Classifications

• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B7/00—Hydraulic cements
  • C04B7/14—Cements containing slag
  • C04B7/147—Metallurgical slag
  • C04B7/153—Mixtures thereof with other inorganic cementitious materials or other activators
  • C04B7/1535—Mixtures thereof with other inorganic cementitious materials or other activators with alkali metal containing activators, e.g. sodium hydroxide or waterglass
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B7/00—Hydraulic cements
  • C04B7/14—Cements containing slag
  • C04B7/147—Metallurgical slag
  • C04B7/153—Mixtures thereof with other inorganic cementitious materials or other activators
  • C04B7/17—Mixtures thereof with other inorganic cementitious materials or other activators with calcium oxide containing activators
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B11/00—Calcium sulfate cements
  • C04B11/28—Mixtures thereof with other inorganic cementitious materials
  • C04B11/30—Mixtures thereof with other inorganic cementitious materials with hydraulic cements, e.g. Portland cements
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
  • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
  • C04B28/04—Portland cements
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
  • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
  • C04B28/06—Aluminous cements
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
  • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
  • C04B28/06—Aluminous cements
  • C04B28/065—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
  • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
  • C04B28/08—Slag cements
  • C04B28/082—Steelmaking slags; Converter slags
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
  • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
  • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
  • C04B28/16—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing anhydrite, e.g. Keene's cement
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
  • C04B40/0028—Aspects relating to the mixing step of the mortar preparation
  • C04B40/0039—Premixtures of ingredients
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B7/00—Hydraulic cements
  • C04B7/14—Cements containing slag
  • C04B7/147—Metallurgical slag
  • C04B7/153—Mixtures thereof with other inorganic cementitious materials or other activators
  • C04B7/17—Mixtures thereof with other inorganic cementitious materials or other activators with calcium oxide containing activators
  • C04B7/19—Portland cements
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B7/00—Hydraulic cements
  • C04B7/14—Cements containing slag
  • C04B7/147—Metallurgical slag
  • C04B7/153—Mixtures thereof with other inorganic cementitious materials or other activators
  • C04B7/21—Mixtures thereof with other inorganic cementitious materials or other activators with calcium sulfate containing activators
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B7/00—Hydraulic cements
  • C04B7/32—Aluminous cements
  • C04B7/323—Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
  • C04B2111/00034—Physico-chemical characteristics of the mixtures
  • C04B2111/00112—Mixtures characterised by specific pH values
• • C—CHEMISTRY; METALLURGY
  • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
  • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
  • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
  • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
  • C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P40/00—Technologies relating to the processing of minerals
  • Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
  • Y02W30/00—Technologies for solid waste management
  • Y02W30/50—Reuse, recycling or recovery technologies
  • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Definitions

• Hydraulic slag-based binder, dry mortar composition comprising this binder and system for activating a slag-based binder Field of the invention
• the invention relates to the field of powder compositions comprising binders based on slag and intended for the preparation of wet formulations for the building, for example, mortars, in particular adhesive mortars.
• the invention relates to a hydraulic binder based on slag, in particular for mortars, in particular for adhesive mortars.
• a subject of the invention is also a dry mortar composition comprising such a binder, as well as a system for activating this binder.
• Conventional hydraulic binders especially for mortars, consist of Portland cements with a CO2 footprint of the order of 870 kg per tonne.
• blast furnace slag crushed granules pozzolanic materials (natural pozzolans, calcined natural pozzolans, synthetic pozzolans), fly ash ( siliceous, calcic), calcined schists, limestones, silica fumes.
• Ground granulated blast furnace slag have hydraulic and pozzolanic properties but require activation by adding lime, soda or gypsum. We speak of sodium, calcium and sulphate activation of the setting and / or hardening of the slag.
• binders for building materials are binders based on ground granulated blast furnace slag in which the alkali concentrations are reduced.
• This PCT application thus discloses an adhesive mortar of the following composition: Portland cement can be replaced or combined with a sulfoaluminate cement.
• Alkaline sulfate can be lithium, sodium, or potassium sulfate.
• the alkaline carbonate can be lithium, sodium or potassium carbonate.
• tile adhesive in the main constituent and a granulated blast furnace slag ground with an acceleration system comprising ultrafine particles of magnesium carbonate and calcium.
• This tile adhesive has the following composition in particular:
• Portland cement can be replaced or combined with a sulfoaluminate cement, an aluminous cement, a belitic cement and / or a pozzolanic mixture cement.
