EP3156524A1 - Dispositif de test et procédé de test pour simulation d'électrodéposition continue à haute vitesse d'une bande d'acier - Google Patents

Dispositif de test et procédé de test pour simulation d'électrodéposition continue à haute vitesse d'une bande d'acier Download PDF

Info

Publication number
EP3156524A1
EP3156524A1 EP14894670.0A EP14894670A EP3156524A1 EP 3156524 A1 EP3156524 A1 EP 3156524A1 EP 14894670 A EP14894670 A EP 14894670A EP 3156524 A1 EP3156524 A1 EP 3156524A1
Authority
EP
European Patent Office
Prior art keywords
bath
test apparatus
sealing ring
test
carbon brushes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14894670.0A
Other languages
German (de)
English (en)
Other versions
EP3156524B1 (fr
EP3156524A4 (fr
Inventor
Rongpin ZHANG
Haijun Wang
Yongliang LU
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Meishan Iron and Steel Co Ltd
Original Assignee
Shanghai Meishan Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Meishan Iron and Steel Co Ltd filed Critical Shanghai Meishan Iron and Steel Co Ltd
Publication of EP3156524A1 publication Critical patent/EP3156524A1/fr
Publication of EP3156524A4 publication Critical patent/EP3156524A4/fr
Application granted granted Critical
Publication of EP3156524B1 publication Critical patent/EP3156524B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/06Suspending or supporting devices for articles to be coated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/02Tanks; Installations therefor
    • C25D17/04External supporting frames or structures
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • C25D17/12Shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/12Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/04Electroplating with moving electrodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/08Electroplating with moving electrolyte e.g. jet electroplating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils
    • C25D7/0614Strips or foils

