EP3283205A2 - Mélangeur pour produits liquides - Google Patents

Mélangeur pour produits liquides

Info

Publication number
EP3283205A2
EP3283205A2 EP16725914.2A EP16725914A EP3283205A2 EP 3283205 A2 EP3283205 A2 EP 3283205A2 EP 16725914 A EP16725914 A EP 16725914A EP 3283205 A2 EP3283205 A2 EP 3283205A2
Authority
EP
European Patent Office
Prior art keywords
axis
rotation
mixer
housing
fluid products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16725914.2A
Other languages
German (de)
English (en)
Inventor
Edoardo Rossetti
Marco Rossetti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ALFA Srl
Original Assignee
ALFA Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ALFA Srl filed Critical ALFA Srl
Publication of EP3283205A2 publication Critical patent/EP3283205A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/02—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
    • B29B7/06—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices
    • B29B7/10—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary
    • B29B7/106—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary using rotary casings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00—Mixers with rotating receptacles
    • B01F29/10—Mixers with rotating receptacles with receptacles rotated about two different axes, e.g. receptacles having planetary motion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00—Mixers with rotating receptacles
    • B01F29/30—Mixing the contents of individual packages or containers, e.g. by rotating tins or bottles
    • B01F29/31—Mixing the contents of individual packages or containers, e.g. by rotating tins or bottles the containers being supported by driving means, e.g. by rotating rollers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00—Mixers with rotating receptacles
    • B01F29/40—Parts or components, e.g. receptacles, feeding or discharging means
    • B01F29/403—Disposition of the rotor axis
    • B01F29/4036—Disposition of the rotor axis with a plurality of rotating receptacles
    • B01F29/40365—Disposition of the rotor axis with a plurality of rotating receptacles arranged for planetary motion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00—Mixers with rotating receptacles
    • B01F29/80—Mixers with rotating receptacles rotating about a substantially vertical axis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
    • B01F2101/30—Mixing paints or paint ingredients, e.g. pigments, dyes, colours, lacquers or enamel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00—Mixers with rotating receptacles
    • B01F29/40—Parts or components, e.g. receptacles, feeding or discharging means
    • B01F29/403—Disposition of the rotor axis
    • B01F29/4032—Disposition of the rotor axis vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00—Mixers with rotating receptacles
    • B01F29/40—Parts or components, e.g. receptacles, feeding or discharging means
    • B01F29/403—Disposition of the rotor axis
    • B01F29/4033—Disposition of the rotor axis inclined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00—Mixers with rotating receptacles
    • B01F29/40—Parts or components, e.g. receptacles, feeding or discharging means
    • B01F29/403—Disposition of the rotor axis
    • B01F29/4035—Disposition of the rotor axis with a receptacle rotating around two or more axes
    • B01F29/40354—Disposition of the rotor axis with a receptacle rotating around two or more axes arranged for planetary motion

