EP3268424A1 - Zusammensetzung für kunststoffabbau - Google Patents

Zusammensetzung für kunststoffabbau

Info

Publication number
EP3268424A1
EP3268424A1 EP15884882.0A EP15884882A EP3268424A1 EP 3268424 A1 EP3268424 A1 EP 3268424A1 EP 15884882 A EP15884882 A EP 15884882A EP 3268424 A1 EP3268424 A1 EP 3268424A1
Authority
EP
European Patent Office
Prior art keywords
plastic
molecular weight
composition
additive
heptane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15884882.0A
Other languages
English (en)
French (fr)
Other versions
EP3268424A4 (de
Inventor
Manuel Rendon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Timplast International LLC
Original Assignee
Timplast International LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Timplast International LLC filed Critical Timplast International LLC
Publication of EP3268424A1 publication Critical patent/EP3268424A1/de
Publication of EP3268424A4 publication Critical patent/EP3268424A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0033—Additives activating the degradation of the macromolecular compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/105—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with enzymes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/16—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with inorganic material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
    • C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C08K5/03—Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/0004—Oxidoreductases (1.)
    • C12N9/0055—Oxidoreductases (1.) acting on diphenols and related substances as donors (1.10)
    • C12N9/0057—Oxidoreductases (1.) acting on diphenols and related substances as donors (1.10) with oxygen as acceptor (1.10.3)
    • C12N9/0059—Catechol oxidase (1.10.3.1), i.e. tyrosinase
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

  • the present invention relates to a composition and, more particularly, to a composition for the degradation of plastic.
  • plastics include polluting substances that are not biodegradable.
  • formulations for environmentally-friendly compositions have been created in the past. None of them, however, use an undercover additive derived from the plastic targeted for degradation, hidden in a chemical cloak synthesized via the same plastic targeted for degradation's polymer structure itself, which is partially dissolved to create a cover for a Nano-programmed chemical addition on the inside. When activated this additive first decomposes the current polymer links between monomers and subsequently supplant them for weaker links susceptible to degradation through water, oxidation and/or anaerobic/aerobic biodegradation.
  • composition that is made of a 100% homogeneous blend that leaves no carbon footprint.
  • composition to program the degradation time with an inverse factor additive/plastic's mass, whose variation changes the plastic targeted for degradation's obsolescence time-ratio.
  • the present invention comprises the following substances: heptane, cellulose, methyl rhenium trioxide, butylated hydroxytoluene, and polyphenol oxidase.
  • sample plastic must be partially desynthesized using heptane.
  • the resulting mix is then combined at 75% of the sample plastic's melting temperature with a precise measure of cellulose, methyl rhenium trioxide, butylated hydroxytoluene, and polyphenol oxidase.
  • the resulting composition is then added as an additive to a predetermined plastic production demand.
  • the resulting plastic, homogenized with the additive subject of the present invention, has weaker links susceptible to oxidation, water degradation, and biodegradation.
  • the types of plastics that can be treated with the present composition are those with a melting temperature below 500 °C.
  • the present invention also works on oil-derived high density polymers.
  • the heptane used in the present invention partially breaks the polymer's structure while retaining the physical characteristics of the original plastic taken for sample in the additive composite.
  • the present invention then uses cellulose, methyl rhenium trioxide, butylated hydroxytoluene, and polyphenol oxidase to replace those broken links for weaker links that are more susceptible to environmental-degrading elements. Every molecule in the plastic is homogenized with the additive.
  • the other ingredients also act to reduce the potency of the heptane so that the plastic degrades over time and not all of a sudden, as heptane has the potential of doing.
  • the additive can be programmed to disintegrate the plastic at a predetermined time.
  • the obsolescence time is addressed stoichiometrically, and depends on the plastic's density. Each type of plastic has a different obsolescence time, yet relating the density of the plastic with the inverse factor additive/plastic's mass, the obsolescence time can be controlled. A higher factor for a shorter time and a lower factor for a longer time.
  • the additive's obsolescence time programmability is given by the following composition:
  • SP clients' needs. (0.1 % is equivalent to an inverse factor (additive/plastic's mass) of 1.
  • BA equals the final additive. Once BA is created, 0.1 % of the molecular weight of the amount of plastic desired to be produced is added in the form of the additive (BA).
  • the above molecular weight percentages disclose the most effective amount known to the applicant. However, each molecular weight percentage can still work in a +/- 5% range, albeit not as effectively.
  • the percentage of the molecular weight in cellulose added can be within the range of 90%) and 100%> and still function.
  • the percentage of methyl rhenium trioxide can be in the range of 45%>-55%o and function.
  • the percentage of butylated hydroxytoluene can be within the range of 10%o-20%o and still function and the percentage of polyphenol oxidase can be within the range of 70%) - 80%o and still function.
  • the amount of additive to be added to the amount of plastic sought to be produced can range between 0.09%> and 1%.
  • composition subject of the present invention there will be less pollution in the environment from plastic while retaining the original molecular structure, quality, thermo plasticity, and other physical, thermic, and mechanical characteristics.
  • the additive composition will have no carbon footprint.
EP15884882.0A 2015-03-12 2015-03-12 Zusammensetzung für kunststoffabbau Withdrawn EP3268424A4 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2015/020204 WO2016144363A1 (en) 2015-03-12 2015-03-12 Composition for the degradation of plastic

