EP3249066B1 - Zierelement aus cermet und uhr, tragbares endgerät und daraus erhaltenes zubehör - Google Patents
Zierelement aus cermet und uhr, tragbares endgerät und daraus erhaltenes zubehör Download PDFInfo
- Publication number
- EP3249066B1 EP3249066B1 EP16755638.0A EP16755638A EP3249066B1 EP 3249066 B1 EP3249066 B1 EP 3249066B1 EP 16755638 A EP16755638 A EP 16755638A EP 3249066 B1 EP3249066 B1 EP 3249066B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- cermet
- nickel
- decorative member
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011195 cermet Substances 0.000 title claims description 65
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 88
- 229910052759 nickel Inorganic materials 0.000 claims description 41
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 36
- 229910052804 chromium Inorganic materials 0.000 claims description 29
- 239000011651 chromium Substances 0.000 claims description 29
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 29
- 229910052758 niobium Inorganic materials 0.000 claims description 23
- 239000010955 niobium Substances 0.000 claims description 23
- 239000010936 titanium Substances 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 19
- 229910052719 titanium Inorganic materials 0.000 claims description 19
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 14
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 239000001301 oxygen Substances 0.000 claims description 13
- 239000013078 crystal Substances 0.000 claims description 12
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims description 10
- 239000011733 molybdenum Substances 0.000 claims description 10
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- 239000010937 tungsten Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 description 21
- 238000000227 grinding Methods 0.000 description 19
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 17
- 238000005259 measurement Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 11
- 229910052737 gold Inorganic materials 0.000 description 11
- 239000010931 gold Substances 0.000 description 11
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- 238000010304 firing Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000009616 inductively coupled plasma Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000006104 solid solution Substances 0.000 description 6
- 238000005238 degreasing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000005286 illumination Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000013001 point bending Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 230000005291 magnetic effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910001020 Au alloy Inorganic materials 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 239000006061 abrasive grain Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003353 gold alloy Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910039444 MoC Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 description 1
- 238000009694 cold isostatic pressing Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910003470 tongbaite Inorganic materials 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C5/00—Bracelets; Wrist-watch straps; Fastenings for bracelets or wrist-watch straps
- A44C5/02—Link constructions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/04—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbonitrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
- B22F5/106—Tube or ring forms
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/067—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds comprising a particular metallic binder
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
- B22F2009/041—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by mechanical alloying, e.g. blending, milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Claims (4)
- Ein Cermet-Zierelement, aufweisend ein Sinterkörper-Cermet,
wobei das Sinterkörper-Cermet aufweist:eine Kristallphase, die Titancarbonitrid enthält, undeine Bindephase, die mindestens ein Metall enthält,wobei die Bindephase aufweist:Nickel als eine Hauptkomponente, mit einer Gitterkonstante von 3,54 Å oder mehr, bestimmt mittels eines Röntgendiffraktometers,Niob undChrom,wobei die Titancarbonitrid-Kristallphase eine Gitterkonstante von 4,27 Å oder mehr und 4,30 Å oder weniger hat, bestimmt mittels eines Röntgendiffraktometers,wobei ein Gehalt an Sauerstoff weniger als 1,0 Masse-% pro 100 Masse-% aller bildenden Komponenten ist,wobei ein Gehalt an freiem Kohlenstoff nicht kleiner als 1,5 Masse-% und nicht größer als 2,5 Masse-% pro 100 Masse-% aller Komponenten im Cermet ist,wobei Nickel in einer Menge von 7,0 bis 11,0 Masse-% vorhanden ist, Niob in einer Menge von 1,5 bis 6,0 Masse-% vorhanden ist, Chrom in einer Menge von 1,0 bis 5,0 Masse-% vorhanden ist, und der Rest Titancarbonitrid ist, pro 100 Masse-% aller Komponenten, die das Cermet bilden,wobei das Cermet mindestens eines von Molybdän, Wolfram und Cobalt enthält, undwobei Molybdän in einer Menge von 0,5 bis 2,0 Masse-% vorhanden ist, Wolfram in einer Menge von 0,05 bis 0,4 Masse-% vorhanden ist, und Cobalt in einer Menge von 0,02 Masse-% bis 0,2 Masse-% vorhanden ist, pro 100 Masse-% aller Komponenten, die das Cermet bilden. - Eine Uhr, aufweisend das Cermet-Zierelement gemäß Anspruch 1.
