ES2084490T3 - Sistemas catalizadores para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono. - Google Patents

Sistemas catalizadores para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono.

Info

Publication number
ES2084490T3
ES2084490T3 ES93906586T ES93906586T ES2084490T3 ES 2084490 T3 ES2084490 T3 ES 2084490T3 ES 93906586 T ES93906586 T ES 93906586T ES 93906586 T ES93906586 T ES 93906586T ES 2084490 T3 ES2084490 T3 ES 2084490T3
Authority
ES
Spain
Prior art keywords
group
polymerization
alqu
enso
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93906586T
Other languages
English (en)
Inventor
Kaspar Evertz
Rueger Schlund
Guenther Schweier
Hans Brintzinger
Werner Roell
Peter Jutzi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2084490T3 publication Critical patent/ES2084490T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Abstract

SISTEMA DE CATALIZADOR PARA POLIMERIZACION DE C2 C10 ALQ OMPLEJO METALOCENO DE LA FORMULA GENERAL (I), EN DONDE LOS SUSTITUYENTES E INDICE TIENEN LA SIGUIENTE SIGNIFICACION: M ES UN METAL DEL GRUPO III, IV O EL GRUPO PROXIMO V DEL SISTEMA PERIODICO O UN METAL A PARTIR DEL GRUPO DE LOS LANTANIDOS, X ES FLUOR, CLORO, BROMO, YODO, HIDROGENO, C1 ALQUIL O FLUORARIL CON RESPECTIVAMENTE 1 HASTA 10 ATOMOS DE CARBONO EL RESTO ALQUIL Y 6 HASTA 20 ATOMOS DE C EN RESTO ARIL, N ES LA VALENCIA DE M CON RESPECTO A SU CIFRA, R1 HASTA R6 SON HIDROGENO, C1 7 MIEMBROS, QUE POR SU PARTE PUEDE PORTAR UN C1 QUIL COMO SUSTITUYENTE, C6 NDE EVENTUALMENTE TAMBIEN PUEDEN SER RESTO VECINOS DE FORMA CONJUNTA PARA GRUPOS CICLICOS QUE MUESTRAN DESDE 4 HASTA 15 ATOMOS DE C, O SI(R8)3 CON R8 SIGNIFICANDO C1 C6 NDEPENDIENTE UNO DE OTRO SON SI(R9)2, GE(R9)2, SN(R9)2 O C(R9)2 ALUMOXANO CICLICO O DE CADENA ABIERTA DE LAS FORMULA GENERALES (II) O (III), DONDE R10 SIGNIFICA UN GRUPO C1 UIL Y M UNA CIFRA COMPLETA DESDE 5 HASTA 30.
ES93906586T 1992-04-03 1993-03-23 Sistemas catalizadores para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono. Expired - Lifetime ES2084490T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4211086A DE4211086A1 (de) 1992-04-03 1992-04-03 Katalysatorsysteme zur Polymerisation von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen

Publications (1)

Publication Number Publication Date
ES2084490T3 true ES2084490T3 (es) 1996-05-01

Family

ID=6455900

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93906586T Expired - Lifetime ES2084490T3 (es) 1992-04-03 1993-03-23 Sistemas catalizadores para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono.

Country Status (10)

