EP2954085B1 - Dispositif de revêtement d'une bande métallique par immersion à chaud - Google Patents
Dispositif de revêtement d'une bande métallique par immersion à chaud Download PDFInfo
- Publication number
- EP2954085B1 EP2954085B1 EP14705302.9A EP14705302A EP2954085B1 EP 2954085 B1 EP2954085 B1 EP 2954085B1 EP 14705302 A EP14705302 A EP 14705302A EP 2954085 B1 EP2954085 B1 EP 2954085B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- nozzle
- extension piece
- trunk
- nozzle extension
- metal strip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 63
- 239000002184 metal Substances 0.000 title claims description 63
- 238000003618 dip coating Methods 0.000 title claims description 15
- 239000011248 coating agent Substances 0.000 claims description 31
- 238000000576 coating method Methods 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 238000005275 alloying Methods 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 6
- 239000010410 layer Substances 0.000 description 27
- 239000000155 melt Substances 0.000 description 21
- 239000000956 alloy Substances 0.000 description 18
- 229910045601 alloy Inorganic materials 0.000 description 17
- 229910000831 Steel Inorganic materials 0.000 description 14
- 239000010959 steel Substances 0.000 description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 12
- 239000004606 Fillers/Extenders Substances 0.000 description 11
- 239000002893 slag Substances 0.000 description 10
- 210000004894 snout Anatomy 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000007547 defect Effects 0.000 description 6
- 230000000087 stabilizing effect Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 241001474791 Proboscis Species 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0034—Details related to elements immersed in bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0034—Details related to elements immersed in bath
- C23C2/00342—Moving elements, e.g. pumps or mixers
- C23C2/00344—Means for moving substrates, e.g. immersed rollers or immersed bearings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
- C23C2/004—Snouts
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/38—Wires; Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/02—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
- B05C11/06—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface with a blast of gas or vapour
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C3/00—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
- B05C3/02—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
- B05C3/12—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length
- B05C3/125—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length the work being a web, band, strip or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S118/00—Coating apparatus
- Y10S118/19—Wire and cord immersion
Definitions
- the invention relates to a device for hot dip coating of metal strip, preferably steel strip, with a Schmelzbadgefäß, opening in the molten glass tubing for introducing a warmed in a continuous furnace metal strip in the molten bath and arranged in Schmelzbadgefäß pulley for deflecting the entering into the molten metal strip in one of the Molten bath pointing direction.
- metal strip preferably steel strip
- Schmelzbadgefäß opening in the molten glass tubing for introducing a warmed in a continuous furnace metal strip in the molten bath and arranged in Schmelzbadgefäß pulley for deflecting the entering into the molten metal strip in one of the Molten bath pointing direction.
- Such a device is for example from the EP 0 650 534 B1 known.
- Devices or systems of this type are also referred to as fire-coating systems. They are characterized by a continuous mode of operation.
- oxides and slag accumulate on the surface of the molten metal within the trunk, which can lead to defects in the coating of the metal strip.
- the slag is dragged off the belt, resulting, for example, in spots of poor adhesion due to alloy layer disturbances and slag inclusions, as well as defects (uncoated spots) in the coating.
- the present invention has for its object to improve a device of the type mentioned in that slag-conditioned surface defects are avoided on the surface of the coated metal strip.
- the device according to the invention comprises a molten bath vessel, a proboscis emptying therein for introducing a heated in a continuous furnace Metal strip in the molten bath and arranged in the molten bath deflection roller for deflecting the entering from the trunk into the molten metal strip in a pointing away from the molten bath direction.
- the device is characterized in that the trunk is provided with a shaft-shaped trunk extension piece for enlarging the trunk immersion depth, wherein the inner width of the trunk extension section tapers towards its outlet opening at least over a partial length thereof, the trunk extension section (6.1) having a connection section (6.11) , in which the lower end of the trunk (6) protrudes, and the connecting portion (6.11) has a basin or trough-shaped receiving space (6.12) has.
- the trunk extension piece according to the invention may be a separately manufactured component, which is attached to the lower end of the trunk while leaving at least one feed opening. But it can also be integrally formed with the trunk or liquid-tight connected to the lower end of the trunk.
- the inner width of the shaft-shaped trunk extension piece essentially corresponds to the clear inner height, preferably the clear vertical inner height, or the inner diameter of the trunk extension piece.