Definitions

  • the present invention relates to a mixer for fluid products, in particular varnishes, paints, enamels, inks and the like.
  • the invention was developed with particular regard, although not exclusively, to a mixer for fluid products contained in containers, pots, tins and the like.
  • the patent US 3.552.723 illustrates a mixer in which one or more sealed containers are made to oscillate about a horizontal axis.
  • the patent US 5.066.136 relates to a vibratory mixer that allows the paint pot to be agitated, said pot remaining parallel to itself relative to a vertical plane when it moves.
  • the patent US 5.507.575 relates to the principle of agitating a pot, also imparting a rotational movement about its vertical axis.
  • the patent US 5.466.065 illustrates a mixer that allows the paint pot to be moved along a path that defines a cone.
  • the patents US 4.281.936, US 4.415.270, US 5.261.744, US 5.383.163, US 5.788.371 and US 5.904.421 relate to gyroscopic paint mixers, in which the pot is subjected to two superimposed rotational movements about two axes of rotation that are perpendicular to one another.
  • the object of the present invention is to produce a mixer that imparts a mixing movement to one or more fluid product containers so as to obtain optimal mixing and homogenisation of the fluid products in a short time.
  • Another object of the present invention is to provide a mixer for fluid products that is mechanically simple, and consequently easy and economical to manufacture, and that involves low, simple and economical maintenance.
  • Another object of the present invention is to provide a mixer for fluid products that is silent.
  • Another object of the present invention is to produce a mixer for fluid products that is manoeuvrable, compact and light ⁇ weight, particularly in view of its preferential intended use in retail outlets for paints, varnishes, inks and the like.
  • the invention relates to a fluid product mixer having the features indicated in the following claims.
  • the fluid product mixer comprises a base on which a support structure is mounted, said structure being rotatable about a first axis of rotation.
  • a housing structure having at least one housing for a container of fluid products to be mixed is mounted on the support structure at a radial distance from the first axis of rotation.
  • the housing structure can be rotated about a second axis of rotation which is at a distance from the first axis of rotation.
  • the second axis of rotation is tilted relative to the first axis of rotation.
  • a motor is mounted on the base for transmitting a rotational movement to the support structure about the first axis of rotation by means of a first transmission.
  • a second transmission transmits the rotational movement to the housing structure about the second axis of rotation.
  • the at least one housing for a fluid product container is at a distance from the second axis of rotation and is preferably parallel thereto. This configuration makes it possible to produce a combined epicyclic movement of the at least one container accommodated on the housing structure. Tilting the second axis of rotation relative to the first axis of rotation produces particularly homogeneous mixing.
  • the first axis of rotation is vertical and a counterweight is positioned radially opposite the support structure so as to balance the centrifugal force thereof during the rotational movement about the first axis of rotation .
  • the second axis of rotation is tilted by approximately 30° relative to the vertical. This tilting favours homogeneous mixing inside the container, which is also tilted relative to the vertical. At the same time, the need to provide a system for holding the container is avoided, since said container remains stable in its housing during the mixing movement without having to be locked from above as is sometimes the case in mixers of the prior art.
  • the housing structure of the mixer comprises three housings for three respective containers of fluid products to be mixed. These three housings are arranged symmetrically about the second axis of rotation so as to be balanced during the rotational movement about said axis.
  • the three-housing arrangement obviously allows for the productivity of the mixer to be three times that of systems of the prior art, which mix just one fluid product container at a time.
  • the one or more housings for fluid product containers are mounted on the housing structure at a radial distance from the second axis of rotation.
  • Each housing can also be rotated about a third axis of rotation which is substantially parallel to the second axis of rotation. This third axis of rotation substantially coincides with an axis of symmetry of the housing, and therefore of the container of fluid product to be mixed.
  • all fluid product containers are subject to a movement that is the combination of three rotations: a rotation about their own axis of symmetry, a revolution about the second axis of rotation, preferably, but not restrictively, tilted by approximately 30° relative to the vertical, and a further rotation about the first axis of rotation which is preferably, but not restrictively, vertical.
  • the mixing of the fluid products that can thereby be achieved inside the container is very homogeneous and takes place fairly quickly.
  • the mixer of the present invention comprises a motor mounted on the base and coupled to a transmission shaft that can be rotated about the first axis of rotation.
  • a transmission shaft that can be rotated about the first axis of rotation.
  • One end of this transmission shaft is fixed to the support structure which comprises a plate having a flat central portion and two side wings tilted by approximately 30° relative to a horizontal plane.
  • the housing structure is mounted on one of the side wings, while a counterweight is mounted on the opposite side wing.
  • the mixer comprises a fixed pulley which is coaxial with the first axis of rotation and a moveable pulley which is coaxial with the second axis of rotation.
  • the fixed pulley and the moveable pulley are coupled by means of a transmission belt that is guided at an angle by two idler rollers. The movement is transmitted simply and automatically with no need to provide a second motor.
  • the arrangement of the idler rollers makes it possible to keep the transmission belt centred in a simple manner despite the tilting of the axes of the two pulleys relative to one another.
  • the mixer comprises a toothed wheel which is mounted so as to be fixed on the support structure and is coaxial with the second transmission axis.
  • the housings for the fluid product containers are each mounted on a respective rotatable spindle, on which, in turn, a toothed wheel which meshes with the toothed wheel mounted so as to be fixed, fits perfectly.
  • the transmission system is simple and reliable and makes it possible for the fluid product containers to rotate about their own axes without having to provide additional motors.
  • each housing for the fluid product containers is substantially truncated-cone- shaped. In this way, it is possible to accommodate and hold the containers with slight interference.
  • the base of the mixer comprises a platform on which a support base is mounted with interposed resilient anti-vibration means.
  • a bearing plate is raised above the support base, under which bearing plate the motor is mounted.
  • the motor controls a vertical transmission shaft that passes through the bearing plate and to the upper end of which the support structure is fixed.
  • Fig. 1 is a perspective view of a mixer of the present invention shown without an outer protective casing for better understanding;
  • Fig. 2 is a plan view of the mixer in Fig. 1 ;
  • Fig. 3 is a section along the line A-A in Fig. 2 ;
  • Fig. 4 is a section along the line B-B in Fig. 2;
  • Fig. 5 is a cross-section through a variant of the portion of the unit supporting the fluid product containers.
  • a mixer for fluid products in particular varnishes, paints, enamels, inks and the like is indicated in general by the reference numeral 10.
  • the mixer 10 comprises a platform 11 mounted on feet 12 which are preferably independently height-ad ustable.
  • a protective casing is fixed to the platform 11, said casing being omitted from the drawings for illustrative clarity.
  • the protective casing is provided with a hatch for access inside the mixer.
  • the mixer can also be produced without a casing when it is positioned inside a more complex machine, for example an automatic paint-dispensing machine.
  • a support base 13 is mounted on the platform 11 with interposed resilient anti-vibration blocks 14 (see Fig. 4), which dampen the vibrations transmitted from the mixer during operation thereof.
  • a bearing plate 15 is raised above the support base 13 and is supported by four columns 16 fixed to the support base 13.
