ES2061946T3 - Componente catalitico y catalizador para la produccion de poliolefina de peso molecular muy alto. - Google Patents
Componente catalitico y catalizador para la produccion de poliolefina de peso molecular muy alto.Info
- Publication number
- ES2061946T3 ES2061946T3 ES89202196T ES89202196T ES2061946T3 ES 2061946 T3 ES2061946 T3 ES 2061946T3 ES 89202196 T ES89202196 T ES 89202196T ES 89202196 T ES89202196 T ES 89202196T ES 2061946 T3 ES2061946 T3 ES 2061946T3
- Authority
- ES
- Spain
- Prior art keywords
- molecular weight
- high molecular
- solid
- group
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 title 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
UN COMPONENTE CATALIZADOR SOLIDO PARA LA POLIMERIZACION A PRESION BAJA DE ETILENO Y ALFA-OLEFINAS C3-C6 DENTRO DE POLIOLEFINAS DE PESO MOLECULAR MUY ALTO, ESTA EN LA FORMA DE UN SOLIDO GRANULAR ESFERICO QUE TIENE AREA DE SUPERFICIE DE ENTRE 20 Y 40 M2/G, UN RADIO DE PORO MEDIO DE ENTRE 5000 Y 40000 A Y UNA POROSIDAD DE ENTRE EL 40 Y EL 90 % DE VOLUMEN, Y SIENDO DEFINIBLE POR LA SIGUIENTE FORMULA ( EN PROPORCIONES ATOMICAS ): DONDE X = HF O ZR; ET = GRUPO ETIL; OET = GRUPO ETOXI; Y OR = GRUPO ALCOXI QUE CONTIENE DE 2 A 8 CARBONOS EN LA PARTE ALQUILICA DERIVADA O LINEAL. ASI UN COMPONENTE CATALIZADOR ES OBTENIDO POR PREPARAR UN SOPORTE GRANULAR ESFERICO SOLIDO PARA PULVERIZAR UNA SOLUCION ETANOLICA DE CLORURO DE MAGNESIO, REACCIONANDO DICHO SOPORTE CON UN HAFNIO O ALCOXIDO DE CIRCONIO O HALOGENALCOXIDO, Y FINALMENTE REACCIONAR EL SOPORTE ASI TRATADO CON UN CLORURO DE ALUMINIO ALQUILICO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT8821877A IT1227054B (it) | 1988-09-09 | 1988-09-09 | Componente di catalizzatore per laproduzione di poliolefine ad altissimo peso molecolare. |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2061946T3 true ES2061946T3 (es) | 1994-12-16 |
Family
ID=11188111
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES89202196T Expired - Lifetime ES2061946T3 (es) | 1988-09-09 | 1989-08-31 | Componente catalitico y catalizador para la produccion de poliolefina de peso molecular muy alto. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5070051A (es) |
EP (1) | EP0358264B1 (es) |
JP (1) | JP2759351B2 (es) |
CN (1) | CN1034336C (es) |
AT (1) | ATE112786T1 (es) |
CA (1) | CA1334405C (es) |
DE (1) | DE68918790T2 (es) |
ES (1) | ES2061946T3 (es) |
FI (1) | FI95386C (es) |
IT (1) | IT1227054B (es) |
NO (1) | NO173508C (es) |
ZA (1) | ZA896766B (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5227439A (en) * | 1990-09-07 | 1993-07-13 | Ecp Enichem Polimeri S.R.L. | Solid component of catalyst for the (co) polymerization of ethylene |
IT1246265B (it) * | 1990-09-07 | 1994-11-17 | Enimont Anic Srl | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
ATE164859T1 (de) * | 1992-01-28 | 1998-04-15 | Dsm Nv | Ethylenpolymer mit einer intrinsike viscosität von wenigstens 4 dl/g und ein verfahren zu seiner herstellung |
IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
CA2206944C (en) * | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
US6329476B1 (en) * | 1997-10-14 | 2001-12-11 | Phillips Petroleum Company | Olefin polymerization processes and products thereof |
WO2004037870A1 (ja) * | 2002-10-23 | 2004-05-06 | Mitsui Chemicals, Inc. | マグネシウムを含む担体成分及びオレフィン重合への応用 |