• the alkaline sulfate can be lithium, sodium or potassium sulfate.
• the alkaline carbonate can be lithium, sodium or potassium carbonate.
• Adhesives according to WO 2011/055063 and WO 2017/198930 have improved performance, in particular with regard to traction adhesion with an extended open time of at least 30 minutes and recovery times. walk. This performance is decisive in view of the commercial attractiveness of tile adhesive.
• European patent application EP2502891A1 describes an activator for pozzolanic and / or latent hydraulic binders comprising: A) 5 - 50% NaOH; B) 10 - 90% CaSO4.0,5H2O (optionally Na2SO4); Ca (NO3) 2-4H20; D) optionally a CaCO3-based filler.
• This activator is incorporated in a binder in an amount of 4% by weight.
• This binder may comprise 60% blast furnace slag and 40% cement or 40% cement, 30% slag and 30% siliceous filler.
• This European patent application does not describe adhesive mortar, screeds or coatings having improved performance with regard in particular to adhesion and return to walking times.
• the invention aims to meet at least one of the following objectives:
• a hydraulic binder in particular for mortars, in particular for adhesive mortars, for screeds or for plasters, for repair mortars, sealing or setting mortars, or high performance mortars, intended for aggressive environments such as sulphated water, salts de-icing, based on crushed granulated blast furnace slag, intended for the preparation of a composition free or practically free of Portland CEM cement (binder having an OPC content for example less than or equal to 30% by weight on a dry basis), which makes it possible to produce a setting and a hardening of which the initial mechanical strength is improved compared to the binders based on known patent granulated blast furnace slag;
• a hydraulic binder in particular for mortars, in particular for adhesive mortars, for screeds or for plasters, based on crushed granulated blast furnace slag, free or practically free of Portland CEM cement (binder having for example a lower OPC content or equal to 30% by weight on a dry basis), which makes it possible to produce a setting and a hardening of which the initial mechanical resistance is improved compared to the binders based on known grinded patent granulated blast furnace slag;
• a dry mortar composition in particular an adhesive mortar, based on ground granulated blast furnace slag, free or practically free of Portland CEM cement (binder having for example an OPC content less than or equal to 5% by weight on dry), which, once mixed with water, meets standard NF EN 12 004-1 (April 2017);
• a dry mortar composition in particular an adhesive mortar, based on ground granulated blast furnace slag, free or practically free of Portland CEM cement (binder having for example an OPC content less than or equal to 5% by weight dry), which, once mixed with water, meets standard NF EN 12 004-1 (April 2017) and which has traction adhesion under different conditions, for example after an extended open time of 30 minutes , significantly improved compared to that obtained for the adhesive mortars according to WO 2011/055063 and WO 2017/198930 (for example> 0.8 N / mm 2 );
• a dry mortar composition in particular an adhesive mortar, a screed or a plaster, based on ground granulated blast furnace slag, free or practically free of Portland cement CEM (binder having for example an OPC content less than or equal at 5% by dry weight), which can be packaged in the form of a ready-to-use dry mortar in bags not labeled Xi according to Regulation (EC) No. 1907/2006-REACH;
• a dry mortar composition in particular an adhesive mortar, based on ground granulated blast furnace slag, free or practically free of Portland CEM cement (binder having for example an OPC content less than or equal to 5% by weight dry), which, once mixed with water, satisfies standard NF EN 12 004-1 (April 2017) and which has an open time of between 20 and 30 minutes at least and / or a setting time between 30 minutes and 6 hours, and / or a return to walking time between 4 and 24 hours, for mixing rates (Water * 100 / binder) included between 20 and 30%;
• a dry mortar composition in particular an adhesive mortar, a screed or a plaster, based on ground granulated blast furnace slag, free or practically free of Portland cement CEM (binder having for example an OPC content less than or equal at 5% by dry weight), which meets at least one of the above objectives and which is economical and eco-responsible;
• wet formulation obtained by mixing with water the dry mortar composition targeted in the above objectives, said wet formulation exhibiting a rheology suitable for its easy implementation and at least one of the aforementioned properties for products in the process of curing or hardening, obtained from this wet formulation;
• the invention satisfies at least one of the above objectives and relates, according to a first aspect, to a hydraulic binder, in particular for mortars, in particular for adhesive mortars, comprising (in% by weight on a dry basis) :
• B more than 5, preferably 5.5 to 30, and more preferably 6 to 20, of at least one calcium aluminate cement and / or at least one calcium sulfoaluminate cement ;
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen from the group comprising - or better still consisting of -: NaHCC> 3; Na2CC> 3; K2CO3 and mixtures thereof; with the conditions according to which:
• C is in an amount sufficient so that the sulfate ions of C can react with B and with A;
• (ii) F is in an amount sufficient so that its reaction with component D in the presence of water causes the pH of the wet formulation obtained at a value greater than or equal to 12, preferably 13, for a water-to-mortar mixing rate of between 10 and 35% by weight.