Country Link
US (1) US5496902A (es)
EP (1) EP0633897B1 (es)
JP (1) JP3270049B2 (es)
AR (1) AR246278A1 (es)
DE (2) DE4211086A1 (es)
ES (1) ES2084490T3 (es)
RU (1) RU94042464A (es)
TW (1) TW362101B (es)
WO (1) WO1993020113A1 (es)
ZA (1) ZA932389B (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3293927B2 (ja) * 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
WO1995009172A1 (fr) * 1993-09-30 1995-04-06 Idemitsu Kosan Co., Ltd. Compose d'un metal de transition, catalyseur de polymerisation d'olefine, et procede de production d'un polymere olefinique a l'aide du catalyseur
DE4337233A1 (de) * 1993-10-30 1995-05-04 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen unter Verwendung von racemischen Metallocenkomplexen als Katalysatoren
FI945959A (fi) * 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
FI945958A (fi) * 1993-12-21 1995-06-22 Hoechst Ag Menetelmä polyolefiinien valmistamiseksi
AT401520B (de) * 1994-03-22 1996-09-25 Danubia Petrochem Polymere Metallocene und deren einsatz für die olefinpolymerisation
WO1996030380A1 (fr) * 1995-03-30 1996-10-03 Idemitsu Kosan Co., Ltd. Compose de metaux de transition, catalyseur de polymerisation pour olefines et procede d'elaboration de polymeres d'olefines
DE19527047A1 (de) * 1995-07-25 1997-01-30 Danubia Petrochem Deutschland Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation
US5708101A (en) * 1995-08-17 1998-01-13 California Institute Of Technology Stereospecific olefin polymerization catalysts
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
JPH10259207A (ja) * 1997-03-21 1998-09-29 Idemitsu Kosan Co Ltd オレフィン重合体の製造方法
DE19736609A1 (de) 1997-08-22 1999-02-25 Basf Ag Verfahren zur Herstellung von Rutheniumkomplexen
EP2028198B1 (en) * 1998-06-25 2010-01-06 Idemitsu Kosan Co., Ltd. Propylene polymer and composition containing the same, molded object and laminate comprising these, and processes for producing propylene polymer and composition containinig the same
US6100212A (en) * 1998-06-30 2000-08-08 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
JP4521092B2 (ja) * 2000-04-20 2010-08-11 出光興産株式会社 遷移金属化合物、オレフィン重合触媒及びオレフィン重合体の製造方法
US6875719B2 (en) * 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
JP4931269B2 (ja) 2000-05-30 2012-05-16 出光興産株式会社 α−オレフィン重合体の製造方法及び潤滑油
JP4772951B2 (ja) * 2000-08-02 2011-09-14 出光興産株式会社 遷移金属化合物、オレフィン重合触媒、オレフィン系重合体の製造方法及びオレフィン系重合体
EP1247814B1 (en) * 2000-09-21 2007-08-22 Idemitsu Kosan Co., Ltd. Transition metal compounds, polymerization catalysts for olefins, olefin polymers and process for their production
DE10296812T5 (de) * 2001-05-15 2004-04-22 Idemitsu Petrochemical Co., Ltd. Verfahren zur Herstellung von Ethylen-Cycloolefin-Copolymer
JP4731067B2 (ja) * 2001-08-29 2011-07-20 出光興産株式会社 α−オレフィン−環状オレフィン共重合体およびその製造方法
WO2003070788A1 (en) * 2002-02-21 2003-08-28 Idemitsu Petrochemical Co., Ltd. Highly flowable 1-butene polymer and process for producing the same
EP1464657A1 (en) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenated metallocene catalyst
ATE446304T1 (de) 2004-01-28 2009-11-15 Idemitsu Kosan Co Übergangsmetallverbindung und katalysator zur olefinpolymerisierung
WO2012077289A1 (ja) * 2010-12-06 2012-06-14 出光興産株式会社 メソ型及びラセミ型メタロセン錯体の製造方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren

Also Published As

Publication number Publication date
TW362101B (en) 1999-06-21
AR246278A1 (es) 1994-07-29
ZA932389B (en) 1994-10-02
EP0633897A1 (de) 1995-01-18
JP3270049B2 (ja) 2002-04-02
WO1993020113A1 (de) 1993-10-14
DE59301806D1 (de) 1996-04-11
JPH07505418A (ja) 1995-06-15
EP0633897B1 (de) 1996-03-06
US5496902A (en) 1996-03-05
RU94042464A (ru) 1996-07-20
DE4211086A1 (de) 1993-10-07

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