AR246278A1 - Sistemas de catalizador para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono. - Google Patents

Sistemas de catalizador para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono.

Info

Publication number
AR246278A1
AR246278A1 AR93324629A AR32462993A AR246278A1 AR 246278 A1 AR246278 A1 AR 246278A1 AR 93324629 A AR93324629 A AR 93324629A AR 32462993 A AR32462993 A AR 32462993A AR 246278 A1 AR246278 A1 AR 246278A1
Authority
AR
Argentina
Prior art keywords
aryl
alkyl
catalyst systems
iii
metal
Prior art date
Application number
AR93324629A
Other languages
English (en)
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Application granted granted Critical
Publication of AR246278A1 publication Critical patent/AR246278A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

SISTEMAS DE CATALIZADOR PARA LA POLIMERIZACION DE ALQU-1-ENOS, QUE CONTIENEN COMO COMPONENTES ACTIVOS: A) UN COMPLEJO DE METALOCENO DE LA FORMULA (I), EN LA QUE LOS SUSTITUYENTES Y LOS INDICES TIENEN LOS SIGUIENTES SIGNIFICADOS: M UN METAL DEL SUBGRUPO (III), (IV) O BIEN (V) DEL SISTEMA PERIODICO O UN METAL DEL GRUPO DE LOS LANTANOIDES; X FLUOR, CLORO, BROMO, YODO, HIDROGENO, ALQUILO, ARILO O BIEN -OR7, DONDE R7 ES ALQUILO, ARILO, ALQUILARILO, ARILALQUILO, FLUORALQUILO O FLUOROARILO, N ES M-2, R1 A R6 HIDROGENO, ALQUILO, CICLOALQUILO, QUE POR SU PARTE PUEDE LLEVAR UN ALQUILO COMO SUSTITUYENTE, ARILO O ARILALQUILO, EN DONDE EN SU CASO, TAMBIEN DOS RADICALES VECINOS PUEDEN REPRESENTAR GRUPOS CICLICOS O BIEN SI(R8)3 SIGNIFICANDO: R8 ALQUILO, ARILO, O CICLOALQUILO, E1, E2:R9-SI-R9, R9-GE-R9, R9-SM-R9, R9-C-R9 SON R9 ALQUILO, CICLOALQUILO O BIEN ARILO, ASI COMO B) UN COMPUESTO DE ALUMOXANO CIDICO DE CADENA ABIERTA QUE CORRESPONDE A LA FORMULA GENERAL (II) O (III),DONDE R10 ES UN GRUPOÑ ALQUILO Y M REPRESENTA UN NUMERO ENTERO DE 5 A 30.
AR93324629A 1992-04-03 1993-03-31 Sistemas de catalizador para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono. AR246278A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4211086A DE4211086A1 (de) 1992-04-03 1992-04-03 Katalysatorsysteme zur Polymerisation von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen

Publications (1)

Publication Number Publication Date
AR246278A1 true AR246278A1 (es) 1994-07-29

Family

ID=6455900

Family Applications (1)

Application Number Title Priority Date Filing Date
AR93324629A AR246278A1 (es) 1992-04-03 1993-03-31 Sistemas de catalizador para la polimerizacion de alqu-1-enos con 2 a 10 atomos de carbono.

Country Status (10)

