EP3333215B1 - Wärmeschrumpfbare polyesterfolie und verpackung - Google Patents

Wärmeschrumpfbare polyesterfolie und verpackung Download PDF

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Publication number
EP3333215B1
EP3333215B1 EP16832982.9A EP16832982A EP3333215B1 EP 3333215 B1 EP3333215 B1 EP 3333215B1 EP 16832982 A EP16832982 A EP 16832982A EP 3333215 B1 EP3333215 B1 EP 3333215B1
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EP
European Patent Office
Prior art keywords
film
shrinkage
heat
less
shrinkable polyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP16832982.9A
Other languages
English (en)
French (fr)
Other versions
EP3333215A1 (de
EP3333215A4 (de
Inventor
Masafumi Inoue
Masayuki Haruta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Publication of EP3333215A1 publication Critical patent/EP3333215A1/de
Publication of EP3333215A4 publication Critical patent/EP3333215A4/de
Application granted granted Critical
Publication of EP3333215B1 publication Critical patent/EP3333215B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
    • B29C61/06—Making preforms having internal stresses, e.g. plastic memory
    • B29C61/0608—Making preforms having internal stresses, e.g. plastic memory characterised by the configuration or structure of the preforms
    • B29C61/0666—Making preforms having internal stresses, e.g. plastic memory characterised by the configuration or structure of the preforms comprising means indicating that the shrinking temperature is reached
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
    • B29C61/006—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor the force created by the liberation of the internal stresses being used for compression moulding or for pressing preformed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
    • B29C61/02—Thermal shrinking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
    • B29C61/06—Making preforms having internal stresses, e.g. plastic memory
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/02—Wrappers or flexible covers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/02—Wrappers or flexible covers
    • B65D65/14—Wrappers or flexible covers with areas coated with adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/02—Articles partially enclosed in folded or wound strips or sheets, e.g. wrapped newspapers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Wrappers (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)

Claims (6)

  1. Eine wärmeschrumpfbare Polyesterfolie, umfassend Ethylenterephthalat als einen konstituierenden Hauptbestandteil und enthaltend 0 Mol-% oder mehr und 5 Mol-% oder weniger eines Monomerbestandteils, der einen amorphen Bestandteil in einem gesamten Polyesterharzbestandteil bilden kann, wobei die wärmeschrumpfbare Polyesterfolie die folgenden Anforderungen (i) bis (iv) erfüllt:
    (i) die Folie weist eine Warmwasser-Wärmeschrumpfung von 15% oder mehr und 50% oder weniger in einer Hauptschrumpfrichtung der Folie auf, wenn sie für 10 Sekunden in Warmwasser mit 90°C behandelt wird;
    (ii) die Folie weist eine Warmwasser-Wärmeschrumpfung von 0% oder mehr und 12% oder weniger in einer orthogonalen Richtung zur Hauptschrumpfrichtung der Folie auf, wenn sie für 10 Sekunden in Warmwasser mit 90°C behandelt wird;
    (iii) die Folie weist eine maximale Schrumpfspannung von 2 MPa oder mehr und 10 MPa oder weniger in der Hauptschrumpfrichtung der Folie, gemessen unter Heißluft mit 90°C, auf; und
    (iv) die Folie enthält 7 Mol-% oder mehr und 30 Mol-% oder weniger einer von Diethylenglykol abgeleiteten konstituierenden Einheit in 100 Mol-% des gesamten Polyesterharzbestandteils.
  2. Die wärmeschrumpfbare Polyesterfolie nach Anspruch 1, wobei die Folie eine Zugbruchfestigkeit von 80 MPa oder mehr und 200 MPa oder weniger in orthogonaler Richtung zur Hauptschrumpfrichtung der Folie aufweist.
  3. Die wärmeschrumpfbare Polyesterfolie nach Anspruch 1 oder 2, wobei die Folie eine Dickeunregelmäßigkeit von 13% oder weniger in der Hauptschrumpfrichtung der Folie aufweist.
  4. Die wärmeschrumpfbare Polyesterfolie nach einem der Ansprüche 1 bis 3, wobei bei einer Messung einer Schrumpfspannung in der Hauptschrumpfrichtung der Folie unter Heißluft mit 90°C eine Schrumpfspannung nach 30 Sekunden ab Beginn der Messung 60% oder mehr und 100% oder weniger, bezogen auf die maximale Schrumpfspannung, beträgt.
  5. Die wärmeschrumpfbare Polyesterfolie nach einem der Ansprüche 1 bis 4, wobei die Hauptschrumpfrichtung die Längsrichtung der Folie ist.
  6. Eine Verpackung mit einem Etikett, abgeleitet von der wärmeschrumpfbaren Polyesterfolie nach einem der Ansprüche 1 bis 5, auf mindestens einem Teil eines Außenumfangs eines zu verpackenden Gegenstands.
EP16832982.9A 2015-08-05 2016-08-01 Wärmeschrumpfbare polyesterfolie und verpackung Active EP3333215B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015154978 2015-08-05
PCT/JP2016/072480 WO2017022703A1 (ja) 2015-08-05 2016-08-01 熱収縮性ポリエステル系フィルムおよび包装体

