ES2145535T3 - Procedimiento para la obtencion de esteres y acidos polienicos. - Google Patents

Procedimiento para la obtencion de esteres y acidos polienicos.

Info

Publication number
ES2145535T3
ES2145535T3 ES97109473T ES97109473T ES2145535T3 ES 2145535 T3 ES2145535 T3 ES 2145535T3 ES 97109473 T ES97109473 T ES 97109473T ES 97109473 T ES97109473 T ES 97109473T ES 2145535 T3 ES2145535 T3 ES 2145535T3
Authority
ES
Spain
Prior art keywords
alkyl
polyene
compounds
allylidene
silyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97109473T
Other languages
English (en)
Inventor
August Ruttimann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
F Hoffmann La Roche AG
Original Assignee
F Hoffmann La Roche AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by F Hoffmann La Roche AG filed Critical F Hoffmann La Roche AG
Application granted granted Critical
Publication of ES2145535T3 publication Critical patent/ES2145535T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/10—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by etherified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/20—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by carboxyl groups or halides, anhydrides, or (thio)esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/30—Compounds having groups
    • C07C43/303—Compounds having groups having acetal carbon atoms bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/734—Ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/30—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1872—Preparation; Treatments not provided for in C07F7/20
    • C07F7/1892—Preparation; Treatments not provided for in C07F7/20 by reactions not provided for in C07F7/1876 - C07F7/1888
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

UN PROCEDIMIENTO PARA LA PRODUCCION DE ESTERES O ACIDOS DE POLIENO CONSISTE EN TRANSFORMAR UN POLIENO TAL O ANALOGO DE ESTE EN PRESENCIA DE UN ACIDO LEWIS, PARA DESPUES, DEPENDIENDO DEL VINILCETENOACETAL UTILIZADO, HIDROLIZAR LA MEZCLA DE REACCION, SEPARANDO A CONTINUACION EL ALCOHOL DEL DERIVADO POLIENO PRODUCIDO EN ESTA FASE BAJO UNAS CONDICIONES BASICAS FUERTES Y REALIZANDO, EN EL CASO DE QUE TODAVIA NO ESTUVIERA PRESENTE EL GRUPO ESTER O CARBOXILO DESEADO, LA CORRESPONDIENTE TRANSFORMACION. EN ESTE PROCEDIMIENTO EXISTEN CIERTOS PRODUCTOS INTERMEDIOS QUE CONFORMAN OTRO ASPECTO DE LA INVENCION. LOS PRODUCTOS FINALES SON, SOBRE TODO, CAROTINOIDES, PUDIENDO SER UTILIZADOS DEL MODO CORRESPONDIENTE, POR EJEMPLO, COMO COLORANTES Y PIGMENTOS PARA ALIMENTOS, PRODUCTOS ANIMALES, ETC.
ES97109473T 1996-06-17 1997-06-11 Procedimiento para la obtencion de esteres y acidos polienicos. Expired - Lifetime ES2145535T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96109660 1996-06-17

Publications (1)

Publication Number Publication Date
ES2145535T3 true ES2145535T3 (es) 2000-07-01

Family

ID=8222898

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97109473T Expired - Lifetime ES2145535T3 (es) 1996-06-17 1997-06-11 Procedimiento para la obtencion de esteres y acidos polienicos.

Country Status (10)

Country Link
US (2) US5763651A (es)
EP (1) EP0814078B1 (es)
JP (1) JP4024343B2 (es)
CN (1) CN1124261C (es)
AT (1) ATE191474T1 (es)
BR (1) BR9703607A (es)
DE (1) DE59701389D1 (es)
DK (1) DK0814078T3 (es)
ES (1) ES2145535T3 (es)
ID (1) ID17801A (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6153769A (en) * 1997-11-27 2000-11-28 Roche Vitamins Inc. Manufacture of polyene aldehydes
EP1186245B1 (en) * 2000-09-11 2017-10-18 DSM IP Assets B.V. Carotenoid esters
CN102863367A (zh) * 2012-09-26 2013-01-09 浙江医药股份有限公司新昌制药厂 一种β-阿朴-8’-胡萝卜酸烷基酯的合成方法
CN105906672B (zh) * 2016-04-29 2017-12-29 暨南大学 藏红花色素类化合物及其用途
CN107056596B (zh) * 2017-06-02 2020-08-25 广州立达尔生物科技股份有限公司 一种2,6,11,15-四甲基-2,4,6,8,10,12,14-十六碳七烯二醛的制备方法
CN110749688A (zh) * 2019-11-07 2020-02-04 贵州省兽药饲料监察所(贵州省兽药残留监测中心) 一种测定饲料中β-阿朴-8＇-胡萝卜素酸乙酯着色剂含量的方法
CN111138703B (zh) * 2019-12-30 2022-02-15 四川大学 一种通过激光辐照聚合物树脂制备线型多烯类颜料的方法
CN116235856A (zh) * 2020-12-08 2023-06-09 江西省科学院应用化学研究所 西红花苷-1和西红花苷-2的应用

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3719622A1 (de) * 1987-06-12 1988-12-29 Basf Ag Verfahren zur herstellung von (gamma)-halogen-tiglinsaeurealkylestern und 0,0-dialkyl-(gamma)-phosphono-tiglinsaeurealkylestern sowie neue phosphonoester-derivate

Also Published As

Publication number Publication date
DE59701389D1 (de) 2000-05-11
ATE191474T1 (de) 2000-04-15
BR9703607A (pt) 1998-11-10
JP4024343B2 (ja) 2007-12-19
DK0814078T3 (da) 2000-09-11
EP0814078A1 (de) 1997-12-29
JPH1059894A (ja) 1998-03-03
ID17801A (id) 1998-01-29
US5763651A (en) 1998-06-09
CN1169418A (zh) 1998-01-07
CN1124261C (zh) 2003-10-15
US5986113A (en) 1999-11-16
EP0814078B1 (de) 2000-04-05

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