EP3696317A1 - Spun-dyed fiber and method for its manufacture - Google Patents

Spun-dyed fiber and method for its manufacture Download PDF

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Publication number
EP3696317A1
EP3696317A1 EP19020073.3A EP19020073A EP3696317A1 EP 3696317 A1 EP3696317 A1 EP 3696317A1 EP 19020073 A EP19020073 A EP 19020073A EP 3696317 A1 EP3696317 A1 EP 3696317A1
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EP
European Patent Office
Prior art keywords
fiber
cellulose
fibers
solution
color pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19020073.3A
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German (de)
English (en)
French (fr)
Inventor
Friedrich Suchomel
Peter Wessely
Claudia MOMMER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lenzing AG
Original Assignee
Lenzing AG
Chemiefaser Lenzing AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lenzing AG, Chemiefaser Lenzing AG filed Critical Lenzing AG
Priority to EP19020073.3A priority Critical patent/EP3696317A1/en
Priority to TW108148377A priority patent/TW202041745A/zh
Priority to PCT/EP2020/053794 priority patent/WO2020165363A1/en
Priority to CN202080014346.0A priority patent/CN113412350A/zh
Priority to EP20703503.1A priority patent/EP3924547A1/en
Publication of EP3696317A1 publication Critical patent/EP3696317A1/en
Withdrawn legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/04—Pigments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08—Composition of the spinning solution or the bath
    • D01F2/12—Addition of delustering agents to the spinning solution
    • D01F2/14—Addition of pigments
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