- the inside width of the snout extender piece is measured transversely, for example perpendicularly, to the plane of the metal band portion passing through the snout extender piece.
- the flow of the melt within the trunk due to the Bernoulli effect is intensified by the tapering of the inner width or inner clear height of the trunk extension piece towards its outlet opening.
- the intensified within the trunk flow is characterized by relatively high turbulence, which cause an increased flow rate at the molten bath and a better mixing / homogenization of the melt and thus prevent slag formation or slag accumulation at Schmelzbadador within the trunk as much as possible. In this way, slag-conditioned surface defects on the surface of the coated metal strip can be avoided.
- a circulation of the melt within the trunk, in particular on the surface of the molten bath is effected in the trunk. Any existing oxide skins are thereby torn open and can not join together.
- An advantageous embodiment of the device according to the invention provides that the inner width or clear inner height of the trunk extension piece tapers towards its outlet opening, at least over a partial length thereof.
- the inner width or inner height of the trunk elongation piece may taper towards its outlet opening, at least over a partial length thereof, stepwise in the form of one or more inner jumps (inner height jumps) and / or in the form of differently angled trunk wall sections. Also in this way can be achieved in a reliable manner a significant intensification of the flow and slagging or Avoid slag accumulation at the molten bath level in the trunk.
- the realization of the rejuvenation (s) of the trunk by one or more inside jumps and / or different from each other angled trunk sections is low in manufacturing terms and allows the formation of special flow profiles in the trunk.
- a further preferred embodiment of the device according to the invention provides that the outlet opening or narrowest point of the trunk extension piece has a clear inner width of not more than 120 mm, preferably not more than 100 mm.
- a further preferred embodiment of the device according to the invention therefore provides that the trunk extension piece ends at a distance in the range of 100 mm to 400 mm, preferably 100 mm to 300 mm, relative to the lateral surface of the deflection roller.
- the length of the trunk extension piece should be so dimensioned that in the case of hot dip coating of the metal strip the penetration depth of the trunk is at least 400 mm.
- the length of the trunk extension piece is dimensioned so that the hot dip coating of the metal strip, the Rute immersion depth is at least 500 mm, more preferably at least 600 mm.
- a further advantageous embodiment of the device according to the invention is characterized in that the trunk extension piece has a connection section in which the lower end of the spout protrudes, wherein the terminal portion and the trunk define at least one supply channel for the separate addition of coating material or at least one alloying additive in the trunk and / or in the trunk extension piece.
- This design allows for the creation of regions of different melt compositions to set certain desired alloy layer properties. By adding a specific coating or alloy material directly into the proboscis acting as a lock, it is possible to decouple the melt composition in the lock (proboscis) from the molten composition in the remainder of the molten bath vessel.
- the molten bath vessel with a substantially pure aluminum melt and to enrich the melt in the lock (trunk) with silicon so that a relatively thin alloy layer is first obtained on the metal strip to be coated.
- the metal strip subsequently coated with pure aluminum as cover coating is then sufficiently ductile by the thin alloy layer in order to be able to realize desired forming processes. Due to the top layer of pure aluminum, the product also has excellent anti-corrosion properties.
- a further advantageous embodiment of the device according to the invention is characterized in that the Gansselverinrungs vinegar is provided with at least one separate channel, by the negative pressure in the trunk or when the molten metal surface (Schmelzbadober Structure) in the trunk against the molten metal surface (Schmelzbadober Design) outside the trunk Molten metal from the Schmelzbadgefäß can flow in the direction of the molten metal surface in the trunk.
- a subsequent flow of molten metal from the melt bath in the upper region of the lock and thus a relatively constant level of the molten metal in the lock are ensured.
- the one or more separate channels can be arranged for this purpose, for example, on the outside of the trunk extension piece.
- Their inlet openings should be sufficiently deep in the molten bath. Preferably, they open at the lower end of the trunk extension piece.
- the at least one separate channel has an end portion which is above a bottom of the connecting portion in a throat area thereof empties.
- a relatively large distance of the outlet opening of the separate channel with respect to the entrance opening of the snout extender is expedient with regard to the separate addition of coating material or an alloying additive into the sluice defined by the trunk so that the sluice flowing from the meltblown vessel via the separate channel into the upper area of the sluice Metal melt can be mixed as homogeneously as possible with the coating material or alloying additive added to the lock, and thus a correspondingly homogeneous coating of the metal strip is achieved.