Publications (3)

Publication Number Publication Date
EP3333215A1 EP3333215A1 (de) 2018-06-13
EP3333215A4 EP3333215A4 (de) 2019-04-10
EP3333215B1 true EP3333215B1 (de) 2021-01-06

Family

ID=57943946

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16832982.9A Active EP3333215B1 (de) 2015-08-05 2016-08-01 Wärmeschrumpfbare polyesterfolie und verpackung

Country Status (8)

Country Link
US (1) US10421231B2 (de)
EP (1) EP3333215B1 (de)
JP (2) JP6597633B2 (de)
KR (1) KR102500312B1 (de)
CN (1) CN107922642B (de)
ES (1) ES2849825T3 (de)
TW (1) TWI694100B (de)
WO (1) WO2017022703A1 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2018147249A1 (ja) * 2017-02-13 2019-02-14 東洋紡株式会社 非晶性のフィルム用共重合ポリエステル原料、熱収縮性ポリエステル系フィルム、熱収縮性ラベル、及び包装体
EP3778727A4 (de) * 2018-03-30 2022-01-05 Toyobo Co., Ltd. Wärmeschrumpfbare folie auf polyesterbasis
CN108586714B (zh) * 2018-05-07 2021-01-22 上海棚发膜结构有限公司 一种三乙烯四胺改性的树脂膜及其制备方法
CN114502480B (zh) * 2019-10-25 2024-04-30 东洋纺株式会社 能够激光印字的膜及使用了该膜的包装体
US20220403156A1 (en) * 2019-10-31 2022-12-22 Toyobo Co., Ltd. Heat-shrinkable polyester-based film roll
MX2022013605A (es) * 2020-04-30 2022-12-06 C I Takiron Corp Pelicula retractil a base de poliester.
JP6862079B1 (ja) * 2020-04-30 2021-04-21 タキロンシーアイ株式会社 ポリエステル系シュリンクフィルムの製造方法及びポリエステル系シュリンクフィルムの使用方法
WO2021230207A1 (ja) * 2020-05-12 2021-11-18 東洋紡株式会社 フィルム用共重合ポリエステル原料、熱収縮性ポリエステル系フィルム、熱収縮性ラベル、及び包装体
US20230257533A1 (en) * 2020-07-09 2023-08-17 Toyobo Co., Ltd. Heat-shrinkable polyester-based film roll
JP7364085B2 (ja) 2020-07-29 2023-10-18 東洋紡株式会社 熱収縮性ポリエステル系フィルム、熱収縮性ラベル、及び包装体
JP7092173B2 (ja) * 2020-10-23 2022-06-28 三菱ケミカル株式会社 熱収縮性フィルム、箱状包装資材及び電池セル、熱収縮性フィルムの製造方法
KR20230151525A (ko) * 2021-02-24 2023-11-01 도요보 가부시키가이샤 열수축성 폴리에스테르계 필름

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JPH0753737A (ja) * 1993-08-18 1995-02-28 Kanebo Ltd ポリエステル系シュリンクフィルム
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JP4882919B2 (ja) * 2006-08-30 2012-02-22 東洋紡績株式会社 熱収縮性ポリエステル系フィルム、およびその製造方法、包装体
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JP5993635B2 (ja) * 2012-07-05 2016-09-14 シーアイ化成株式会社 熱収縮性ポリエステル系フィルムおよびその製造方法
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TWI576367B (zh) * 2012-08-29 2017-04-01 東洋紡股份有限公司 熱收縮性聚酯系薄膜
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Also Published As

Publication number Publication date
EP3333215A1 (de) 2018-06-13
CN107922642A (zh) 2018-04-17
US20180229422A1 (en) 2018-08-16
TW201714931A (zh) 2017-05-01
JP6597633B2 (ja) 2019-10-30
WO2017022703A1 (ja) 2017-02-09
KR20180039062A (ko) 2018-04-17
JP2020073637A (ja) 2020-05-14
TWI694100B (zh) 2020-05-21
CN107922642B (zh) 2021-01-01
JP6802535B2 (ja) 2020-12-16
ES2849825T3 (es) 2021-08-23
US10421231B2 (en) 2019-09-24
EP3333215A4 (de) 2019-04-10
KR102500312B1 (ko) 2023-02-14
JPWO2017022703A1 (ja) 2018-06-07

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