Definitions

  • the present invention relates to an electroplating test apparatus, and in particular to a test apparatus for simulating high-speed continuous electroplating of strip steel, which belongs to the technical field of electroplating.
  • An electroplating process is a complex electrochemical process, and the quality of a plated product is related to factors, such as the surface condition of a plated part, the flowing condition of electroplating solution and the degree of contact between the electroplating solution and air, besides the formula of the electroplating solution.
  • a traditional simulative electroplating test adopts a Hull cell
  • a Hull cell test can test the influence of current density and electrode distance on plating surface quality, but this test method cannot reflect the influence of flowing condition of electroplating solution on plating surface quality.
  • the utility model patent 201320146361.8 proposes an electroplating bath for uniform electroplating, and the uniform electroplating test bath comprises a bath body, an anode and a cathode, and is characterized in that the anode and the cathode adopt a flat plate structure, and the anode and the cathode are arranged in parallel to each other.
  • the anode and the cathode in the test bath adopt the flat plate structure and are arranged in parallel to each other, a uniform electric field is generated between the anode and the cathode, and thereby a sample with uniform plating can be obtained.
  • the rotational speed is low, moreover, only single-bath electroplating can be carried out, high-speed electroplating and process flows, such as alkaline wash, pickling, reflowing and passivation, cannot be simulated, and therefore a test apparatus which can meet the requirement of a high-speed continuous electroplating test needs to be developed.
  • the present invention provides a high-speed continuous electroplating test apparatus with an ingenuously designed structure, and the test apparatus can be utilized to carry out high-speed continuous electroplating of strip steel, and is applied to the development of new products and the evaluation of electroplating process parameters.
  • a test apparatus for simulating high-speed continuous electroplating of strip steel characterized in that the test apparatus comprises a supporting underframe, a workbench is arranged on the supporting underframe, a working bath is fixed on the workbench, the test apparatus also comprises a working electrode system, a circulating pump, a reservoir, a cleaning bath, a transmission shaft, an auxiliary electrode and a specimen working electrode, the reservoir is arranged under the working bath, the transmission shaft is connected to the working electrode system, both the auxiliary electrode and the working electrode system are connected to a rectifier to form a closed loop, the specimen working electrode is mounted on the working electrode system, and by adjusting the rotation of motors, a high-speed strip steel production process can be simulated.
  • the working bath includes one or the combination of several of an alkaline wash bath, a pickling bath, an electroplating bath, a reflowing bath, a passivation bath and a fluxing bath.
  • a heater and a temperature controller are arranged in the reservoir, a centrifugal pump injects working solution into the working bath after the working solution is heated to set temperature, and the upper part of the working bath is provided with overflow orifices to ensure the height of solution level.
  • the bottom is provided with a weep hole to ensure that no test solution remains under a non-working state.
  • the flow velocity of the solution is regulated by the flow of the centrifugal pump, the centrifugal pump adopts a variable-frequency motor, and flow control is realized by changing the rotational speed of the motor.
  • the motors are a rotating motor and a vertical lifting motor, and the vertical lifting motor is connected to a rotating platform to realize vertical motion; the rotating motor is connected to a moving screw of the vertical lifting motor, and high speed rotation of the working electrode system is realized by means of the transmission shaft.
  • the working electrode system comprises an upper sealing ring nut, a lower sealing ring nut, an upper sealing ring, a lower sealing ring and a polytetrafluoroethylene filling layer, the upper sealing ring and the lower sealing ring are arranged respectively on the upper and lower sides of the polytetrafluoroethylene filling layer, and are fixed respectively by the upper sealing ring nut and the lower sealing ring nut, the working electrode system also comprises carbon brushes, and the carbon brushes are arranged inside the polytetrafluoroethylene filling layer.
  • the working electrode system comprises a fastening nut, a fastening bolt, an upper sealing ring, a lower sealing ring, a bottom cover, a polytetrafluoroethylene filling layer and carbon brushes, wherein the carbon brushes are horizontal carbon brushes and vertical carbon brushes, the carbon brushes are embedded in the outer wall of the polytetrafluoroethylene filling layer, and extend to the internal axis of the polytetrafluoroethylene filling layer, and the upper sealing ring and the lower sealing ring are arranged respectively on the upper part of the polytetrafluoroethylene filling layer and the bottom cover.
  • the horizontal carbon brushes are located inside the polytetrafluoroethylene filling layer, the four horizontal carbon brushes are perpendicular in pairs, the outer ends of the horizontal carbon brushes are connected respectively to the vertical carbon brushes embedded in a groove of the outer wall of the polytetrafluoroethylene filling layer, the inner ends of the horizontal carbon brushes extend into the transmission shaft, and the horizontal carbon brushes are not in direct contact.
  • the fastening bolt When the fastening bolt is screwed into the fastening nut, the four horizontal carbon brushes are pushed away, the horizontal carbon brushes push away the vertical carbon brushes to be in tight contact with a specimen, and thereby the specimen, the transmission shaft and the carbon brushes form a three-in-one conductor; the upper sealing ring and the lower sealing ring are arranged respectively on the upper part of the polytetrafluoroethylene filling layer and the bottom cover; one end of the fastening bolt is big, the other end is small, and the adoption of the big- and small-end arrangement facilitates screwing and unscrewing the fastening bolt; when the fastening bolt is screwed, the small end of the fastening bolt pushes away the four horizontal carbon brushes, as a result, the vertical carbon brushes embedded in the groove of the outer wall of the polytetrafluoroethylene filling layer are pushed away, the vertical carbon brushes are connected tightly to the specimen, the contact area between the specimen, the carbon brushes and the transmission shaft is enlarged, and the
