ES2100927T3 - Copolimeros elastomeros solidos de bloques y aleatorios. - Google Patents
Copolimeros elastomeros solidos de bloques y aleatorios.Info
- Publication number
- ES2100927T3 ES2100927T3 ES91300315T ES91300315T ES2100927T3 ES 2100927 T3 ES2100927 T3 ES 2100927T3 ES 91300315 T ES91300315 T ES 91300315T ES 91300315 T ES91300315 T ES 91300315T ES 2100927 T3 ES2100927 T3 ES 2100927T3
- Authority
- ES
- Spain
- Prior art keywords
- block
- polymer
- copolymer
- disclosed
- conjugated diene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/94—Hydrogenation of a polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Materials For Medical Uses (AREA)
- Polyurethanes Or Polyureas (AREA)
- Silicon Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Dental Preparations (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
SE DESCRIBE UN BLOQUE LINEAL DE COPOLIMERO QUE CONSTA DE AL MENOS UN TRIBLOQUE I-B-I, EN DONDE I ES UN BLOQUE DE UN DIENO POLIMERIZADO CONJUGADO , DIFERENTE DE LA FORMULA (1), DE AL MENOS 4 ATOMOS DE CARBONO, COMO POR EJEMPLO 1,3-BUTADIENO. EL BLOQUE B ES SELECTIVAMENTE HIDROGENADO, DONDE CADA UNO DE LOS BLOQUES I RETIENE UNA CANTIDAD SUFICIENTE DE SU INSATURACION ORIGINAL PARA VULCANIZAR EL COPOLIMERO. TAMBIEN SE DESCRIBE UN BLOQUE LINEAL DE COPOLIMERO ALTERNATIVO QUE CONTIENE AL MENOS UN TRIBLOQUE DEL PRIMER BLOQUE DE POLIMERO HECHO A PARTIR DE UNA OLEFINA ARIL SUSTITUIDA, COMO POR EJEMPLO EL ESTIRENO, Y EL DIENO CONJUGADO UTILIZADO PARA POLIMERIZAR EL BLOQUE I, LA SEGUNDA MITAD DEL BLOQUE DEL POLIMERO DEL DIENO UTILIZADO PARA POLIMERIZAR EL BLOQUE B, Y EL TERCER BLOQUE DE POLIMERO QUE ES IDENTICO AL PRIMER BLOQUE. EN ESTE COPOLIMERO ALTERNATIVO EL BLOQUE MEDIO ES TAMBIEN SELECTIVAMENTE HIDROGENADO, DEJANDO DE ESE MODO LOS BLOQUES DE POLIMERO TERMINAL CON UNA CANTIDAD SUFICIENTE DE DOBLESENLACES PARA VULCANIZAR EL COPOLIMERO. LOS POLIMEROS PUEDEN SER ENTRECRUZADOS O FUNCIONALIZADOS A TRAVES DE LOS BLOQUES TERMINALES QUE CONTIENEN LA INSATURACION DE VINILO. TAMBIEN SE DESCRIBE UN BLOQUE ALEATORIO Y RAMIFICADO, Y COPOLIMEROS CASUALES HECHOS DE LOS MISMOS MONOMEROS, COMO LOS COPOLIMEROS DE UN BLOQUE LINEAL. TAMBIEN SE DESCRIBEN METODOS DE PRODUCCION Y DE LA HIDROGENACION SELECTIVA DE LOS POLIMEROS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/466,233 US5187236A (en) | 1990-01-16 | 1990-01-16 | Solid block and random elastomeric copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2100927T3 true ES2100927T3 (es) | 1997-07-01 |
Family
ID=23850994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91300315T Expired - Lifetime ES2100927T3 (es) | 1990-01-16 | 1991-01-16 | Copolimeros elastomeros solidos de bloques y aleatorios. |
Country Status (17)
Country | Link |
---|---|
US (4) | US5187236A (es) |
EP (1) | EP0438287B1 (es) |
JP (1) | JPH07116271B2 (es) |
KR (1) | KR0185401B1 (es) |
CN (3) | CN1050849C (es) |
AT (1) | ATE152144T1 (es) |
AU (1) | AU649989B2 (es) |
BR (1) | BR9100181A (es) |
CA (1) | CA2034194C (es) |
DE (1) | DE69125732T2 (es) |
DK (1) | DK0438287T3 (es) |
ES (1) | ES2100927T3 (es) |
FI (1) | FI101888B (es) |
GR (1) | GR3023816T3 (es) |