- Fig. 3 is a section of a conventional plant for hot dip coating of metal strip, especially steel strip outlined.
- the metal strip 1 is protected from corrosion.
- the metal strip 1 is first cleaned in a continuous furnace 2 and annealed recrystallizing. Subsequently, the strip 1 is melt-dipped by being passed through a molten metal bath 3.
- the coating metal for the band for example, zinc, zinc alloys, aluminum and aluminum alloys are used.
- the molten bath vessel 4 is electrically heated.
- an alloy layer of iron and the coating metal is formed on the strip surface.
- the metal layer is formed, the composition of which corresponds to the chemical analysis of the molten metal vessel 4 located in the molten metal.
- the layer thickness of the metal layer serving as corrosion protection is usually adjusted by means of stripping nozzles 5.
- the continuous furnace 2 typically comprises a directly heated preheater (not shown) and indirectly heated reduction and holding zones (not shown) and subsequent cooling zones. At the end of the cooling zone, the furnace 2 is connected to the molten bath 3 via a lock (trunk) 6. In the indirect heated oven part and in the cooling zones, a reducing atmosphere of nitrogen and hydrogen is set.
- the steel strip 1 is annealed recrystallizing in the furnace 2, so that the steel work-hardened during rolling obtains the required technological properties after the passage. In addition, due to the hydrogen content in the furnace atmosphere, a reduction of possibly present iron oxides takes place. In the subsequent cooling zones, the strip 1 is cooled and enters the same at a temperature corresponding to the molten bath 3.
- An arranged in the molten bath deflection roller 7 causes the deflection of the entering from the trunk 6 in the molten bath steel strip 1 in a preferably vertical direction.
- At least one stabilizing roller 8 and optionally a pressure roller (pass-line roller) 9 ensure a smooth, vibration-free passage of the belt 1 through the wide flat nozzles 5 of the nozzle wiper device arranged above the molten bath.
- the strip 1 Upon exiting the molten bath 3, the strip 1 entrains a quantity of coating material dependent on the strip speed from the molten bath.
- the resulting layer thickness of the metal overlay is considerably higher than the desired layer thickness.
- the excess coating metal is stripped from the flat nozzles 5 by means of directed air or gas jets, so that the desired metal coating layer thickness remains on the belt 1.
- the invention proposes to increase the immersion depth of the trench 6 and to taper the inner width of the dipped trunk extension piece 6.1 towards its exit opening at least over a partial length thereof.
- the inventive extension of the trunk 6 can be realized in different embodiments.
- the proboscis 6 of a generic coating system which essentially according to the coating system Fig. 3 can correspond to or corresponds to, provided with a shaft-shaped trunk extension piece 6.1 to increase the Rouvreleintauchianae.
- the trunk extension piece 6.1 has a connection section 6.11 into which the lower end of the trunk 6 protrudes.
- the connecting section 6.11 has a basin-shaped or trough-shaped receiving space 6.12, whose peripheral side wall is fastened to a carrier 6.13 mounted on the upper edge of the melting bath vessel 4.
- connection section 6.11 or receiving space 6.12 an elongated opening 6.14 is formed through which the metal strip to be coated 1 runs in the shaft-shaped trunk extension piece 6.1.
- the inner width (inner clear height) W of the trunk extension piece 6.1 tapers towards its outlet opening 6.15.
- the tapering of the inner width results from the fact that the walls 6.16, 6.17 of the trunk extension piece 6.1 which face the upper side and lower side of the band 1 converge in the direction of the exit opening 6.15.
- the inner diameter of the trunk extender 6.1 is thus characterized in this embodiment by a continuous taper.
- the outlet opening 6.15 or narrowest point of the trunk extension piece 6.1 preferably has a clear inner width W of not more than 120 mm, particularly preferably not more than 100 mm (cf. Fig. 4 ). Furthermore, the trunk extension piece 6.1 is dimensioned such that it ends opposite to the lateral surface of the deflection roller 7 at a distance A in the range of 100 mm to 400 mm, preferably 100 mm to 300 mm. For example, the distance A of the lower end of the snout extender 6.1 from the lateral surface of the guide roller 7 is about 200 mm.
