EP2942406B1 - Élément de barboteur céramique résistant au feu - Google Patents

Élément de barboteur céramique résistant au feu Download PDF

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Publication number
EP2942406B1
EP2942406B1 EP14167036.4A EP14167036A EP2942406B1 EP 2942406 B1 EP2942406 B1 EP 2942406B1 EP 14167036 A EP14167036 A EP 14167036A EP 2942406 B1 EP2942406 B1 EP 2942406B1
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EP
European Patent Office
Prior art keywords
refractory ceramic
gas
plate
chamber
gas purging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP14167036.4A
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German (de)
English (en)
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EP2942406A1 (fr
Inventor
Bojan Zivanovic
Bernhard Handle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Refractory Intellectual Property GmbH and Co KG
Original Assignee
Refractory Intellectual Property GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES14167036.4T priority Critical patent/ES2572686T3/es
Application filed by Refractory Intellectual Property GmbH and Co KG filed Critical Refractory Intellectual Property GmbH and Co KG
Priority to PL14167036T priority patent/PL2942406T3/pl
Priority to EP14167036.4A priority patent/EP2942406B1/fr
Priority to US14/913,625 priority patent/US9863708B2/en
Priority to JP2017510732A priority patent/JP6526794B2/ja
Priority to CN201580001824.3A priority patent/CN105517728B/zh
Priority to CA2923382A priority patent/CA2923382C/fr
Priority to PCT/EP2015/054285 priority patent/WO2015169466A1/fr
Publication of EP2942406A1 publication Critical patent/EP2942406A1/fr
Priority to CL2016000588A priority patent/CL2016000588A1/es
Application granted granted Critical
Publication of EP2942406B1 publication Critical patent/EP2942406B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/001Extraction of waste gases, collection of fumes and hoods used therefor
    • F27D17/002Details of the installations, e.g. fume conduits or seals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002Treatment with gases
    • B22D1/005Injection assemblies therefor
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories
    • C21C5/4673Measuring and sampling devices
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories
    • C21C5/48Bottoms or tuyéres of converters
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/05Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/16Introducing a fluid jet or current into the charge
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D9/00Cooling of furnaces or of charges therein
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/072Treatment with gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/16Introducing a fluid jet or current into the charge
    • F27D2003/161Introducing a fluid jet or current into the charge through a porous element

