EP3541521A1 - Procédé de production de farine de grains entiers - Google Patents
Procédé de production de farine de grains entiersInfo
- Publication number
- EP3541521A1 EP3541521A1 EP17811208.2A EP17811208A EP3541521A1 EP 3541521 A1 EP3541521 A1 EP 3541521A1 EP 17811208 A EP17811208 A EP 17811208A EP 3541521 A1 EP3541521 A1 EP 3541521A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- caryopses
- reactor
- ground
- process according
- rotor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000020985 whole grains Nutrition 0.000 title claims abstract description 31
- 235000012054 meals Nutrition 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 30
- 230000008569 process Effects 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 38
- 239000002245 particle Substances 0.000 claims abstract description 23
- 235000013339 cereals Nutrition 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000018044 dehydration Effects 0.000 claims abstract description 17
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 17
- 238000000227 grinding Methods 0.000 claims abstract description 14
- 238000007599 discharging Methods 0.000 claims abstract description 6
- 230000009471 action Effects 0.000 claims abstract description 4
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 235000015173 baked goods and baking mixes Nutrition 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 235000013312 flour Nutrition 0.000 description 17
- 235000015895 biscuits Nutrition 0.000 description 11
- 235000014594 pastries Nutrition 0.000 description 10
- 244000098338 Triticum aestivum Species 0.000 description 8
- 150000002632 lipids Chemical class 0.000 description 7
- 230000008901 benefit Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 239000011782 vitamin Substances 0.000 description 4
- 229940088594 vitamin Drugs 0.000 description 4
- 229930003231 vitamin Natural products 0.000 description 4
- 235000013343 vitamin Nutrition 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 235000016709 nutrition Nutrition 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 235000019640 taste Nutrition 0.000 description 3
- 241000219317 Amaranthaceae Species 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 240000005979 Hordeum vulgare Species 0.000 description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 102000003820 Lipoxygenases Human genes 0.000 description 2
- 108090000128 Lipoxygenases Proteins 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 240000006394 Sorghum bicolor Species 0.000 description 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000002144 chemical decomposition reaction Methods 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 235000007558 Avena sp Nutrition 0.000 description 1
- 240000006162 Chenopodium quinoa Species 0.000 description 1
- 235000014966 Eragrostis abyssinica Nutrition 0.000 description 1
- 244000140063 Eragrostis abyssinica Species 0.000 description 1
- 240000008620 Fagopyrum esculentum Species 0.000 description 1
- 235000009419 Fagopyrum esculentum Nutrition 0.000 description 1
- 241000219050 Polygonaceae Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 244000082988 Secale cereale Species 0.000 description 1
- 240000000359 Triticum dicoccon Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 108010050181 aleurone Proteins 0.000 description 1
- 235000012735 amaranth Nutrition 0.000 description 1
- 239000004178 amaranth Substances 0.000 description 1
- 230000002547 anomalous effect Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 235000012970 cakes Nutrition 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000019522 cellular metabolic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007515 enzymatic degradation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 210000004276 hyalin Anatomy 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 235000012830 plain croissants Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 235000011845 white flour Nutrition 0.000 description 1
- 235000011875 whole grain product Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02B—PREPARING GRAIN FOR MILLING; REFINING GRANULAR FRUIT TO COMMERCIAL PRODUCTS BY WORKING THE SURFACE
- B02B1/00—Preparing grain for milling or like processes
- B02B1/04—Wet treatment, e.g. washing, wetting, softening
- B02B1/06—Devices with rotary parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02B—PREPARING GRAIN FOR MILLING; REFINING GRANULAR FRUIT TO COMMERCIAL PRODUCTS BY WORKING THE SURFACE
- B02B1/00—Preparing grain for milling or like processes
- B02B1/08—Conditioning grain with respect to temperature or water content
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02B—PREPARING GRAIN FOR MILLING; REFINING GRANULAR FRUIT TO COMMERCIAL PRODUCTS BY WORKING THE SURFACE
- B02B5/00—Grain treatment not otherwise provided for
- B02B5/02—Combined processes
Definitions
- the present invention relates to the sector of the food industry. More particularly, the invention relates to a process for the production of whole grain meal obtained from cereals.
- Cereals e.g. wheat, rice, corn, barley, sorghum, etc.
- Cereals are consumed the world over as the basis of an alimentary diet since they are the primary source of carbohydrates owing to the high starch content of the endosperm which is located in the central part of the caryopsis.
- the following layers which form the bran, are located as follows in the caryopsis, starting from the outside: pericarp, testa, nucellar layer (or hyaline layer) and aleurone, while the internal part consists of endosperm and germ.