  • the bottom of the polytetrafluoroethylene filling layer is provided with an internal thread, and the upper part of the bottom cover is provided with an external thread.
  • the interior of the polytetrafluoroethylene filling layer is hollow, the bottom cover is connected to the internal thread of the bottom of the polytetrafluoroethylene filling layer through the external thread, and the upper sealing ring and the lower sealing ring can firmly fix the specimen on the outer wall of the working electrode system.
  • a quenching bath is arranged on the bottom in the reflowing bath, an induction coil is arranged at the middle upper part of the reflowing bath, the induction coil is connected to the rectifier, and an on-line infrared temperature detector is arranged in the induction coil, wherein the on-line infrared temperature detector is connected to a temperature controller, and is used to measure the surface temperature of strip steel.
  • the auxiliary electrode plate is shaped like a cylinder, the specimen working electrode is inserted into the center of the auxiliary electrode plate via a working platform, both are connected to the rectifier to form a closed loop, and the functions of a cathode and an anode can be exchanged by changing the positive and negative electrodes of the rectifier, so as to simulate the process of cathode and anode exchange in the processes of alkaline wash and pickling.
  • a sprinkler is arranged in the cleaning bath, the sprinkler comprises nozzles and a pipeline connected to the nozzles, and the nozzles are connected to the centrifugal pump through the pipeline.
  • the nozzles in the cleaning bath automatically perform sprinkling to clean the specimen, preventing the subsequent test from being affected, and the cleaned specimen enters the next working process.
  • test method adopting the test apparatus is characterized in that the test method is as follows: the test process can be controlled automatically; test parameters are set before a test begins, firstly, a test type (alkaline wash, pickling, electroplating, reflowing, passivation or the combination of them) needs to be set, and secondly, working parameters, including bath solution temperature, current density, retention time of a specimen in bath, etc., are set; after parameter setting, a system is prepared, so that the test apparatus is in a standby state; after system preparation is complete, the system requests an operator to send an instruction for starting the test; and after the system receives the instruction, the test process is carried out automatically until all test work is complete.
  • a test type alkaline wash, pickling, electroplating, reflowing, passivation or the combination of them
  • the test apparatus simulates the whole process of continuous strip steel production, including technical processes, such as alkaline wash, pickling, electroplating, reflowing and passivation, or separately simulates one technical process, the whole process of continuous strip steel production is simulated by adjusting the trends and rotational speeds of the two motors, the horizontal motion and vertical motion of strip steel can be realized, and the rotational speed control range is between 0m/min and 350m/min.
  • the test apparatus also has a reflowing step and a quenching step to implement the production of a plated plate, such as a tinned plate, by the reflowing step, a strip steel specimen is first dipped in flux by a moving unit, and is lifted to an induction heater of a moving support for reflowing after dipping, and after reflowing is complete, the specimen is immersed into water of the cleaning bath, so that the quenching function is carried out.
  • a plated plate such as a tinned plate
  • the technique has the following advantages: (1) the test apparatus can simulate the whole process of continuous strip steel production, including technical processes, such as alkaline wash, pickling, electroplating and passivation, and not only can simulate the whole process, but also can separately simulate one technical process, the simulative tests do not interfere with one another, consequently, the accuracy of the tests is further ensured, and electroplating-related personnel can conveniently carry out work, such as development of new product processes and evaluation of electroplating process parameters; (2) a specimen is mounted on the working electrode system, the working electrode system is mounted on the workbench, the vertical lifting motor is used to realize vertical motion, the rotating motor is used to realize the high-speed rotation of the working electrode system, the whole process of high-speed strip steel production is simulated by adjusting the rotational speed of the rotating motor, and the speed control range is between 0m/min and 350m/min; (3) the simulative test of each technical process uses a unique power supply, the specimen is always connected to one electrode of the power supply, while electrodes in each
  • Example 1 See FIG. 1, FIG. 1-1 , FIG. 1-2 and FIG. 3 , a test apparatus for simulating high-speed continuous electroplating of strip steel.
  • the test apparatus comprises a supporting underframe (4), a workbench is arranged on the supporting underframe (4), a working bath (3) is fixed on the workbench, the test apparatus also comprises a working electrode system (5), a circulating pump (8), a reservoir (10), a cleaning bath, a transmission shaft (11), an auxiliary electrode (9) and a specimen working electrode (14), the reservoir (10) is arranged under the working bath, the transmission shaft (11) is connected to the working electrode system (5), both the auxiliary electrode (9) and the working electrode system (5) are connected to a rectifier to form a closed loop, the specimen working electrode (14) is mounted on the working electrode system (5), and by adjusting the rotation of motors, a high-speed strip steel production process can be simulated.
  • All the baths of the test apparatus are mounted at fixed positions on the supporting underframe, the specimen working electrode is mounted on the working electrode system (5), and the working electrode system (5) is mounted on the workbench.
  • the whole electroplating process can be operated automatically, and the whole operation process is simple, efficient and good in safety.
  • Example 2 See FIG. 1 and FIG. 2 , as an improvement of the present invention, the working bath includes one or the combination of several of an alkaline wash bath, a pickling bath, an electroplating bath, a reflowing bath, a passivation bath and a fluxing bath.