IE (1) | IE910121A1 (es) |
NO (2) | NO301935B1 (es) |
PT (1) | PT96498B (es) |
Families Citing this family (66)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6034184A (en) * | 1998-06-23 | 2000-03-07 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: Mannich reaction products |
US6228817B1 (en) | 1990-01-16 | 2001-05-08 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers |
US5276100A (en) * | 1990-01-16 | 1994-01-04 | Mobil Oil Corporation | Solid elastomeric block copolymers |
US5359009A (en) * | 1990-01-16 | 1994-10-25 | Mobil Oil Corporation | Method for making solid elastomeric block copolymers |
US6103676A (en) * | 1998-06-23 | 2000-08-15 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: hydroformylation/reductive amination reaction products |
US5663239A (en) * | 1990-01-16 | 1997-09-02 | Mobil Oil Corporation | Star-branched block elastomeric copolymers |
US5637783A (en) * | 1990-01-16 | 1997-06-10 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers |
US5268427A (en) * | 1990-01-16 | 1993-12-07 | Mobil Oil Corporation | Solid block and random elastomeric copolymers |
US5773524A (en) * | 1990-01-16 | 1998-06-30 | Mobil Oil Corporation | Epoxidized liquid elastomeric copolymers |
US6162768A (en) * | 1990-01-16 | 2000-12-19 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: free radically initiated direct grafting reaction products |
US5292820A (en) * | 1990-01-16 | 1994-03-08 | Mobil Oil Corporation | Solid elastomeric block copolymers |
US5210359A (en) * | 1990-01-16 | 1993-05-11 | Mobil Oil Corporation | Vulcanizable liquid compositions |
US6054539A (en) * | 1998-07-31 | 2000-04-25 | Mobil Oil Corporation | Selectively hydrogenated polymer compositions: polybutadiene-isoprene-polybutadiene |
US5633415A (en) * | 1990-01-16 | 1997-05-27 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers |
US5780540A (en) * | 1990-01-16 | 1998-07-14 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers |
US6248702B1 (en) | 1990-01-16 | 2001-06-19 | Mobil Oil Corporation | Dispersant and dispersant viscosity index improvers from selectively hydrogenated aryl-substituted olefin containing diene copolymers |
US5310490A (en) * | 1991-03-13 | 1994-05-10 | Exxon Chemical Products Inc. | Viscosity modifer polymers |
US5310814A (en) * | 1991-03-15 | 1994-05-10 | Exxon Chemical Patents Inc. | Viscosity modifier polybutadiene polymers |
US5382604A (en) * | 1991-10-07 | 1995-01-17 | Shell Oil Company | Crosslinked epoxy functionalized polydiene block polymers and adhesives |
US5399626A (en) * | 1991-04-29 | 1995-03-21 | Shell Oil Company | Viscous conjugated diene block copolymers |
US5229464A (en) * | 1991-04-29 | 1993-07-20 | Shell Oil Company | Epoxidized viscous conjugated diene block copolymers |
US5686535A (en) * | 1991-04-29 | 1997-11-11 | Shell Oil Company | Viscous conjugated diene block copolymers |
WO1995025136A1 (en) * | 1992-03-05 | 1995-09-21 | Exxon Research And Engineering Co. | Sulfonated unhydrogenated copolymers of styrene and butadiene |
US5247026A (en) * | 1992-06-19 | 1993-09-21 | Shell Oil Company | Randomly epoxidized small star polymers |
