EP3337879A1 - Compositions lubrifiantes - Google Patents
Compositions lubrifiantesInfo
- Publication number
- EP3337879A1 EP3337879A1 EP16754263.8A EP16754263A EP3337879A1 EP 3337879 A1 EP3337879 A1 EP 3337879A1 EP 16754263 A EP16754263 A EP 16754263A EP 3337879 A1 EP3337879 A1 EP 3337879A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- grease composition
- composition according
- weight
- boron nitride
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 91
- 239000004519 grease Substances 0.000 title claims abstract description 66
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 28
- 239000003921 oil Substances 0.000 claims abstract description 31
- 229910052582 BN Inorganic materials 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 22
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011230 binding agent Substances 0.000 claims abstract description 16
- -1 aluminum silicates Chemical class 0.000 claims abstract description 15
- 239000000440 bentonite Substances 0.000 claims abstract description 14
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 14
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims abstract description 6
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims abstract description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 5
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 3
- 239000000654 additive Substances 0.000 claims description 13
- 238000005461 lubrication Methods 0.000 claims description 13
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 13
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000005096 rolling process Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000002608 ionic liquid Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000009434 installation Methods 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 239000007866 anti-wear additive Substances 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- DGVMNQYBHPSIJS-UHFFFAOYSA-N dimagnesium;2,2,6,6-tetraoxido-1,3,5,7-tetraoxa-2,4,6-trisilaspiro[3.3]heptane;hydrate Chemical compound O.[Mg+2].[Mg+2].O1[Si]([O-])([O-])O[Si]21O[Si]([O-])([O-])O2 DGVMNQYBHPSIJS-UHFFFAOYSA-N 0.000 claims 1
- 229910021485 fumed silica Inorganic materials 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 230000001698 pyrogenic effect Effects 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 20
- 235000012216 bentonite Nutrition 0.000 description 12
- 239000002562 thickening agent Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- 239000002199 base oil Substances 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 239000002480 mineral oil Substances 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 3
- 239000010701 perfluoropolyalkylether Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 3
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 238000002050 diffraction method Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000010702 perfluoropolyether Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000005910 alkyl carbonate group Chemical group 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000005228 aryl sulfonate group Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VMDFASMUILANOL-WXXKFALUSA-N bisoprolol fumarate Chemical compound [H+].[H+].[O-]C(=O)\C=C\C([O-])=O.CC(C)NCC(O)COC1=CC=C(COCCOC(C)C)C=C1.CC(C)NCC(O)COC1=CC=C(COCCOC(C)C)C=C1 VMDFASMUILANOL-WXXKFALUSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- AIXMJTYHQHQJLU-UHFFFAOYSA-N chembl210858 Chemical compound O1C(CC(=O)OC)CC(C=2C=CC(O)=CC=2)=N1 AIXMJTYHQHQJLU-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- NCXUIEDQTCQZRK-UHFFFAOYSA-L disodium;decanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CCCCCCCCC([O-])=O NCXUIEDQTCQZRK-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- CTYRPMDGLDAWRQ-UHFFFAOYSA-N phenyl hydrogen sulfate Chemical compound OS(=O)(=O)OC1=CC=CC=C1 CTYRPMDGLDAWRQ-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- AFNRRBXCCXDRPS-UHFFFAOYSA-N tin(ii) sulfide Chemical compound [Sn]=S AFNRRBXCCXDRPS-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/50—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen
- C10M105/54—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing halogen containing carbon, hydrogen, halogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M113/00—Lubricating compositions characterised by the thickening agent being an inorganic material
- C10M113/10—Clays; Micas
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/02—Mixtures of base-materials and thickeners
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
- C10M2201/0416—Carbon; Graphite; Carbon black used as thickening agents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/061—Carbides; Hydrides; Nitrides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/061—Carbides; Hydrides; Nitrides
- C10M2201/0616—Carbides; Hydrides; Nitrides used as thickening agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
