ES2127372T3 - Oligomerizacion de olefinas. - Google Patents

Oligomerizacion de olefinas.

Info

Publication number
ES2127372T3
ES2127372T3 ES94900556T ES94900556T ES2127372T3 ES 2127372 T3 ES2127372 T3 ES 2127372T3 ES 94900556 T ES94900556 T ES 94900556T ES 94900556 T ES94900556 T ES 94900556T ES 2127372 T3 ES2127372 T3 ES 2127372T3
Authority
ES
Spain
Prior art keywords
zeolite
acid
oligomerization
activity
reduction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94900556T
Other languages
English (en)
Inventor
Minas Robert Apelian
James Robert Boulton
Shiu Lun Anthony Fung
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of ES2127372T3 publication Critical patent/ES2127372T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Steroid Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

UN PROCESO PARA PRODUCIR SUSTANCIALMENTE HIDROCARBUROS LINEALES POR OLIGOMERIZACION DE UNA OLEFINA BAJA A TEMPERATURA Y PRESION ELEVADAS, COMPRENDE EL CONTACTO DE OLEFINA CON BAJO NUMERO DE CARBONOS EN CONDICIONES DE OLIGOMERIZACION CON ZEOLITA ACIDICA SILICIOSA CON LOS POROS INTERMEDIOS CONSTREÑIDOS, POR EJEMPLO, ZSM-22, -23 O -35, QUE TIENE ACTIVIDAD ACIDA BRONSTED. LA ZEOLITA ES PRETRATADA CON UN ACIDO DICARBOXILICO, POR EJEMPLO, ACIDO OXALICO, EN CONDICIONES PARA EFECTUAR UNA REDUCCION DE POR LO MENOS EL 20 % EN LA ACIDEZ DE LA SUPERFICIE DE LA ZEOLITA, TAL COMO LA DETERMINADA POR LA CONVERSION DEL TRI-TERCIARIOBUTILOBENCENO, SIN REDUCCION SUSTANCIAL DE LA ACTIVIDAD GLOBAL DE LA ZEOLITA COMO LA INDICADA POR EL VALOR ALFA.
ES94900556T 1992-11-04 1993-11-04 Oligomerizacion de olefinas. Expired - Lifetime ES2127372T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/971,112 US5284989A (en) 1992-11-04 1992-11-04 Olefin oligomerization with surface modified zeolite catalyst

Publications (1)

Publication Number Publication Date
ES2127372T3 true ES2127372T3 (es) 1999-04-16

Family

ID=25517943

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94900556T Expired - Lifetime ES2127372T3 (es) 1992-11-04 1993-11-04 Oligomerizacion de olefinas.

Country Status (10)

Country Link
US (1) US5284989A (es)
EP (1) EP0667839B1 (es)
JP (1) JP3395137B2 (es)
AU (1) AU667609B2 (es)
CA (1) CA2141568A1 (es)
DE (1) DE69322878T2 (es)
ES (1) ES2127372T3 (es)
SG (1) SG66220A1 (es)
TW (1) TW333538B (es)
WO (1) WO1994010108A1 (es)

