ES2071911T3 - Un metodo nuevo de preparacion del dioxido de titanio. - Google Patents
Un metodo nuevo de preparacion del dioxido de titanio.Info
- Publication number
- ES2071911T3 ES2071911T3 ES91301183T ES91301183T ES2071911T3 ES 2071911 T3 ES2071911 T3 ES 2071911T3 ES 91301183 T ES91301183 T ES 91301183T ES 91301183 T ES91301183 T ES 91301183T ES 2071911 T3 ES2071911 T3 ES 2071911T3
- Authority
- ES
- Spain
- Prior art keywords
- titanium dioxide
- treated
- base
- acid
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C3/043—Drying, calcination
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/84—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by UV- or VIS- data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
- C01P2004/52—Particles with a specific particle size distribution highly monodisperse size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Cosmetics (AREA)
Abstract
LA INVENCION SE REFIERE A UN METODO PARA PREPARAR DIOXIDO DE TITANIO CRISTALINO, EN EL QUE: A) EL HIDRATO DE DIOXIDO DE TITANIO SOLIDO SE TRATA CON UNA BASE, B) EL PRECIPITADO TRATADO CON LA BASE SE TRATARA TAMBIEN CON ACIDO HIDROCLORHIDRICO, Y C) EL PRECIPITADO TRATADO CON LA BASE Y CON EL ACIDO SE NEUTRALIZA. SE HA TOMADO EN CONSIDERACION QUE LOS CRISTALES DE RUTILIO UTILIZABLES, UN TAMAÑO DE CRISTAL MAS APROPIADO Y UNA DISTRIBUCION DE TAMAÑO DE CRISTALES Y QUE LOS QUIMICOS PUEDEN SALVARSE Y EL CONTENIDO FINAL DEL ACIDO HIDROCLORHIDRICO DE LA ETAPA A) SE AJUSTA A UN VALOR INFERIOR QUE EL QUE SE UTILIZA NORMALMENTE, ALREDEDOR DE 8 A 25 G/LITRO, PARA LA PRECIPITACION DE DIOXIDO DE TITANIO MICROCRISTALINO. DONDE LA NEUTRALIZACION DE LA ETAPA C) PUEDE EFECTUARSE TAMBIEN ELEVANDO EL PH A SU MAYOR VALOR QUE NORMALMENTE, POR EJ: EL VALOR ALREDEDOR DE 4.0 A 6.0.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI901053A FI89900C (fi) | 1990-03-01 | 1990-03-01 | Nytt framstaellningsfoerfarande av titandioxid |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2071911T3 true ES2071911T3 (es) | 1995-07-01 |
Family
ID=8529973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91301183T Expired - Lifetime ES2071911T3 (es) | 1990-03-01 | 1991-02-13 | Un metodo nuevo de preparacion del dioxido de titanio. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5443811A (es) |
EP (1) | EP0444798B1 (es) |
JP (1) | JPH0676215B2 (es) |
AU (1) | AU632663B2 (es) |
DE (1) | DE69109519T2 (es) |
ES (1) | ES2071911T3 (es) |
FI (1) | FI89900C (es) |
NO (1) | NO303906B1 (es) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3053667B2 (ja) * | 1991-06-10 | 2000-06-19 | 株式会社資生堂 | ホトクロミック性紫外線遮蔽粉体及びその製造方法、皮膚外用剤 |
DE4222905A1 (de) * | 1992-07-11 | 1994-01-13 | Kronos Titan Gmbh | Subpigmentäres Titandioxid mit verbesserter Photostabilität |
DE69411662T2 (de) * | 1993-10-22 | 1998-12-24 | Ishihara Sangyo Kaisha | Dendrit- oder sternförmige Titandioxid-Mikropartikel und Verfahren zur seiner Herstellung |
US5332433A (en) * | 1993-11-24 | 1994-07-26 | Kerr-Mcgee Chemical Corporation | Titanium dioxide dispersibility |
WO1997015526A1 (en) * | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Hydrothermal process for making ultrafine metal oxide powders |
