ES2099599T3 - Procedimiento para la desulfuracion de gases y recuperacion de azufre. - Google Patents

Procedimiento para la desulfuracion de gases y recuperacion de azufre.

Info

Publication number
ES2099599T3
ES2099599T3 ES94909972T ES94909972T ES2099599T3 ES 2099599 T3 ES2099599 T3 ES 2099599T3 ES 94909972 T ES94909972 T ES 94909972T ES 94909972 T ES94909972 T ES 94909972T ES 2099599 T3 ES2099599 T3 ES 2099599T3
Authority
ES
Spain
Prior art keywords
sulfur
desulfuration
gases
recovery
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94909972T
Other languages
English (en)
Inventor
Andre Philippe
Jean Nougayrede
Georges Kvasnikoff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Societe Nationale Elf Aquitaine Production SA
Original Assignee
Societe National Elf Aquitaine
Societe Nationale Elf Aquitaine Production SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe National Elf Aquitaine, Societe Nationale Elf Aquitaine Production SA filed Critical Societe National Elf Aquitaine
Application granted granted Critical
Publication of ES2099599T3 publication Critical patent/ES2099599T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
    • C01B17/0469—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide at least one catalyst bed operating below the dew-point of sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Industrial Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

EL GAS QUE SE TRATA CONTIENE H2S Y SE SOMETE A UNA OXIDACION CATALITICA (A) DEL H2S EN AZUFRE A TEMPERATURAS EN EL INTERVALO DE 60 (GRADOS) C A 180 (GRADOS) C CON DEPOSITO DE AZUFRE FORMADO EN EL CATALIZADOR Y REGENERACION PERIODICA DEL CATALIZADOR CARGADO DE AZUFRE (1B), A CONTINUACION SE ENFRIA EL CATALIZADOR REGENERADO EN EL INTERVALO DE 60 (GRADOS) C A 180 (GRADOS) C PARA UNA REUTILIZACION EN LA FASE DE OXIDACION CATALITICA.
ES94909972T 1993-03-16 1994-03-16 Procedimiento para la desulfuracion de gases y recuperacion de azufre. Expired - Lifetime ES2099599T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9302994A FR2702673B1 (fr) 1993-03-16 1993-03-16 Procédé d'élimination de l'H2S contenu dans un gaz en concentration inférieure à 5 % en volume avec récupération de cet H2S sous la forme de soufre.

Publications (1)

Publication Number Publication Date
ES2099599T3 true ES2099599T3 (es) 1997-05-16

Family

ID=9444992

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94909972T Expired - Lifetime ES2099599T3 (es) 1993-03-16 1994-03-16 Procedimiento para la desulfuracion de gases y recuperacion de azufre.

Country Status (11)

