ES2090938T3 - Compuestos sulfonio seleccionados, idoneos en particular como iniciadores para la reticulacion termica de material polimerizable cationicamente. - Google Patents

Compuestos sulfonio seleccionados, idoneos en particular como iniciadores para la reticulacion termica de material polimerizable cationicamente.

Info

Publication number
ES2090938T3
ES2090938T3 ES93810499T ES93810499T ES2090938T3 ES 2090938 T3 ES2090938 T3 ES 2090938T3 ES 93810499 T ES93810499 T ES 93810499T ES 93810499 T ES93810499 T ES 93810499T ES 2090938 T3 ES2090938 T3 ES 2090938T3
Authority
ES
Spain
Prior art keywords
alcoxi
compounds
cationically polymerizable
polymerizable material
ring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93810499T
Other languages
English (en)
Inventor
Beat Dr Muller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Application granted granted Critical
Publication of ES2090938T3 publication Critical patent/ES2090938T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/76Dibenzothiophenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • C07C381/12Sulfonium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D327/00Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms
    • C07D327/02Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms one oxygen atom and one sulfur atom
    • C07D327/06Six-membered rings
    • C07D327/08[b,e]-condensed with two six-membered carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D339/00Heterocyclic compounds containing rings having two sulfur atoms as the only ring hetero atoms
    • C07D339/08Six-membered rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/226Mixtures of di-epoxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/687Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08Saturated oxiranes
    • C08G65/10Saturated oxiranes characterised by the catalysts used
    • C08G65/105Onium compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)

Abstract

SE DESCRIBEN COMPUESTOS SULFONICO DE FORMULA (1) O (2). LOS COMPUESTOS SON APROPIADOS COMO ENDURECEDORES TERMICOS PARA MATERIAL POLIMERIZABLE CATIONICAMENTE. SIENDO: R, UN RESTO CICLOALQUILO MONONUCLEADO CON C 3 A 8 EN EL ANILLO O UN RESTO CICLOALQUILO MONONUCLEADO CON C 3 A 8 EN EL ANILLO, EN LA QUE ESTA ANILLADO UN ANILLO CONTENIENDO OTRO ATOMO DE CARBONO; X, UN ANION NO NUCLEOFILO Y Z, UN ENLACE SENCILLO, UN ATOMO DE OXIGENO O DE AZUFRE, UN GRUPO DE FORMULA >5+-RX-. TENIENDO R Y X UN SIGNIFICADO MENCIONADO Y >C=0 O UN PUENTE DE METILENO. LOS COMPUESTOS PUEDEN ESTAR NO SUBSTITUIDOS O PRESENTAR UNO O VARIOS SUBSTITUYENTES SELECCIONADOS DEL GRUPO HIDROGENO, NITRO, ALQUILO DE C 1 A 8, FENILO, HIDROXILO, ALCOXI DE C 1 A 8, FENOXI, BENCILOXI, ALCOXICARBONILO DE C 1 A 4 EN EL RESTO ALCOXI O ACILO DE C 1 A 12.
ES93810499T 1992-07-21 1993-07-13 Compuestos sulfonio seleccionados, idoneos en particular como iniciadores para la reticulacion termica de material polimerizable cationicamente. Expired - Lifetime ES2090938T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH229192 1992-07-21

Publications (1)

Publication Number Publication Date
ES2090938T3 true ES2090938T3 (es) 1996-10-16

Family

ID=4230346

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93810499T Expired - Lifetime ES2090938T3 (es) 1992-07-21 1993-07-13 Compuestos sulfonio seleccionados, idoneos en particular como iniciadores para la reticulacion termica de material polimerizable cationicamente.

Country Status (9)