DE19543204C2 (de) | 1995-11-20 | 1997-09-18 | Bayer Ag | Verfahren zur Herstellung von nanodispersem Titandioxid und seine Verwendung |
EP1052224B2 (en) * | 1996-08-30 | 2014-02-12 | Showa Denko K.K. | Particles, aqueous dispersion and film of titanium oxide, and preparation thereof |
US6099798A (en) * | 1997-10-31 | 2000-08-08 | Nanogram Corp. | Ultraviolet light block and photocatalytic materials |
US7226966B2 (en) | 2001-08-03 | 2007-06-05 | Nanogram Corporation | Structures incorporating polymer-inorganic particle blends |
US7384680B2 (en) | 1997-07-21 | 2008-06-10 | Nanogram Corporation | Nanoparticle-based power coatings and corresponding structures |
US6290735B1 (en) * | 1997-10-31 | 2001-09-18 | Nanogram Corporation | Abrasive particles for surface polishing |
US6387531B1 (en) | 1998-07-27 | 2002-05-14 | Nanogram Corporation | Metal (silicon) oxide/carbon composite particles |
AUPP355798A0 (en) * | 1998-05-15 | 1998-06-11 | University Of Western Australia, The | Process for the production of ultrafine powders |
KR100277164B1 (ko) * | 1998-07-16 | 2001-01-15 | 장인순 | 저온균질침전법을이용한사염화티타늄수용액으로부터의결정성tio₂초미립분말의제조방법 |
EP1160275A4 (en) * | 1998-07-17 | 2002-03-20 | Daikin Ind Ltd | CROSSLINKABLE ELASTOMERIC COMPOSITION, SEALING MATERIAL PRODUCED FROM THIS COMPOSITION, AND ASSOCIATED FILLER FOR USE THEREOF |
US6528568B2 (en) | 2001-02-23 | 2003-03-04 | Millennium Inorganic Chemicals, Inc. | Method for manufacturing high opacity, durable pigment |
CA2478430C (en) * | 2002-03-06 | 2009-04-28 | F. Hoffmann-La Roche Ag | Modified oxidic nano-particle with hydrophobic inclusions, method for the production and use of said particle |
US7521039B2 (en) | 2002-11-08 | 2009-04-21 | Millennium Inorganic Chemicals, Inc. | Photocatalytic rutile titanium dioxide |
WO2006023644A2 (en) * | 2004-08-20 | 2006-03-02 | 3M Innovative Properties Company | Transdermal drug delivery device with translucent protective film |
WO2007039953A1 (ja) | 2005-09-30 | 2007-04-12 | Sakai Chemical Industry Co., Ltd. | ルチル型微粒子酸化チタンの製造方法 |
US20080305133A1 (en) | 2005-12-09 | 2008-12-11 | Dsm Ip Assets B.V. | Novel Cosmetic or Dermatological Combinations Comprising Modified Titanium Dioxide Particles |
US7972691B2 (en) * | 2006-12-22 | 2011-07-05 | Nanogram Corporation | Composites of polymers and metal/metalloid oxide nanoparticles and methods for forming these composites |
US8119233B2 (en) * | 2007-02-17 | 2012-02-21 | Nanogram Corporation | Functional composites, functional inks and applications thereof |
FI124294B (fi) * | 2007-08-16 | 2014-06-13 | Sachtleben Pigments Oy | Menetelmä hyvin dispergoituvan mikrokiteisen titaanidioksidituotteen valmistamiseksi, tuote ja sen käyttö |
EP2123606A1 (en) | 2008-05-19 | 2009-11-25 | Kemira Pigments Oy | Ultrafine titanium dioxide nanoparticles and dispersions thereof |
FI122244B (fi) | 2008-07-07 | 2011-10-31 | Sachtleben Pigments Oy | Menetelmä pienikiteisen rutiilimuotoisen titaanioksidin valmistamiseksi ja menetelmällä valmistettu tuote |
US8840814B2 (en) | 2008-11-04 | 2014-09-23 | Sachtleben Pigments Oy | Process of preparing alkali metal titanates |