- the deflection roller 7 is associated with a stabilizing roller 8 in order to plan a flat, vibration-free passage of the belt 1 through the flat nozzles 5 of the nozzle scraping device arranged above the molten bath sure.
- the support arms of the deflection roller 7 and the stabilizing roller 8 are in Fig. 1 denoted by 7.1 and 8.1.
- the stabilizing roller 8 can be combined with a guide roller or pressure roller 9, which is likewise arranged in a dipped manner (cf. Fig. 2 ).
- connection portion 6.11 of the trunk extension piece 6.1 and the trunk 6 at least one supply channel 6.18, via the immersed portion of the trunk 6 and / or in the trunk extension piece 6.1 coating material B and / or at least one alloying additive LZ can be added separately ,
- the trunk extension piece 6.1 does not have a trough-shaped or basin-shaped connection section.
- the trunk extension piece 6.1 is attached directly to the end of the trunk 6, ie between the submerged end of the trunk 6 and the trunk extension piece 6.1 no supply gap or channel is provided.
- the trunk extender 6.1 is composed of several of the top and bottom of the band 1 facing walls or wall sections 6.19, 6.20, 6.21, 6.22. While the upper walls / wall sections 6.19, 6.20 are substantially parallel to one another, the lower walls / wall sections 6.21, 6.22 are angled away from upper walls / wall sections 6.19, 6.20 and converge in the direction of the exit opening 6.15.
- the continuous inner diameter taper of the trunk extender piece 6.1 thus extends in this embodiment over a partial length of the trunk extender piece.
- FIGS. 6 and 7 is the velocity distribution in the molten bath vessel during operation of a coating device of the prior art ( Fig. 6 ) and during operation of a coating device according to the invention ( Fig. 7 ) adjusting melt flow outlined.
- a comparison of FIGS. 6 and 7 illustrates that by the invention trunk extension 6.1, the flow in the trunk 6, in particular is intensified in the area enclosed by the trunk 6 area 3.1 of the molten bath, which causes a constant replacement of the melt at the molten surface in the trunk 6.
- a circulation of the melt within the trunk 6, in particular on the surface of the molten bath in the trunk 6, is effected.
- no slag can accumulate, causing surface defects in the coating of the belt 1.
- the trunk extension according to the invention also offers the possibility of creating areas in the melt pool 3 with different melt compositions in order to set certain desired alloy layer properties. This will be explained below with reference to FIGS. 8 to 10 explained in more detail.
- a relatively thin alloy layer 11 is formed at the steel-coating metal interface.
- the thickness of the alloy layer 11 is for example about 4 microns.
- On the alloy layer 11 follows the overlying cover layer 12 of aluminum and embedded iron silicon needles.
- FAL type 1 coating is sufficiently ductile due to the thin alloy layer 11 in order to achieve satisfactory transformations of the coated steel strip 1 and steel sheet satisfactorily.
- the corrosion protection afforded by this coating is not as good as with a pure aluminum coating with the trade name FAL Type 2.
- Fig. 9 shows a section of a coated by dipping in a pure aluminum melt steel strip 1 in cross section.
- This coating provides excellent corrosion protection.
- the top layer is made of pure aluminum. Due to the lack of silicon in the melt, a relatively thick alloy layer 11 'forms at the interface steel-coating metal. The thickness of the Brittle alloy layer 11 'may be in this case, for example, up to 20 microns.
- Fig. 1 or Fig. 2 illustrated inventive device in which the trunk 6 and the connecting portion 6.11 of the snout extension 6.1 define at least one supply channel 6.18, allows in the trunk 6 to enrich a silicon-containing melt, which leads to a thin alloy layer 11 similar to the alloy layer of the product FAL type 1.
- the trunk 6 can be added via the basin-shaped connection section 6.11 of the trunk extension piece 6.1 and the supply channel 6.18 to an AlFeSi coating material.
- a pure aluminum melt is used, so that a cover layer 12 'of pure aluminum is obtained.
- This product (“FAL Type 3") combines the advantages of the FAL Type 1 and FAL Type 2 products. This gives a product which is sufficiently ductile due to the thin alloy layer 11 in order to be able to realize desired larger transformations and which moreover has excellent anti-corrosion properties by the cover layer 12 'of pure aluminum.
- FIGS. 11 to 14 a further embodiment of a trunk extension piece according to the invention is shown.