Definitions

  • This invention relates to a spun-dyed man-made cellulosic fiber with incorporated color pigment which contains a polycationic compound on its outer surface. Furthermore a method for the manufacture of such a fiber is disclosed.
  • WO 2004/081279 A1 discloses a method for dyeing cellulosic fibers, wherein a polycationic compound is incorporated into the cellulosic fibers during their manufacture.
  • the cationic cellulose fibers thus obtained show improved affinity for direct dyestuffs, acid dyestuffs and reactive dyestuffs.
  • the fibers according to this invention are not spun-dyed fibers and the applied dyestuffs are not pigments.
  • EP 0683251 A1 discloses numerous polycationic compounds suitable for the process according to WO 2004/081279 A1 .
  • such polycationic compounds can decrease the spinnability of the spinning solution significantly, in particular in the viscose process.
  • long-chain polycationic compounds induce too early coagulation of the cellulose.
  • Polycationic compounds with short chain length on the one hand have insufficient pigment fixation effect, on the other hand they are washed out in the spin bath and pollute the spin bath cycles.
  • WO 2014/118804A1 discloses black colored man-made cellulosic fibers and a black colorant formulation for preparing the same in a viscose process.
  • a formulation containing among others a black color pigment, i.e. carbon black, as well as a surface active agent, an anti-coagulating agent and a steric stabilizer is mixed into a viscose dope.
  • the surface active agent as well as the anti-coagulating agent should be anionic substances.
  • the black colored fibers were then washed for in total 15 minutes at the remarkably high washing bath temperature of 90°C with water, subsequently sulphuric acid and finally sodium hydroxide solutions. It must be assumed that during these washing steps all surplus black pigments are washed out of the fibers. But due to the harsh conditions, long processing times and the large quantities of washing lyes with black pigments such a process is neither economically nor ecologically feasible. However, in a usual commercially feasible fiber plant the washing steps cannot be washed for more than about 1 to 4 minutes in total.
  • the problem to be solved consisted in providing spun-dyed cellulosic fibers without or with at least drastically reduced bleeding as well as a process for manufacturing such fibers without long processing times and without producing large quantities of used washing lyes containing black pigments.
  • the fiber according to the invention shows a zeta potential of zero or positive at a pH of 3.0 or lower. All presently known spun-dyed cellulosic man-made fibers have a negative zeta potential.
  • the incorporated color pigment in particular is a negatively charged color pigment, e.g. carbon black, but among others also indigo in the oxidized form would be suitable.
  • the color pigment is carbon black.
  • the fiber according to the invention has a positive zeta potential in an acidic environment and at any pH value the zeta potential is significantly more positive (or less negative) than that of the untreated fiber without polycations.
  • the zeta potential of a fiber treated according to the invention may be at least 1mV more positive than that of the same fiber, i.e. containing the same incorporated pigment, but without the treatment of the invention, at the same pH value. Typically it may be about 3mV more positive over the whole pH range from pH 3 to pH 11.
  • the polycationic compound is one out of the group containing polymeric quaternary ammonium compounds, in particular poly(diallyldimethylammonium chloride), cationically modified starch and polyethylenimines.
  • polymeric quaternary ammonium compounds in particular poly(diallyldimethylammonium chloride), cationically modified starch and polyethylenimines.
  • a high electrical charge density is beneficial because it allows obtaining the intended effect with low quantity of the polycationic compound.
  • Polyvinylpyrollidon is a polycation as well, but shows significantly less performance in the present invention.
  • Polyamines first have to be treated with an acid, e.g. acetic acid, before they can be applied to the fibers, which is a practical disadvantage.
  • Poly(diallyldimethylammonium chloride) is a harmless compound which is e.g. used in cosmetics.
  • the fiber contains between 0,50 and 0,02 %(w/w), preferably between 0,2 and 0,04%(w/w), of the polycationic compound, in relation to the bone dry weight of the fiber.
  • the fiber shows a bleeding number of between 4.0 and 5.0 according to the bleeding test.
  • the fiber is a xanthate fiber.
  • a xanthate fiber in the context of this invention is a cellulosic fiber which was manufactured by extrusion of a spinning solution containing a dissolved cellulosic compound into a spin bath, wherein the cellulosic compound is cellulose xanthate and wherein the cellulose xanthate is regenerated into cellulose while passing the spin bath.
  • the most common xanthate fibers are called "Viscose" resp. "Modal” according to BISFA (International Bureau for the Standardization of Man-Made Fibres): “Terminology of man-made fibres", 2009 Editi on (hereinafter the "BISFA terminology").
  • Viscose fiber is produced by extruding a solution of a cellulose derivative through very small spinneret holes and then coagulating by changing the pH and by converting the derivative back to cellulose.
  • Cellulose as wood pulp is usually used as the starting material although other sources of cellulose such as bamboo and cotton linters are also used.
  • the wood pulp is steeped in sodium hydroxide and then reacted with carbon disulphide to convert it to cellulose xanthate.
  • the xanthate is dissolved in a sodium hydroxide solution to yield a viscous, golden colored liquid which is commonly called viscose.
  • the viscose is de-aerated and filtered. It is then extruded through precious metal spinnerets into a spinbath - a so-called wet spinning technology - consisting of sulphuric acid, sodium sulphate and zinc sulphate.
  • the acid reacts with the sodium hydroxide in the viscose to cause coagulation of the cellulose xanthate.
  • the acid also reacts with the cellulose xanthate converting it back to cellulose.