  • the test apparatus can simulate the whole process of continuous strip steel production, including technical processes, such as alkaline wash, pickling, electroplating and passivation, and not only can simulate the whole process, but also can separately simulate one technical process, separate simulations do not interfere with one another, and thereby the accuracy of test effects is further ensured.
  • the rest of structures and advantages are exactly the same as those of the example 1.
  • Example 3 See FIG. 3 , as an improvement of the present invention, a heater (17) and a temperature controller are arranged in the reservoir, a centrifugal pump (20) injects working solution into the working bath (3) after the solution is heated to set temperature, and the upper part of the working bath (3) is provided with overflow orifices (12) to ensure the height of solution level. The bottom is provided with a weep hole (16) to ensure that no test solution remains under a non-working state.
  • the flow velocity of the solution is regulated by the flow of the centrifugal pump (20), the centrifugal pump (20) adopts a variable-frequency motor, and flow can be controlled by changing the rotational speed of the motor.
  • the rest of structures and advantages are exactly the same as those of the example 1.
  • Example 4 See FIG. 1 , as an improvement of the present invention, the motors are a rotating motor (1) and a vertical lifting motor (2), and the vertical lifting motor (2) is connected to a rotating platform to realize vertical motion; the rotating motor is connected to a moving screw of the vertical lifting motor, high speed rotation of the working electrode system is realized by means of the transmission shaft, the vertical lifting motor realizes vertical motion, the rotating motor realizes the high-speed rotation of the working electrode system, the whole process of high-speed strip steel production is simulated by adjusting the rotational speed of the rotating motor, and the speed control range is between 0m/min and 350m/min.
  • the speed control range is between 0m/min and 350m/min.
  • the working electrode system (5) comprises an upper sealing ring nut (21), a lower sealing ring nut (22), an upper sealing ring (23), a lower sealing ring (25) and a polytetrafluoroethylene filling layer (26), the upper sealing ring and the lower sealing ring are arranged respectively on the upper and lower sides of the polytetrafluoroethylene filling layer, and are fixed respectively by the upper sealing ring nut and the lower sealing ring nut, the working electrode system (5) also comprises carbon brushes (25), and the carbon brushes (25) are arranged inside the polytetrafluoroethylene filling layer.
  • the carbon brushes are arranged inside the polytetrafluoroethylene filling layer, the carbon brushes have good conductivity, wear resistance and corrosion resistance, consequently, strip steel has good conductivity, and the conductive effect is enhanced; and the upper round sealing ring and the lower round sealing ring are sleeved respectively on the upper side and the lower side of the polytetrafluoroethylene filling layer to prevent electroplating solution from flowing into a part between the polytetrafluoroethylene and the specimen working electrode (14), causing the shift of the specimen working electrode (14), and affecting the electroplating effect.
  • the rest of structures and advantages are exactly the same as those of the example 1.
  • Example 6 See FIG. 1 and FIG. 3 , as an improvement of the present invention, the auxiliary electrode (9) is shaped like a cylinder, the specimen working electrode (14) is inserted into the center of the auxiliary electrode via a working platform, both are connected to the rectifier to form a closed loop, and the functions of a cathode and an anode can be exchanged by changing the positive and negative electrodes of the rectifier, so as to simulate the process of cathode and anode exchange in the processes of alkaline wash and pickling.
  • the rest of structures and advantages are exactly the same as those of the example 1.
  • Example 7 See FIG. 4 , as an improvement of the present invention, a sprinkler is arranged in the cleaning bath (18), the sprinkler comprises nozzles (19) and a pipeline connected to the nozzles, and the nozzles are connected to the centrifugal pump (20) through the pipeline.
  • the vertical lifting motor places the specimen at a specified position of the working bath. After working for a certain period of time, the vertical lifting motor lifts the specimen out of the working bath, and the rotating platform moves the specimen to the cleaning bath.
  • the nozzles in the cleaning bath automatically perform sprinkling to clean the specimen, preventing the subsequent test from being affected, and the cleaned specimen enters the next working process.
  • the rest of structures and advantages are exactly the same as those of the example 1.
  • Example 8 See FIG. 5 , a quenching bath (30) is arranged on the bottom in the reflowing bath, an induction coil (28) is arranged at the middle upper part of the reflowing bath, and the induction coil (28) is connected to the rectifier, an on-line infrared temperature detector (29) is arranged in the induction coil, wherein the on-line infrared temperature detector (29) is connected to a temperature controller, and is used to measure the surface temperature of strip steel.
  • a reflowing function and a quenching function are realized in the reflowing bath, the strip steel rotates at certain speed, and passes through the induction coil (28) from top down at constant speed, and thereby a good reflowing effect can be ensured.
  • the reflowing coil is located at the middle upper part of the bath, the quenching bath (30) is located on the bottom, and the reflowing coil is 20cm high, and is connected to the rectifier;
  • the on-line infrared temperature detector is arranged at the middle of the reflowing coil, is connected to the temperature controller, and is used to measure the surface temperature of the strip steel; when the strip steel gets into the reflowing coil, the rectifier is started, and the surface temperature of the strip steel is monitored by the infrared temperature detector; after completely passing through the reflowing coil, the strip steel gets into the quenching bath on the bottom of the reflowing bath and is quenched;
  • a tinned plate (2.8g/m2) is taken as an example, the rotational speed of the strip steel is 100r/min, and when the time which the strip steel takes to get into the reflowing coil and completely leave the reflowing coil is 4.8s to 5.5s, the reflowing effect of the tinne