  • a motor 17 is mounted under the bearing plate 15 and controls a transmission shaft 18 positioned vertically, optionally with a reduction unit 17' interposed, preferably a bevel gear unit.
  • the transmission shaft 18 passes through the bearing plate 15 and has at its upper end a flange 20, by means of which it is fixed to a rotary plate 21.
  • the rotary plate 21 has a horizontal central zone 22 from which two opposite wings 23' , 23" extend at an angle to a horizontal plane. Preferably, although non-restrictively, the wings 23', 23" are angled by approximately 30° relative to a horizontal plane.
  • a rotary support unit 24 is mounted on one of the two wings 23' , while a counterweight 25 is mounted on the opposite wing 23".
  • the support unit 24 is mounted on an idler shaft 26, which can rotate when idling about an axis that is perpendicular to the plane of the wing 23' on which the support unit 24 is mounted.
  • the idler shaft 26 is tilted by approximately 30° relative to the vertical.
  • the idler shaft 26 is mounted, preferably with interposed ball bearings, on a bushing 27 which is fixed to the wing 23' , and supports a housing unit 28 for the containers of fluid product to be mixed.
  • the housing unit 28 comprises three housings arranged symmetrically about the axis of the idler shaft 26.
  • the configuration in the example is that which has demonstrated the best performance in terms of mixing fluid products, with specific reference being made to small containers, for example between 50 and 200 mL, and preferably 100 mL . It is, however, possible to vary both the number and arrangement of the housings for containers. For example, a single housing could be provided for a larger container, for instance half a litre or more, which is positioned so as to have its axis in line with the axis of the idler shaft 26, or offset therefrom. As can be seen in Fig. 3, the housing unit 28 is mounted on a plate 29 by means of screws or similar, for easier replacement with an identical or different housing unit.
  • the housing unit 28 comprises three cavities 30 which are substantially truncated-cone-shaped for accommodating the same number of containers of fluid product to be mixed having the same shape.
  • the size of the cavities 30 is such as to be able to accommodate the containers and hold them by means of slight interference owing to their truncated-cone shape.
  • the housing unit 28 is, however, tilted such that no centrifugal forces are generated during use that might push the containers out of the corresponding cavities 30.
  • unlike many mixers of the prior art for example vibrational or gyroscopic mixers, it is not necessary in the mixer of the present invention to provide a stop or a cover to hold the fluid product containers from above.
  • the housing unit 28 is preferably configured so that none of the cavities 30 extend beyond the vertical axis of rotation of the transmission shaft 18.
  • a moveable pulley 32 is fixed to the lower end of the idler shaft 26, said pulley being connected by a transmission belt 33 to a fixed pulley 34 which is mounted on the bearing plate 15 and is coaxial with the transmission shaft 18.
  • the belt 33 is guided at an angle from one pulley to the other by means of two idler rollers 31 which can be rotated when idling so as to have substantially horizontal axes.
  • the idler rollers 31 are mounted on supports 35 fixed to the rotary plate 21, substantially at the bend between the central horizontal zone 22 and the angled wing 23' that supports the housing unit 28.
  • the adoption of the idler rollers 31 instead of idling guide pulleys allows for the transmission belt 33 to be kept constantly aligned between the moveable pulley 32 and the fixed pulley 34.
  • the motor 17 is activated so as to put into rotation, in a predetermined direction and at a predetermined speed, the transmission shaft 18 and therewith the rotary plate 21, which in turn drives the housing unit 28 in rotation about its vertical axis, the weight of said housing unit being counterbalanced by the counterweight 25.
  • the rotation of the housing unit 28 about the axis of the transmission shaft 18 causes the moveable pulley 32 mounted on the lower end of the idler shaft 26 to rotate in a manner controlled via the belt 33 by the fixed pulley 34 which is coaxial with the transmission shaft 18.
  • the rotational movement about the axis of the idler shaft 28 is therefore superimposed on the rotational movement about the vertical axis of the transmission shaft 18, combining as an epicyclic movement.
  • each container tilting of each container relative to the vertical adds a vertical component to the movement of each particle of fluid contained inside each fluid product container accommodated in the cavities 30.
  • the result is uniform mixing, in a short period, of the fluid product contained in the containers accommodated in the cavities 30 of the housing unit 28.
  • Fig. 5 illustrates a variant of the mixer of the present invention, in which a housing unit 50 comprises one or more cups 51 for accommodating fluid product containers 52 that can subsequently rotate about their own axis.
  • Each cup 51 (of which only one is depicted in Fig. 5, for illustrative simplicity) comprises a cavity 53 for accommodating a container 52 of fluid products to be mixed.
  • the cavity 53 is preferably truncated-cone-shaped in order to hold the container 52 with slight interference.
  • the tilting of each cup 51, the axis of which is preferably at approximately 30° relative to the vertical, is such that, as in the example previously described, it is not necessary to provide a system for holding the containers 52 from above.
  • Each cup 51 is supported in rotation by a spindle 55 supported by a hub 56, preferably with interposed ball bearings 57.
  • the hub 56 is fixed to a support plate 58.
  • An idler shaft 59 is fixed to the centre of the support plate 58, which idler shaft, like the idler shaft 28 of the previous example shown in Fig. 1 to 4, is mounted on one wing 23' of the rotary plate 21 by means of a bushing 60, preferably with interposed ball bearings 61.
  • the moveable pulley 32 is mounted at the lower end of the idler shaft 59, said pulley being connected, as stated above, to the fixed pulley 34 which is coaxial with the transmission shaft 18 by means of the transmission belt 33 guided by the idler rollers 31.
  • a central toothed wheel 62 is mounted so as to be fixed and coaxial with the bushing 60 that supports the idler shaft 59.
  • the central toothed wheel 62 can be produced in one piece on the outer surface of the said bushing 60.
  • friction wheels or pulleys connected to one another by a transmission belt can be provided .
  • the motor 17 is excited so as to put into rotation in a predetermined direction and at a predetermined speed the transmission shaft 18 and therewith the rotary plate 21, which in turn drives the housing unit 50 in rotation about its vertical axis, the weight of said housing unit being counterbalanced by the counterweight 25.
  • the rotation of the housing unit 50 about the axis of the transmission shaft 18 causes the moveable pulley 32 mounted at the lower end of the idler shaft 59 to rotate in a manner controlled via the transmission belt 33 by the fixed pulley 34 which is coaxial with the transmission shaft 18.
  • the rotational movement about the axis of the idler shaft 59 is therefore superimposed on the rotational movement about the vertical axis of the transmission shaft 18, and this causes the support plate 59 to rotate about the axis of the idler shaft 59.
  • the rotation of the support plate 59 then causes the toothed wheels 64 to rotate on the central toothed wheel 62, consequently rotating each cup 51, and therefore each container 54 of fluid products, about its own axis, such that it is tilted relative to the horizontal.
  • each particle of fluid product inside each container 54 is subject to (a) a rotational movement about the axis of the container 54 as a result of the rotation of the cup 51 about the axis of the spindle 55, (b) a movement of revolution about the axis of the idler shaft 59 as a result of the rotation imparted to the moveable pulley 32 by the fixed pulley 34 via the transmission belt 33, and (c) a movement of translation about the vertical axis of the transmission shaft 18 as a result of the rotation imparted by said transmission shaft to the rotary plate 21 that supports the housing unit 50. Furthermore, the tilting of each container 54 relative to the horizontal plane causes the particles of fluid product inside each container 54 to be remixed in the vertical direction so as to obtain homogenous mixing in a short period.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Mixers With Rotating Receptacles And Mixers With Vibration Mechanisms (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Accessories For Mixers (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

