ES2046996T3 - Procedimiento para purificar organofosfitos terciarios. - Google Patents
Procedimiento para purificar organofosfitos terciarios.Info
- Publication number
- ES2046996T3 ES2046996T3 ES88105185T ES88105185T ES2046996T3 ES 2046996 T3 ES2046996 T3 ES 2046996T3 ES 88105185 T ES88105185 T ES 88105185T ES 88105185 T ES88105185 T ES 88105185T ES 2046996 T3 ES2046996 T3 ES 2046996T3
- Authority
- ES
- Spain
- Prior art keywords
- purify
- procedure
- tertiary organophosphites
- organophosphites
- tertiary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000008301 phosphite esters Chemical group 0.000 title abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6578—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/032,906 US4835299A (en) | 1987-03-31 | 1987-03-31 | Process for purifying tertiary organophosphites |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2046996T3 true ES2046996T3 (es) | 1994-02-16 |
Family
ID=21867504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88105185T Expired - Lifetime ES2046996T3 (es) | 1987-03-31 | 1988-03-30 | Procedimiento para purificar organofosfitos terciarios. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4835299A (show.php) |
| EP (1) | EP0285136B2 (show.php) |
| JP (1) | JPH064660B2 (show.php) |
| KR (1) | KR930005259B1 (show.php) |
| CN (1) | CN1019396B (show.php) |
| CA (1) | CA1314053C (show.php) |
| DE (1) | DE3886577T3 (show.php) |
| ES (1) | ES2046996T3 (show.php) |
| IN (1) | IN171049B (show.php) |
| MX (1) | MX166895B (show.php) |
| PL (1) | PL152658B1 (show.php) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW213465B (show.php) * | 1991-06-11 | 1993-09-21 | Mitsubishi Chemicals Co Ltd | |
| US5391799A (en) * | 1992-05-05 | 1995-02-21 | Ciba-Geigy Corporation | Process for the preparation 6-chloro-2,4,8,10-tetra-butyldibenzo[d,f][1,3,2]dioxaphoshepin |
| US5292785A (en) * | 1992-05-05 | 1994-03-08 | Ciba-Geigy Corporation | Bis-phosphite stabilized compositions |
| US5310890A (en) * | 1992-07-22 | 1994-05-10 | Ciba-Geigy Corporation | Carbohydrate substituted dibenzoi(d,g)(1,3,2)dioxaphosphocin stabilizers |
| US5310889A (en) * | 1992-07-22 | 1994-05-10 | Ciba-Geigy Corporation | Carbohydrate substituted dibenzo(d,f)(1,3,2)dioxaphosphepin stabilizers |
| US5789625A (en) * | 1995-12-06 | 1998-08-04 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US5763670A (en) * | 1995-12-06 | 1998-06-09 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation processes |
| US5892127A (en) * | 1996-04-24 | 1999-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for producing 1,6-hexanedials and derivatives |
| TW482765B (en) * | 1996-08-05 | 2002-04-11 | Sumitomo Chemical Co | Phosphites, process for producing the same and their use |
| US5892119A (en) * | 1996-11-26 | 1999-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US5917095A (en) * | 1996-11-26 | 1999-06-29 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| EP1312598B1 (en) | 1998-12-10 | 2005-02-16 | Mitsubishi Chemical Corporation | Process for producing aldehyde |
| DE10148551A1 (de) * | 2001-10-01 | 2003-04-10 | Bayer Ag | Chirale Monophosphorverbindungen |
| DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
| RU2337090C2 (ru) * | 2002-08-31 | 2008-10-27 | Оксено Олефинхеми Гмбх | Способ гидроформилирования олефиновых соединений в присутствии циклических эфиров угольной кислоты |
| KR101035146B1 (ko) | 2006-11-06 | 2011-05-17 | 주식회사 엘지화학 | 옥소 공정에서 재결정화 과정에 의한 촉매 리간드 산화물의 분리 방법 |