  • the fibre may then be cut into lengths to form staple fibre or it may be kept as continuous filament or tow depending on the design of the spinning machine and the product required.
  • the fibre is washed to remove non-cellulose products of the reaction such as sodium sulphate and hydrogen sulphide, finished with a spin finish and anti-stat to aid downstream processing and dried.
  • Modern viscose plants are designed to recover as much of the by-products of the process as possible. This is essential to avoid environmental pollution and to ensure the safety of the workforce and surrounding community. Better recovery and recycling of by-products can also give a positive economic benefit.
  • Modal fibre is a high wet modulus fibre produced using a modified version of the viscose process.
  • An additive is mixed with the spinning solution which slows down the regeneration of the cellulose during spinning. Together with modified spinbath and viscose composition, the additive allows the fibre to be stretched to a much greater extent than normal viscose. This gives a fibre with a higher orientation which is stronger than viscose and has a modulus closer to that of cotton.
  • Modal fibre is often used in blend with cotton to give softer fabrics than would be made with cotton alone. It is used widely in knitted fabrics for lingerie and ladies apparel.
  • Lyocell is produced by a solvent spinning process.
  • the solvent is a mixture of an amine oxide, in particular N-methylmorpholine-N-oxide ("NMMO") which is non-toxic, in water.
  • NMMO N-methylmorpholine-N-oxide
  • a slurry of cellulose in a mixture of amine oxide and water is prepared. Water is removed from the slurry by evaporation and as the water content decreases, the cellulose dissolves in the amine oxide producing a solution which is a viscous liquid above 80°C.
  • the solution is extruded through spinneret holes via an air gap into an aqueous coagulation bath - a so-called dry-jet wet spinning technology.
  • the solvent is diluted by the water and the cellulose coagulates to form a fibre.
  • the fibre is washed to remove any amine oxide solvent, cut into staple fibre, finished with a lubricant and an antistatic agent and then dried.
  • the tow of newly formed fibre is cut into staple fibre of the required length and then washed on a moving wash bed. The washed fibre is dried in a flatbed dryer.
  • lyocell is produced as a continuous filament yarn by winding a bundle of filaments onto a package for subsequent use.
  • lyocell is produced directly as a nonwoven fleece by using a solution-blowing extrusion spinneret and subsequent coagulation, washing and winding.
  • the fiber is a Modal fiber (according to the BISFA terminology).
  • the fiber is a Lyocell fiber (according to the BISFA terminology).
  • a fiber according to the invention which is dispersed in water may not show neutral behavior but may influence the pH value of the water. This effect can be measured easily and is called the "fiber pH".
  • the skilled in the art may consider this among others in further fiber processing within the textile chain.
  • the fiber pH of the fiber according to the invention is higher than 6.1. It may be preferably lower than 8,5 and in particular may be between 6.1 and 7.3.
  • Another aspect of the present invention is a method for the manufacture of a spun-dyed man-made cellulosic fiber with incorporated color pigment with the following steps:
  • the incorporated color pigment in particular is a negatively charged color pigment, e.g. carbon black, but among others also indigo in the oxidized form would be suitable.
  • the color pigment is carbon black.
  • the polycationic compound is one out of the group containing polymeric quaternary ammonium compounds, in particular poly(diallyldimethylammonium chloride), cationically modified starch and polyethylenimines.
  • the polycationic compound is poly(diallyldimethylammonium chloride) ("PolyDADMAC").
  • the fibers between step c. and step g. always contain at least 50%(w/w), preferably at least 60%(w/w) water in relation to the cellulose content. Usually they contain significantly more water, due to the nature of the process steps. For example after coagulation the fibers are highly swollen and may contain more than 200%(w/w) water in relation to the cellulose content. Even after washing and before drying the fibers contain more than 100%(w/w) water in relation to the cellulose content.
  • the cellulose-containing spinning solution is a solution of the xanthate type - i.e. either according to the viscose process or according to the modal process, as described above - and step b. is performed according to a wet spinning technology and wherein the fiber tow is guided through a second drawing zone between step c. and step d..
  • the cellulose-containing spinning solution is a solution of the lyocell type and step b. is performed according to a dry-jet wet spinning technology.
  • step g. is characterized by the following parameters:
  • Some commercial viscose fiber plants have aftertreatment units which allow a treatment time of about 60 seconds.
  • the polycation concentration required in the treatment bath depends on the content of the color pigment in the fibers, which itself depends on the fiber titer.
  • thinner fibers i.e. fibers with a lower fiber titer, need a higher pigment concentration than thicker fibers due to various optical effects depending on the fiber diameter and fiber surface.
  • a 1,5dtex modal fiber has a carbon black content of 4,3%(w/w)
  • a 1,0dtex modal fiber needs a content of 4,9%(w/w) of the same carbon black pigment in order to achieve the same black appearance in the end products (yarns, fabrics, garments).
  • a thicker fiber e.g.
  • 1,7dtex viscose will only require 3,8%(w/w) of the same carbon black pigment. Accordingly to obtain a bleeding number of 5,0, said 1,5dtex modal fiber had to be treated with a PolyDADMAC concentration of 0,75g/l in the treatment bath, while said 1,0dtex modal fiber required 0,85g/l and said 1,7dtex viscose fiber required 0,5g/l, only.
  • Step g. may be characterized by a ratio of fiber mass to treatment liquid of between 1:0,1 and 1:5, preferably between 1:0,5 and 1:4, more preferably between 1:0,8 and 1:3.
  • PolyDADMAC with a molecular weight of more than 25.000 Dalton may be used.