- C10M2201/0626—Oxides; Hydroxides; Carbonates or bicarbonates used as thickening agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/0656—Sulfides; Selenides; Tellurides used as thickening agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
- C10M2201/0856—Phosphorus oxides, acids or salts used as thickening agent
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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- C10M2201/102—Silicates
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- C10M2201/103—Clays; Mica; Zeolites
- C10M2201/1036—Clays; Mica; Zeolites used as thickening agents
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
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- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
- C10M2213/043—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen used as base material
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- C10M2213/06—Perfluoro polymers
- C10M2213/0606—Perfluoro polymers used as base material
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- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/062—Polytetrafluoroethylene [PTFE]
- C10M2213/0623—Polytetrafluoroethylene [PTFE] used as base material
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- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/062—Polytetrafluoroethylene [PTFE]
- C10M2213/0626—Polytetrafluoroethylene [PTFE] used as thickening agents
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- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/051—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen
- C10M2229/0515—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen used as base material
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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- C10N2010/06—Groups 3 or 13
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Definitions
- the present invention relates to lubricating grease compositions which are particularly suitable as high-temperature lubricating greases and for lubrication in kiln systems,
- Greases generally contain a thickener dissolved or dispersed in a base oil, often with dispersants for better and more stable distribution of the thickener.
- the thickener is used to adjust the desired consistency, with a variety of inorganic and organic
- the base oils are mineral oils and synthetic oils. Frequently, perfluorinated polyalkyl ethers (PFPE), i. fluorinated synthetic oils with good lubricating properties that are chemically non-reactive, high temperature stable and therefore non-toxic (see, e.g.
- PFPE perfluorinated polyalkyl ethers
- WO 97/47710 describes lubricating grease compositions containing as a base oil a mixture of a hydrocarbon oil and a perfluorinated one
- Polyalkyletheröl PFPE
- a thiourea-based thickener PFPE
- the composition may also include polytetrafluoroethylene (PTFE) and conventional additives.
- PTFE polytetrafluoroethylene
- EP 657 524 describes lubricating grease compositions comprising a hydrogenated base mineral oil and / or a synthetic oil, a perfluorinated polyalkyl ether oil and a
- Thickener PTFE included.
- Thickening agent in particular a polyurea, and a distributed in the grease inorganic material such as silica.
- WO 2008/154997 A1 describes a grease containing a base oil, an ionic liquid, a thickener and an additive.
- the ionic liquid should cause an increase in the life and lubricity of the lubricant and serve to adjust the viscosity and the electrical conductivity.
- Lubricants such as polyfluorinated compounds, to the limits of Material resilience and are therefore no longer applicable in spite of excellent sliding and lubricating properties in the higher temperature range.
- WO 2013/037456 therefore describes high-temperature fats which contain a fluorine-free base oil, a thickener which may be PTFE, additives and optionally a further fluorine-free oil component.
- EP 1589291 A1 discloses a furnace exhaust guide having rolling elements arranged in a rolling element cage.
- Molybdenum sulfide Molybdenum sulfide, tungsten disulfide or boron nitride, and which is applied and baked in the form of a paint
- WO 2010/046456 A1 describes a pullout guide for an oven, in which the tracks of the pullout guide are lubricated with boron nitride and / or a lubricant containing polysiloxane.
- EP 648 832 A1 describes lubricating grease compositions which are fluorinated
- Polymer oil Polymer oil, boron nitride and optionally solid fluorinated polymers.
- Grease compositions are said to have good lubricating properties even under harsh operating conditions.
- Perfluoropolyether oil having a kinematic viscosity of 50-1500 mm 2 / s at 40 ° C, optionally contain a thickener and other conventional additives.
- Grease compositions are also believed to be useful in contact with graphite or molybdenum disulfide at higher temperatures.
- PTFE-containing greases form toxic fumes at higher temperatures and are also relatively quickly washed out during cleaning operations by water.