• This binder composition rich in slag is a remarkable alternative to binders based on CEM I in terms of a substantial reduction in the carbon footprint (mass of CO2 equivalent per tonne).
• the fine adjustment of the concentrations of the components ABCDEF optimizes the hydration and the dissolution under alkaline conditions (pH> 12) of the slag A.
• the ratio of the concentrations of component [C] and of component [B] is defined as follows:
• the hydraulic binder according to the invention comprises:
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen from the group comprising - or better still consisting of -: NaHCC> 3; Na2CC> 3; K2CO3 and mixtures thereof, NaHCC> 3 being preferred;
• G 0 to 10, preferably from 0 to 20 of at least one binding agent other than A, B and D, preferably chosen from the group comprising - or better still consisting of -: siliceous or silicic binders aluminous, fly ash, advantageously silico-aluminous fly ash, silico-calcaluminous fly ash, calcined or expanded clay dust and / or metakaolins.
• the invention therefore relates to a dry mortar composition
• a dry mortar composition comprising the binder according to the invention.
• the invention relates to a dry adhesive mortar composition
• a dry adhesive mortar composition comprising (in% by weight on a dry basis): A. 10 to 50, preferably 15 to 40 of at least one granulated and ground blast furnace slag;
• B 0.5 to 20, preferably 1 to 15 of at least one calcium aluminate cement and / or at least one calcium sulfoaluminate cement;
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen from the group comprising - or better still consisting of -: NaHCC> 3; Na2CC> 3; K2CO3 and mixtures thereof, NaHCC> 3 being preferred;
• mineral sands such as siliceous, limestone, silico-limestone, light mineral sands such as perlite, vermiculite, expanded glass beads, sands from recycling mineral materials such as deconstruction concrete, crushed glass, sands from recycling organic materials such as crushed tires, crushed polyurethane, and mixtures thereof;
• at least one retarder preferably chosen from the group comprising - or better still consisting of -: tartaric acid and its salts, citric acid and its salts, gluconic acid and its salts, and mixtures thereof.
• the invention relates to a mortar-adhesive composition
• a mortar-adhesive composition comprising (in% by weight on a dry basis):
• B 0.5 to 20, preferably 1 to 15 of at least one calcium aluminate cement and / or at least one calcium sulfoaluminate cement;
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen from the group comprising - or better again consisting of -: NaHCO3; Na2CO3; K2CO3 and mixtures thereof, NaHCO3 being preferred;
• mineral sands such as siliceous, limestone, silico-limestone, light mineral sands such as perlite, vermiculite, expanded glass beads, sands from recycling mineral materials such as deconstruction concrete, crushed glass, sands from recycling organic materials such as crushed tires, crushed polyurethanes, and mixtures thereof;
• J 0.01 to 0.5, preferably 0.05 to 0.3 of at least retarder preferably chosen from the group comprising - or better still consisting of -: tartaric acid and its salts, citric acid and its salts, gluconic acid and its salts and mixtures thereof.
• This adhesive mortar composition is eco-responsible and efficient. It meets the requirements of standard EN NF 12004 April 2017 on tile adhesives. It is a dry composition of ready-to-use mortar which can be packaged in bags without X labeling, of alkaline corrosive risk. However, the sulfo-alkaline activation of the slag A is made possible with a pH greater than 12 during mixing with water according to a water / mortar mixing ratio of between 15 and 30%, for example 25%. This adhesive sets quickly: adhesion> 0.5 N / mm 2 to 6 hours or 24 hours. It should also be noted that the concentration I of redispersible polymer in this adhesive mortar according to the invention remains limited, which benefits the economy of the composition.