- Flour is the main product obtained from the process of grinding the soft wheat and consists of the innermost starchy parts of the caryopsis (endosperm) after separation from the outermost parts (the bran, which represents about 15% of the total content of the caryopsis, and the germ, which forms about 3%) traditionally intended for livestock feeding.
- Meal is conventionally produced by breaking (grinding) the caryopses as such, followed by sieving of the fragments produced, which may contain only endosperm or parts of endosperm accompanied by bran and germ. The aforementioned fragments are then conveyed away for successive grinding and separation steps aimed at releasing and separating as far as possible the fractions of endosperm from the other components of the caryopsis.
- the whole grain flours which are commercially available are obtained by adding to a "white" flour, obtained essentially from the endosperm alone, the bran obtained by means of the aforementioned abrasion and decortication operations, after the same has undergone regrinding treatment, in order to reduce the particle size, and heat stabilization treatment, in order to prevent the oxidation caused by enzymatic degradation.
- the bran obtained in this way is in fact subject to degradation, even after a short period of time, owing to occurrence of oxidation reactions (rancidity) affecting the lipid components present in the bran, which may also contain germ parts very rich in lipids.
- Rancidity is generally caused by the activation of enzymes (lipase and lipoxygenase) which are present in the bran and attack the lipid portion present. Consequently, attempts have been made to prevent this phenomenon by deactivating these enzymes with heat.
- the heat treatment of bran may result in darkening of the bran, the creation of unpleasant tastes and chemical degradation affecting the lipid portion.
- the problem underlying the present invention has therefore been that of providing a meal which may be correctly defined as "whole grain", since obtained from the grinding of the entire caryopsis, said meal being able to be stored for a long period of time at room temperature without being affected by rancidity or degradation and having optimum organoleptic properties.
- a process for the production of a whole grain cereal meal which comprises the steps of: a) grinding cereal caryopses into particles of diameter of not less than 2 mm; b) providing a wet heat treatment reactor comprising a cylindrical tubular body with horizontal axis, having at least one opening for the introduction of the ground caryopses of step a) and water or an aqueous solution and at least one discharge opening, a heating jacket for raising the temperature of said tubular body to a temperature of at least 80°C, and a rotor, arranged inside the cylindrical tubular body and comprising a shaft provided with elements projecting radially therefrom; c) feeding a continuous flow of said ground caryopses into said reactor, wherein the rotor is rotated at a speed greater than or equal to 150 rpm; d) feeding into said reactor, together with said flow of ground caryopses, a continuous flow of water or aqueous solution, which is dispersed into
- a continuous flow of steam is fed into the wet heat treatment reactor through the aforementioned at least one inlet opening.
- a flow of gas preferably air, heated to a temperature of at least 100°C, is also fed into this reactor, through the aforementioned at least one inlet opening.
- the aforementioned aqueous solution may contain one or more water- soluble ingredients, selected from the group comprising salts, in particular sodium chloride, flavorings, water-soluble vitamins, in particular ascorbic acid, and natural antioxidants.
- water- soluble ingredients selected from the group comprising salts, in particular sodium chloride, flavorings, water-soluble vitamins, in particular ascorbic acid, and natural antioxidants.
- the temperature of the inner wall of the reactor for the wet heat treatment is preferably kept at 100- 160°C, conveniently at 100- 120°C.
- the rotational speed of the rotor of the reactor for wet heat treatment is preferably set to 500-3000 rpm.
- the residence time of the ground caryopses inside the wet thermal treatment reactor is preferably between 20 and 60 seconds.
- the temperature of the inner wall of the thermal dehydration and treatment reactor is preferably kept at 120-280°C, conveniently at 150- 190°C.
- the rotational speed of the rotor of the thermal dehydration and treatment reactor is preferably set to 300- 1200 rpm.
- the temperature of the gas flow fed into the thermal dehydration and treatment reactor is preferably between 120°C and 250°C, conveniently between 140°C and 190°C.
- the residence time of the ground caryopses inside the thermal dehydration and treatment reactor is preferably between 30 and 70 seconds.
- the water or aqueous solution fed into the wet heat treatment has preferably a temperature of 80- 1 10°C, conveniently 90- 1 10°C.
- the ratio between the flow rate of the water or aqueous solution fed into the wet heat treatment reactor and the flow rate of the wet ground caryopses particles fed into the wet heat treatment reactor is preferably comprised between 1 : 10 and 1 :2, conveniently between 1 :4 and 1 :2.5.
- the aforementioned elements radially projecting from the rotor shaft may be for example rod-like or in the form of vanes or V-blades or beaters.
- the process according to the invention may also comprise, prior to the aforementioned step b), a step where the aforementioned cereal caryopses ground into particles of diameter of not less than 2 mm are immersed in water at 80- 100°C for a time of between 15 and 60 minutes.