PL2358641T3 (pl) * | 2008-11-04 | 2014-11-28 | Sachtleben Pigments Oy | Sposób wytwarzania tytanianów |
CN102272218B (zh) | 2009-01-08 | 2014-07-16 | 纳克公司 | 聚硅氧烷聚合物与无机纳米颗粒的复合物 |
SI23218A (sl) * | 2009-11-04 | 2011-05-31 | CINKARNA Metalurško kemična industrija Celje, d.d. | Nanodelci rutila in postopek sinteze za pridobivanje nanodelcev rutila |
KR101771754B1 (ko) | 2009-11-18 | 2017-08-25 | 디에스엠 아이피 어셋츠 비.브이. | 국소용 조성물 |
SI23501A (sl) * | 2010-10-25 | 2012-04-30 | CINKARNA Metalurško kemiÄŤna industrija Celje, d.d. | Postopek za pridobivanje nanodelcev anatasa visoke specifične površine in sferične morfologije |
CN104549204B (zh) * | 2014-12-23 | 2017-02-22 | 中国科学院宁波材料技术与工程研究所 | 一种二氧化钛/碳纳微米球粉体的制备方法及其应用 |
CN108473336B (zh) * | 2015-12-25 | 2021-01-26 | 株式会社资生堂 | 二氧化钛粉体和配合有其的化妆品 |
BR112018069675A2 (pt) | 2016-03-29 | 2019-02-05 | Venator Germany Gmbh | método para tratar partículas de dióxido de titânio, uma partícula de dióxido de titânio e usos do mesmo |
WO2019076790A1 (en) | 2017-10-17 | 2019-04-25 | Venator P&A Finland Oy | PROCESS FOR PRODUCING COATED TITANIUM DIOXIDE PARTICLES, COATED TITANIUM DIOXIDE PARTICLES, AND PRODUCTS COMPRISING SAID PARTICLES |
CN108002435B (zh) * | 2017-12-14 | 2019-12-06 | 四川龙蟒钛业股份有限公司 | 一种提高硫酸法钛白粉生产质量的方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE381790C (de) * | 1923-09-24 | Westinghouse Electric & Mfg Co | Triebgehaeuse | |
US2494492A (en) * | 1942-01-31 | 1950-01-10 | American Cyanamid Co | Production of rutile titanium dioxide |
US2480869A (en) * | 1943-12-30 | 1949-09-06 | Max J Mayer | Seed for production of titanium dioxide and process of making same |
US2448683A (en) * | 1944-02-09 | 1948-09-07 | Du Pont | Titanium oxide production |
CA962142A (en) * | 1971-06-07 | 1975-02-04 | Canadian Titanium Pigments Limited | Ultra-violet screener |
US4166147A (en) * | 1973-04-16 | 1979-08-28 | Minnesota Mining And Manufacturing Company | Shaped and fired articles of tio2 |
DE2817551C2 (de) * | 1978-04-21 | 1984-07-19 | Kronos Titan-Gesellschaft Mbh, 5090 Leverkusen | Titandioxidhydrat mit besonderer Struktur sowie seine Herstellung |
FI62130C (fi) * | 1980-07-18 | 1982-11-10 | Kemira Oy | Ytbelagt titandioxidpigment och foerfarande foer framstaellning daerav |
US4605631A (en) * | 1984-03-19 | 1986-08-12 | Norton Company | Advanced preparation of ceramic powders |
GB8712752D0 (en) * | 1987-05-30 | 1987-07-01 | Tioxide Group Plc | Particulate material |
-
1990
- 1990-03-01 FI FI901053A patent/FI89900C/fi active IP Right Grant
-
1991
- 1991-02-13 DE DE69109519T patent/DE69109519T2/de not_active Expired - Lifetime
- 1991-02-13 AU AU71015/91A patent/AU632663B2/en not_active Expired
- 1991-02-13 ES ES91301183T patent/ES2071911T3/es not_active Expired - Lifetime
- 1991-02-13 EP EP91301183A patent/EP0444798B1/en not_active Expired - Lifetime
- 1991-02-27 NO NO910766A patent/NO303906B1/no unknown
- 1991-02-28 JP JP3059364A patent/JPH0676215B2/ja not_active Expired - Lifetime
-
1993
- 1993-05-24 US US08/066,915 patent/US5443811A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
NO910766L (no) | 1991-09-02 |