• a subject of the invention is also a dry composition of improved C2F rapid-hardening adhesive mortar, meeting, once mixed with water, the standard NF EN 12004 April 2017 comprising (in% by weight on dry ):
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen from the group comprising - or better still consisting of -: NaHCC>3;Na2CC>3; K2CO3 and mixtures thereof, NaHCC> 3 being preferred;
• Another object of the invention is a dry composition of improved C2S1 deformable adhesive mortar, meeting, when mixed with water, the NF EN 12004 April 2017 standard comprising
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen in the group comprising - or better still consisting of -: NaHCC> 3; Na2CC> 3; K2CO3 and mixtures thereof, NaHCC> 3 being preferred;
• mineral sands such as siliceous, limestone, silico-limestone, mineral sands light weight such as perlite, vermiculite, expanded glass beads, sands from recycling mineral materials such as deconstruction concrete, crushed glass, sands from recycling organic materials such as crushed tires, crushed polyurethane, and mixtures thereof;
• a retarder preferably chosen from the group comprising - or better still consisting of -: tartaric acid and its salts, citric acid and its salts, gluconic acid and its salts and mixtures thereof.
• Another object of the invention is a dry composition of highly deformable C2S2 improved adhesive mortar, meeting, once mixed with water, the standard NF EN 12004 April 2017 comprising (in% by weight on sec):
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen from the group comprising - or better still consisting of -: NaHCC> 3; Na2CC> 3; K2CO3 and mixtures thereof, NaHCC> 3 being preferred;
• a retarder preferably chosen from the group comprising - or better still consisting of -: tartaric acid and its salts, citric acid and its salts, gluconic acid and its salts and mixtures thereof.
• the dry mortar composition according to the invention can also be that of a screed or a coating.
• This composition can comprise (in% by weight on a dry basis):
• B 0.5 to 20, preferably 1 to 15 of at least one calcium aluminate cement and / or at least one calcium sulfoaluminate cement;
• At least one alkalinization reagent consisting of at least one alkali metal carbonate and / or bicarbonate, other than E, preferably chosen from the group comprising - or better still constituted by -: NaHCC>3;Na2CC>3; K2CO3 and mixtures thereof, NaHCC> 3 being preferred;
• mineral sands such as siliceous, limestone, silico-limestone, light mineral sands such as perlite, vermiculite, expanded glass beads, sands from recycling mineral materials such as deconstruction concrete, crushed glass, sands from recycling organic materials such as crushed tires, crushed polyurethanes, and mixtures thereof;
• a retarder preferably chosen from the group comprising - or better still consisting of -: tartaric acid and its salts, citric acid and its salts, gluconic acid and its salts and mixtures thereof.
• the invention also relates to an improvement in dry mortars, in particular adhesive mortars, screeds and coatings, this improvement consisting in using the binder and / or the activation system according to the invention in a dry composition or a wet formulation of mortar, in particular of adhesive mortar, plaster or screed.
• the dry mortar composition according to the invention can include one or more additives chosen from the group comprising - ideally constituted by -: water retainers, fillers, light fillers, water repellents, dyes / pigments, fibers, antifoams, thinners, air entrainers or foaming agents, in situ gas generators, flame retardants, biocides, dispersants and their mixtures.
• the invention relates to a system for activating a hydraulic binder for mortars, in particular for adhesive mortars, comprising (in% by dry weight):
• This binder also comprises (in% by weight on a dry basis):
• the invention relates to a system for activating a hydraulic binder for mortars, in particular for adhesive mortars, coatings or screeds, characterized in that it comprises (in% by weight on sec): C. 60 to 93, preferably 70 to 90 of at least one source of sulfate ions;
• At least one alkali metal carbonate and / or bicarbonate, other than E preferably chosen from the group comprising - or better still consisting of -: NaHCO 3; Na2CO3; K2CO3 and mixtures thereof; and in that the binder comprises (in% by weight on a dry basis):
• the invention relates to a process for preparing the binder or the dry composition according to the invention.
• This process consists essentially in mixing the components of said composition, these components being taken separately and / or in the form of partial or complete mixture (s).
• the invention in another of its aspects, relates to a wet formulation of mortar comprising a dry composition according to the invention mixed with water, according to a water / mortar mixing rate of between 10 and 35%, preferably between 15 and 30%.
• the wet formulation according to the invention is endowed with good processing performance such as "workability” or rheological properties suitable for pumping.
• this coating exhibits in particular good mechanical performance.