- Meal is understood as meaning a finely divided product which is obtained from the grinding of cereal seeds and may be in the form of flour, semolina or fine granules.
- cereals is understood as meaning plants belonging to different families, in particular Graminacee (wheat, rice, barley, rye, oat, corn, sorghum and teff), Polygonaceae (buckwheat), Amaranthaceae (amaranth) and Chenopodiaceae (quinoa).
- the present invention also relates to a whole grain cereal meal obtained by means of the aforementioned process, such as a bakery product obtained from such whole grain meal.
- the whole grain meal obtained with the process according to the present invention is particularly suitable for making bakery products which, compared to the bakery products made with refined flour, have the major advantage that they contain the components of high nutritional value present in the bran (fiber, minerals, vitamins), while at the same time they have organoleptic/ structural properties (color, taste, texture) entirely comparable to those of corresponding products obtained from completely bran-free meal. Moreover, these organoleptic/ structural properties remain substantially unchanged for the entire shelf-life of the finished product.
- FIG. 1 shows in schematic form an embodiment of a plant for implementing the process according to the present invention.
- an apparatus used for the process according to the present invention comprises a wet heat treatment reactor consisting essentially of a cylindrical tubular body 1 , closed at the opposite ends by end plates 2, 3 and coaxially provided with a heating/ cooling jacket intended to be passed through by a fluid, for example diathermic oil, so as to keep the inner wall of the body 1 at a predefined temperature.
- a wet heat treatment reactor consisting essentially of a cylindrical tubular body 1 , closed at the opposite ends by end plates 2, 3 and coaxially provided with a heating/ cooling jacket intended to be passed through by a fluid, for example diathermic oil, so as to keep the inner wall of the body 1 at a predefined temperature.
- the tubular body 1 is provided with inlet openings 5, 6 and 10, i.e. 5 for the water or aqueous solution, 6 for the caryopses and 10 for the steam, as well as a discharge opening 7.
- the tubular body 1 rotatably supports a rotor 8 comprising a shaft 8 provided with elements radially projecting therefrom in the form of blades 9 which are arranged helically and oriented so as to centrifuge and at the same time convey towards the outlet the flows of ground caryopses and water or aqueous solution.
- a motor M is provided for operation of the rotor at variable speeds ranging from 150 to 3000 rpm.
- the wet caryopses Upon exiting the reactor, the wet caryopses are fed via a pipe 1 1 , communicating with the discharge opening 7 of the wet heat treatment reactor, to the injector device 51.
- the body of the injector device 51 has a tubular shape and is provided with an inlet opening 55 which receives the ground caryopses from the pipe 1 1 , and an outlet opening 57.
- the tubular body 51 rotatably supports a bladed or screw rotor 58 which imparts to the wet ground caryopses an advancing thrust towards the outlet opening 57 so as to convey said wet ground caryopses to the inlet opening 105 of a thermal dehydration and treatment reactor 101.
- This reactor 101 which has a structure entirely similar to the wet treatment reactor mentioned further above, is not described in detail.
- the components of the thermal dehydration and treatment reactor which are identical to those of the wet heat treatment reactor are indicated by the same reference numbers increased by 100.
- the dried ground caryopses output from the thermal dehydration and treatment reactor are conveyed to a storage container 18 which separates them from the steam and air which are also output from this reactor.
- the dried ground caryopses are fed to a conventional cereal mill in order to reduce further the particle size and obtain corresponding whole grain cereal meal.
- the whole grain cereal meal obtained with the process according to the present invention in addition to the aforementioned advantages (presence of components with a high nutritional value (fiber, minerals, vitamins) together with organoleptic/ structural properties entirely similar to those of corresponding entirely bran-free meal and long storage life at room temperature, offers the further advantage of rapid baking times compared to the previously known whole grain meal.
- the mixtures for different types of bakery products obtained with the whole grain meal produced by the process according to the invention require an oven baking time which is substantially shorter than that required by mixtures prepared with conventional whole grain meal (but also non whole grain meal).
- the baking time may be reduced by about 30-40%.
- the wet heat treatment reactor 1 in which the bladed rotor 8 was rotated at a speed of 700 rpm, was continuously fed, via the opening 6, with a flow of soft wheat caryopses rough-ground beforehand inside a mill to obtain particles with a diameter of not less than 2 mm (average diameter 2.5 mm) (80 kg/h) having a moisture content of 13.5%.
- a flow of water at 80°C was continuously fed (20 kg/h) through the opening 5
- a flow of steam was continuously fed (15 kg/h) through the opening 10 at 105°C.
- the wall temperature was controlled to remain at a value of 180°C, while the rotational speed of the bladed rotor 108 was kept constantly at 1000 rpm.