La présente invention concerne un mélangeur pour produits liquides, comprenant une base, une structure de support montée sur la base et pouvant tourner autour d'un premier axe de rotation, et une structure de boîtier ayant au moins un boîtier pour un récipient de produits liquides à mélanger, ladite structure de boîtier étant montée sur la structure de support à une distance radiale du premier axe de rotation. La structure de boîtier peut être mise en rotation autour d'un second axe de rotation qui est situé à une distance radiale du premier axe de rotation. Un moteur est monté sur la base pour transmettre un mouvement de rotation à la structure de support autour du premier axe de rotation au moyen d'une première transmission. Une seconde transmission transmet le mouvement de rotation à la structure de boîtier autour du second axe de rotation. Le boîtier pour un récipient de produit liquide est situé à une distance radiale du second axe de rotation de manière à conférer, pendant l'utilisation, un mouvement épicycloïdal combiné à au moins un récipient logé sur la structure de boîtier.
EP16725914.2A 2015-04-17 2016-04-18 Mélangeur pour produits liquides Withdrawn EP3283205A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITBO2015A000192A ITBO20150192A1 (it) 2015-04-17 2015-04-17 Miscelatore per prodotti fluidi
PCT/IB2016/052196 WO2016166738A2 (fr) 2015-04-17 2016-04-18 Mélangeur pour produits liquides