- PTFE-free greases in turn have the disadvantage that they are washed out even faster by water than PTFE-containing greases.
- the object of the present invention is therefore to provide lubricating grease compositions with improved water washability.
- the lubricating grease compositions are said to have improved temperature stability and to provide a longer lubricating life at high temperatures.
- This object is achieved by a grease composition comprising at least one high-viscosity, fluorinated oil, hexagonal boron nitride and a binder.
- the present invention therefore relates to a grease composition comprising
- the kinematic viscosity is measured with SVM 300 Viscometer, Anton Paar at a temperature of 40 ° C.
- component (a) comprises fluorinated, in particular perfluorinated, polyalkyl ether oils or fluorinated silicone oils, in particular perfluorinated silicone oils, and
- Suitable perfluorinated polyalkyl ether oils are described, for example, in WO 97/47710 or EP 657 524, to which reference is made in its entirety.
- the perfluorinated polyalkyl ether oils correspond to the formula:
- a 1 is -CF 3 , -C 2 F 5 , or -C 3 F 7 ;
- a 2 is -OCF 3 , -OC 2 F 5 , or -OC 3 F 7 ; a, b, c, d, e and f are statistically distributed and are 0 or an integer from 1 to 200, wherein not all of them can simultaneously stand for 0.
- e / a and f / a are in the range of 20 to 50 and b / a in the range of 0.5 to 2.
- c and d are 0.
- Particularly preferred are the perfluorinated polyalkyl ethers of the following units:
- perfluorinated polyalkyletherols correspond to the formula:
- a, e and f are randomly distributed and represent 0 or an integer of 1 to 200, not all of which can simultaneously stand for 0 and e / a and f / a are in the range of 20 to 50.
- the perfluorinated polyalkyletherols correspond to the formula:
- A - (X) a -O-A '- (X') b - where A 'is a perfluoropolyether chain containing one or more of (CF 2 O),
- X and X ' are the same or different and are -CF 2 -, -CF 2 CF 2 - or
- a and b are the same or different and stand for integers having a value of 0 or 1, with the proviso that in the case of the block A bound to the end group TO, the subscript a stands for 1 and in which the end group T ' bound block A, the index b is 0;
- B is a block of units derived from one or more olefins of the formula (Ia) of which at least one is free-radically homopolymerizable
- j is an integer from 1 to 5
- j ' is an integer from 0 to 4, with the proviso that (j + j') is greater than 2 and less than 5;
- Ri, R2, RSS, R 4, R E, R 6, R 7 and R 8 are identical or different and are selected from halogen; H; CrC 6 - (per) haloalkyl, wherein the halogen is F and / or Cl; C 1 -C 6 -alkyl optionally containing heteroatoms; and CrC 6 -oxy (per) fluoroalkyl are selected;
- z is an integer greater than or equal to 2;
- B ' is a block which is derived from one or more olefins of the formula (Ia), but where at least one of the substituents R 1 to R 8 is different than in block B, where (j + j') is greater than or equal to 2 and less than 5;
- component (a) may additionally comprise a non-fluorinated oil, in particular a mineral oil.
- the non-fluorinated oil is generally contained in an amount of 0.1 to 40% by weight, more preferably 0.5 to 30% by weight, based on the amount of the fluorinated oil.
- the grease composition further comprises boron nitride, especially hexagonal boron nitride.
- the grease composition comprises hexagonal ⁇ -boron nitride.
- the boron nitride has a BET surface area in the range of 10 to 20 m 2 / g, determined according to ISO 9277: 2010.
- the boron nitride has an average particle size D50 of 1 to 10 ⁇ m, in particular 2 to 6 ⁇ m, determined by means of laser diffractometry (Malvern Mastersizer 3000).
- a suitable boron nitride for example, under the trade name BORONID ® from ESK Ceramics GmbH & Co. KG, Germany, available.