Country Link
EP (1) EP0640058B1 (es)
JP (1) JPH07509438A (es)
CN (1) CN1043029C (es)
AT (1) ATE147710T1 (es)
CA (1) CA2135906A1 (es)
DE (1) DE69401473T2 (es)
DK (1) DK0640058T3 (es)
ES (1) ES2099599T3 (es)
FR (1) FR2702673B1 (es)
RU (1) RU2114685C1 (es)
WO (1) WO1994021555A1 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2727101B1 (fr) * 1994-11-17 1996-12-20 Elf Aquitaine Procede pour oxyder directement en soufre par voie catalytique l'h2s contenu en faible concentration dans un gaz et catalyseur pour la mise en oeuvre de ce procede
FR2734809B1 (fr) * 1995-05-30 1997-07-18 Elf Aquitaine Procede de desulfuration catalytique d'un gaz renfermant les composes h2s et so2 et eventuellement cos et/ou cs2, avec recuperation desdits composes sous la forme de soufre et catalyseur pour la mise en oeuvre dudit procede
FR2740767B1 (fr) * 1995-11-03 1997-12-26 Elf Aquitaine Procede d'oxydation complete en soufre de l'h2s present dans un gaz et son application a la recuperation quasi totale, sous la forme de soufre, des composes soufres contenus dans un gaz residuaire d'usine a soufre
NL1002524C2 (nl) * 1996-03-04 1997-09-05 Gastec Nv Katalysator voor de selectieve oxidatie van zwavelverbindingen tot elementaire zwavel, werkwijze voor de bereiding van een dergelijke kata- lysator en werkwijze voor de selectieve oxidatie van zwavelverbindingen elementaire zwavel.
FR2757084B1 (fr) * 1996-12-13 1999-01-29 Rhodia Chimie Sa Utilisation pour l'oxydation directe des composes soufres en soufre et/ou sulfates a basse temperature d'un catalyseur a base de molybdene
FR2762592B1 (fr) * 1997-04-24 1999-06-18 Elf Aquitaine Procede d'elimination des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre avec recuperation desdits composes sous la forme de soufre
FR2857276B1 (fr) * 2003-07-11 2006-08-11 Inst Francais Du Petrole Procede d'elimination de composes soufres par oxydation directe
CA2586381C (en) * 2004-11-09 2011-02-08 Fluor Technologies Corporation Configurations and methods for sox removal in oxygen-containing gases
EP2536660A2 (en) * 2010-02-18 2012-12-26 Shell Internationale Research Maatschappij B.V. Process for selective oxidation of hydrogen sulphide
CN101791517B (zh) * 2010-04-08 2012-05-23 北京至清时光环保工程技术有限公司 一种从含有硫化氢的酸性气体中回收硫的方法
CN104307360A (zh) * 2014-10-28 2015-01-28 南京大学（苏州）高新技术研究院 一种气相脱硫氧化剂及其应用和脱除硫化氢的方法
EP3067109B1 (en) * 2015-03-12 2018-12-05 Prosernat Process for removing sulfur compounds from a gas with hydrogenation and direct oxidation steps
CN107233794B (zh) * 2016-03-29 2020-04-10 中国石油天然气集团有限公司 一种去除气体中硫化氢的方法
CN106698360B (zh) * 2016-12-14 2019-04-09 山东迅达化工集团有限公司 低浓度酸性气的硫磺回收工艺
CN106629625B (zh) * 2016-12-14 2019-04-05 山东迅达化工集团有限公司 处理低浓度酸性气的硫磺回收工艺
CN107442159B (zh) * 2017-09-06 2020-07-21 淄博天净环保技术有限公司 选择性氧化硫化氢成元素硫的催化剂及其制备方法和应用
CN109095468A (zh) * 2017-12-27 2018-12-28 山西铁峰化工有限公司 一种以硫化氢为原料制备二硫化碳的方法
CN110124477B (zh) * 2018-02-09 2021-06-25 中国石油化工股份有限公司 用于分解硫化氢的催化剂装填方法和分解硫化氢的方法
CN112316655B (zh) * 2020-08-31 2022-07-22 中石化南京化工研究院有限公司 一种脱除气体中的h2s并回收硫黄的方法
CN113652271A (zh) * 2021-08-06 2021-11-16 德微科技有限公司 脱硫剂再生方法和脱硫-再生方法及系统
CN113652270B (zh) * 2021-08-06 2023-03-14 德微科技有限公司 脱硫方法、装置及系统
CN114132962A (zh) * 2021-12-13 2022-03-04 武汉科技大学 一种利用液相氢还原制备三氧化二钒的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3143400A1 (de) * 1981-11-02 1983-06-01 Mobil Oil Corp., 10017 New York, N.Y. Verfahren zur verringerung des schwefelgehaltes in gasstroemen unter gewinnung von elementarem schwefel
DE3740439A1 (de) * 1987-11-28 1989-06-08 Veg Gasinstituut Nv Verfahren zur entfernung von schwefelwasserstoff aus gasen
FR2658091B1 (fr) * 1990-02-13 1992-05-07 Elf Aquitaine Procede de desulfuration d'un melange gazeux renfermant h2s et so2 avec recuperation desdits composes sous la forme de soufre.
DE4025471A1 (de) * 1990-08-10 1992-02-13 Linde Ag Verfahren zur schwefelrueckgewinnung aus einem h(pfeil abwaerts)2(pfeil abwaerts)s-haltigen gasstrom unter hohem druck

Also Published As

Publication number Publication date
EP0640058B1 (fr) 1997-01-15
RU94046134A (ru) 1996-09-20
ATE147710T1 (de) 1997-02-15
DK0640058T3 (da) 1997-07-07
JPH07509438A (ja) 1995-10-19
DE69401473D1 (de) 1997-02-27
CN1105178A (zh) 1995-07-12
RU2114685C1 (ru) 1998-07-10
FR2702673B1 (fr) 1995-04-28
CA2135906A1 (fr) 1994-09-29
CN1043029C (zh) 1999-04-21
DE69401473T2 (de) 1997-07-17
FR2702673A1 (fr) 1994-09-23
EP0640058A1 (fr) 1995-03-01
WO1994021555A1 (fr) 1994-09-29

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