  • the molecular weight may be lower than 1.000.000 Dalton, preferably between 50.000 and 1.000.000 Dalton; if the molecular weight is higher, then the viscosity of the treatment liquid becomes too high and cannot be used effectively according to the invention.
  • a molecular weight of 100.000 Dalton gives no significant viscosity increase; 400.000 Dalton still give no problems in terms of increased viscosity.
  • the fiber samples are loosened by hand to obtain good accessibility for the liquid.
  • 200ml of demineralized water are poured into a Labomat beaker of a Mathis laboratory dyeing device and are heated up to 85°C as fast as possible.
  • 5g of the loosened fiber sample is put into the beaker and the whole beaker content is heated up to 98°C as fast as possible, kept at this temperature for 5 minutes and subsequently cooled down to 70°C as fast as possible.
  • the water is poured into a 100ml glass bottle (colorless glass) until the bottle is completely filled. The bottle is allowed to cool down to room temperature.
  • the color of the water is then compared to a grey scale according to (ISO 105-A03: 1993; augmented scale including four half-steps and, thus, 9 steps).
  • the value obtained according to this ISO standard will be between 1 and 5 and, for the purposes of this invention, is called "bleeding number". A bleeding number of 5 means that there is no bleeding at all.
  • EKA Electrokinetic Analyzer
  • the streaming solution is used to rinse the Electrokinetic Analyzer (EKA) device, and then discarded. 500 ml of the streaming solution is used for the zeta potential measurements.
  • the measuring cell of the Electrokinetic Analyzer (EKA) device is cylindrical with an inner diameter of 2 cm.
  • the pre-wet fiber sample is placed in the approximate middle of the cell, and is book-ended on both sides by Ag/AgCI electrodes.
  • the electrodes have perforations that allow the flow of streaming solution through the fiber sample.
  • the fiber sample has to be tightly packed to ensure that there is no significant movement of the fibers with the flow of the streaming solution.
  • the packing density can be controlled by the distance between the two electrodes, which in these measurements was between 0.5-0.6 cm.
  • the packing density was between 0.27-0.32 g/cm3 in these measurements. It is ensured there is no air trapped in the fiber sample by circulating the streaming solution through the fiber sample, and the measurement is started with the onboard software of the Electrokinetic Analyzer (EKA) device.
  • the measurements were performed as the streaming solution pH was altered from the initial value of pH 11 to pH 3 in pH0.25 unit steps by the addition of 0.1 M HCI. This is performed with an autotitrator under software control (available among others from company Anton Paar/Austria.
  • the streaming solution is replaced with a solution of 0.1 M KCI, and the solution is flushed through the system with repeated rinses.
  • the nitrogen content of the fibers was measured with a LECO FP 328 nitrogen analyzer (supplier: LECO Corporation/Saint Joseph, U.S.A.) according to the Dumas method.
  • the fibers were used in a conditioned state, conditioned until equilibrium is reached in a standard atmosphere at 20°C and 65% relative air humidity. The nitrogen content is given in relation to the weight of the fibers in conditioned state.
  • Fibers of a linear density of 1,5dtex were manufactured according to a modal process as described in AT 287905 B , with a carbon black content of 4,3%(w/w). After coagulation the fiber tow was drawn, washed with water, cutted to a staple length of 39mm and laid down on the sieve belt of a conventional aftertreatment line in order to form a fiber fleece. The fiber fleece was washed again with water and subsequently impregnated in a separate stage of the aftertreatment line for a retention time of 60 seconds with a treatment liquid containing a PolyDADMAC, at a PolyDADMAC concentration in the treatment liquid according to Table 1.
  • the PolyDADMAC was supplied by company SNF (specification: " ⁇ 100.000 Dalton").
  • the fiber fleece was washed, most of the liquid phase squeezed off and finished with a spin finish at 5 g/l spin finish in the bath liquid. Thereafter the fibers were evaluated by the bleeding test for bleeding.
  • the results are given in Table 1; the colors of the washing waters from the bleeding test are shown in Fig. 1 ; the numbers are the numbers of the examples; "0" is pure water. Acceptable fibers must have a bleeding number of 4 or higher.
  • Example 1 comparative, no polycationic treatment
  • Example 4 according to the invention was measured as described above, in dependence of the pH of the surrounding liquid. Results are shown in Figure 2 .
  • the fiber according to the invention has a positive zeta potential in an acidic environment and at any pH value the fiber surface is significantly more positive (or less negative) than the untreated fiber without polycations. By the zeta potential the presence of the polycations can be detected over the whole pH range.
  • Example 1 showed a nitrogen content of 0,015 % (w/w)
  • Example 2 showed 0,018% (w/w)
  • Example 4 showed 0,022% (w/w).
  • Fibers with 1,0dtex resp. 1,7dtex were manufactured according to the same method as in Example 1 (see Table 1).
  • a 1,0dtex modal fiber needs a content of 4,9%(w/w) of the same carbon black pigment in order to achieve the same black appearance in the end products (yarns, fabrics, garments).
  • a thicker fiber, e.g. 1,7dtex viscose will only require 3,8%(w/w) of the same carbon black.
  • Polycation concentration in the treatment bath and fiber properties see Table 1.
  • Table 1 Example Fiber titer [dtex] carbon black content [%(w/w)] Polycation conc.
EP19020073.3A 2019-02-15 2019-02-15 Spun-dyed fiber and method for its manufacture Withdrawn EP3696317A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP19020073.3A EP3696317A1 (en) 2019-02-15 2019-02-15 Spun-dyed fiber and method for its manufacture
TW108148377A TW202041745A (zh) 2019-02-15 2019-12-30 色紡纖維及其製造方法
PCT/EP2020/053794 WO2020165363A1 (en) 2019-02-15 2020-02-13 Spun-dyed fiber and method for its manufacture
CN202080014346.0A CN113412350A (zh) 2019-02-15 2020-02-13 色纺纤维及其制造方法
EP20703503.1A EP3924547A1 (en) 2019-02-15 2020-02-13 Spun-dyed fiber and method for its manufacture