Publications (1)

Publication Number Publication Date
EP3283205A2 true EP3283205A2 (fr) 2018-02-21

Family

ID=53765247

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16725914.2A Withdrawn EP3283205A2 (fr) 2015-04-17 2016-04-18 Mélangeur pour produits liquides

Country Status (11)

Country Link
US (1) US20180104662A1 (fr)
EP (1) EP3283205A2 (fr)
JP (1) JP2018513007A (fr)
KR (1) KR20170138523A (fr)
CN (1) CN107530658A (fr)
AU (1) AU2016249094A1 (fr)
BR (1) BR112017021033A2 (fr)
CL (1) CL2017002582A1 (fr)
IT (1) ITBO20150192A1 (fr)
MX (1) MX2017013340A (fr)
WO (1) WO2016166738A2 (fr)

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US11059008B2 (en) * 2017-10-20 2021-07-13 Richard W. Alexander Revolving chamber oscillation mixing devices and associated methods
CN109433069B (zh) * 2018-11-24 2021-07-16 湖北文太新材料有限公司 一种原料混合机
CN110237755B (zh) * 2019-06-24 2024-08-09 中国工程物理研究院激光聚变研究中心 一种抛光磁流变液搅拌匀滑装置
CN111000467B (zh) * 2019-12-28 2020-12-18 黄赛士 一种用于安全生产的混合原料均匀搅拌添加器
WO2021260597A1 (fr) * 2020-06-24 2021-12-30 Shiseido Company, Limited Systèmes et procédés pour chauffer et mélanger des compositions
CN111790297A (zh) * 2020-08-19 2020-10-20 陈晓熠 一种混合效果中药丸剂摇匀装置
IT202100026975A1 (it) * 2021-10-20 2022-01-20 Hero Europe S R L Dispositivo di miscelazione per prodotti fluidi contenuti in contenitori
CN117920009B (zh) * 2024-03-25 2024-06-14 泉州高品医学检验实验室有限责任公司 一种实验用旋涡混合器

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Also Published As

Publication number Publication date
BR112017021033A2 (pt) 2018-07-03
JP2018513007A (ja) 2018-05-24
ITBO20150192A1 (it) 2016-10-17
CN107530658A (zh) 2018-01-02
WO2016166738A3 (fr) 2016-12-08
MX2017013340A (es) 2018-02-26
WO2016166738A2 (fr) 2016-10-20
KR20170138523A (ko) 2017-12-15
AU2016249094A1 (en) 2017-10-26
CL2017002582A1 (es) 2018-04-20
US20180104662A1 (en) 2018-04-19

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