- Ein mobiles Endgerät, aufweisend das Cermet-Zierelement gemäß Anspruch 1.
- Ein Zubehörteil, aufweisend das Cermet-Zierelement gemäß Anspruch 1.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015036810 | 2015-02-26 | ||
| PCT/JP2016/055670 WO2016136894A1 (ja) | 2015-02-26 | 2016-02-25 | サーメット製装飾部材ならびにこれを用いてなる時計、携帯端末機および装身具 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP3249066A1 EP3249066A1 (de) | 2017-11-29 |
| EP3249066A4 EP3249066A4 (de) | 2018-02-14 |
| EP3249066B1 true EP3249066B1 (de) | 2019-05-22 |
Family
ID=56789506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16755638.0A Active EP3249066B1 (de) | 2015-02-26 | 2016-02-25 | Zierelement aus cermet und uhr, tragbares endgerät und daraus erhaltenes zubehör |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3249066B1 (de) |
| JP (1) | JP6423516B2 (de) |
| WO (1) | WO2016136894A1 (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6774369B2 (ja) * | 2017-04-25 | 2020-10-21 | 三菱重工航空エンジン株式会社 | 金属部材及びその製造方法 |
| EP4079478A1 (de) * | 2021-04-20 | 2022-10-26 | Comadur S.A. | Spritzgussverfahren für dekorartikel |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011047033A (ja) * | 2009-07-27 | 2011-03-10 | Kyocera Corp | 装飾部品用セラミックスおよびこれを用いた装飾部品 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2183549A1 (en) * | 1972-05-10 | 1973-12-21 | Ugine Carbone | Sintered metalcarbonitride material - for watch cases |
| JPS597341B2 (ja) * | 1978-09-25 | 1984-02-17 | 三菱マテリアル株式会社 | 耐食性のすぐれた硬質焼結合金 |
| JPH08199283A (ja) * | 1994-07-29 | 1996-08-06 | Hokkaido Sumiden Seimitsu Kk | 炭窒化チタン基合金 |
| JP4596692B2 (ja) * | 2001-06-28 | 2010-12-08 | 京セラ株式会社 | 焼結合金及びその製造方法 |
| EP2298948B1 (de) * | 2008-05-28 | 2019-05-01 | Kyocera Corporation | Keramik für ein dekoratives element und dekoratives element dasselbe umfassend |
| WO2010050493A1 (ja) * | 2008-10-29 | 2010-05-06 | 京セラ株式会社 | 装飾部品用セラミックスおよび装飾部品 |
| JP2011130894A (ja) * | 2009-12-24 | 2011-07-07 | Kyocera Corp | 装飾部品用駒成形体およびこれを焼成してなる装飾部品用駒 |
| JP5864421B2 (ja) * | 2011-03-07 | 2016-02-17 | 住友電工ハードメタル株式会社 | 装飾部品用材料 |
| JP5730455B1 (ja) * | 2013-08-30 | 2015-06-10 | 京セラ株式会社 | 装飾部品ならびにこれを用いてなる時計、携帯端末機および装身具 |
-
2016
- 2016-02-25 WO PCT/JP2016/055670 patent/WO2016136894A1/ja active Application Filing
- 2016-02-25 JP JP2017502477A patent/JP6423516B2/ja active Active
- 2016-02-25 EP EP16755638.0A patent/EP3249066B1/de active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011047033A (ja) * | 2009-07-27 | 2011-03-10 | Kyocera Corp | 装飾部品用セラミックスおよびこれを用いた装飾部品 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3249066A4 (de) | 2018-02-14 |
| WO2016136894A1 (ja) | 2016-09-01 |
| JP6423516B2 (ja) | 2018-11-14 |
| JPWO2016136894A1 (ja) | 2018-01-18 |
| EP3249066A1 (de) | 2017-11-29 |
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