- the grease composition further comprises a binder.
- the binder generally has an average particle size D50 in the range of 1 to 10 ⁇ m, preferably 2 to 8 ⁇ m, determined by means of laser diffractometry.
- the binder is selected from bentonite,
- Particularly preferred is the binder organically modified bentonite or a mixture of organically modified bentonite with at least one further binder selected from alkali metal phosphates, aluminum phosphates, alkali metal silicates, alkaline earth metal silicates, aluminum silicates, alkaline earth metal carbonates, silica, titania, alumina and mixtures thereof.
- the further binder is generally contained in an amount of 0.1 to 50 wt .-%, in particular 0.5 to 40 wt .-%, based on the amount of organically modified bentonite.
- silica organically modified fumed silica is preferable, and as the titania, organic-modified fumed titania is preferable.
- Modified fumed silica and modified fumed titanium dioxide are products that have been surface-treated with an organosilane, especially with an alkylsilane.
- Corresponding products such as Aerosil R 912, Aerosil 812, Aerosil 805, Aerosil R 202, Aeroxide ® Ti0 2 T 805, Aeroxide ® Ti0 2 NKT 90, VP NKT 65 are commercially available, for example from Evonik Industries AG, Germany or Wacker Chemie AG, Germany.
- Bentonite is a mixture of different clay minerals with the most important
- montmorillonite (60% to 80%). Further accompanying minerals are quartz, mica, feldspar, pyrite or calcite.
- quartz, mica, feldspar, pyrite or calcite The term "bentonite” includes all of course
- Bentonite is commercially available in the form of various commercial products.
- Organic hydrophobically modified bentonite can, for example, by the reaction of natural or purified bentonite with quaternary ammonium compounds in the sense of a cation exchange reaction in which, for example, alkali cations against quaternary Ammonium compounds are exchanged done.
- Quaternary ammonium compounds suitable for this reaction are, for example, those of the general formula R 1 R 2 R 3 R 4 N + X " , where X is one equivalent of an anion, for example sulfate, hydrogensulfate, alkylsulfate, arylsulfate, alkylsulfonate, arylsulfonate, halide, phosphate , carbonate, alkyl phosphate, alkyl carbonate, nitrate, alkoxide, hydroxide, tetrafluoroborate or perchlorate, in particular halide, and R 1, R 2, R 3 or R 4 may be the same or different and may stand for -C 2 o alkyl.
- X is one equivalent of an anion, for example sulfate, hydrogensulfate, alkylsulfate, arylsulfate, alkylsulfonate, arylsulfonate, halide, phosphate ,
- R 1 and R 2 identical or different, represent -C 4 alkyl and R 3 and R 4, identical or different, are 2 -C 2 o-alkyl is Ci.
- quaternary ammonium salts can be used, where X is halide, in particular chloride, R 1 and R 2 are methyl and R 3 and R 4, identical or different, are C 6 -C 8 -alkyl BARAGEL ⁇
- the commercial product is bentonite modified with Me 2 N (Ci. 6 - Ci 8 alkyl) 2 CI.
- the lubricating grease composition additionally comprises water in an amount of 0.01 to 1% by weight, in particular 0.05 to 0.2% by weight, based on the total mass of the composition.
- Water serves as an activating agent for bentonite, in particular for activating the dispersing and thickening properties of the bentonite.
- the lubricating grease composition according to the invention may contain at least one additive, in particular an additive which is customary in the field of lubricating grease compositions.
- the additive is selected from antioxidants, for example, functionalized perfluoropolyalkyl ethers as described in EP 1 354 932 A1 and US 5,550,277; Wear protection additives, for example functionalized perfluoropolyalkyl ethers, as described in WO 2016/020232;
- Corrosion inhibitors for example sodium sebacate, functionalized perfluoropolyalkyl ethers as described in US 5,550,277; Dyes, for example azo dyes and solid lubricants, for example molybdenum disulfide, tungsten disulfide, tin sulfide.