Definitions

  • the invention relates to a refractory ceramic Gas Crowelement, that is, a gas purging device, especially for metallurgical vessels with which metal melts are treated, for example, for a ladle or a tundish.
  • a gas purging device especially for metallurgical vessels with which metal melts are treated, for example, for a ladle or a tundish.
  • These vessels / aggregates include those for non-ferrous metals such as lead.
  • a generic gas purging device as shown in the DE 197 55 199 C1 is known, has a refractory, ceramic gas purging plug and a, arranged at the bottom of the gas purging gas distribution chamber from which gas-permeable areas extend through the gas purging plug to the gas outlet end of the gas purging plug.
  • the gas purging device comprises a gas supply line, which opens into the gas distribution chamber with a gas outlet side opening.
  • a treatment gas or a gas / solid mixture is injected into the molten metal.
  • the known gas purging device has basically proven, but requires a flexible (flexible) cover, for example, from a thin sheet. Frequent changes in gas pressure or at higher temperatures in the gas distribution chamber may limit the functionality of the cover.
  • a gas purging device in which a plate-shaped closure member is guided spring-loaded in Gaszu melt.
  • the closure member can move between corresponding stops in the gas supply pipe. In the end positions, the gas supply is interrupted.
  • the invention is based on the object to offer a refractory ceramic Gas Crowelement the generic type, which also has a high reliability even if the gas pressure fluctuates and / or the ceramic part of the Gas Kunststoffenses is partially worn.
  • the main difference to the gas flushing device according to DE 197 55 199 C1 is that in the Gasverteilhunt a plate is arranged loosely, while in the known device, a cover is fixed to the chamber.
  • the plate moves within the gas distribution chamber between a first end position (when the gas is off, for example) and a second end position (at regular gas pressure) substantially in the axial direction of the gas purging element, that is, in the main direction in which the gas is ceramic Part of the gas purging element flows through.
  • the gas may flow through the gas distribution chamber into the gas permeable portion of the refractory ceramic body even when the plate is in its (raised) second end position.
  • the plate should have in the second end position at a distance from the part of the refractory ceramic body, which is flowed through by the gas.
  • the upper part of the Gasverteilhunt (viewed in the direction of the fundamental gas flow) remains free and prevents the plate is applied directly to the bottom of the refractory ceramic body.
  • the chamber extends over at least 90% of the cross-sectional area of the body at the first end.
  • the Gasverteilhunt has a nearly identical cross-section as the adjacent refractory body, that is, both aligned in the axial direction.
  • the gas distribution chamber may be formed by a metal housing.
  • the gas supply conduit opens into a portion of the chamber opposite the refractory ceramic body. If one considers the gas purging element in a position as it is usually installed in the bottom of a metallurgical vessel, then the gas supply line in this case opens from below into the chamber. This orientation of the gas purging element also applies below, unless otherwise indicated.
  • the movable plate covers the gas supply line when the gas pressure is below a minimum value to push the plate upwards. In this lower position, the plate thus fulfills a safety function against a possible molten metal infiltration. If molten metal penetrates into the chamber, it is initially held back by the plate.
  • the plate in a porous plate, in particular an open-pored plate, the plate can even absorb molten metal. In addition, melt is prevented from flowing into the gas supply pipe 30.
  • the second end position, so the raised position of the plate can be defined by one or more attacks, training a clearance between the plate and the first (lower) end of the refractory ceramic body.
  • This at least one stop may project from the first end of the refractory ceramic body in the direction of the plate, it is also possible that the at least one stop is formed on the inside of the chamber, preferably in the vicinity of the ceramic body. It is also possible to form the stop or stops on the plate, for example by projecting nubs or webs on the side facing the ceramic body.
  • the cross-sectional area (base area) of the plate is regularly slightly smaller than the internal cross-section of the chamber in order to allow said movement of the plate in the axial direction of the gas purging device.
  • the plate is designed so that circumferentially a substantially uniform gap to the inner wall of the chamber remains.
  • the gap is dimensioned so that a good mobility of the plate results without these tilted.
  • the ceramic body may be aligned with so-called undirected porosity and / or with directed porosity.
  • Undirected porosity can be characterized by a “sponge-like structure” in which the gas is zig-zag-shaped along open pores flows through the ceramic.
  • directed porosity the gas flow is largely linear based on defined channels, slots or the like. The channels usually run in the axial direction of the purifier.
  • the plate may also be at least partially gas permeable.
  • the plate can also have a kind of sponge structure, that is a kind of "undirected porosity".
  • the plate may for example consist of a sintered metal or of a refractory ceramic part with undirected porosity.
  • an embodiment provides to cool the chamber.
  • the chamber may have a valve to which a cooling gas line is connected.
  • the chamber may have at least one wall which is part of a cooling device, for example, the bottom of the chamber may be double-walled and flowed through by a coolant.
  • the plate has at least one opening, which is penetrated by a rod which extends in the axial direction of the gas purging device, wherein the opening has a cross section which is slightly larger than the rod cross section.
  • This rod can perform several functions: First, the rod serves to guide the plate in the axial direction of the gas purging element.
  • the rod can also fulfill additional functions.
  • the rod may be a thermocouple with which the temperature in the gas purging element is measured.
  • the rod can serve as a residual strength indicator.
  • the rod may be a hollow rod whose end is closed in the ceramic body. If the hollow rod is charged with gas and the ceramic body is worn so far that the closed end of the hollow rod melts the gas escapes, the gas pressure drops accordingly and indicates the wear.
  • A-A run channels 12 through the ceramic body 10, which thus has a directed porosity.
  • a chamber 20 which extends over the entire cross-sectional area of the body 10 at the lower end 10u and is made of metal.
  • the chamber 20 has a closed bottom 20b, a circumferential wall 20w and a ceiling 20d with openings 20o in extension of the channels 12th
  • a further gas supply line 40 can be seen, which is closed to the interior of the chamber 20 out, in particular FIG. 2 shows, but also can be open.
  • a refractory ceramic plate 50 is arranged according to FIG. 1 is located on the bottom 20b of the chamber 20 and is dimensioned so that circumferentially there is a gap between the plate 50 and wall 20w.
  • the plate 50 has a so-called non-directional porosity, that is, a sponge-like internal structure, so that gas flowing in via the conduit 30 can flow through the open porosity of the plate 50.
  • the plate 50 is simultaneously raised ( FIG. 2 ) until it reaches its maximum upper position when the plate 50 abuts against the stopper 20a.
  • FIG. 2 Fig. 2 shows that there is still a distance between the top of the plate 50 and the top 20d of the chamber 20, so that the gas which has flowed through the plate 50 or between the plate 50 and the wall 20w into the space 20r, from there through the Openings 20o and the channels 12 can flow in the direction of the (not shown) molten metal.
  • the distance between the plate 50 and body 10 can be achieved by nubs extending from the bottom of the body 10 between the channels 12 and projecting downwards.
  • the axial mobility of the plate 50 is supported by a rod-shaped thermocouple 70, which by corresponding
  • Openings in the bottom 20b, in the plate 50, in the ceiling 20d extends into the ceramic body 10 and ends there at a distance from the upper end 10o of the Gas Standiatas (not shown).
  • the opening in the plate 50 is so large that the plate 50 easily moves in the axial direction A, when the gas pressure is increased or decreased.
  • FIG. 2 shows the gas purging device in the functional state, FIG. 1 the case that no gas flows; the plate 50 then fulfills a safety function by covering the gas supply line 30.
  • the closure of the gas line 40 can be dimensioned so that it melts or is destroyed when a certain temperature is exceeded in the gas distribution chamber 20, so that, for example, in the case of an unexpected increase in temperature, for example by infiltrating molten metal, a cooling gas via line 40 in the chamber can be passed to freeze the melt.
  • thermocouple 70 With the thermocouple 70, the temperature at corresponding locations in the ceramic body 10 can be measured. This also indicates indicative of a particular state of wear or molten metal infiltration
  • the embodiments of the Figures 3 . 4 differ from the embodiments according to the FIGS. 1, 2 in that adjoining the chamber 20 is an additional cooling chamber 60 which, like the chamber 20, extends over the entire cross section of the lower end 10u of the body 10, the gas conduit 40 being open at the upper end in this embodiment. This makes it possible to continuously cool the space 60 and thus also the bottom 20b of the chamber 20.
  • the cooling space 60 like the chamber 20, is formed by a metal box.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Continuous Casting (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)