• the invention also relates to a process for preparing a wet mortar formulation consisting in mixing with mixing water, advantageously according to a water / mortar mixing ratio of between 10 and 35%, preferably between 15. and 30%, the components of the dry composition according to the invention, these components being taken separately and / or in the form of partial or complete mixture (s).
• the invention further relates to the use of an activation system comprising (in% by dry weight):
• the invention relates to the use of an activation system comprising (in% by weight on a dry basis): C. 60 to 95, preferably 70 to 90 of at least one source of sulfate ions;
• At least one alkali metal carbonate and / or bicarbonate, other than E preferably chosen from the group comprising - or better still consisting of -: NaHCO 3; Na2CO3; K2C03 and mixtures thereof with a hydraulic binder; for activating a hydraulic binder for mortars, in particular for adhesive mortars, this binder comprising (in% by dry weight):
• polymer interchangeably denotes “homopolymer” and “copolymer”;
• dry describes a mortar or concrete in powder form, before mixing with an appropriate liquid, preferably water; a dry mortar or a dry concrete is also a mortar or a concrete ready for use, that is to say ready to be mixed with a mixing liquid to form a wet formulation intended to be used, before hardening, in building material applications;
• “screed” more specifically designates a mortar used as a homogeneous waterproofing structure of a certain thickness (standard NF EN 13 300 18 - August 2000).
• adheresive mortar or “adhesive” designates a dry, wet or hardened composition used to bond tiles to a support; • "paste” means a wet composition containing water;
• filler is a filler with an apparent density greater than 0.75
• the inventors have had the merit of developing an eco-responsible ABCDEF binder based on granulated and ground blast furnace slag, which makes it possible to formulate dry compositions, in particular of mortar and in particular of adhesive mortars, which lead after hardening (mixing to water) to hardened adherent products, or mechanically resistant and meeting the specifications expected in the final applications of building products, in particular adhesive mortars according to standard EN NF 12004 April 2017.
• the granulated and ground blast furnace slag A is a granulated, ground and dried blast furnace slag, the average vitrification rate of which is greater than 90% (measured by X-ray diffraction).
• This slag meets the European standard EN 15167-1 from September 1, 2006.
• this slag is a granulated CE ground blast furnace slag, produced in Fos-sur-Mer by the company ECOCEM® and having the following characteristics:
• Any other granulated and ground blast furnace slag having the above characteristics with a range of variation of +/- 10% constitutes an A slag suitable for entering into the composition of the binder according to the invention.
• At least part of the slag A has a Blaine specific surface area of between 3000 and 5000 cm 2 / g, preferably between 4200 and 4700 cm 2 / g, and, optionally, at least another part of the slag A has a Blaine specific surface greater than 5,000 and less than or equal to 20,000 cm 2 / g, preferably between 6500 and 8500 cm 2 / g.
• CAC Calcium aluminate-based cements
• molten aluminous cements result from firing until melting of a mixture of limestone and bauxite, followed by grinding without gypsum to a fineness comparable to that Portland cements.
• the minimum guaranteed strengths on “normal mortar” are as follows: compressive strength N / mm 2 to 6 hours:>18; at 24 hours:> 40. These cements are defined by standard EN14647.
• the cement based on calcium sulfoaluminate may be an alitic sulfoaluminous cement, a yé'elimitique cement and / or a belitic cement and / or a binder with a high content of cement phase and rich in alumina: (e.g. AI 2 O3> 30%)
• Source C of sulfate ions may be an alitic sulfoaluminous cement, a yé'elimitique cement and / or a belitic cement and / or a binder with a high content of cement phase and rich in alumina: (e.g. AI 2 O3> 30%)
• Source C of sulfate ions e.g. AI 2 O3> 30%
• the source C of sulfate ions is selected from the group comprising - or better still constituted by -: natural or synthetic gypsum, calcium sulfate hemihydrate, bassanite, anhydrite, selenite, alabaster, fibrous gypsum, sacharoid gypsum, marine gypsum, rosé des sables phosphogypsum (gypsum obtained from the manufacture of phosphoric acid), desulfurization gypsum, titanogypsum (gypsum obtained from the neutralization of sulfuric acid produced during of the titanium dioxide synthesis process), citrogypsum (gypsum from the manufacture of citric acid), tartarogypsum (gypsum from the manufacture of tartaric acid), borogypsum (gypsum from the manufacture of boric acid), lactogypsum (gypsum from the manufacture of lactic acid) and mixtures thereof.
