ES2130860T3 - Empleo de poliuretanos hidrosolubles o dispersables en agua como agente auxiliar en preparados cosmeticos y farmaceuticos y poliuretanos, que contienen polioles de acido polilactico incorporados por polimerizacion. - Google Patents

Empleo de poliuretanos hidrosolubles o dispersables en agua como agente auxiliar en preparados cosmeticos y farmaceuticos y poliuretanos, que contienen polioles de acido polilactico incorporados por polimerizacion.

Info

Publication number
ES2130860T3
ES2130860T3 ES97103009T ES97103009T ES2130860T3 ES 2130860 T3 ES2130860 T3 ES 2130860T3 ES 97103009 T ES97103009 T ES 97103009T ES 97103009 T ES97103009 T ES 97103009T ES 2130860 T3 ES2130860 T3 ES 2130860T3
Authority
ES
Spain
Prior art keywords
water
polyurethanes
dispersible
cosmetic
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97103009T
Other languages
English (en)
Inventor
Son Nguyen Dr Kim
Axel Dr Sanner
Karin Dr Sperling-Vietmeier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2130860T3 publication Critical patent/ES2130860T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/20Pills, tablets, discs, rods
    • A61K9/2004Excipients; Inactive ingredients
    • A61K9/2022Organic macromolecular compounds
    • A61K9/2031Organic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polyethylene glycol, polyethylene oxide, poloxamers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/20Pills, tablets, discs, rods
    • A61K9/28Dragees; Coated pills or tablets, e.g. with film or compression coating
    • A61K9/2806Coating materials
    • A61K9/2833Organic macromolecular compounds
    • A61K9/2853Organic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polyethylene glycol, polyethylene oxide, poloxamers, poly(lactide-co-glycolide)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/428Lactides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4283Hydroxycarboxylic acid or ester
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6659Compounds of group C08G18/42 with compounds of group C08G18/34
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00Compositions for adhesives
    • C08G2170/80Compositions for aqueous adhesives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00Drug, bio-affecting and body treating compositions
    • Y10S424/01Aerosol hair preparation

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Engineering & Computer Science (AREA)
  • Birds (AREA)
  • Manufacturing & Machinery (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Cosmetics (AREA)

Abstract

POLIURETANOS HIDROSOLUBLES O DISPERSABLES EN AGUA COMPUESTOS POR A) AL MENOS UN COMPUESTO, QUE CONTIENE AL MENOS DOS O VARIOS ATOMOS DE HIDROGENO ACTIVO POR MOLECULA, B) AL MENOS UN DIOL QUE CONTIENE UN GRUPO ACIDO O SALINO, Y C) AL MENOS UN DIISOCIANATO, CON INDICES DE ACIDEZ DE 12 A 150 O DE LAS SALES DE ESTOS POLIURETANOS, CARACTERIZADOS PORQUE CONTIENEN DENTRO DE SU ESTRUCTURA POLIMERICA COMO COMPUESTOS DEL GRUPO A) AL MENOS EN UN 5 % MOLAR DE UN POLICONDENSADO DE ACIDO LACTICO Y DE UN POLIOL DE FORMULA GENERAL EN LA QUE Y ES EL RADICAL DE UN ALCOHOL BI- A TETRAVALENTE, N ES 1 - 50, Y M ES 1 - 4, PROCEDIMIENTO PARA SU OBTENCION Y SU UTILIZACION.
ES97103009T 1992-07-29 1993-07-17 Empleo de poliuretanos hidrosolubles o dispersables en agua como agente auxiliar en preparados cosmeticos y farmaceuticos y poliuretanos, que contienen polioles de acido polilactico incorporados por polimerizacion. Expired - Lifetime ES2130860T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4225045A DE4225045A1 (de) 1992-07-29 1992-07-29 Verwendung von wasserlöslichen oder in Wasser dispergierbaren Polyurethanen als Hilfsmittel in kosmetischen und pharmazeutischen Zubereitungen und Polyurethane, die Polymilchsäurepolyole einpolymerisiert enthalten

Publications (1)

Publication Number Publication Date
ES2130860T3 true ES2130860T3 (es) 1999-07-01

Family

ID=6464377

Family Applications (2)

Application Number Title Priority Date Filing Date
ES97103009T Expired - Lifetime ES2130860T3 (es) 1992-07-29 1993-07-17 Empleo de poliuretanos hidrosolubles o dispersables en agua como agente auxiliar en preparados cosmeticos y farmaceuticos y poliuretanos, que contienen polioles de acido polilactico incorporados por polimerizacion.
ES93915942T Expired - Lifetime ES2107673T3 (es) 1992-07-29 1993-07-17 Empleo de poliuretanos hidrosolubles o dispersables en agua como agentes auxiliares en preparaciones cosmeticas y farmaceuticas y poliuretanos, que contienen polioles del acido polilactico incorporados por polimerizacion.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES93915942T Expired - Lifetime ES2107673T3 (es) 1992-07-29 1993-07-17 Empleo de poliuretanos hidrosolubles o dispersables en agua como agentes auxiliares en preparaciones cosmeticas y farmaceuticas y poliuretanos, que contienen polioles del acido polilactico incorporados por polimerizacion.