  • the working electrode system (5) can also be so configured that the working electrode system (5) comprises a fastening nut (32), a fastening bolt (31), an upper sealing ring (23), a lower sealing ring (24), a bottom cover (27), a polytetrafluoroethylene filling layer (26) and carbon brushes (25), wherein the carbon brushes are horizontal carbon brushes and vertical carbon brushes, there are four horizontal carbon brushes and four vertical carbon brushes, the horizontal carbon brushes are located inside the polytetrafluoroethylene filling layer (26), the four horizontal carbon brushes are perpendicular in pairs, the outer ends of the horizontal carbon brushes are connected respectively to the vertical carbon brushes embedded in a groove of the outer wall of the polytetrafluoroethylene filling layer, the inner ends of the horizontal carbon brushes extend into the transmission shaft, and the horizontal carbon brushes are not in direct contact.
  • the carbon brushes are horizontal carbon brushes and vertical carbon brushes, there are four horizontal carbon brushes and four vertical carbon brushes, the horizontal carbon brushes are located inside the polytetrafluoroethylene filling layer (
  • the fastening bolt When the fastening bolt is screwed into the fastening nut, the four horizontal carbon brushes are pushed away, the horizontal carbon brushes push away the vertical carbon brushes to be in tight contact with a specimen, and thereby the specimen working electrode, the transmission shaft and the carbon brushes form a three-in-one conductor; the upper sealing ring (23) and the lower sealing ring (24) are arranged respectively on the upper part of the polytetrafluoroethylene filling layer and the bottom cover; one end of the fastening bolt is big, the other end is small, and the adoption of the big- and small-end arrangement facilitates screwing and unscrewing the fastening bolt; when the fastening bolt is screwed, the small end of the fastening bolt pushes away the four horizontal carbon brushes, as a result, the vertical carbon brushes embedded in the groove of the outer wall of the polytetrafluoroethylene filling layer are pushed away, the vertical carbon brushes are connected tightly to the specimen, the contact area between the specimen, the carbon brushes and the transmission shaft is
  • the bottom of the polytetrafluoroethylene filling layer is provided with an internal thread, and the upper part of the bottom cover is provided with an external thread.
  • the interior of the polytetrafluoroethylene filling layer is hollow, the bottom cover is connected to the internal thread of the bottom of the polytetrafluoroethylene filling layer through the external thread, and the upper sealing ring and the lower sealing ring can firmly fix the specimen on the outer wall of the working electrode system.
  • the fastening bolt is screwed into the fastening nut, as a result, the carbon brushes on the outer wall of the polytetrafluoroethylene filling layer are pushed away around to be in tight contact with the inner wall of the strip steel, and the strip steel, the transmission shaft and the carbon brushes form a three-in-one conductor.
  • the bottom cover is then screwed, at this moment, the strip steel is wrapped by the upper sealing ring and the lower sealing ring, and the good sealing effect can prevent the solution from entering the inner wall of the specimen to affect the test effect.
  • the bottom cover needs to be unscrewed first, at this moment, the specimen cannot be taken down, and if the specimen is forcibly taken down, the carbon brushes will be damaged; the fastening bolt is then unscrewed, so that the carbon brushes embedded in the outer wall of the polytetrafluoroethylene filling layer retract into the polytetrafluoroethylene filling layer; finally, the specimen is taken down, and other tests are carried out.
  • the rest of structures and advantages are exactly the same as those of the example 1.
  • Example 10 See FIG. 1 to FIG. 7 , a test method adopting the test apparatus.
  • the test method is as follows: the test process can be controlled automatically; test parameters are set before a test begins, firstly, a test type (alkaline wash, pickling, electroplating, reflowing, passivation or the combination of them) needs to be set, and secondly, working parameters, including bath solution temperature, current density, retention time of a specimen in bath, etc., are set; after parameter setting, a system is prepared, so that the test apparatus is in a standby state; after system preparation is complete, the system requests an operator to send an instruction for starting the test; and after the system receives the instruction, the test process is carried out automatically until all test work is complete.
  • a test type alkaline wash, pickling, electroplating, reflowing, passivation or the combination of them
  • the test apparatus simulates the whole process of continuous strip steel production, including technical processes, such as alkaline wash, pickling, electroplating, reflowing and passivation, or separately simulates one technical process, the whole process of continuous strip steel production is simulated by adjusting the trends and rotational speeds of the two motors, the horizontal motion and vertical motion of strip steel can be realized, and the rotational speed control range is between 0m/min and 350m/min.
  • the test apparatus also has a reflowing step and a quenching step to implement the production of a plated plate, such as a tinned plate, by the reflowing step, a strip steel specimen is first dipped in flux by a moving unit, and is lifted to an induction heater of a moving support for reflowing after dipping, and after reflowing is complete, the specimen is immersed into water of the cleaning bath, so that the quenching function is carried out.
  • a plated plate such as a tinned plate
  • the present invention can also combine at least one of the technical features of the embodiments 2, 3, 4, 5, 6, 7 and 8 and the embodiment 1 together to form a new embodiment.
  • the present invention can also combine at least one of the technical features of the embodiments 2, 3, 4, 6, 7, 8 and 9 and the embodiment 1 together to form a new embodiment.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Electroplating Methods And Accessories (AREA)
EP14894670.0A 2014-06-11 2014-11-29 Dispositif de test et procédé de test pour simulation d'électrodéposition continue à haute vitesse d'une bande d'acier Active EP3156524B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410256940.7A CN105220196B (zh) 2014-06-11 2014-06-11 一种用于模拟带钢高速连续电镀的试验装置及试验方法
PCT/CN2014/092602 WO2015188598A1 (fr) 2014-06-11 2014-11-29 Dispositif de test et procédé de test pour simulation d'électrodéposition continue à haute vitesse d'une bande d'acier