• natural or synthetic gypsum calcium
• C is in sufficient quantity so that the sulfate ions of C can react with B and with A; that is, sufficient sulfate C remains for the activation of slag A, once all the aluminous or sulfoaluminous cement B has been consumed.
• the C / A and C / B mass ratios are for example the following:
• Component D Ca (OHh and / or Portland cement CEM
• Lime..ça (OH) _2 It can be provided by quicklime, slaked lime, aerial lime, or hydraulic lime.
• ca (OH) 2 is chosen from the group comprising - ideally constituted by - the following lime: CL 90, DL 85, CL 80, DL 80, CL 70, DL 70, HL 2, HL 3.5, HL 5, NHL 2, NHL 3.5, NHL 5, NHL - Z, and mixtures thereof
• Portland cement complies with that defined in European standard EN 197-1 which includes 5 CEM I classes: Portland cement; CEM II: composite Portland cement; CEM III: blast furnace cement; CEM IV: pozzolanic cement; CEM V: composite cement.
• it can be lithium carbonate, potassium carbonate and / or sodium carbonate.
• Lithium carbonate is preferred.
• F is a metal carbonate and / or bicarbonate, preferably NaHCC>3;Na2CC>3; K2CO3, KHCO3 being preferred.
• [D] and [F] are in sufficient quantities to react in a formulation comprising the binder, aggregates, fillers, water, and, optionally, additives, and to bring the pH of this wet formulation to a higher value or equal to 12, preferably greater than or equal to 13. This may correspond, for example, to the following [F] / [D] ratios:
• Binding agent G different from A, B and D
• G is preferably chosen from the group comprising - or better still constituted by -: siliceous or silico-aluminous binders, fly ash, advantageously silico-aluminous fly ash, silico-calcaluminous fly ash, calcined clay dust or expanded and / or metakaolins.
• metakaolins obtained by flash process or traditional process, type C or F fly ash.
• This composition is for example an adhesive mortar, a screed or a coating.
• the ABCDEF components their respective proportions are defined above.
• the aggregates or fillers H, the redispersible polymers I, the thickeners J and the retarders K are defined below.
• fillers and / or sands preferably from siliceous, limestone, silico-limestone, magnesian sands and their mixtures, siliceous, limestone and sand-lime fillers, magnesians and their mixtures, and / or from metal oxides, aluminas, and / or from glass beads and natural and synthetic silicate minerals preferably chosen from clays, micas, metakaolins, silica fumes and mixtures thereof.
• I is chosen from the group comprising or better still constituted by the families of acrylic homo or copolymer resins, vinyl acetate-ethylene copolymers, styrene-acrylic copolymers, terpolymers of vinyl acetate, of vinyl versatate and of acid dialkyl ester. maleic, vinyl acetate and vinyl versatate copolymers, styrene and butadiene copolymers, and mixtures thereof.
• I is chosen from the group comprising or better still consisting of polysaccharides and preferably cellulose or starch ethers and mixtures thereof, and preferably from the group comprising methylcelluloses, hydroxyethylcelluloses, methylhydroxy-propylcelluloses, methylhydroxyethyl- celluloses and their mixtures, or from modified or unmodified guar ethers and mixtures thereof or the mixture of these different families [0052]
• K retarders are chosen from the group comprising or better still consisting of polysaccharides and preferably cellulose or starch ethers and mixtures thereof, and preferably from the group comprising methylcelluloses, hydroxyethylcelluloses, methylhydroxy-propylcelluloses, methylhydroxyethyl- celluloses and their mixtures, or from modified or unmodified guar ethers and mixtures thereof or the mixture of these different families [0052]
• K is chosen from the group comprising or better still consisting of calcium chelating agents, carboxylic acids and their salts, polysaccharides and their derivatives, phosphonates, lignosulphonates, phosphates, borates, and salts of lead, zinc , copper, arsenic and antimony, and more particularly from tartaric acid and its salts, preferably its sodium or potassium salts, citric acid and its salts, preferably its sodium salt (trisodium citrate), gluconates sodium; sodium phosphonates; sulphates and their sodium or potassium salts, and mixtures thereof
• additives can also be used in the dry composition of mortar, in particular of adhesive mortar.
• additives can be setting accelerators, water retainers, light fillers, water repellents, dyes, fibers, antifoams, rheological agents, air entraining agents or foaming agents, agents generating gas, flame retardants ... and their mixtures.