- inventive compositions for example sodium sebacate, functionalized perfluoropolyalkyl ethers as described in US 5,550,277
- Dyes for example azo dyes and solid lubricants, for example molybdenum disulfide, tungsten disulfide, tin sulfide.
- the inventive composition each based on the total weight of the composition. According to a further embodiment, the inventive composition
- Grease composition (a) 50-96% by weight of at least one perfluorinated polyalkyl ether oil
- the lubricant composition is substantially free of PTFE.
- the grease composition is substantially free of an ionic liquid.
- the grease composition is substantially free of graphite.
- “Substantially free” means that the lubricating grease composition contains less than 0.5% by weight of PTFE, less than 0.5% by weight of ionic liquid or less than 0.5% by weight of graphite, in particular each 0% by weight. % of these components, based on the
- Grease compositions have a number of advantageous properties compared to known greases: very good compatibility of all components,
- the lubricating grease compositions according to the invention are for lubrication in
- applications include the lubrication of: Rolling and plain bearings, sliding guides, valves, joints, slides, column guides, ejectors and other sliding surfaces such as in
- Circular conveyors paint lines, calenders, kiln cars, fans, switches,
- Film stretching plants extraction plants, textile machines, wood press systems, pumps, dryers, motors, tire molds, construction machines, electrical and automotive engineering,
- Paper industry and steel industry and machinery and equipment e.g. in the food and feed industry.
- the grease composition according to the invention for the lubrication of sliding guides and wheels in kiln systems or rolling and sliding bearings in
- the application of the grease composition is carried out by applying to the parts to be lubricated in a suitable amount for lubrication.
- the grease composition of the invention is applied as a paste.
- the grease composition can be easily applied be without the grease composition, for example, at the ends of the tracks of Ofenauszugsschienen run out or drip.
- Optional post-treatment after application of the lubricating grease composition by vibratory grinding allows better distribution and adhesion of the grease on, for example, a metallic substrate.
- the lubricant composition is thixotropic, i. upon mechanical action the viscosity decreases and the original viscosity returns after the end of the shear stress. This allows the pastes to be relatively easily spread on the surface of, for example, oven tray rails under pressure loading without dripping.
- BARAGEL® (14.9 wt%, organic hydrophobically modified bentonite from Elementis Specialties Inc., USA) was added to the mixing kettle, the heater was turned off, and the resulting mixture was stirred for five minutes. Then, 0.1% by weight of water was added and the mixture was stirred for 30 minutes. After cooling to room temperature, boron nitride (5% by weight Boronid®, ESK Ceramics GmbH & Co. KG, Germany) and a corrosion inhibitor (2% by weight, Irgacor®, BASF SE, Germany) were added to the mixing vessel and the resulting Mixture was stirred for 30 min. The resulting BARAGEL® (14.9 wt%, organic hydrophobically modified bentonite from Elementis Specialties Inc., USA) was added to the mixing kettle, the heater was turned off, and the resulting mixture was stirred for five minutes. Then, 0.1% by weight of water was added and the mixture was stirred for 30 minutes. After cooling to room temperature, boron nitride
- Grease was homogenized with a roller mill.
- the data in% by weight are each based on the total weight of the grease.
- the grease composition prepared according to Example 1 was first subjected to a VKA test (four-ball apparatus, ASTM D1831 / DIN 51350-4).
- the VKA welding force became 4800 N and the VKA wear 0.9 mm at 150 kg / 1 min
- Comparative samples (Comparative Example 1, Comparative Example 2, Comparative Example 3) were carried out washability tests. For this, the various samples were on
- Example 1 weight loss after the third wash: ⁇ 50%; Rail is easy to move.