Publications (3)

Publication Number Publication Date
EP3156524A1 true EP3156524A1 (fr) 2017-04-19
EP3156524A4 EP3156524A4 (fr) 2018-01-24
EP3156524B1 EP3156524B1 (fr) 2019-03-27

Family

ID=54832849

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14894670.0A Active EP3156524B1 (fr) 2014-06-11 2014-11-29 Dispositif de test et procédé de test pour simulation d'électrodéposition continue à haute vitesse d'une bande d'acier

Country Status (3)

Country Link
EP (1) EP3156524B1 (fr)
CN (1) CN105220196B (fr)
WO (1) WO2015188598A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202100015917A1 (it) * 2021-06-17 2022-12-17 Dreamet Srl Metodo e Apparato per il Trattamento di Superfici Metalliche

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105696045B (zh) * 2014-11-29 2018-03-27 上海梅山钢铁股份有限公司 用于模拟带钢高速连续电镀的试验装置及试验方法
CN107287649A (zh) * 2016-03-30 2017-10-24 上海梅山钢铁股份有限公司 高速镀锡板生产模拟试验装置及试验方法
CN109457288A (zh) * 2018-12-26 2019-03-12 华侨大学 多工位的平台式旋转电镀实验装置
CN109338439A (zh) * 2018-12-27 2019-02-15 肇庆市英拓自动化设备科技有限公司 用于微型电子元器件的离心电镀机