Country Link
US (1) US5496902A (es)
EP (1) EP0633897B1 (es)
JP (1) JP3270049B2 (es)
AR (1) AR246278A1 (es)
DE (2) DE4211086A1 (es)
ES (1) ES2084490T3 (es)
RU (1) RU94042464A (es)
TW (1) TW362101B (es)
WO (1) WO1993020113A1 (es)
ZA (1) ZA932389B (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3293927B2 (ja) * 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
WO1995009172A1 (fr) * 1993-09-30 1995-04-06 Idemitsu Kosan Co., Ltd. Compose d'un metal de transition, catalyseur de polymerisation d'olefine, et procede de production d'un polymere olefinique a l'aide du catalyseur
DE4337233A1 (de) * 1993-10-30 1995-05-04 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen unter Verwendung von racemischen Metallocenkomplexen als Katalysatoren
FI945958A (fi) * 1993-12-21 1995-06-22 Hoechst Ag Menetelmä polyolefiinien valmistamiseksi
FI945959A (fi) * 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
AT401520B (de) * 1994-03-22 1996-09-25 Danubia Petrochem Polymere Metallocene und deren einsatz für die olefinpolymerisation
US6339135B1 (en) * 1995-03-30 2002-01-15 Idemitsu Kosan Co., Ltd. Transition metal compound, catalyst for olefin polymerization, process for preparing olefin polymer
DE19527047A1 (de) * 1995-07-25 1997-01-30 Danubia Petrochem Deutschland Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation
US5708101A (en) * 1995-08-17 1998-01-13 California Institute Of Technology Stereospecific olefin polymerization catalysts
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
DE19623707A1 (de) * 1996-06-14 1997-12-18 Hoechst Ag Übergangsmetallverbindung
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
JPH10259207A (ja) * 1997-03-21 1998-09-29 Idemitsu Kosan Co Ltd オレフィン重合体の製造方法
DE19736609A1 (de) 1997-08-22 1999-02-25 Basf Ag Verfahren zur Herstellung von Rutheniumkomplexen
EP1865007B1 (en) * 1998-06-25 2009-03-25 Idemitsu Kosan Co., Ltd. Propylene polymer and composition containing the same, molded object and laminate comprising these, and processes for producing propylene polymer and composition containing the same
US6100212A (en) * 1998-06-30 2000-08-08 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
JP4521092B2 (ja) * 2000-04-20 2010-08-11 出光興産株式会社 遷移金属化合物、オレフィン重合触媒及びオレフィン重合体の製造方法
US6875719B2 (en) * 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
JP4931269B2 (ja) 2000-05-30 2012-05-16 出光興産株式会社 α−オレフィン重合体の製造方法及び潤滑油
JP4772951B2 (ja) * 2000-08-02 2011-09-14 出光興産株式会社 遷移金属化合物、オレフィン重合触媒、オレフィン系重合体の製造方法及びオレフィン系重合体
EP1247814B1 (en) * 2000-09-21 2007-08-22 Idemitsu Kosan Co., Ltd. Transition metal compounds, polymerization catalysts for olefins, olefin polymers and process for their production
WO2002092641A1 (fr) * 2001-05-15 2002-11-21 Idemitsu Petrochemical Co., Ltd. Procede de production de copolymeres ethylene-cycloolefines
JP4731067B2 (ja) * 2001-08-29 2011-07-20 出光興産株式会社 α−オレフィン−環状オレフィン共重合体およびその製造方法
JP3979997B2 (ja) 2002-02-21 2007-09-19 出光興産株式会社 高流動１−ブテン系重合体及びその製造方法
EP1464657A1 (en) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenated metallocene catalyst
EP1710247B1 (en) 2004-01-28 2009-10-21 Idemitsu Kosan Co., Ltd. Transition metal compound and catalyst for olefin polymerization
JPWO2012077289A1 (ja) * 2010-12-06 2014-05-19 出光興産株式会社 メソ型及びラセミ型メタロセン錯体の製造方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren

Also Published As

Publication number Publication date
EP0633897B1 (de) 1996-03-06
EP0633897A1 (de) 1995-01-18
ES2084490T3 (es) 1996-05-01
RU94042464A (ru) 1996-07-20
TW362101B (en) 1999-06-21
JP3270049B2 (ja) 2002-04-02
US5496902A (en) 1996-03-05
WO1993020113A1 (de) 1993-10-14
ZA932389B (en) 1994-10-02
JPH07505418A (ja) 1995-06-15
DE59301806D1 (de) 1996-04-11
DE4211086A1 (de) 1993-10-07

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