- the PTFE-containing Comparative Example 2 develops toxic, vaporous
- Comparative samples (Comparative Examples 4 and 5) were run endurance tests. For this purpose, the various samples were applied to furnace extension rails and the pull-out rails mounted on side rails. Then the grids were installed in an oven. A test load was placed in the middle of a baking tray in the oven. The entry and exit of the weighted baking sheet was carried out using a
- Pneumatic cylinder performed.
- the rails were subjected to an endurance test with 24000 cycles. After every 6000 cycles, motive force and lowering of the rails were checked, and also after every 6000 cycles, the rails were subjected to a dishwasher washing cycle. After a total of 24,000 cycles was the
- composition of the comparative examples (wt .-%, based on the total weight of
- Example 1 The sample passed the test (5 washes, good
- Comparative Example 5 The sample failed the test (failed after 12,000 cycles, balls stuck for lack of greasing).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15181667 | 2015-08-20 | ||
PCT/EP2016/069423 WO2017029287A1 (fr) | 2015-08-20 | 2016-08-16 | Compositions lubrifiantes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3337879A1 true EP3337879A1 (fr) | 2018-06-27 |
EP3337879B1 EP3337879B1 (fr) | 2021-11-17 |
Family
ID=53938190
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16754263.8A Active EP3337879B1 (fr) | 2015-08-20 | 2016-08-16 | Compositions de graisse de lubrification |
Country Status (6)
Country | Link |
---|---|
US (1) | US20180245010A1 (fr) |
EP (1) | EP3337879B1 (fr) |
CN (1) | CN108026465A (fr) |
ES (1) | ES2902836T3 (fr) |
HK (1) | HK1257564A1 (fr) |
WO (1) | WO2017029287A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3784761B1 (fr) | 2018-04-26 | 2024-03-06 | Shell Internationale Research Maatschappij B.V. | Composition lubrifiante et son utilisation comme pâte lubrifiante |
CN111996064A (zh) * | 2020-09-23 | 2020-11-27 | 上海虎头化工有限公司 | 一种超高温润滑脂及其制备方法 |
CN112646636A (zh) * | 2020-12-22 | 2021-04-13 | 刘超 | 一种润滑油添加剂及其制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1271409B (it) * | 1993-09-13 | 1997-05-28 | Dow Corning | Composizioni utilizzabili come grassi a base di oli di polimeri fluorurati e nitruro di boro esagonale |
DE19622906A1 (de) * | 1996-06-07 | 1997-12-11 | Klueber Lubrication | Schmierfettzusammensetzungen |
CN101128569B (zh) * | 2005-02-22 | 2012-12-12 | Nok克鲁勃株式会社 | 润滑剂 |
JP4926411B2 (ja) * | 2005-04-08 | 2012-05-09 | 出光興産株式会社 | グリース組成物 |
DE112009005504B4 (de) * | 2008-02-01 | 2017-03-09 | Nok Klueber Co. Ltd. | Verwendung einer fluorhaltigen Diamid-Verbindung als Rostschutzzusatz einer Schmiermittelzusammensetzung |
-
2016
- 2016-08-16 CN CN201680047719.8A patent/CN108026465A/zh active Pending
- 2016-08-16 EP EP16754263.8A patent/EP3337879B1/fr active Active
- 2016-08-16 ES ES16754263T patent/ES2902836T3/es active Active
- 2016-08-16 WO PCT/EP2016/069423 patent/WO2017029287A1/fr active Application Filing
- 2016-08-16 US US15/753,786 patent/US20180245010A1/en not_active Abandoned
-
2018
- 2018-12-27 HK HK18116649.1A patent/HK1257564A1/zh unknown
Also Published As
Publication number | Publication date |
---|---|
HK1257564A1 (zh) | 2019-10-25 |
EP3337879B1 (fr) | 2021-11-17 |
US20180245010A1 (en) | 2018-08-30 |
ES2902836T3 (es) | 2022-03-30 |
WO2017029287A1 (fr) | 2017-02-23 |
CN108026465A (zh) | 2018-05-11 |
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