | 2015-06-16 | 2020-05-26 | 현대중공업파워시스템 주식회사 | 복합 화력발전 시스템 |
US20170356319A1 (en) * | 2016-06-09 | 2017-12-14 | General Electric Company | Exhaust Gas Heat Exchange for Ammonia Evaporation Using a Heat Pipe |
KR102362761B1 (ko) * | 2017-11-22 | 2022-02-15 | 씨에스케이(주) | 가스 처리 장치 |
WO2019168652A1 (en) * | 2018-02-27 | 2019-09-06 | Exxonmobil Chemical Patents Inc. | System and process for delivering controlled quantities of ammonia to ammonia-consuming devices |
CN109012152A (zh) * | 2018-07-30 | 2018-12-18 | 芜湖凯奥尔环保科技有限公司 | 一种脱硝废水废气净化系统 |
CN109464892A (zh) * | 2018-12-28 | 2019-03-15 | 启明星宇节能科技股份有限公司 | 脱硝自动化控制系统 |
CN111558286A (zh) * | 2020-05-12 | 2020-08-21 | 江苏峰峰鸿运环保科技发展有限公司 | 一种sncr-scr联合脱硝方法及装置 |
US11906248B2 (en) * | 2021-07-13 | 2024-02-20 | Pts Power Inc. | Exhaust gas path heat energy utilization system and method |
JP2023016065A (ja) * | 2021-07-21 | 2023-02-02 | 三菱重工業株式会社 | アンモニア燃料供給ユニット、発電プラント、及びボイラの運転方法 |
KR102710999B1 (ko) * | 2023-12-22 | 2024-09-27 | 에스에이치엔솔 주식회사 | 시멘트 제조장치용 선택적 촉매 환원 시스템 및 그 제어방법. |
Family Cites Families (14)
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US3897539A (en) * | 1971-10-31 | 1975-07-29 | Inst Gas Technology | Tail gas nitrogen oxide abatement process |
US3900554A (en) * | 1973-03-16 | 1975-08-19 | Exxon Research Engineering Co | Method for the reduction of the concentration of no in combustion effluents using ammonia |
JPS5499771A (en) * | 1978-01-24 | 1979-08-06 | Mitsubishi Heavy Ind Ltd | Controlling method for ammonia injection at dry process exhaust gas dieitration method |
EP0278241B1 (de) * | 1987-02-11 | 1992-07-08 | Deutsche Babcock Anlagen Gmbh | Verfahren zum Einmischen von Ammoniak in einen Rauchgasstrom |
DE3739162A1 (de) * | 1987-11-19 | 1989-06-01 | Krupp Koppers Gmbh | Verfahren zum entfernen von sauren komponenten und stickoxiden aus den abgasen industrieller feuerungsanlagen |
JPH0286813A (ja) * | 1988-09-22 | 1990-03-27 | Mitsubishi Heavy Ind Ltd | 排煙脱硝装置 |
US5047220A (en) * | 1989-03-27 | 1991-09-10 | Foster Wheeler Energy Corporation | Catalytic denitrification control process and system for combustion flue gases |
JPH0386212A (ja) * | 1989-08-30 | 1991-04-11 | Mitsubishi Heavy Ind Ltd | 排ガスの脱硝方法 |
US5024171A (en) * | 1990-03-19 | 1991-06-18 | Wahlco, Inc. | Reduction of acidic emissions from combustion of sulfur-laden fuels |
DE4010566A1 (de) * | 1990-04-02 | 1991-10-10 | Krc Umwelttechnik Gmbh | Verfahren zur abscheidung von kohlenstoffhaltigen und/oder stickoxidhaltigen schadstoffen in rauchgasen |
US5020457A (en) * | 1990-06-22 | 1991-06-04 | The United States Of America As Represented By The United States Department Of Energy | Destruction of acid gas emissions |
US5098680A (en) * | 1990-10-15 | 1992-03-24 | Exxon Research & Engineering Company | Aqueous ammonia injection scheme |
JP3100191B2 (ja) * | 1991-09-02 | 2000-10-16 | 三菱重工業株式会社 | 排煙脱硝装置 |
US5237939A (en) * | 1992-08-20 | 1993-08-24 | Wahlco Environmental Systems, Inc. | Method and apparatus for reducing NOx emissions |
-
1992
- 1992-07-31 US US07/923,718 patent/US5296206A/en not_active Expired - Lifetime
-
1993
- 1993-07-02 CA CA002099521A patent/CA2099521C/en not_active Expired - Lifetime
- 1993-07-09 EP EP93305391A patent/EP0583878B1/en not_active Expired - Lifetime
- 1993-07-09 ES ES93305391T patent/ES2147742T3/es not_active Expired - Lifetime
- 1993-07-09 PT PT93305391T patent/PT583878E/pt unknown
- 1993-07-19 KR KR1019930013527A patent/KR100259104B1/ko not_active IP Right Cessation
- 1993-07-27 JP JP5185168A patent/JPH084712B2/ja not_active Expired - Lifetime
- 1993-07-28 MX MX9304556A patent/MX9304556A/es not_active IP Right Cessation
- 1993-07-30 CN CN93109100A patent/CN1036247C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH06154552A (ja) | 1994-06-03 |
KR100259104B1 (ko) | 2000-06-15 |
PT583878E (pt) | 2000-08-31 |
CN1083740A (zh) | 1994-03-16 |
JPH084712B2 (ja) | 1996-01-24 |
ES2147742T3 (es) | 2000-10-01 |
CA2099521C (en) | 2004-03-30 |
CN1036247C (zh) | 1997-10-29 |
EP0583878B1 (en) | 2000-05-03 |
US5296206A (en) | 1994-03-22 |
CA2099521A1 (en) | 1994-02-01 |
EP0583878A1 (en) | 1994-02-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration | ||
MM | Annulment or lapse due to non-payment of fees |