ES2124017T3 - Procedimiento para la obtencion de nitrilos de glicina cuaternizados. - Google Patents

Procedimiento para la obtencion de nitrilos de glicina cuaternizados.

Info

Publication number
ES2124017T3
ES2124017T3 ES95930486T ES95930486T ES2124017T3 ES 2124017 T3 ES2124017 T3 ES 2124017T3 ES 95930486 T ES95930486 T ES 95930486T ES 95930486 T ES95930486 T ES 95930486T ES 2124017 T3 ES2124017 T3 ES 2124017T3
Authority
ES
Spain
Prior art keywords
pct
nitrils
procedure
obtaining
date mar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95930486T
Other languages
English (en)
Inventor
Ulrich Annen
Hans-Peter Seelmann-Eggebert
Rudi Widder
Reinhard Muller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2124017T3 publication Critical patent/ES2124017T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D295/145—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals with the ring nitrogen atoms and the carbon atoms with three bonds to hetero atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/15—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals with the ring nitrogen atoms and the carbon atoms with three bonds to hetero atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/24—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compounds Of Unknown Constitution (AREA)

Abstract

OBTENCION DE NITRILOS CUATERNIZADOS DE GLICINA (I), EN DONDE R{SUP,1} Y R{SUP,2} PUEDEN SER IGUALES O DIFERENTES Y SIGNIFICAN EN CADA CASO UN RADICAL ALIFATICO, CICLOALIFATICO O ARALIFATICO CON 1 A 30 ATOMOS DE C, O TAMBIEN R{SUP,1} Y R{SUP,2} PUEDEN FORMAR JUNTOS CON EL ATOMO DE N AL CUAL ESTAN UNIDOS UN CICLO HETEROCICLICO SATURADO O INSATURADO DE CINCO O SEIS MIEMBROS, QUE PUEDE CONTENER ADEMAS OTROS HETEROATOMOS, PUEDE ESTAR BENZOANILLADOS Y TENER OTROS GRUPOS ALQUILICOS COLATERALES, Y ADEMAS R{SUP,2} PUEDE SER HIDROGENO, R{SUP,3} ES ALQUILO DE C{SUB,1} A C{SUB,4} O BENCILO, R{SUP,4} ES HIDROGENO, ALQUILO DE C{SUB,1} A C{SUB,20}, QUE PUEDE ESTAR INTERRUMPIDO POR UNO O VARIOS ATOMOS DE OXIGENO NO VECINOS, O UN RADICAL (A), SIENDO R{SUP,5} UN ENLACE QUIMICO O UN PUENTE DE ALQUILENO DE C{SUB,1} A C{SUB,6}, Y X{SUP,-} ES UN ION CONTRARIO; POR REACCION DE AMINAS (II), EN DONDE LAS VARIABLES R{SUP,1} Y R{SUP,2} TIENEN EL SIGNIFICADO ANTES CITADO, CON UN MONOALDEHIDO (IIIA) R{SUP,6}CHO, O UN DIALDEHIDO (IIIB) OCH-R{SUP,5}-CHO, EN DONDE R{SUP,5} TIENE EL SIGNIFICADO ANTES CITADO Y R{SUP,6} ES HIDROGENO O UN ALQUILO DE C{SUB,1}-C{SUB,20}, Y ACIDO CIANICO O UN CIANURO DE METAL ALCALINO EN MEDIO ACUOSO Y A CONTINUACION CUATERNIZACION CON UN ALQUILANTE (IV) R{SUP,3}-X, TENIENDO R{SUP,3} EL SIGNIFICADO ANTES CITADO Y X UN GRUPO INICIAL, REALIZANDO UNA TRAS OTRA LA REACCION DE LAS MINAS (II) CON LOS ALDEHIDOS (III) Y ACIDO CIANICO O CIANURO DE METAL ALCALINO Y LA CUATERNIZACION SIN AISLAMIENTO DE PRODUCTOS INTERMEDIOS EN MEDIO ACUOSO.
ES95930486T 1994-09-02 1995-08-17 Procedimiento para la obtencion de nitrilos de glicina cuaternizados. Expired - Lifetime ES2124017T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4431212A DE4431212A1 (de) 1994-09-02 1994-09-02 Verfahren zur Herstellung von quaternierten Glycinnitrilen

Publications (1)

Publication Number Publication Date
ES2124017T3 true ES2124017T3 (es) 1999-01-16

Family

ID=6527209

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95930486T Expired - Lifetime ES2124017T3 (es) 1994-09-02 1995-08-17 Procedimiento para la obtencion de nitrilos de glicina cuaternizados.