- the ground caryopses were then fed to a cylinder mill where they underwent further grinding until a soft wheat whole grain flour with a grain size smaller than or equal to 300 ⁇ (diameter) was obtained.
- a dough for short pastry biscuits with the composition shown below was prepared using the soft wheat whole grain flour according to Example 1 :
- the ingredients of the short pastry biscuit were worked using conventional kneading methods inside a planetary machine with beater, mixing sugar and fat of the base recipe until a homogeneous dough was obtained and then adding the remaining ingredients.
- short pastry biscuits were prepared from a dough which had a composition similar to that described above, but in which a type 0 flour was used instead of the soft wheat whole grain flour of Example 1.
- the processing steps of Example 1 were repeated in an identical manner.
- the short pastry biscuits obtained from Examples 2 and 3 underwent evaluation by a panel of trained tasters who gave their opinion on various characteristics of the biscuits, such as the overall appearance, the consistency when tasted, the crumbliness and the fragrance, giving a score of 1 to 10 for each of the characteristics assessed.
- the overall average score was 8.1 for the short pastry biscuit according to Example 2 and 8.2 for the short pastry biscuit according to Example 3, namely substantially the same evaluation, despite the presence in the short pastry biscuit according to Example 2 of a significant amount of bran, which, as is well-known, tends to have a negative effect on the organoleptic and structural properties of the oven products.
- Brioches, croissants and cakes made using both batters and Danish pastry doughs were also prepared using the whole grain flour of Example 2, again with optimum results in terms of organoleptic/ structural properties and confirming in all cases the substantial reduction in the aforementioned baking times.
Landscapes
- Cereal-Derived Products (AREA)
- Fodder In General (AREA)
- Noodles (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL17811208T PL3541521T3 (pl) | 2016-11-21 | 2017-11-16 | Proces wytwarzania mąki pełnoziarnistej |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT102016000117537A IT201600117537A1 (it) | 2016-11-21 | 2016-11-21 | Procedimento per la produzione di sfarinati integrali |
PCT/EP2017/079517 WO2018091615A1 (fr) | 2016-11-21 | 2017-11-16 | Procédé de production de farine de grains entiers |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3541521A1 true EP3541521A1 (fr) | 2019-09-25 |
EP3541521B1 EP3541521B1 (fr) | 2021-12-29 |
Family
ID=58266142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17811208.2A Active EP3541521B1 (fr) | 2016-11-21 | 2017-11-16 | Procédé de production de farine de grains entiers |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3541521B1 (fr) |
ES (1) | ES2909591T3 (fr) |
IT (1) | IT201600117537A1 (fr) |
PL (1) | PL3541521T3 (fr) |
WO (1) | WO2018091615A1 (fr) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB647085A (en) * | 1948-03-02 | 1950-12-06 | Herbert Horace Ward | Improvements relating to the treatment of oats and groats from oats |
FR1007288A (fr) * | 1948-03-16 | 1952-05-05 | Procédé d'amélioration des grains de céréales et produits qu'on en tire | |
CA1321525C (fr) | 1987-06-18 | 1993-08-24 | Joseph John Tkac | Procede de mouture de la farine |
CA1313330C (fr) | 1988-12-16 | 1993-02-02 | Joseph Tkac | Procede pour l'elimination des couches de son des grains de ble |
US5066506A (en) * | 1990-06-01 | 1991-11-19 | General Mills, Inc. | Method of preparing stabilized whole grain flour |
ITMI20022066A1 (it) | 2002-09-30 | 2004-04-01 | Barilla Alimentare Spa | Procedimento per la produzione di sfarinati di grano. |
WO2016120234A1 (fr) * | 2015-01-29 | 2016-08-04 | Ambiente E Nutrizione S.R.L. | Procédé d'amélioration de propriétés organoleptique et nutritionnelle de farine de légumineuse et de constituants et dérivés de celle-ci |
-
2016
- 2016-11-21 IT IT102016000117537A patent/IT201600117537A1/it unknown
-
2017
- 2017-11-16 WO PCT/EP2017/079517 patent/WO2018091615A1/fr active Application Filing
- 2017-11-16 EP EP17811208.2A patent/EP3541521B1/fr active Active
- 2017-11-16 ES ES17811208T patent/ES2909591T3/es active Active
- 2017-11-16 PL PL17811208T patent/PL3541521T3/pl unknown
Also Published As
Publication number | Publication date |
---|---|
EP3541521B1 (fr) | 2021-12-29 |
WO2018091615A1 (fr) | 2018-05-24 |
PL3541521T3 (pl) | 2022-04-25 |
IT201600117537A1 (it) | 2018-05-21 |
ES2909591T3 (es) | 2022-05-09 |
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