CA2121522C (en) * | 1993-04-23 | 2001-12-25 | Makoto Nishikawa | Thermoplastic polymer composition |
US5536772A (en) * | 1993-06-18 | 1996-07-16 | Shell Oil Company | Radiation cured conjugated diene block copolymer compositions |
US5438102A (en) * | 1993-06-24 | 1995-08-01 | Mobil Oil Corporation | Solid elastomeric block copolymers |
USH1517H (en) * | 1993-07-12 | 1996-02-06 | Shell Oil Company | Radiation curable printing ink composition |
USH1786H (en) * | 1993-07-12 | 1999-02-02 | Shell Oil Company | Process for radiation cured conjugated diene-vinyl aromatic hydrocarbon block copolymers |
US5589542A (en) * | 1993-11-03 | 1996-12-31 | Shell Oil Company | Multiblock hydrogenated polymers for adhesives |
US5571865A (en) * | 1994-05-16 | 1996-11-05 | Kuraray Co., Ltd. | Thermoplastic polymer composition |
DE69623083T2 (de) * | 1995-07-05 | 2003-04-30 | Bridgestone Corp | Kautschukmischung für Reifenlauffläche |
US5623019A (en) * | 1995-07-13 | 1997-04-22 | Bayer Corporation | Compatibilized thermoplastic molding composition |
US6215033B1 (en) | 1998-12-11 | 2001-04-10 | Mobil Oil Corporation | Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: blends with lower molecular weight components |
US6319881B1 (en) | 1998-06-23 | 2001-11-20 | Exxonmobil Oil Corporation | Haze free oil additive compositions containing dispersants from selectively hydrogenated diene copolymers |
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CA2377195A1 (fr) * | 2000-04-25 | 2001-11-01 | Michelin Recherche Et Technique S.A. | Copolymeres a blocs pour des compositions de caoutchouc utilisables pour des pneumatiques |
US6492439B2 (en) * | 2000-12-28 | 2002-12-10 | Firestone Polymers, Llc | Asphalt compositions |
US7962226B2 (en) * | 2001-04-06 | 2011-06-14 | Cochlear Limited | Cochlear endosteal electrode carrier member |
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AR037598A1 (es) * | 2001-11-30 | 2004-11-17 | Tredegar Film Prod Corp | Compuesto suave y elastico |
US7241540B2 (en) * | 2004-04-27 | 2007-07-10 | Kraton Polymers U.S. Llc | Photocurable compositions and flexographic printing plates comprising the same |
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JP5140918B2 (ja) * | 2004-10-29 | 2013-02-13 | Jsr株式会社 | ゴム組成物及び成形品 |
EP1652867A1 (en) * | 2004-10-29 | 2006-05-03 | JSR Corporation | Block copolymer, rubber composition containing the same and molded product |
EP2230265A1 (en) | 2006-08-08 | 2010-09-22 | Asahi Kasei Chemicals Corporation | Hydrogenated block copolymers and crosslinking compositions containing the same |
US7429635B2 (en) * | 2006-09-28 | 2008-09-30 | Equistar Chemicals, Lp | Preparation of ultra high molecular weight linear low density polyethylene |
FR2918064B1 (fr) * | 2007-06-28 | 2010-11-05 | Michelin Soc Tech | Procede de preparation d'un copolymere dienique a bloc polyether, composition de caoutchouc renforcee et enveloppe de pneumatique. |
JP5650405B2 (ja) * | 2008-02-08 | 2015-01-07 | 旭化成ケミカルズ株式会社 | 熱可塑性エラストマー組成物及びその製造方法 |
US8772210B2 (en) * | 2008-03-31 | 2014-07-08 | Exxonmobil Research And Engineering Company | High viscosity index PAO with polyurea thickeners in grease compositions |