- the trunk extender 6.1 a connection portion 6.11, in which the lower end of the trunk protrudes.
- the connection section 6.11 defines a basin-shaped or trough-shaped receiving space 6.12, whose peripheral side wall is fastened to a carrier 6.13 mounted on the upper edge of the melting bath vessel.
- connection section 6.11 or receiving space 6.12 an elongated opening 6.14 is formed through which the metal strip to be coated in the Shaft-shaped trunk extension 6.1 runs.
- the inner width (inner clear height) W of the trunk extension piece 6.1 tapers towards its outlet opening 6.15.
- the tapering of the inner width W results from the fact that the walls 6.16, 6.17 of the trunk elongation piece 6.1 which face the upper side and underside of the band 1 converge in the direction of the outlet opening 6.15.
- the front wall 6.16 includes with the bottom 6.25 an acute angle, which is for example about 65 °.
- the rear wall 6.17 includes with the bottom 6.25 an acute angle, which is for example about 60 ° (see. Fig. 14 ).
- the outlet opening 6.15 or narrowest point of the trunk extension piece 6.1 has a clear inner width W of, for example, less than 130 mm, preferably not more than 120 mm, particularly preferably not more than 100 mm. Furthermore, the snout extension piece 6.1 is dimensioned such that during hot dip coating of the metal strip, the swell penetration depth is at least 400 mm, preferably at least 500 mm, particularly preferably at least 600 mm.
- the trunk extender piece 6.1 is provided with separate channels 6.23, 6.24, through which metal melt can flow out of the melt bath vessel 4 in the direction of the molten bath level in the trunk or in the receiving space 6.12 when the melt level in the trunk is lowered compared to the melt level (molten bath level).
- the separate channels 6.23, 6.24 are preferably arranged on the outside of the front wall 6.16 of the trunk extension piece 6.1.
- the respective channel 6.23, 6.24 may consist of a tube or be formed from a U-profile, the legs of which are connected to the wall of the trunk extension piece 6.1, for example, welded.
- corresponding channels may be arranged on the outside of the rear wall 6.17 and / or on the narrower side walls of the trunk extension piece 6.1.
- the channels 6.23, 6.24 open above the bottom 6.25 of the connection section 6.11.
- the upper end portions 6.231, 6.241 of the channels 6.23, 6.24 are on the outside of the front wall arranged the connecting portion 6.11, which faces in the operation of the running out of the molten bath vessel 4 section of the band 1.
- the upper end sections 6.231, 6.241 of the channels 6.23, 6.24 go into channel sections, which are arranged on the underside of the bottom 6.25 (see. Fig. 14 ).
- the upper outlet openings of the channels 6.23, 6.24 are thus above the bottom 6.25 in a throat area, which is defined by the bottom 6.25 and the front wall of the connection section 6.11.
- the embodiment of the invention is not limited to the embodiments shown in the drawing. Rather, several variants are conceivable, which make use of the invention specified in the appended claims even with different design. For example, it is also within the scope of the invention if the inner width of the dipped trunk extension piece 6.1 tapers towards its outlet opening 6.15, at least over a partial length, stepwise in the form of one or more inside jumps and / or in the form of differently angled trunk wall sections.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
Claims (11)
- Ensemble pour le revêtement d'un feuillard métallique par immersion dans un bain fondu, l'ensemble présentant un récipient (4) à bain fondu, une trompe (6) qui introduit dans le bain fondu (3) un feuillard métallique chauffé dans un four traversé en continu et un rouleau de renvoi (7) disposé dans le récipient à bain fondu et renvoyant dans une direction sortant du bain fondu le feuillard métallique (1) pénétrant dans le bain fondu (3),
caractérisé en ce que
la trompe (6) est dotée d'une prolongation (6.1) de trompe en forme de puits qui augmente la profondeur d'immersion de la trompe,
en ce que la largeur intérieure de la prolongation (6.1) de trompe augmente au moins sur une partie de sa longueur en direction de son ouverture de sortie (6.15),
en ce que la prolongation (6.1) de trompe présente une section de raccordement (6.11) dans laquelle pénètre l'extrémité inférieure de la trompe (6) et
en ce que la section de raccordement (6.11) présente un espace de réception (6.12) en forme de bassin ou de cuve. - Ensemble selon la revendication 1, caractérisé en ce que la largeur intérieure (W) de la prolongation (6.1) de trompe se rétrécit de manière constante au moins sur une partie de sa longueur en direction de son ouverture de sortie (6.15).