| US7863487B2 (en) * | 2007-03-20 | 2011-01-04 | Dow Technology Investments Llc | Hydroformylation process with improved control over product isomers |
| JP5416119B2 (ja) | 2007-09-07 | 2014-02-12 | ダウ グローバル テクノロジーズ エルエルシー | 脂肪族ジアルデヒドの脂肪族ジオールへの水素化 |
| US7872157B2 (en) * | 2007-12-26 | 2011-01-18 | Eastman Chemical Company | Phosphonite containing catalysts for hydroformylation processes |
| US7872156B2 (en) * | 2007-12-26 | 2011-01-18 | Eastman Chemical Company | Fluorophosphite containing catalysts for hydroformylation processes |
| WO2010003073A1 (en) | 2008-07-03 | 2010-01-07 | Dow Technology Investments Llc | Process of controlling heavies in a recycle catalyst stream |
| CN102281948B (zh) | 2008-11-14 | 2015-11-25 | 堪萨斯大学 | 聚合物负载的过渡金属催化剂络合物及使用方法 |
| US7928267B1 (en) | 2009-06-22 | 2011-04-19 | Eastman Chemical Company | Phosphite containing catalysts for hydroformylation processes |
| EP2488539B2 (en) | 2009-10-16 | 2023-12-20 | Dow Technology Investments LLC | Gas phase hydroformylation process |
| JP2013515061A (ja) | 2009-12-22 | 2013-05-02 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 混合リガンドヒドロホルミル化プロセスにおけるノルマル：イソアルデヒド比の制御 |
| PL2516372T5 (pl) | 2009-12-22 | 2020-08-10 | Dow Technology Investments Llc | Regulowanie stosunku aldehyd normalny : izoaldehyd w procesie hydroformowania z mieszanymi ligandami przez regulowanie ciśnienia cząsteczkowego gazu syntezowego |
| CN103951550B (zh) | 2009-12-22 | 2016-06-01 | 陶氏技术投资有限责任公司 | 通过控制烯烃分压来控制混合配体加氢甲酰化工艺中的正构:异构醛比率 |
| CN103153462B (zh) | 2010-10-05 | 2016-06-01 | 陶氏技术投资有限责任公司 | 加氢甲酰基化方法 |
| DE102011002639A1 (de) * | 2011-01-13 | 2012-07-19 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von Biphephos |
| SA112330271B1 (ar) | 2011-04-18 | 2015-02-09 | داو تكنولوجى انفستمنتس ال ال سى | تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء |
| IN2014CN03131A (show.php) * | 2011-10-31 | 2015-07-03 | Dow Technology Investments Llc | |
| ES2589461T3 (es) | 2011-12-30 | 2016-11-14 | Basf Se | Procedimiento para producir 6-clorodibenzo [d,f][1,3,2]dioxafosfepina |
| CN104144935B (zh) | 2011-12-30 | 2016-07-06 | 巴斯夫欧洲公司 | 6，6’-[[3，3’，5，5’-四(1，1-二甲基乙基)-[1，1’-联苯]-2，2’-二基]双(氧基)]双-二苯并[d，f][1，3，2]-二氧杂磷杂庚因的结晶溶剂化物和非溶剂化形式 |
| US9108988B2 (en) | 2011-12-30 | 2015-08-18 | Basf Se | Method of purifying organic diphosphite compounds |
| US8796481B2 (en) | 2011-12-30 | 2014-08-05 | Basf Se | Crystalline solvate and non-solvated forms of 6,6′-[[3,3′,5,5′-tetrakis(1,1-dimethylethyl)-[1,1′biphenyl]-2,2′-diyl]bis(oxy)]bis-dibenzo [d,f] [1,3,2]-dioxaphosphepine |
| US8841474B2 (en) | 2011-12-30 | 2014-09-23 | Basf Se | Process for preparing 6-chlorodibenzo[D,F][1,3,2]dioxaphosphepin |
| ES2708393T3 (es) | 2011-12-30 | 2019-04-09 | Basf Se | Procedimiento para la purificación de compuestos orgánicos de difosfito |
| EP2822921B1 (de) | 2012-03-07 | 2018-06-20 | Basf Se | Verfahren zur wärmeintegration bei der hydrierung und destillation von c3-c20 aldehyden |
| US8889917B2 (en) | 2012-04-12 | 2014-11-18 | Basf Se | Method of supplementing the catalyst in continuous hydroformylation |
| MY172695A (en) | 2012-04-12 | 2019-12-10 | Basf Se | Method for replenishing the catalyst in continuous hydroformylation |
| JP6329136B2 (ja) | 2012-06-04 | 2018-05-23 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
| MY181661A (en) | 2012-08-29 | 2020-12-31 | Dow Technology Investments Llc | Catalyst preparation process |
| US9328047B2 (en) | 2012-09-25 | 2016-05-03 | Dow Technology Investments Llc | Process for stabilizing a phosphite ligand against degradation |