Country Status (13)

Country Link
US (1) US5763639A (es)
EP (1) EP0778832B1 (es)
JP (1) JP3801632B2 (es)
KR (1) KR100341979B1 (es)
CN (1) CN1054849C (es)
AT (1) ATE173253T1 (es)
AU (1) AU3385395A (es)
CA (1) CA2198637C (es)
DE (2) DE4431212A1 (es)
DK (1) DK0778832T3 (es)
ES (1) ES2124017T3 (es)
NZ (1) NZ292146A (es)
WO (1) WO1996007650A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6183665B1 (en) 1995-06-07 2001-02-06 The Clorox Company Granular N-alkyl ammonium acetonitrile compositions
US6010994A (en) * 1995-06-07 2000-01-04 The Clorox Company Liquid compositions containing N-alkyl ammonium acetonitrile salts
US5888419A (en) * 1995-06-07 1999-03-30 The Clorox Company Granular N-alkyl ammonium acetontrile compositions
US6235218B1 (en) 1995-06-07 2001-05-22 The Clorox Company Process for preparing N-alkyl ammonium acetonitrile compounds
US5739327A (en) * 1995-06-07 1998-04-14 The Clorox Company N-alkyl ammonium acetonitrile bleach activators
JP2002509528A (ja) * 1996-11-29 2002-03-26 ザ・クロロックス・カンパニー Ｎ−アルキルアンモニウムアセトニトリル化合物の調製方法
DE19649384A1 (de) * 1996-11-29 1998-06-04 Basf Ag Textilwaschmittel-Formulierung auf Basis von quaternierten Glycinnitrilen, Bleichmitteln, nichtionischen und/oder anionischen Tensiden und Calcium- und/oder Magnesiumionen sequestierenden Verbindungen
ES2214641T3 (es) * 1996-11-29 2004-09-16 Mid-America Commercialization Corporation Sales de n-alquil amonio acetonitrilo, procedimientos para las mismas y composiciones que las contienen.
US6191306B1 (en) * 1999-08-03 2001-02-20 Eastman Chemical Company Process for the preparation of cyclopropylglycine
DE10057045A1 (de) * 2000-11-17 2002-05-23 Clariant Gmbh Teilchenförmige Bleichaktivatoren auf der Basis von Acetonitrilen

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2503582C3 (de) * 1975-01-29 1979-10-04 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von N-Alkylglycinnitrilen
DE2555769C3 (de) * 1975-12-11 1980-01-03 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von an der Aminogruppe aliphatisch substituierten Glycinnitrilen
DE2620445C3 (de) * 1976-05-08 1980-08-28 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Glycinnitrilen
US4134889A (en) * 1976-05-08 1979-01-16 Basf Aktiengesellschaft Manufacture of glycinonitriles
US4420614A (en) * 1980-10-03 1983-12-13 Ici Australia Limited Cyanophenoxybenzyl amines
GB9011618D0 (en) * 1990-05-24 1990-07-11 Unilever Plc Bleaching composition
GB9012001D0 (en) * 1990-05-30 1990-07-18 Unilever Plc Bleaching composition

Also Published As

Publication number Publication date
KR970705551A (ko) 1997-10-09
EP0778832B1 (de) 1998-11-11
CN1054849C (zh) 2000-07-26
KR100341979B1 (ko) 2002-11-29
JP3801632B2 (ja) 2006-07-26
JPH10505351A (ja) 1998-05-26
DE59504236D1 (de) 1998-12-17
CA2198637A1 (en) 1996-03-14
NZ292146A (en) 1998-01-26
EP0778832A1 (de) 1997-06-18
US5763639A (en) 1998-06-09
DK0778832T3 (da) 1999-07-26
ATE173253T1 (de) 1998-11-15
DE4431212A1 (de) 1996-03-07
CN1159802A (zh) 1997-09-17
WO1996007650A1 (de) 1996-03-14
AU3385395A (en) 1996-03-27
CA2198637C (en) 2003-12-30

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