US7872086B2 (en) * | 2008-01-17 | 2011-01-18 | Tonen Chemical Corporation | Polymeric material and its manufacture and use |
EP2631252B1 (en) | 2010-10-21 | 2015-09-09 | Mitsui Chemicals, Inc. | Method for producing ethylene-based polymer particles, and stretch-molded article obtained from ethylene-based polymer particles |
WO2018063899A1 (en) | 2016-09-29 | 2018-04-05 | Dow Global Technologies Llc | Magnesium halide-supported titanium (pro) catalysts |
CN110867548B (zh) * | 2018-08-27 | 2023-06-06 | 中国石油化工股份有限公司 | 聚乙烯及隔膜和用途 |
IT202000000826A1 (it) | 2020-01-17 | 2021-07-17 | Versalis Spa | Composizioni elastomeriche poliolefiniche ad alto dumping. |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1016022B (de) * | 1954-01-19 | 1957-09-19 | Dr Dr E H Karl Ziegler | Verfahren zur Herstellung von hochmolekularen Polyaethylenen |
BE792668A (fr) * | 1971-12-13 | 1973-06-13 | Basf Ag | Procede de preparation d'une masse de contact finement divisee,destineea la polymerisation d'olefines |
FR2252355B1 (es) * | 1973-11-22 | 1976-10-01 | Solvay | |
US3992322A (en) * | 1975-04-11 | 1976-11-16 | Universal Oil Products Company | Preparation of polymerization catalyst systems |
JPS55116704A (en) * | 1979-03-02 | 1980-09-08 | Mitsubishi Chem Ind Ltd | Catalyst for polymerization of olefin |
IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
IT1151627B (it) * | 1982-06-10 | 1986-12-24 | Anic Spa | Procedimento per la preparazione di copolimeri dell'etilene con basso valore delle densita' |
IT1203330B (it) * | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
-
1988
- 1988-09-09 IT IT8821877A patent/IT1227054B/it active
-
1989
- 1989-08-31 DE DE68918790T patent/DE68918790T2/de not_active Expired - Lifetime
- 1989-08-31 AT AT89202196T patent/ATE112786T1/de not_active IP Right Cessation
- 1989-08-31 ES ES89202196T patent/ES2061946T3/es not_active Expired - Lifetime
- 1989-08-31 EP EP89202196A patent/EP0358264B1/en not_active Expired - Lifetime
- 1989-09-04 ZA ZA896766A patent/ZA896766B/xx unknown
- 1989-09-06 NO NO893577A patent/NO173508C/no not_active IP Right Cessation
- 1989-09-06 CA CA000610417A patent/CA1334405C/en not_active Expired - Lifetime
- 1989-09-08 FI FI894242A patent/FI95386C/fi active IP Right Grant
- 1989-09-08 JP JP1231799A patent/JP2759351B2/ja not_active Expired - Lifetime
- 1989-09-09 CN CN89107056A patent/CN1034336C/zh not_active Expired - Lifetime
-
1991
- 1991-02-22 US US07/659,533 patent/US5070051A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
FI95386B (fi) | 1995-10-13 |
FI894242A (fi) | 1990-03-10 |
CN1040990A (zh) | 1990-04-04 |
EP0358264B1 (en) | 1994-10-12 |
CA1334405C (en) | 1995-02-14 |
CN1034336C (zh) | 1997-03-26 |
DE68918790D1 (de) | 1994-11-17 |
FI95386C (fi) | 1996-01-25 |
ATE112786T1 (de) | 1994-10-15 |
NO893577D0 (no) | 1989-09-06 |
EP0358264A2 (en) | 1990-03-14 |
NO893577L (no) | 1990-03-12 |
FI894242A0 (fi) | 1989-09-08 |
NO173508B (no) | 1993-09-13 |
IT8821877A0 (it) | 1988-09-09 |
ZA896766B (en) | 1990-06-27 |
EP0358264A3 (en) | 1991-07-17 |
NO173508C (no) | 1993-12-22 |
JPH02107605A (ja) | 1990-04-19 |
US5070051A (en) | 1991-12-03 |
IT1227054B (it) | 1991-03-14 |
JP2759351B2 (ja) | 1998-05-28 |
DE68918790T2 (de) | 1995-03-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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