Publications (2)

Publication Number Publication Date
EP3268424A1 true EP3268424A1 (de) 2018-01-17
EP3268424A4 EP3268424A4 (de) 2018-07-18

Family

ID=56878630

Family Applications (1)

Application Number Title Priority Date Filing Date
EP15884882.0A Withdrawn EP3268424A4 (de) 2015-03-12 2015-03-12 Zusammensetzung für kunststoffabbau

Country Status (7)

Country Link
EP (1) EP3268424A4 (de)
JP (1) JP2018511309A (de)
CN (1) CN107406620A (de)
BR (1) BR112017018857A2 (de)
CA (1) CA3001284A1 (de)
MX (1) MX2017011690A (de)
WO (1) WO2016144363A1 (de)

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5212219A (en) * 1987-05-21 1993-05-18 Epron Industries Limited Degradable plastics
JP3423094B2 (ja) * 1995-01-19 2003-07-07 三井化学株式会社 生分解性ポリマー組成物
US6482872B2 (en) * 1999-04-01 2002-11-19 Programmable Materials, Inc. Process for manufacturing a biodegradable polymeric composition
AU2003211387A1 (en) * 2002-02-21 2003-09-09 Kao Corporation Biodegradable film
JP4233345B2 (ja) * 2002-02-21 2009-03-04 花王株式会社 生分解性フィルムの製造方法及び生分解性フィルム
ITMI20041627A1 (it) * 2004-08-06 2004-11-06 Lachifarma S R L Lab Chimi Co Processo per il recupero di tirosolo idrossitirosolo e altri componenti fenolici da acque di vegetazione e metodo di ossidazione catalitica di tirosolo a idrossitirosolo
JP4869842B2 (ja) * 2006-09-05 2012-02-08 ヤマハリビングテック株式会社 樹脂製品の製造方法および樹脂製品の補修方法
JP2009233166A (ja) * 2008-03-27 2009-10-15 Terumo Corp 生体吸収性材料およびそれを用いた生体内留置物
EP2389169A1 (de) * 2009-01-26 2011-11-30 Egalet A/S Formulierungen mit kontrollierter freisetzung und kontinuierlicher wirksamkeit
KR101105292B1 (ko) * 2009-06-05 2012-01-17 주식회사 리젠 바이오텍 생분해성 고분자 미세입자와 그의 제조방법
CN103797126A (zh) * 2011-04-29 2014-05-14 诺维信股份有限公司 用于增强纤维素材料的降解或转化的方法
HUE046178T2 (hu) * 2012-05-17 2020-02-28 Cartiheal 2009 Ltd Biomátrix hidrogélek és alkalmazási eljárásaik
CN102671718B (zh) * 2012-06-11 2015-06-17 淄博东大弘方化工有限公司 一种具有季胺基团的特大孔结构强碱阴离子交换树脂及其制备工艺
EP2984168A4 (de) * 2013-04-11 2016-11-23 B G Negev Technologies Ltd Zusammensetzungen und verfahren zum biologischen abbau von kunststoffen
US9181412B2 (en) * 2014-01-20 2015-11-10 Bioplast, Llc Composition for the degradation of plastic

Also Published As

Publication number Publication date
WO2016144363A1 (en) 2016-09-15
BR112017018857A2 (pt) 2018-04-24
CA3001284A1 (en) 2016-09-15
CN107406620A (zh) 2017-11-28
EP3268424A4 (de) 2018-07-18
JP2018511309A (ja) 2018-04-26
MX2017011690A (es) 2018-02-09

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