Country Link
US (1) US5374697A (es)
EP (1) EP0580552B1 (es)
JP (1) JP3548967B2 (es)
KR (1) KR100280015B1 (es)
BR (1) BR9302930A (es)
CA (1) CA2100815A1 (es)
DE (1) DE59303487D1 (es)
ES (1) ES2090938T3 (es)
TW (1) TW237466B (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0776917B1 (de) 1995-11-29 2002-05-29 Vantico AG Core/Shell-Partikel und diese enthaltende härtbare Epoxidharzzusammensetzungen
US6093493A (en) * 1997-07-03 2000-07-25 Ciba Specialty Chemicals Corp. Method for the coating or encapsulation of fluidizable substrates
KR100279497B1 (ko) * 1998-07-16 2001-02-01 박찬구 술포늄 염의 제조방법
US6764616B1 (en) 1999-11-29 2004-07-20 Huntsman Advanced Materials Americas Inc. Hydrophobic epoxide resin system
DE60134574D1 (de) * 2000-12-15 2008-08-07 San Apro Ltd Verfahren zur herstellung von sulfoniumsalzen
US20040216838A1 (en) * 2001-05-21 2004-11-04 Ekman Anders V. Processes for the production of components fo electronic apparatuses
US7230121B2 (en) 2001-07-19 2007-06-12 Lamberti Spa Sulfoniun salts, methods for their preparation and use thereof as photoinitiators for radiation curable systems
JP2004323642A (ja) * 2003-04-23 2004-11-18 Riso Kagaku Corp カチオン重合性組成物及びインク
KR101197539B1 (ko) * 2003-11-04 2012-11-12 헨켈 아게 운트 코. 카게아아 술포늄염 광개시제 및 그의 용도
JP4569095B2 (ja) * 2003-11-11 2010-10-27 コニカミノルタエムジー株式会社 カチオン重合性組成物、活性エネルギー線硬化型インクジェットインク、カチオン重合性組成物の製造方法及び活性エネルギー線硬化型インクジェットインクの製造方法
JP2006089722A (ja) * 2004-08-26 2006-04-06 Konica Minolta Medical & Graphic Inc カチオン重合性組成物、活性エネルギー線硬化型インクジェットインク及びカチオン重合性組成物の製造方法
KR100637450B1 (ko) 2005-02-16 2006-10-23 한양대학교 산학협력단 플루오로알킬술폰늄염의 광산발생기가 치환된 화합물과 이를 중합한 공중합체
SG185053A1 (en) 2010-04-29 2012-12-28 Huntsman Adv Mat Switzerland Curable composition
WO2012113829A1 (en) 2011-02-23 2012-08-30 Basf Se Sulfonium sulfates, their preparation and use
CN102786457A (zh) * 2012-08-22 2012-11-21 林州市科能材料科技有限公司 一种硫类离子液体的合成方法
CN108350150B (zh) 2015-06-16 2021-09-10 亨斯迈先进材料许可(瑞士)有限公司 环氧树脂组合物
WO2017001182A1 (en) 2015-07-02 2017-01-05 Huntsman Advanced Materials (Switzerland) Gmbh A thermosetting epoxy resin composition for the preparation of outdoor articles, and the articles obtained therefrom
WO2020205994A1 (en) 2019-04-02 2020-10-08 Ecolab Usa Inc. Pure chlorine dioxide generation system with reduced acid usage
DE102022102650A1 (de) 2022-02-04 2023-08-10 Delo Industrie Klebstoffe Gmbh & Co. Kgaa Kationisch polymerisierbare flammgeschützte Massen
DE102022106647A1 (de) 2022-03-22 2023-09-28 Delo Industrie Klebstoffe Gmbh & Co. Kgaa Niedertemperaturhärtende Massen auf Basis von Glycidylethern
WO2024158178A1 (ko) * 2023-01-25 2024-08-02 동우 화인켐 주식회사 열경화성 수지 조성물, 경화막 및 고체 촬상 소자

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4058401A (en) * 1974-05-02 1977-11-15 General Electric Company Photocurable compositions containing group via aromatic onium salts
US4216288A (en) * 1978-09-08 1980-08-05 General Electric Company Heat curable cationically polymerizable compositions and method of curing same with onium salts and reducing agents
US4251521A (en) * 1979-02-07 1981-02-17 Sandoz, Inc. Alkyl diaryl sulfonium salts
US5247113A (en) * 1989-01-16 1993-09-21 Ciba-Geigy Corporation Araliphatic sulfonium and their use
EP0379464B1 (de) * 1989-01-16 1993-02-10 Ciba-Geigy Ag Araliphatische Sulfoniumsalze und deren Verwendung
EP0508951B1 (de) * 1991-04-08 1996-08-21 Ciba-Geigy Ag Thermisch härtbare Zusammensetzungen

Also Published As

Publication number Publication date
CA2100815A1 (en) 1994-01-22
TW237466B (es) 1995-01-01
DE59303487D1 (de) 1996-09-26
JP3548967B2 (ja) 2004-08-04
EP0580552B1 (de) 1996-08-21
KR940002222A (ko) 1994-02-16
JPH06184093A (ja) 1994-07-05
EP0580552A1 (de) 1994-01-26
BR9302930A (pt) 1994-03-01
US5374697A (en) 1994-12-20
KR100280015B1 (ko) 2001-02-01

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