• the setting accelerator additive can be selected from the group comprising or better still consisting of the alkali and alkaline earth salts of hydroxides, halides, nitrates, nitrites, carbonates, thiocyanates, sulphates, thiosulphates.
• perchlorates silica, aluminum, and / or from carboxylic and hydrocarboxylic acids and their salts, alkanolamines, insoluble silicate compounds such as silica fumes, fly ash or natural pozzolans, quaternary silicate ammonium compounds, compounds finely divided minerals such as silica gels or finely divided calcium and / or magnesium carbonates, and mixtures thereof;
• this additional setting accelerator (e) preferably being chosen from the group comprising or better still consisting of chlorides and their sodium or calcium salts; carbonates and their sodium or lithium salts, sulphates and their sodium or potassium salts, calcium hydroxides and formates and mixtures thereof;
• the coloring additive is advantageously chosen from the group comprising or better still constituted by organic and / or inorganic pigments, and more particularly from oxides of iron, titanium, chromium, tin, nickel, cobalt, Zinc, antimony, and / or from polysulphurized sodium aluminosilicates, carbon, cobalt, manganese or zinc sulphides, and / or from pigments with high transparency or high reflectance to infrared and their mixtures.
• the light filler additive is advantageously selected from the group comprising or better still constituted by: expanded perlite, expanded vermiculite, silica aerogels, expanded polystyrene, cenospheres (fillites®), hollow alumina beads, expanded clays, pumice, hollow glass beads (type 3M®) or expanded glass granules (Poraver®, Liaver®), silicate foam grains, rhyolite (Noblite®).
• the water-repellent additive is advantageously chosen from the group comprising or better still consisting of fluorinated, silanized, silicone or siloxane agents, metal salts of fatty acids and their mixtures, preferably from sodium, potassium and / or magnesium salts. oleic and / or stearic acids and mixtures thereof.
• the fiber additive preferably comprises mineral, animal, plant and synthetic fibers, more particularly chosen from the group comprising or better still constituted by fibers of polyamide, polyacrylonitrile, polyacrylate, cellulose, polypropylene, polyvinyl alcohol , glass, metallic, linen, polycarbonate, sisal, jute, hemp and mixtures of these fibers.
• the anti-foam additive is preferably chosen from the group comprising or better still consisting of polyether polyols, hydrocarbon molecules, silicone molecules, hydrophobic esters, nonionic surfactants, polyoxiranes, and mixtures thereof.
• the rheological agent additive is preferably chosen from the group comprising or better still consisting of thickening agents, thinning agents (mineral and / or organic) and their mixtures, and preferably from the subgroup comprising or better still consisting of polysaccharides and their derivatives, polyvinyl alcohols, mineral thickeners, linear polyacrylamides, polynaphthalene sulfonates, polymelamine sulfonates, polycarboxylate ethers, polycarboxylate esters and mixtures thereof.
• the surfactant additive is anionic, nonionic or amphoteric.
• Sources of anionic surfactants are, for example, alkyl sulfates, alkyl ether sulfates, alkaryl sulfonates, alkylsuccinates, alkylsulpho succinates, alkoyl sarcosinates, alkyl phosphates, alkylether phosphates, alkylether carboxylates, and / or alpha olefin sulfonates. .preferentially sodium lauryl sulfate.
• the nonionic surfactants are, for example, ethoxylated fatty alcohols, mono or dialkyl alkanolamides, and / or alkyl polyglucosides.
• Amphoteric surfactants are, for example, alkyl amine oxides, alkyl betaines, alkyl amido propyl betaines, alkyl sulphobetaines, alkyl glycinates, alkyl amphopropionates, and / or alkyl amidopropyl hydroxysultaines.
• the additive which generates gas in situ is advantageously chosen from adjuvants which, on contact with the compositions according to the invention, generate oxygen, hydrogen, nitrogen, carbon monoxide or dioxide, ammonia. , methane. They can be chosen from the adjuvants described in US Pat. No.
• the flame retardant additive is advantageously chosen from the group comprising or better still constituted by flame retardants having chemical and / or physical actions, halogenated flame retardants, phosphorous flame retardants, nitrogenous flame retardants, systems intumescent agents, mineral flame retardants, metal hydroxides, zinc compounds, borates, antimony oxides, nanocomposites based on clays based on aluminum silicates, and mixtures thereof; preferably from the subgroup comprising or better still consisting of tetrachlorobisphenolA (TBBPA), chloroparaffins, organic phosphates, red phosphorus, phosphonates, phosphinates, melamine, its salts and homologues, aluminum or magnesium hydroxides, zinc hydroxystannates, zinc borate, and mixtures thereof.
