ES2113710T3 - Proceso para la polimerizacion de olefinas en fase gaseosa. - Google Patents

Proceso para la polimerizacion de olefinas en fase gaseosa.

Info

Publication number
ES2113710T3
ES2113710T3 ES95303163T ES95303163T ES2113710T3 ES 2113710 T3 ES2113710 T3 ES 2113710T3 ES 95303163 T ES95303163 T ES 95303163T ES 95303163 T ES95303163 T ES 95303163T ES 2113710 T3 ES2113710 T3 ES 2113710T3
Authority
ES
Spain
Prior art keywords
polymerization
gaseous
mixture
zone
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95303163T
Other languages
English (en)
Inventor
Geoffrey Chapman
Bruno Grenouiller
Stephen Kevin Lee
Michael Bernard Power
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of ES2113710T3 publication Critical patent/ES2113710T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/02Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/001Removal of residual monomers by physical means
    • C08F6/005Removal of residual monomers by physical means from solid polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA MANUFACTURAR DE FORMA CONTINUA (CO-)POLIMERO DE ETILENO EN UNA FASE GASEOSA EN UNA ZONA DE POLIMERIZACION A TRAVES DE LA CUAL PASA UNA MEZCLA DE REACCION ESENCIALMENTE GASEOSA QUE COMPRENDE LOS (CO-)MONOMEROS. ADEMAS, EL PROCESO COMPRENDE LA TRANSFERENCIA DE UNA MEZCLA (A) FORMADA POR LA MEZCLA DE REACCION GASEOSA Y EL (CO-)POLIMERO SOLIDO EN UNA ZONA DE DESPRESURIZACION, Y LA SEPARACION DE LA MEZCLA (A) EN UNA FASE SOLIDA (B) Y UNA FASE GASEOSA (C) QUE SE HACE RETORNAR A LA ZONA DE POLIMERIZACION. LA FASE SOLIDA (B) SE EXPONE A (1) AL MENOS UN LAVADO NO DESACTIVANTE CON RESPECTO A LOS RESIDUOS CATALITICOS ACTIVOS, Y SUBSECUENTEMENTE (2) A UN LAVADO DE DESACTIVACION CON UNA MEZCLA GASEOSA DE NITROGENO, AGUA Y OXIGENO. EL (CO-)POLIMERO ASI OBTENIDO TIENE MUY BAJOS CONTENIDOS DE (CO-)MONOMEROS NO REACCIONADOS Y COMPUESTOS ORGANICOS VOLATILES, Y EXHIBE UN ALTO INDICE DE BLANCURA Y UNA LARGA ESTABILIDAD TERMICA A LO LARGO DEL TIEMPO.
ES95303163T 1994-05-16 1995-05-10 Proceso para la polimerizacion de olefinas en fase gaseosa. Expired - Lifetime ES2113710T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9406221A FR2719847B1 (fr) 1994-05-16 1994-05-16 Procédé de polymérisation d'oléfine en phase gazeuse.

Publications (1)

Publication Number Publication Date
ES2113710T3 true ES2113710T3 (es) 1998-05-01

Family

ID=9463419

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95303163T Expired - Lifetime ES2113710T3 (es) 1994-05-16 1995-05-10 Proceso para la polimerizacion de olefinas en fase gaseosa.

Country Status (15)

Country Link
US (1) US5789501A (es)
EP (1) EP0683176B1 (es)
JP (1) JP3606477B2 (es)
KR (1) KR100346670B1 (es)
CN (1) CN1118786A (es)
CA (1) CA2149374A1 (es)
DE (1) DE69501850T2 (es)
EG (1) EG20607A (es)
ES (1) ES2113710T3 (es)
FI (1) FI952376A (es)
FR (1) FR2719847B1 (es)
HK (1) HK1010055A1 (es)
MY (1) MY118447A (es)
NO (1) NO307658B1 (es)
TW (1) TW357152B (es)