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Application Number Priority Date Filing Date Title
EP19020073.3A EP3696317A1 (en) 2019-02-15 2019-02-15 Spun-dyed fiber and method for its manufacture

Publications (1)

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EP3696317A1 true EP3696317A1 (en) 2020-08-19

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EP20703503.1A Pending EP3924547A1 (en) 2019-02-15 2020-02-13 Spun-dyed fiber and method for its manufacture

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EP20703503.1A Pending EP3924547A1 (en) 2019-02-15 2020-02-13 Spun-dyed fiber and method for its manufacture

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EP (2) EP3696317A1 (zh)
CN (1) CN113412350A (zh)
TW (1) TW202041745A (zh)
WO (1) WO2020165363A1 (zh)

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CN116657264A (zh) * 2023-06-01 2023-08-29 潍坊欣龙生物材料有限公司 一种提高黑色纤维素纤维的色深度和光泽度的方法

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AT287905B (de) 1968-09-20 1971-02-10 Chemiefaser Lenzing Ag Verfahren zur Herstellung von Faden aus regenerierter Cellulose
JPS63303108A (ja) * 1987-06-03 1988-12-09 Nippon Shokubai Kagaku Kogyo Co Ltd 原液染ビスコ−スレ−ヨン用着色剤
EP0683251A1 (de) 1994-05-17 1995-11-22 Hoechst Aktiengesellschaft Aminierung von cellulosischen Synthesefasern
EP1093536B1 (en) 1998-06-05 2003-10-01 Tencel Limited Nonwoven fabric and method of its manufacture
WO2004081279A1 (de) 2003-03-13 2004-09-23 Lenzing Aktiengesellschaft Verfahren zum färben einer mischung aus zwei oder mehr unterschiedlichen fasertypen
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WO2014118804A1 (en) 2013-01-29 2014-08-07 Aditya Birla Science & Technology Company Limited Black colored fiber and a black colorant formulation for preparing the same
WO2015154110A1 (en) * 2014-04-07 2015-10-15 Lenzing Ag Colored blends of fibers and their use
EP2977507A1 (en) * 2013-03-19 2016-01-27 Mitsubishi Rayon Co., Ltd. Cationizing agent, method for firmly fixing water-insoluble particles, and method for producing dyed material

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CN104532408A (zh) * 2014-09-24 2015-04-22 江苏金太阳纺织科技有限公司 阳离子接枝改性无盐染色再生纤维素纤维的制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB885462A (en) * 1958-01-28 1961-12-28 Courtaulds Ltd Improvements in and relating to the production of coloured filaments, threads and the like from viscose
AT287905B (de) 1968-09-20 1971-02-10 Chemiefaser Lenzing Ag Verfahren zur Herstellung von Faden aus regenerierter Cellulose
JPS63303108A (ja) * 1987-06-03 1988-12-09 Nippon Shokubai Kagaku Kogyo Co Ltd 原液染ビスコ−スレ−ヨン用着色剤
EP0683251A1 (de) 1994-05-17 1995-11-22 Hoechst Aktiengesellschaft Aminierung von cellulosischen Synthesefasern
EP1093536B1 (en) 1998-06-05 2003-10-01 Tencel Limited Nonwoven fabric and method of its manufacture
WO2004081279A1 (de) 2003-03-13 2004-09-23 Lenzing Aktiengesellschaft Verfahren zum färben einer mischung aus zwei oder mehr unterschiedlichen fasertypen
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