• TBPA tetrachlorobisphenolA
• the invention also relates to a CDEF activation system for AB binder.
• the invention also relates to a wet formulation obtained from the dry composition defined above mixed with water, preferably with a mixing ratio of between 10 and 35%, preferably between 15 and 30%.
• the invention also relates to a process for preparing the above-mentioned wet formulation.
• the invention also relates to the use of a CDEF activation system for AB binder.
• the invention also relates to the hardened products for the building obtained from the aforementioned wet formulation and / or that obtained by the process defined below, namely in particular the following hardened products: products obtained on site by hardening of the wet formulations resulting from the mixing compositions according to the invention, eg: adhesive mortars, joints, leveling coatings, smoothing coatings; screeds, light screeds for heated floors; exterior coatings such as Thick Mineral Coatings (RME) or Thin (RMM) and mineral paints; components of Exterior Thermal Insulation (ETI) systems including the insulation glue, the undercoat used to fix the mesh and the exterior finish plaster; tile adhesives; tile joints; joint plasters; interior and exterior plasters, for example single-layer plasters; insulating material for the exterior or interior of buildings; filling mortars or concretes; setting and sealing mortar, concrete repair mortars, freeze-thaw resistant mortars, concrete waterproofing system, waterproofing membranes; injection grout, light grout for cementing oil wells; mortars or lightweight concrete intended to be placed
• the invention also relates to building or civil engineering works produced at least in part with a wet formulation, this formulation hardening after its application and its shaping, or from hardened building products.
• the invention also relates to the processes for preparing the aforementioned dry composition, the process for applying the wet formulation defined above on a building surface or the process for manufacturing hardened products for the building, building works. or civil engineering by means of the wet formulation according to the invention.
• Table 1 below gives the formulas of 3 adhesive mortar compositions C2S, C2S2, C2F, according to Examples 1, 2 and 3
• Binder A granulated and ground blast furnace slag Ecocem® ground slag
• Component B TERNAL® RG calcium aluminate cement from Imerys® Aluminates - CaO-AbOs - 2CaO.AI2O3.SiO2 - 12Ca0.7AI 2 0 3 - 2Ca0.Si0 2 - 4Ca0.AI 2 03.Fe 2 03
• Component C source of CaS0 4 sulfate ions "SULFACAL AH MICRO AF”, micronized anhydrite from SMA FAULQUEMONT 57
• Component D Tradical® H90 from LHOIST (Précy sur Oise / U59)
• Component I redispersible polymer based on a vinyl acetate / vinyl chloride / ethylene copolymer having a minimum film-forming temperature of 5 ° C.
• Component J Hydroxyethylmethylcellulose (HEMC) of MW 40,000 or pregelatinized starch ether 500-1500 mPa.s OPAGEL CMT d'AVEBE®
• Component E lithium carbonate from RODACHEM BV
• Component F alkalinization reagent NaHCO3 from BRENNTAG SA
• Retarder K tartaric acid from Ets FAURE ET FILS, trisodium citrate from BRENNTAG SA, sodium gluconates from UNIVAR, citric acid from UNIVAR.
• NF EN 196-1 The standard used for the test to determine flexural and compressive strengths is NF EN 196-1.
• the powdered raw materials are weighed independently following the formulations.
• the raw materials are then mixed in a “GUEDU” type powder mixer for 3 minutes.
• the binder, the activation system and the mortars, in particular the adhesive mortars, according to the invention are economical, have a good open time and good transfer, satisfactory setting time at 5 and 20 ° C, good deformability with low levels of redispersible polymer, absence of corrosive “Xi” labeling on the bags of dry mortar.
• the wet formulations according to the invention also exhibit good workability, which facilitates processing.
• Tables 3 & 4 below give the formulas and the performances of 3 compositions of C2S1 adhesive mortars and of 2 compositions of C2F adhesive mortars. The materials used, the preparation of the mortars and the tests are the same as for Examples 1 to 3. Table 3 [0071] Table 4
• Table 6 below gives the formulas and the performances of 2 adhesive mortar compositions.
• the preparation of the mortars and the tests are the same as for examples 1 to 10

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