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WO2002083754A1 (en) 2001-04-12 2002-10-24 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
FR2774991B1 (fr) 1998-02-18 2000-03-17 Inst Francais Du Petrole Procede de polymerisation en presence d'alpha-olefines
EP1522553B1 (en) 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US6022946A (en) * 1998-12-23 2000-02-08 Union Carbide Chemicals & Plastics Technology Corporation Process for deactivation of polyolefin compositions utilizing carbon dioxide as a deactivation agent
US6111034A (en) * 1998-12-31 2000-08-29 Union Carbide Chemicals & Plastics Technology Corporation Static control in olefin polymerization
DE19922677C1 (de) 1999-05-18 2001-04-19 Elenac Gmbh Verfahren zum Trocknen und Entgasen von Polyolefinen und nach diesem Verfahren hergestelltes Polyethylen
US7776998B2 (en) 2002-10-30 2010-08-17 Ineos Manufacturing Belgium Nv Polymer treatment
WO2005111091A1 (en) * 2004-04-30 2005-11-24 Dow Global Technologies Inc. Reduction of discoloration in polyolefin resins
DE102005005506A1 (de) * 2005-02-04 2006-08-10 Basell Polyolefine Gmbh Verfahren und Vorrichtung zur Polymerisation von Ethylen
CA2659237A1 (en) 2006-08-03 2008-02-07 Basell Polyolefine Gmbh Process for the polyolefin finishing
EP2172495A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Method for the production of polymers
EP2172494A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Process
EP2376220A1 (en) * 2008-12-18 2011-10-19 ExxonMobil Chemical Patents Inc. High pressure polymerization process
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
WO2013056979A1 (en) * 2011-10-17 2013-04-25 Ineos Europe Ag Polymer degassing process control
EP2743278A1 (en) 2012-12-11 2014-06-18 Basell Polyolefine GmbH Process for degassing and buffering polyolefin particles obtained by olefin polymerization
EP2743279A1 (en) 2012-12-11 2014-06-18 Basell Polyolefine GmbH Process for treating polyolefin particles obtained by gas-phase polymerization
EP2796472B1 (en) 2013-04-22 2017-06-28 Borealis AG Two-stage process for producing polypropylene compositions
EP3235832B1 (en) 2013-04-22 2018-06-20 Borealis AG Polypropylene compositions
ES2628082T3 (es) 2013-04-22 2017-08-01 Borealis Ag Procedimiento con múltiples etapas para producir composiciones de polipropileno resistentes a baja temperatura
EP2853562A1 (en) 2013-09-27 2015-04-01 Borealis AG Two-stage process for producing polypropylene compositions
EP2860203B1 (en) 2013-10-10 2016-12-14 Borealis AG Multistage process for producing polyethylene compositions
EP2883887A1 (en) 2013-12-13 2015-06-17 Borealis AG Multistage process for producing polyethylene compositions
EP2883885A1 (en) 2013-12-13 2015-06-17 Borealis AG Multistage process for producing polyethylene compositions
US9745389B2 (en) 2014-02-26 2017-08-29 Ineos Europe Ag Polymerisation process and polymerisation unit comprising a degassing section
EP2913346B1 (en) 2014-02-28 2016-11-02 Borealis AG Process for polymerizing olefins in a fluidized bed
EP2913345B1 (en) 2014-02-28 2016-11-02 Borealis AG Gas phase polymerization process
US10308737B2 (en) 2014-09-30 2019-06-04 Borealis Ag Process for polymerising ultra-high molecular weight polyethylene
BR112017005285B1 (pt) 2014-12-08 2021-09-28 Borealis Ag Processo para extrudar e peletizar um copolímero de propileno
KR101894687B1 (ko) 2015-02-20 2018-10-04 보레알리스 아게 프로필렌의 헤테로상의 공중합체를 제조하기 위한 공정
PL3103818T3 (pl) 2015-06-12 2018-12-31 Borealis Ag Sposób i aparat do polimeryzacji olefin w fazie gazowej
EP3109261B1 (en) 2015-06-23 2018-12-26 Borealis AG Process for producing lldpe resins
EP3184166A1 (en) 2015-12-22 2017-06-28 Borealis AG A method for withdrawing agglomerates from a fluidised bed reactor
EP3184167B8 (en) 2015-12-22 2022-03-30 Borealis AG A method for returning polymer to a fluidised bed reactor
EP3464457B1 (en) 2016-05-31 2021-09-01 Borealis AG Polymer composition and a process for production of the polymer composition
US20190256695A1 (en) 2016-06-22 2019-08-22 Borealis Ag Polymer composition and a process for production of the polymer composition
PL3519444T3 (pl) 2016-09-28 2021-05-04 Borealis Ag Proces wytwarzania powlekanej rury
EP3544815B1 (en) 2016-11-25 2020-12-30 Borealis AG A process for producing polyolefin film composition and films prepared thereof
EP3545033B1 (en) 2016-11-25 2023-06-14 Borealis AG New composition and process
GB201620525D0 (en) 2016-12-02 2017-01-18 Ineos Europe Ag Process
EP3418308B1 (en) 2017-06-20 2020-03-11 Borealis AG A method, an arrangement and use of an arrangement for olefin polymerisation
EP3418309A1 (en) 2017-06-20 2018-12-26 Borealis AG A method, an arrangement and use of an arrangement of preparing polymer
EP3418330B2 (en) 2017-06-21 2023-07-19 Borealis AG Polymer composition and a process for production of the polymer composition
ES2786567T3 (es) 2017-06-23 2020-10-13 Borealis Ag Procedimiento y aparato para la retirada de material polimérico de un reactor de polimerización de olefinas con gases y sólido
US10730032B2 (en) * 2018-05-16 2020-08-04 Chevron Phillips Chemical Company Lp Polymer flake degassing system and methods
CA3095977C (en) 2018-06-14 2023-07-04 Borealis Ag Process for polymerizing olefin in a gas phase reactor with improved thermal homogeneity
WO2020136165A1 (en) 2018-12-28 2020-07-02 Borealis Ag A process for producing polyolefin film composition and films prepared thereof
WO2020136164A1 (en) 2018-12-28 2020-07-02 Borealis Ag A process for producing polyolefin film composition and films prepared thereof
US20220306774A1 (en) 2019-06-24 2022-09-29 Borealis Ag Process for preparing polypropylene with improved recovery
EP3868793A1 (en) 2020-02-24 2021-08-25 Borealis AG Process for producing alpha-olefin polymers in a multistage polymerization process
CN117480191A (zh) 2021-06-11 2024-01-30 博里利斯股份公司 一种生产多峰乙烯聚合物的方法以及由其制备的薄膜
EP4344869A1 (en) 2022-09-30 2024-04-03 Borealis AG Multimodal ethylene copolymer composition and films comprising the same
WO2024083689A1 (en) 2022-10-18 2024-04-25 Borealis Ag Multilayer film