Country Status (7)

Country Link
US (1) US6372876B1 (es)
EP (2) EP0779310B1 (es)
JP (1) JP3844775B2 (es)
CA (2) CA2140665C (es)
DE (3) DE4225045A1 (es)
ES (2) ES2130860T3 (es)
WO (1) WO1994003510A1 (es)

Families Citing this family (217)

* Cited by examiner, † Cited by third party
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EP0619111B2 (en) * 1993-04-06 2005-09-14 National Starch and Chemical Investment Holding Corporation Use of polyurethanes with carboxylate functionality for hair fixative applications
DE4438846A1 (de) * 1994-11-02 1996-05-09 Henkel Kgaa Haarbehandlungsmittel
US6365697B1 (en) 1995-11-06 2002-04-02 Basf Aktiengesellschaft Water-soluble or water-dispersible polyurethanes with terminal acid groups, the production and the use thereof
DE19541658A1 (de) 1995-11-08 1997-05-15 Basf Ag Wasserlösliche oder wasserdispergierbare Pfropfpolymere, ihre Herstellung und ihre Verwendung
US6106808A (en) * 1996-09-20 2000-08-22 Helene Curtis, Inc. Hair spray containing carboxylated polyurethane resins
US6132704A (en) * 1996-09-20 2000-10-17 Helene Curtis, Inc. Hair styling gels
US6106809A (en) * 1996-09-20 2000-08-22 Helene Curtis, Inc. Hair spray compositions containing carboxylated polyurethane resins
US6007793A (en) * 1996-09-20 1999-12-28 Helene Curtis, Inc. Hair spray compositions containing carboxylated polyurethane resins
US6113881A (en) * 1996-09-20 2000-09-05 Helene Curtis, Inc. Hair styling mousse compositions comprising carboxylated polyurethane resins
DE19744473A1 (de) * 1997-10-09 1999-04-15 Basf Ag Verwendung von wasserlöslichen oder wasserdispergierbaren Polyurethanen als Überzugsmittel oder Bindemittel für pharmazeutische Darreichungsformen
JP4165669B2 (ja) * 1998-02-09 2008-10-15 日本エヌエスシー株式会社 化粧品用樹脂組成物およびその製法
US5968494A (en) 1998-02-24 1999-10-19 National Starch And Chemical Investment Holding Corporation Polyurethanes with carboxylate functionality for hair fixative applications
DE19807908A1 (de) 1998-02-25 1999-08-26 Basf Ag Kosmetisches Mittel
US6776287B1 (en) 1998-03-03 2004-08-17 Aquasol Limited Water soluble films
DE19821731A1 (de) 1998-05-14 1999-11-18 Basf Ag Kosmetisches Mittel
DE19821732A1 (de) 1998-05-14 1999-11-18 Basf Ag Vernetzte, wasserlösliche oder wasserdispergierbare Polyurethane
CN1145660C (zh) 1998-08-26 2004-04-14 Basf公司 滋发剂组合物及其用途
DE19838851A1 (de) 1998-08-26 2000-03-02 Basf Ag Kosmetisches Mittel
FR2782636B1 (fr) 1998-08-27 2001-09-14 Oreal Compositions contenant un polycondensat comprenant au moins un motif polyurethanne et/ou polyuree et une silicone comprenant au moins une fonction carboxylique
FR2782635B1 (fr) * 1998-08-27 2001-09-14 Oreal Dispositif aerosol contenant un polycondensat comprenant au moins un motif polyurethanne et/ou polyuree
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FR2782637B1 (fr) 1998-08-27 2000-11-24 Oreal Composition capillaire contenant un polycondensat comprenant au moins un motif polyurethanne et/ou polyuree et un polyol
FR2785182B1 (fr) 1998-11-03 2002-04-12 Oreal Dispositif flacon pompe contenant un polycondensat comprenant au moins un motif polyurethanne et/ou polyuree
FR2786391B1 (fr) 1998-11-26 2002-08-02 Oreal Composition de coiffage comprenant un polymere aux caracteristiques particulieres et un polymere filmogene ionique
DE19958526A1 (de) * 1998-12-17 2000-06-21 Henkel Kgaa Polyester-Polyurethan-Klebstoff und seine Verwendung
DE19900457A1 (de) * 1999-01-08 2000-07-13 Basf Ag Verfahren zur Herstellung von festen Dosierungsformen
FR2788972B1 (fr) 1999-02-03 2001-04-13 Oreal Composition capillaire comprenant une base lavante, un polymere cationique et un polyurethane anionique et utilisation
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DE19928771A1 (de) * 1999-06-23 2000-12-28 Beiersdorf Ag Kombinationen aus wasserlöslichen und/oder wasserdispergierbaren siliconmodifizierten Kammpolymeren und einer oder mehrere Substanzen gewählt aus der Gruppe der physiologisch verträglichen Polyurethane
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DE10113053A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern und organischen Hydrololloiden