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2270339A1 (en) * 1974-02-06 1975-12-05 Euro Ceram Electroplating, esp. of dental prosthesis with gold - in machine with twelve baths arranged in a circle round substrate carrier
JPH0533196A (ja) * 1991-07-31 1993-02-09 Tanaka Kikinzoku Kogyo Kk メツキ装置
US5985106A (en) * 1995-07-14 1999-11-16 Velasquez; Geronimo Z. Continuous rack plater
CN2327701Y (zh) * 1998-04-29 1999-07-07 宝山钢铁(集团)公司 高速电镀工艺试验装置
JP3091966B1 (ja) * 1999-06-17 2000-09-25 株式会社山本鍍金試験器 電気めっき試験装置及びその方法
CN2618927Y (zh) * 2003-04-29 2004-06-02 宝山钢铁股份有限公司 高速电镀工艺试验装置
CN101407934B (zh) * 2008-11-04 2010-07-14 中冶连铸技术工程股份有限公司 电镀锌液自动配置-更新系统
JP6099256B2 (ja) * 2012-01-20 2017-03-22 ローム アンド ハース エレクトロニック マテリアルズ エルエルシーRohm and Haas Electronic Materials LLC スズおよびスズ合金のための改良されたフラックス方法
CN102706729B (zh) * 2012-06-08 2014-04-16 上海交通大学 工况模拟导电辊材料损伤失效的实验装置

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202100015917A1 (it) * 2021-06-17 2022-12-17 Dreamet Srl Metodo e Apparato per il Trattamento di Superfici Metalliche

Also Published As

Publication number Publication date
CN105220196A (zh) 2016-01-06
EP3156524B1 (fr) 2019-03-27
EP3156524A4 (fr) 2018-01-24
WO2015188598A1 (fr) 2015-12-17
CN105220196B (zh) 2018-03-06

Similar Documents

Publication Publication Date Title
EP3156524B1 (fr) Dispositif de test et procédé de test pour simulation d'électrodéposition continue à haute vitesse d'une bande d'acier
CN108977866B (zh) 一种激光辅助喷雾微弧氧化装置
CN103966637B (zh) 电刷镀实验平台
CN205165068U (zh) 一种电机转子涂漆装置
CN106890756B (zh) 浸甩一体涂覆机及其工作方法
CN202199557U (zh) 一种全自动胶缸清洗系统
CN204134814U (zh) 一种固体染色设备
CN204018147U (zh) 一种升降机构及涂层装置
CN112663102B (zh) 一种内管均匀电镀装置
CN207862471U (zh) 一种环保型全自动滚镀设备
CN105696045B (zh) 用于模拟带钢高速连续电镀的试验装置及试验方法
CN205313690U (zh) 一种钛合金微弧氧化和阳极氧化一体的加工设备
CN107385498A (zh) 铜排镀锡用缸槽及全自动铜排镀锡生产设备和方法
CN207894793U (zh) 一种钢丝绳的盐雾测试装置
CN101165221A (zh) 长铜排连续移动射流镀锡的方法及设备
CN205062214U (zh) 一种线材连续电镀设备
WO2015188597A1 (fr) Dispositif de test d'électroplacage en continu simulant différentes vitesses linéaires d'acier en bande
CN202509123U (zh) 一种旋转式小零件连续热浸镀装置
CN203960377U (zh) 模拟带钢高速连续电镀的工作电极系统及电镀试验装置
CN209039625U (zh) 一种用于自动滚镀镍生产线的节水式阳极设备
CN110994327B (zh) 一种接地棒用生产方法及其生产设备
CN103397364A (zh) 一种铝硅合金表面陶瓷化处理方法及设备
CN203484270U (zh) 拉链头自动喷漆用装具
CN209318027U (zh) 一种防锈油涂抹装置
CN103898701A (zh) 一种纺织品的加工方法

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20161225

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20180104

RIC1 Information provided on ipc code assigned before grant

Ipc: C25D 7/06 20060101ALI20171220BHEP

Ipc: C25D 17/12 20060101ALI20171220BHEP

Ipc: C25D 17/06 20060101ALI20171220BHEP

Ipc: C25D 5/04 20060101ALI20171220BHEP

Ipc: C25D 5/08 20060101ALI20171220BHEP

Ipc: C25D 17/00 20060101AFI20171220BHEP

Ipc: C25D 17/04 20060101ALI20171220BHEP

Ipc: C25D 21/12 20060101ALI20171220BHEP

Ipc: C25D 17/10 20060101ALI20171220BHEP

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20181015

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1113205

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190415

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602014043847

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190627

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190628

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190627

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1113205

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190727

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190727

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602014043847

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

26N No opposition filed

Effective date: 20200103

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191130

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191130

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191129

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20191130

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20191129

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191129

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191130

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191129

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20141129

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20231107

Year of fee payment: 10