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* Cited by examiner, † Cited by third party
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JPS5231269B2 (es) * 1974-06-13 1977-08-13
DE2735355A1 (de) * 1977-08-05 1979-02-15 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des aethylens
US4156075A (en) * 1977-08-29 1979-05-22 Eastman Kodak Company Two step polyolefin catalyst deactivation
US4314053A (en) * 1980-05-08 1982-02-02 Standard Oil Company (Indiana) Process for reducing polyolefin die smoke
US4372758A (en) * 1980-09-02 1983-02-08 Union Carbide Corporation Degassing process for removing unpolymerized monomers from olefin polymers
US4758654A (en) * 1987-04-28 1988-07-19 Union Carbide Corporation Method for treating resin in a purge vessel
DE3815487A1 (de) * 1988-05-06 1989-11-16 Basf Ag Verfahren zur niederdruckcopolymerisation von ethylen mit (alpha)-olefinen und ethylencopolymerisate mit niederem restmonomerengehalt

Also Published As

Publication number Publication date
FR2719847A1 (fr) 1995-11-17
TW357152B (en) 1999-05-01
KR100346670B1 (ko) 2002-11-29
DE69501850T2 (de) 1998-07-16
FR2719847B1 (fr) 1996-08-09
MY118447A (en) 2004-11-30
FI952376A0 (fi) 1995-05-16
JP3606477B2 (ja) 2005-01-05
NO951910L (no) 1995-11-17
JPH0841115A (ja) 1996-02-13
US5789501A (en) 1998-08-04
EG20607A (en) 1999-09-30
EP0683176A1 (en) 1995-11-22
NO307658B1 (no) 2000-05-08
NO951910D0 (no) 1995-05-15
FI952376A (fi) 1995-11-17
DE69501850D1 (de) 1998-04-30
CA2149374A1 (en) 1995-11-17
CN1118786A (zh) 1996-03-20
HK1010055A1 (en) 1999-06-11
KR950032310A (ko) 1995-12-20
EP0683176B1 (en) 1998-03-25

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