| WO2014088816A1 (en) | 2012-12-06 | 2014-06-12 | Dow Technology Investments Llc | Hydroformylation process |
| CN104725170B (zh) | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
| JP2016540780A (ja) | 2013-12-19 | 2016-12-28 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
| DE102014201756A1 (de) | 2014-01-31 | 2015-08-06 | Evonik Degussa Gmbh | Reinigung chlorverschmutzter Organophosphorverbindungen |
| DE102014202500A1 (de) | 2014-02-12 | 2015-08-13 | Evonik Degussa Gmbh | Verfahren zur Reduzierung des Chlorgehalts von Organobisphosphiten |
| KR20160132013A (ko) * | 2014-03-12 | 2016-11-16 | 스미또모 가가꾸 가부시끼가이샤 | 가공 안정제 |
| US10131608B2 (en) | 2014-03-31 | 2018-11-20 | Dow Technology Investments Llc | Hydroformylation process |
| CN106660915B (zh) * | 2014-05-14 | 2020-08-14 | 陶氏技术投资有限责任公司 | 稳定的有机磷化合物 |
| CN106414467A (zh) | 2014-05-20 | 2017-02-15 | 赢创德固赛有限公司 | 使用二甲基氨基丁烷、三乙胺或三乙醇胺降低有机单亚磷酸酯的氯含量的方法 |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| RU2730501C2 (ru) | 2015-07-28 | 2020-08-24 | Дау Текнолоджи Инвестментс Ллк | Способ приготовления стабилизированного раствора фосфорорганического соединения |
| EP3147291A1 (de) | 2015-09-28 | 2017-03-29 | Evonik Degussa GmbH | Verfahren zur reduzierung des chlorgehalts von organotetraphosphiten |
| TWI709566B (zh) | 2015-09-30 | 2020-11-11 | 美商陶氏科技投資公司 | 用於製造有機磷化合物的方法 |
| TWI709568B (zh) | 2015-09-30 | 2020-11-11 | 美商陶氏科技投資公司 | 用於製造有機磷化合物的方法 |
| PL3374340T3 (pl) | 2015-11-10 | 2022-04-11 | Dow Technology Investments Llc | Sposób wytwarzania aldehydów |
| EP3176174A1 (de) | 2015-12-03 | 2017-06-07 | Evonik Degussa GmbH | Verfahren zur reduzierung des chlorgehalts von organotetraphosphiten |
| EP3414220B1 (en) | 2016-02-11 | 2021-10-13 | Dow Technology Investments LLC | Processes for converting olefins to alcohols, ethers, or combinations thereof |
| US10981851B2 (en) | 2017-10-25 | 2021-04-20 | Dow Technology Investments Llc | Hydroformylation process |
| JP7269238B2 (ja) | 2017-11-13 | 2023-05-08 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセスからロジウムを回収するためのプロセス |
| CN113179638B (zh) | 2018-11-29 | 2023-11-28 | 陶氏技术投资有限责任公司 | 加氢甲酰化工艺 |
| KR20220024858A (ko) | 2019-06-27 | 2022-03-03 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 귀금속 회수를 위한 히드로포르밀화 공정으로부터 용액을 제조하는 공정 |
| TWI874467B (zh) | 2019-11-05 | 2025-03-01 | 美商陶氏科技投資有限公司 | 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法 |
| WO2021126421A1 (en) | 2019-12-19 | 2021-06-24 | Dow Technology Investments Llc | Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms |
| CN114075244B (zh) * | 2020-08-18 | 2024-06-04 | 中国石油化工股份有限公司 | 一种双齿亚磷酸酯及其纯化方法和应用 |
| EP4011891A1 (de) | 2020-12-09 | 2022-06-15 | Covestro Deutschland AG | Verfahren zur herstellung von flammgeschützten pur/pir-hartschaumstoffen |
| CA3201268A1 (en) | 2020-12-14 | 2022-06-23 | Michael A. Brammer | Processes to improve catalytic metal accountability in hydroformylation processes |
| CN118103532A (zh) | 2021-11-11 | 2024-05-28 | 陶氏技术投资有限责任公司 | 用于从加氢甲酰化过程中回收铑的方法 |
| CN115677757B (zh) * | 2022-11-21 | 2023-07-25 | 江苏极易新材料有限公司 | 一种低氯离子含量的三(2,4-二叔丁基苯基)亚磷酸酯提纯方法 |
| WO2024228768A1 (en) | 2023-05-04 | 2024-11-07 | Dow Technology Investments Llc | Hydroformylation process |
| WO2025029349A1 (en) | 2023-08-03 | 2025-02-06 | Dow Technology Investments Llc | Hydroformylation process |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA694472A (en) * | 1964-09-15 | E. Jones William | Selective extraction process | |
| US3356775A (en) * | 1963-07-31 | 1967-12-05 | Monsanto Co | Purification of triaryl phosphates |