US8247358B2 (en) * | 2008-10-03 | 2012-08-21 | Exxonmobil Research And Engineering Company | HVI-PAO bi-modal lubricant compositions |
US20110169384A1 (en) * | 2010-01-13 | 2011-07-14 | Brass Smith, LLC (Subsidiary of Kevry Corp.) | Food shield |
US9188276B2 (en) | 2010-06-10 | 2015-11-17 | Metal & Cable Corp., Inc. | Magnetic mounting system |
US9472937B2 (en) | 2010-08-27 | 2016-10-18 | Metal & Cable Corp., Inc. | Cable/cable tray mount |
JP6106658B2 (ja) * | 2012-03-01 | 2017-04-05 | 住友ゴム工業株式会社 | 分枝共役ジエン重合体の製造方法 |
JP6159574B2 (ja) * | 2013-05-16 | 2017-07-05 | 住友ゴム工業株式会社 | 分枝共役ジエン共重合体および水添分枝共役ジエン共重合体、ゴム組成物、並びに空気入りタイヤ |
JP6164927B2 (ja) * | 2013-05-16 | 2017-07-19 | 住友ゴム工業株式会社 | 空気入りタイヤ |
IN2013MU03272A (es) | 2013-10-18 | 2015-07-17 | Reliance Ind Ltd | |
JP7119343B2 (ja) * | 2017-11-02 | 2022-08-17 | 住友ゴム工業株式会社 | ジエン系共重合体及びゴム組成物 |
JP7119342B2 (ja) * | 2017-11-02 | 2022-08-17 | 住友ゴム工業株式会社 | ジエン系共重合体及びゴム組成物 |
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MX2022005463A (es) * | 2019-11-07 | 2022-07-12 | Dynasol Elastomeros Sa De Cv | Copolimeros de dieno modificados y su uso. |
CN111053945B (zh) * | 2019-12-30 | 2021-12-10 | 安徽雄亚塑胶科技有限公司 | 一种环保高强度高回弹tpe止血带材料及其制备方法 |
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-
1990
- 1990-01-16 US US07/466,233 patent/US5187236A/en not_active Expired - Lifetime
-
1991
- 1991-01-15 AU AU69337/91A patent/AU649989B2/en not_active Ceased
- 1991-01-15 NO NO910160A patent/NO301935B1/no not_active IP Right Cessation
- 1991-01-15 IE IE012191A patent/IE910121A1/en unknown
- 1991-01-15 CA CA002034194A patent/CA2034194C/en not_active Expired - Fee Related
- 1991-01-15 FI FI910215A patent/FI101888B/fi active IP Right Grant
- 1991-01-16 PT PT96498A patent/PT96498B/pt not_active IP Right Cessation
- 1991-01-16 DK DK91300315.8T patent/DK0438287T3/da active
- 1991-01-16 EP EP91300315A patent/EP0438287B1/en not_active Expired - Lifetime
- 1991-01-16 JP JP3216663A patent/JPH07116271B2/ja not_active Expired - Fee Related
- 1991-01-16 CN CN91101111A patent/CN1050849C/zh not_active Expired - Fee Related
- 1991-01-16 DE DE69125732T patent/DE69125732T2/de not_active Expired - Lifetime
- 1991-01-16 AT AT91300315T patent/ATE152144T1/de not_active IP Right Cessation
- 1991-01-16 ES ES91300315T patent/ES2100927T3/es not_active Expired - Lifetime
- 1991-01-16 BR BR9100181-1A patent/BR9100181A/pt not_active IP Right Cessation
- 1991-01-16 KR KR1019910000863A patent/KR0185401B1/ko not_active IP Right Cessation
-
1993
- 1993-03-11 US US08/029,507 patent/US5306780A/en not_active Expired - Lifetime
-
1994
- 1994-04-11 US US08/225,681 patent/US5376722A/en not_active Expired - Lifetime
- 1994-12-21 US US08/361,072 patent/US5457161A/en not_active Expired - Fee Related
-
1997
- 1997-06-19 GR GR970401454T patent/GR3023816T3/el unknown
- 1997-08-04 NO NO973582A patent/NO973582D0/no not_active Application Discontinuation
-
1998
- 1998-07-13 CN CN98115496A patent/CN1221001A/zh active Pending
-
1999
- 1999-05-29 CN CN99107124A patent/CN1248585A/zh active Pending
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