NO910766D0 (no) | 1991-02-27 |
FI901053A (fi) | 1991-09-02 |
NO303906B1 (no) | 1998-09-21 |
JPH0676215B2 (ja) | 1994-09-28 |
EP0444798A2 (en) | 1991-09-04 |
FI89900B (fi) | 1993-08-31 |
DE69109519D1 (de) | 1995-06-14 |
US5443811A (en) | 1995-08-22 |
AU632663B2 (en) | 1993-01-07 |
FI89900C (fi) | 1993-12-10 |
AU7101591A (en) | 1991-09-05 |
FI901053A0 (fi) | 1990-03-01 |
EP0444798B1 (en) | 1995-05-10 |
EP0444798A3 (en) | 1992-02-26 |
JPH04214030A (ja) | 1992-08-05 |
DE69109519T2 (de) | 1995-09-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2071911T3 (es) | Un metodo nuevo de preparacion del dioxido de titanio. | |
ES2044925T3 (es) | Composiciones farmaceuticas de liberacion retardada. | |
ES2100954T3 (es) | Un metodo para hacer un gel biocompatible insoluble al agua y gel obtenido por dicho metodo. | |
ES2085147T3 (es) | Procedimiento para la preparacion de sales inorganicas. | |
ATE100310T1 (de) | Verfahren zur herstellung radioopaquen, vernetzten poly(carbonsaeure)-zahnzements. | |
DE69010217T3 (de) | Kieselsäuresole, verfahren zur herstellung von kieselsäuresolen sowie verwendung der sole. | |
DK531885A (da) | Fremgangsmaade til desinfektion og middel dertil | |
PL355108A1 (en) | Fibers from plant seeds and use | |
UA42745C2 (uk) | Спосіб виготовлення таблеток, які містять пароксетин, та таблетка, яка містить пароксетин | |
ES2140430T3 (es) | Procedimiento para aumentar el brillo del cabello y para reparar el cabello dañado por productos alcalinos. | |
EP0450189A3 (en) | High temperature stable negative resists and process for the production of high temperature stable relief structure | |
EP0254413A3 (en) | Silver-ionic water and its uses | |
ES2066390T3 (es) | Nuevos derivados del espiro-(4.5)-decano, su procedimiento de preparacion y las composiciones farmaceuticas que los contienen. | |
DE3883235D1 (de) | Weisses desodorierungsmittel und verfahren zu seiner herstellung. | |
ES2088877T3 (es) | Procedimiento de preparacion del 3-pirrolidinol. | |
HUP0101177A2 (hu) | Glikogén alkalmazása mesterséges könnyként felhasználható oldat előállítására | |
ES2020888A6 (es) | Un procedimiento para la conversacion de lentes de contacto en un solo paso. | |
ATE336987T1 (de) | Gelzubereitung enthaltend einen gelösten oder suspendierten wirkstoff,insbesondere zur anwendung auf einer schleimhaut und herstellungsverfahren | |
ITMI911571A0 (it) | Sospensione acquosa concentrata di idrato di calcio, procedimento e impianto per prepararla | |
IT7921299A0 (it) | Derivati fosforanilici contenenti azoto, processo di loro preparazione e metodi di loro impiego nella regolazione della crescita delle piante. | |
MD186C2 (ro) | Metodă de tratament al endometritei după operaţia cezariană | |
DE59902305D1 (de) | Bioaktive implantate und verfahren zu deren herstellung | |
NO180717C (no) | Produksjonsanlegg og fremgangsmåte for fremstilling av cyanursyre | |
DE3887201D1 (de) | Erythromycin-Derivate und ihre Herstellung und Verwendung. | |
ES2134913T3 (es) | Ortesis cervical para intervencion de urgencia. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 444798 Country of ref document: ES |