EP3030346A1 - Catalyseur contenant de l'iridium et procédé pour une réaction de guerbet en phase gazeuse - Google Patents

Catalyseur contenant de l'iridium et procédé pour une réaction de guerbet en phase gazeuse

Info

Publication number
EP3030346A1
EP3030346A1 EP14749771.3A EP14749771A EP3030346A1 EP 3030346 A1 EP3030346 A1 EP 3030346A1 EP 14749771 A EP14749771 A EP 14749771A EP 3030346 A1 EP3030346 A1 EP 3030346A1
Authority
EP
European Patent Office
Prior art keywords
catalyst
range
weight
condensation
alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14749771.3A
Other languages
German (de)
English (en)
Inventor
Andreas Kuschel
Stephan Schunk
Andreas Lanver
Stephan Deuerlein
Gauthier Luc Maurice AVERLANT
Michal Ludwik LEJKOWSKI
Verena MORMUL
Guido WASSERSCHAFF
Regine Helga BEBENSEE
Andreas Strasser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP14749771.3A priority Critical patent/EP3030346A1/fr
Publication of EP3030346A1 publication Critical patent/EP3030346A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/468—Iridium
    • B01J35/40—
    • B01J35/613—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0063—Granulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Abstract

L'invention concerne un catalyseur et un procédé de condensation d'alcools en phase gazeuse par réaction de guerbet. De préférence, le catalyseur selon l'invention est utilisé dans un procédé de production de butanol par condensation d'éthanol. Le catalyseur comporte un matériau de support en composés similaires à de l'hydrotalcite, en particulier de l'hydrotalcite, partiellement ou totalement thermiquement désintégré, en contact avec de l'iridium et/ou du ruthénium comme promoteur, la teneur en iridium et/ou en ruthénium étant de l'ordre de 0,05 - 4 % en poids, de préférence de 0,1 - 3,5 % en poids et idéalement de 0,2 - 3,0 % en poids et la taille moyenne des particules de promoteur étant < 100 nm, de préférence < 75 nm , mieux encore < 50 nm et idéalement < 20 nm. La teneur en alcali des catalyseurs est très faible, c'est-à-dire < 1 % en poids, de préférence < 0,5 % en poids. Dans un mode de réalisation préféré, le procédé est mis en œuvre à une température de l'ordre de 0 - 450 °C, une pression de l'ordre de 0,05 - 60 bar et une teneur en alcool dans le courant de substance de départ de l'ordre de 0,5 - 90 % en volume.
EP14749771.3A 2013-08-07 2014-08-04 Catalyseur contenant de l'iridium et procédé pour une réaction de guerbet en phase gazeuse Withdrawn EP3030346A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP14749771.3A EP3030346A1 (fr) 2013-08-07 2014-08-04 Catalyseur contenant de l'iridium et procédé pour une réaction de guerbet en phase gazeuse

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13179564 2013-08-07
PCT/EP2014/066727 WO2015018793A1 (fr) 2013-08-07 2014-08-04 Catalyseur contenant de l'iridium et procédé pour une réaction de guerbet en phase gazeuse
EP14749771.3A EP3030346A1 (fr) 2013-08-07 2014-08-04 Catalyseur contenant de l'iridium et procédé pour une réaction de guerbet en phase gazeuse

Publications (1)

Publication Number Publication Date
EP3030346A1 true EP3030346A1 (fr) 2016-06-15

Family

ID=48917440

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14749771.3A Withdrawn EP3030346A1 (fr) 2013-08-07 2014-08-04 Catalyseur contenant de l'iridium et procédé pour une réaction de guerbet en phase gazeuse

Country Status (2)

Country Link
EP (1) EP3030346A1 (fr)
WO (1) WO2015018793A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9765001B2 (en) 2014-01-17 2017-09-19 Basf Se Method for producing arylpropenes
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
RU2018105604A (ru) 2015-07-15 2019-08-15 Басф Се Способ получения арилпропена
WO2017009458A1 (fr) 2015-07-15 2017-01-19 Basf Se Procédé de préparation d'un arylpropène
EP3325457B1 (fr) 2015-07-22 2020-01-01 Basf Se Procédé de préparation d'acide furanne-2,5-dicarboxylique
CN108368017B (zh) 2015-12-15 2021-07-09 切弗朗菲利浦化学公司 由金属内酯和阴离子聚电解质形成α,β-不饱和羧酸和其盐
US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
US10544080B2 (en) 2017-06-14 2020-01-28 Chevron Phillips Chemical Company Lp Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor
CN107469861B (zh) * 2017-08-30 2020-09-04 江南大学 一种用于双酚F合成的Ir@Cu@BINAL@HT催化剂及制备方法
US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates
CN111468185A (zh) * 2020-04-16 2020-07-31 江苏星诺新材料科技有限公司 一种负载型光催化剂及其制备方法与应用
CN113398925B (zh) * 2021-07-07 2023-01-03 南京工业大学 一种负载铱多相催化剂及其制备方法和应用

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8071822B2 (en) * 2008-01-28 2011-12-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid
KR101523122B1 (ko) * 2008-03-06 2015-05-26 도다 고교 가부시끼가이샤 탄화수소를 분해하는 다공질 촉매체 및 그의 제조 방법, 탄화수소로부터 수소를 포함하는 혼합 개질 가스를 제조하는 방법, 및 연료 전지 시스템

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
None *
See also references of WO2015018793A1 *

Also Published As

Publication number Publication date
WO2015018793A1 (fr) 2015-02-12

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