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US6071863A (en) * 1995-11-14 2000-06-06 Bp Amoco Corporation Biodegradable polyalphaolefin fluids and formulations containing the fluids
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EG22088A (en) * 1996-04-16 2002-07-31 Procter & Gamble Alkoxylated sulfates
EG21174A (en) * 1996-04-16 2000-12-31 Procter & Gamble Surfactant manufacture
PH11997056158B1 (en) * 1996-04-16 2001-10-15 Procter & Gamble Mid-chain branched primary alkyl sulphates as surfactants
ES2185936T3 (es) * 1996-04-16 2003-05-01 Procter & Gamble Composiciones liquidas de limpieza que contienen tensioactivos ramificados en mitad de la cadena seleccionados.
US5779882A (en) * 1996-07-22 1998-07-14 Mobil Oil Corporation Modified MCM-56, its preparation and use
US6093856A (en) * 1996-11-26 2000-07-25 The Procter & Gamble Company Polyoxyalkylene surfactants
ZA989155B (en) 1997-10-10 1999-04-12 Procter & Gamble Mixed surfactant system
US6242406B1 (en) 1997-10-10 2001-06-05 The Procter & Gamble Company Mid-chain branched surfactants with cellulose derivatives
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US6403853B1 (en) 2000-09-21 2002-06-11 Uop Llc Olefin oligomerization using surface modified molecular sieve catalyst
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US7507868B2 (en) * 2002-03-29 2009-03-24 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
WO2003082778A1 (en) * 2002-03-29 2003-10-09 Exxonmobil Chemical Patents Inc. Process for olefin oligomerization
FR2926812B1 (fr) 2008-01-28 2010-04-30 Inst Francais Du Petrole Procede d'oligomerisation des olefines utilisant un catalyseur a base de silice-alumine.
US8178740B2 (en) * 2008-12-09 2012-05-15 Uop Llc Olefin upgrading process
US20100144513A1 (en) * 2008-12-09 2010-06-10 Nicholas Christopher P Catalyst for Olefin Upgrading
US20100144514A1 (en) * 2008-12-09 2010-06-10 Nicholas Christopher P Process for Making Catalyst for Olefin Upgrading
US8450232B2 (en) * 2009-01-14 2013-05-28 Lummus Technology Inc. Catalysts useful for the alkylation of aromatic hydrocarbons
ES2391700T3 (es) 2009-07-03 2012-11-29 Bp Corporation North America Inc. Procedimiento de oligomerización de alquenos
EP2269734A1 (en) 2009-07-03 2011-01-05 BP Corporation North America Inc. Modified zeolite catalyst
FR2951164B1 (fr) 2009-10-08 2011-10-21 Inst Francais Du Petrole Procede d'oligomerisation d'une charge hydrocarbonee olefinique utilisant un catalyseur a base d'une silice-alumine macroporeuse
US20110147263A1 (en) * 2009-12-18 2011-06-23 Exxonmobil Research And Engineering Company Process and system to convert olefins to diesel and other distillates
WO2011135206A1 (fr) 2010-04-28 2011-11-03 IFP Energies Nouvelles Procede d'oligomerisation des olefines utilisant au moins un catalyseur organique possedant une forte densite de sites acides
EP2386354B1 (en) 2010-05-14 2019-07-24 Bp Oil International Limited Alkene oligomerization process
FR2973394A1 (fr) 2011-03-31 2012-10-05 IFP Energies Nouvelles Procede d'oligomerisation d'une charge hydrocarbonee olefinique utilisant un catalyseur comprenant un materiau de la famille des zif de type structural sod
ES2443539B1 (es) 2012-07-19 2014-12-04 Consejo Superior De Investigaciones Científicas (Csic) Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39
EP2792730A1 (en) 2013-04-16 2014-10-22 Sasol Technology (Proprietary) Limited Process for producing jet fuel from a hydrocarbon synthesis product stream
FR3017621B1 (fr) * 2014-02-19 2017-05-26 Ifp Energies Now Procede d'oligomerisation d'olefines utilisant un catalyseur comprenant une zeolithe et un liant alumine ayant subi une etape de traitement thermique specifique
FR3017622B1 (fr) * 2014-02-19 2017-05-26 Ifp Energies Now Procede d'oligomerisation d'olefines utilisant un catalyseur comprenant une zeolithe et un liant silicique ayant subi une etape de traitement thermique specifique
US9416071B2 (en) 2014-05-06 2016-08-16 Uop Llc Hydrocarbon conversion processes using lactamium-based ionic liquids
WO2017011232A1 (en) 2015-07-10 2017-01-19 Uop Llc Synthesis of non-cyclic amide and thioamide based ionic liquids
WO2017011222A1 (en) 2015-07-10 2017-01-19 Uop Llc Hydrocarbon conversion processes using non-cyclic amide and thioamide based ionic liquids
FR3053355B1 (fr) 2016-06-30 2019-07-26 IFP Energies Nouvelles Procede d'oligomerisation utilisant un catalyseur zeolithique et un catalyseur comprenant une silice alumine
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CN112867701A (zh) 2018-10-17 2021-05-28 埃克森美孚化学专利公司 烯烃的低聚
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Also Published As

Publication number Publication date
DE69322878D1 (de) 1999-02-11
AU667609B2 (en) 1996-03-28
SG66220A1 (en) 1999-07-20
EP0667839A4 (en) 1995-08-30
AU5549994A (en) 1994-05-24
TW333538B (en) 1998-06-11
WO1994010108A1 (en) 1994-05-11
EP0667839A1 (en) 1995-08-23
US5284989A (en) 1994-02-08
DE69322878T2 (de) 1999-05-27
JPH08502959A (ja) 1996-04-02
EP0667839B1 (en) 1998-12-30
CA2141568A1 (en) 1994-05-11
JP3395137B2 (ja) 2003-04-07

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