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DE10143960A1 (de) * 2001-09-07 2003-03-27 Basf Ag Kosmetische und dermatologische Zubereitungen in Stiftform, enthaltend ein aminosubstituiertes Hydroxybenzophenon
DE10143962A1 (de) * 2001-09-07 2003-03-27 Basf Ag Kosmetische und dermatologische Zubereitungen in Form von O/W-Emulsionen, enthaltend ein aminosubstituiertes Hydroxybenzophenon
DE10143963A1 (de) * 2001-09-07 2003-03-27 Basf Ag Kosmetische und dermatologische Zubereitungen in Form von W/O-Emulsionen, enthaltend ein aminosubstituiertes Hydroxybenzophenon
FR2831437B1 (fr) * 2001-10-26 2004-02-06 Oreal Composition de traitement cosmetique des cheveux comprenant un polyurethane fixant non associatif et un polyurethane associatif anionique ou non ionique, et procede de traitement cosmetique
FR2831804B1 (fr) * 2001-11-08 2004-07-30 Oreal Procede de deformation permanente des cheveux mettant en oeuvre des silicones aminees particulieres
FR2831805B1 (fr) * 2001-11-08 2004-08-06 Oreal Procede de deformation permanente des cheveux mettant en oeuvres des silicones aminees particulieres
FR2831802B1 (fr) * 2001-11-08 2004-10-15 Oreal Compositions cosmetiques contenant une silicone aminee et un agent epaississant et leurs utilisations
FR2831809B1 (fr) * 2001-11-08 2004-07-23 Oreal Composition oxydante pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere
FR2831813B1 (fr) * 2001-11-08 2004-10-01 Oreal Utilisation de silicones aminees particulieres en pre-traitement de colorations directes ou d'oxydation de fibres keratiniques
FR2831814B1 (fr) * 2001-11-08 2004-09-10 Oreal Utilisations de silicones aminees particulieres en pre- ou post-traitement de decolorations de fibres keratiniques
FR2831818B1 (fr) * 2001-11-08 2004-07-16 Oreal Composition oxydante pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere
AU2002301801B2 (en) * 2001-11-08 2004-09-30 L'oreal Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof
FR2831803B1 (fr) * 2001-11-08 2004-07-30 Oreal Compositions cosmetiques contenant une silicone aminee et un agent epaississant et leurs utilisations
AU2002301803B2 (en) * 2001-11-08 2004-09-09 L'oreal Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof
FR2831817B1 (fr) * 2001-11-08 2003-12-19 Oreal Composition reductrice pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere
FR2831815B1 (fr) * 2001-11-08 2004-08-06 Oreal Composition reductrice pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere
US7854925B2 (en) 2002-04-04 2010-12-21 Akzo Nobel N.V. Use of solubilized, anionic polyurethanes in skin care compositions
MXPA03008714A (es) 2002-09-26 2004-09-10 Oreal Polimeros secuenciados y composiciones cosmeticas que comprenden tales polimeros.
AU2003299071A1 (en) * 2002-09-26 2004-04-19 L'oreal Glossy non-transfer composition comprising a sequenced polymer
GB0222522D0 (en) 2002-09-27 2002-11-06 Controlled Therapeutics Sct Water-swellable polymers
WO2004043330A2 (fr) 2002-11-07 2004-05-27 L'oreal Composition cosmetique comprenant au moins un carbonate cyclique particulier apte a polymeriser
US20040241104A1 (en) * 2003-03-11 2004-12-02 L'oreal Aerosol device comprising a cosmetic composition comprising at least one polyurethane and at least one propellant comprising dimethyl ether and at least one C3-C5 hydrocarbon
US20050158265A1 (en) * 2003-06-17 2005-07-21 Sabine Vrignaud Cosmetic hair composition comprising tridecyl trimellitate and at least one fixing polymer
US20050063933A1 (en) * 2003-06-17 2005-03-24 Sabine Vrignaud Cosmetic hair composition comprising isoeicosane and at least one nonsilicone fixing polymer
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CA2140665A1 (en) 1994-02-17
WO1994003510A1 (de) 1994-02-17
CA2402950A1 (en) 1994-02-17
DE59309565D1 (de) 1999-06-10
US6372876B1 (en) 2002-04-16
CA2140665C (en) 2003-05-20
DE59307474D1 (de) 1997-11-06
JP3844775B2 (ja) 2006-11-15
ES2107673T3 (es) 1997-12-01
EP0779310B1 (de) 1999-05-06
DE4225045A1 (de) 1994-02-03
EP0779310A3 (de) 1997-07-02
EP0656021A1 (de) 1995-06-07
EP0779310A2 (de) 1997-06-18

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