- Ensemble selon les revendications 1 ou 2, caractérisé en ce que la largeur intérieure (W) de la prolongation (6.1) de trompe se rétrécit par gradins au moins sur une partie de sa longueur en direction de son ouverture de sortie (6.15), sous la forme d'un ou de plusieurs sauts de largeur intérieure et/ou sous la forme de sections (6.19, 6.20, 6.21, 6.22) différemment coudées de la paroi de la trompe.
- Ensemble selon l'une des revendications 1 à 3, caractérisé en ce que la ouverture de sortie (6.15) ou l'emplacement le plus étroit de la prolongation (6.1) de trompe présente une largeur intérieure (W) d'au plus 120 mm et de préférence d'au plus 100 mm.
- Ensemble selon l'une des revendications 1 à 4, caractérisé en ce que la prolongation (6.1) de trompe se termine à une distance (A) de la surface d'enveloppe du rouleau de renvoi (7) comprise dans la plage de 100 mm à 400 mm et de préférence de 100 mm à 300 mm.
- Ensemble selon l'une des revendications 1 à 5, caractérisé en ce que la prolongation (6.1) de trompe présente une section de raccordement (6.11) dans laquelle pénètre l'extrémité inférieure de la trompe (6) et en ce que la section de raccordement (6.11) et la trompe (6) définissent un canal d'amenée (6.18) qui apporte séparément le matériau de revêtement (B) ou au moins un additif d'alliage (LZ) dans la trompe (6) et/ou dans la prolongation (6.1) de trompe.
- Ensemble selon l'une des revendications 1 à 6, caractérisé en ce que la longueur de la prolongation (6.1) de trompe est dimensionnée de telle sorte que lors du revêtement du feuillard métallique (1) par immersion dans un bain fondu, la profondeur d'immersion de la trompe soit d'au moins 400 mm, de préférence d'au moins 500 mm et de façon particulièrement préférable d'au moins 600 mm.
- Ensemble selon l'une des revendications 1 à 7, caractérisé en ce que la prolongation (6.1) de trompe est dotée d'un ou plusieurs canaux séparés (6.23, 6.24) par lequel en cas de dépression dans la trompe (6) ou lorsque la surface du bain de métal fondu dans la trompe (6) descend par rapport à la surface du bain de métal fondu à l'extérieur de la trompe (6), du métal fondu puisse s'écouler hors du récipient (4) à bain fondu en direction de la surface du bain de métal fondu dans la trompe (6).
- Ensemble selon la revendication 8, caractérisé en ce que le ou les canaux séparés (6.23, 6.24) sont disposés sur le côté extérieur de la prolongation (6.1) de trompe.
- Ensemble selon les revendications 8 ou 9, caractérisé en ce que le ou les canaux séparés (6.23, 6.24) débouchent à l'extrémité inférieure de la prolongation (6.1) de trompe.