| US3415906A (en) * | 1964-05-29 | 1968-12-10 | Hooker Chemical Corp | Phosphite phospholane and phosphorinane compounds |
| US3511880A (en) * | 1966-09-16 | 1970-05-12 | Union Oil Co | Hydrocarbonylation process |
| US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
| SU389100A1 (ru) * | 1971-05-24 | 1973-07-05 | Способ разделения моно- и диалкиловых эфиров фосфорной кислоты | |
| FR2259104B1 (show.php) * | 1974-01-25 | 1976-11-26 | Rhone Poulenc Ind | |
| US3876395A (en) * | 1974-03-07 | 1975-04-08 | Union Carbide Corp | Method for the adsorption of sulfur dioxide |
| US3917469A (en) * | 1974-07-24 | 1975-11-04 | Union Carbide Corp | Method for the removal of sulfur dioxide from gas mixtures |
| US4351759A (en) * | 1978-01-03 | 1982-09-28 | Ciba-Geigy Corporation | Alkylated 2,2'-biphenylene phosphites and stabilized compositions |
| DE2837027A1 (de) * | 1978-08-24 | 1980-03-06 | Bayer Ag | Neue phosphorigsaeureester und ihre verwendung zur stabilisierung von polyamiden |
| US4258215A (en) * | 1979-08-29 | 1981-03-24 | Eastman Kodak Company | Hydroformylation process |
| ATE26696T1 (de) * | 1982-06-11 | 1987-05-15 | Davy Mckee London | Hydroformylierungsverfahren. |
| ATE28183T1 (de) * | 1982-06-11 | 1987-07-15 | Davy Mckee London | Hydroformylierungsverfahren. |
| US4532085A (en) * | 1983-07-05 | 1985-07-30 | Stauffer Chemical Company | Phosphate ester recovery |
| GB8334359D0 (en) * | 1983-12-23 | 1984-02-01 | Davy Mckee Ltd | Process |
| US4599206A (en) * | 1984-02-17 | 1986-07-08 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4737588A (en) * | 1984-12-28 | 1988-04-12 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US4748261A (en) * | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
| US4668651A (en) * | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
| US4774361A (en) * | 1986-05-20 | 1988-09-27 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
-
1987
- 1987-03-31 US US07/032,906 patent/US4835299A/en not_active Expired - Lifetime
-
1988
- 1988-03-30 CN CN88102776A patent/CN1019396B/zh not_active Expired
- 1988-03-30 MX MX010970A patent/MX166895B/es unknown
- 1988-03-30 IN IN203/MAS/88A patent/IN171049B/en unknown
- 1988-03-30 DE DE3886577T patent/DE3886577T3/de not_active Expired - Lifetime
- 1988-03-30 ES ES88105185T patent/ES2046996T3/es not_active Expired - Lifetime
- 1988-03-30 CA CA000562929A patent/CA1314053C/en not_active Expired - Fee Related
- 1988-03-30 EP EP88105185A patent/EP0285136B2/en not_active Expired - Lifetime
- 1988-03-30 KR KR1019880003471A patent/KR930005259B1/ko not_active Expired - Fee Related
- 1988-03-31 JP JP63076654A patent/JPH064660B2/ja not_active Expired - Lifetime
- 1988-03-31 PL PL1988271548A patent/PL152658B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3886577D1 (de) | 1994-02-10 |
| JPH064660B2 (ja) | 1994-01-19 |
| MX166895B (es) | 1993-02-11 |
| EP0285136A2 (en) | 1988-10-05 |
| JPH02231497A (ja) | 1990-09-13 |
| KR930005259B1 (ko) | 1993-06-17 |
| EP0285136B1 (en) | 1993-12-29 |
| CA1314053C (en) | 1993-03-02 |
| EP0285136A3 (en) | 1989-11-23 |
| DE3886577T2 (de) | 1994-04-28 |
| PL152658B1 (en) | 1991-01-31 |
| KR880011179A (ko) | 1988-10-27 |
| IN171049B (show.php) | 1992-07-04 |
| US4835299A (en) | 1989-05-30 |
| CN88102776A (zh) | 1988-11-23 |
| DE3886577T3 (de) | 2000-01-13 |
| CN1019396B (zh) | 1992-12-09 |
| EP0285136B2 (en) | 1999-10-20 |
| PL271548A1 (en) | 1989-01-23 |
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