- Ensemble selon l'une des revendications 8 à 10 en combinaison avec la revendication 6, caractérisé en ce que le ou les canaux séparés (6.23, 6.24) présentent une section d'extrémité (6.231, 6.241) qui débouche au-dessus du fond (6.25) de la section de raccordement (6.11) dans une partie en creux de cette dernière.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013101131.4A DE102013101131A1 (de) | 2013-02-05 | 2013-02-05 | Vorrichtung zum Schmelztauchbeschichten von Metallband |
PCT/EP2014/052148 WO2014122128A1 (fr) | 2013-02-05 | 2014-02-04 | Procédé et dispositif de revêtement d'une bande métallique par immersion à chaud |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2954085A1 EP2954085A1 (fr) | 2015-12-16 |
EP2954085B1 true EP2954085B1 (fr) | 2019-01-02 |
Family
ID=50137618
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP14705302.9A Active EP2954085B1 (fr) | 2013-02-05 | 2014-02-04 | Dispositif de revêtement d'une bande métallique par immersion à chaud |
Country Status (5)
Country | Link |
---|---|
US (1) | US9453275B2 (fr) |
EP (1) | EP2954085B1 (fr) |
DE (1) | DE102013101131A1 (fr) |
ES (1) | ES2715857T3 (fr) |
WO (1) | WO2014122128A1 (fr) |
Cited By (1)
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EP3872201A1 (fr) | 2020-02-28 | 2021-09-01 | ThyssenKrupp Steel Europe AG | Produit en acier revêtu par immersion à chaud pourvu de revêtement de zinc-aluminium-magnésium, ainsi que procédé de fabrication et utilisation d'un dispositif de revêtement par immersion à chaud d'une bande d'acier |
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DE102015211489B3 (de) | 2015-06-22 | 2016-06-30 | Thyssenkrupp Ag | Rolle zur Umlenkung oder Führung eines zu beschichtenden Metallbandes in einem metallischen Schmelzenbad |
CN107523774B (zh) * | 2016-06-20 | 2019-10-25 | 宝山钢铁股份有限公司 | 一种抑制带钢连续热镀锌机组锌锅底渣生成的方法 |
CN106622854A (zh) * | 2016-12-23 | 2017-05-10 | 鞍山发蓝股份公司 | 采用浸漆方式生产包装用涂漆带钢的刮漆装置 |
KR102521021B1 (ko) * | 2018-03-08 | 2023-04-12 | 상라오 징코 솔라 테크놀러지 디벨롭먼트 컴퍼니, 리미티드 | 태양 전지 패널용 플럭스 도포 부재 및 방법, 그리고 태양 전지 패널의 인터커넥터 부착 장치 |
DE102018206185A1 (de) | 2018-04-23 | 2019-10-24 | Thyssenkrupp Ag | Vorrichtung und Verfahren zum Schmelztauchbeschichten eines Metallbandes mit mindestens zwei Schichten |
CN109266987A (zh) * | 2018-08-29 | 2019-01-25 | 广州倬粤动力新能源有限公司 | 锌丝的加工设备 |
US11384419B2 (en) * | 2019-08-30 | 2022-07-12 | Micromaierials Llc | Apparatus and methods for depositing molten metal onto a foil substrate |
CN110670007B (zh) * | 2019-09-30 | 2021-09-10 | 惠民万顺节能新材料有限公司 | 一种便于镀后处理钢材热浸镀锌 |
US11898251B2 (en) * | 2020-05-22 | 2024-02-13 | Cleveland-Cliffs Steel Properties Inc. | Snout for use in a hot dip coating line |
WO2021236862A1 (fr) | 2020-05-22 | 2021-11-25 | Cleveland-Cliffs Steel Properties Inc. | Busette de coulée destinée à être utilisée dans une ligne de revêtement par immersion à chaud |
EP4215637A1 (fr) | 2022-01-25 | 2023-07-26 | John Cockerill S.A. | Dispositif de nettoyage d'un museau dans une installation de galvanisation par immersion à chaud |
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-
2014
- 2014-02-04 ES ES14705302T patent/ES2715857T3/es active Active
- 2014-02-04 EP EP14705302.9A patent/EP2954085B1/fr active Active
- 2014-02-04 US US14/765,691 patent/US9453275B2/en active Active
- 2014-02-04 WO PCT/EP2014/052148 patent/WO2014122128A1/fr active Application Filing
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3872201A1 (fr) | 2020-02-28 | 2021-09-01 | ThyssenKrupp Steel Europe AG | Produit en acier revêtu par immersion à chaud pourvu de revêtement de zinc-aluminium-magnésium, ainsi que procédé de fabrication et utilisation d'un dispositif de revêtement par immersion à chaud d'une bande d'acier |
DE102020105375A1 (de) | 2020-02-28 | 2021-09-02 | Thyssenkrupp Steel Europe Ag | Schmelztauchbeschichtetes Stahlerzeugnis mit Zink-Aluminium-Magnesium-Beschichtung sowie Herstellverfahren und Verwendung einer Vorrichtung zum Schmelztauchbeschichten von Stahlband |
Also Published As
Publication number | Publication date |
---|---|
EP2954085A1 (fr) | 2015-12-16 |
US20150368776A1 (en) | 2015-12-24 |
ES2715857T3 (es) | 2019-06-06 |
DE102013101131A1 (de) | 2014-08-07 |
WO2014122128A9 (fr) | 2015-09-24 |
US9453275B2 (en) | 2016-09-27 |
WO2014122128A1 (fr) | 2014-08-14 |
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