Claims (15)

  1. Elément réfractaire céramique pour l'apport de gaz avec les caractéristiques suivantes :
    a) l'élément comprend un corps réfractaire céramique (10) pouvant être traversé par un gaz en direction axiale (A-A) de l'élément entre sa première extrémité (10u) et sa deuxième extrémité (10o),
    b) une chambre (20) étant formée à la première extrémité (10u) du corps (10), laquelle s'étend sur au moins 50 % de la superficie en section transversale du corps (10) à la première extrémité (10u),
    c) une conduite d'apport de gaz (30) débouche, à distance du corps réfractaire céramique (10), dans la chambre (20),
    d) vers le corps en céramique (10), la chambre (20) est au moins partiellement perméable aux gaz
    e) dans la chambre (20), au moins une plaque (50) est disposée de manière librement mobile, en direction axiale (A-A) de l'élément de barbotage, entre une première position finale tournant le dos au corps réfractaire céramique (10) et une deuxième position finale, laquelle est tournée vers le corps réfractaire céramique résistant au feu (10), mais cependant à distance de la partie du corps (10) pouvant être traversée par le gaz, la deuxième position finale définie par une ou plusieurs butées (20a),
    f) la plaque (50) étant dimensionnée, configurée et disposée dans la chambre (20) de manière à ce qu'un flux de gaz depuis la conduite d'apport de gaz (30) à travers la chambre (20) jusqu'à la première extrémité (10u) du corps réfractaire céramique (10) soit garanti également lorsque la plaque (50) est dans sa deuxième position finale.
  2. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la chambre (20) s'étend sur au moins 90 % de la superficie en section transversale du corps (10) au niveau de la première extrémité (10u).
  3. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la chambre (20) est formée par un boîtier métallique.
  4. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la conduite d'apport de gaz (30) débouche dans une partie de la chambre (20) qui est située vis-à-vis du corps réfractaire céramique (10).
  5. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) recouvre la conduite d'apport de gaz (30) dans la première position finale.
  6. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) repose, dans la deuxième position finale, contre une ou plusieurs butée(s) (20a) en formant un espace libre (20r) entre la plaque (50) et la première extrémité (10u) du corps réfractaire céramique (10).
  7. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) repose, dans la deuxième position finale, contre au moins une butée qui dépasse de la première extrémité du corps réfractaire céramique en direction vers la plaque (50), en formant un espace libre (20r) entre la plaque (50) et la première extrémité (10u) du corps réfractaire céramique (10).
  8. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) repose, dans la deuxième position finale, contre au moins une butée (20a) qui est formée du côté intérieur de la chambre (20), en formant un espace libre (20r) entre la plaque (50) et la première extrémité (10u) du corps réfractaire céramique (10).
  9. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) présente, sur son côté qui est voisin du corps réfractaire céramique (10), au moins une partie saillante, en formant un espace libre (20r) entre la plaque (50) et la première extrémité (10u) du corps réfractaire céramique (10) dans la deuxième position finale.
  10. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) est au moins partiellement perméable aux gaz.
  11. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) se compose d'un matériau réfractaire céramique.
  12. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la chambre (20) peut être refroidie.
  13. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la chambre (20) présente au moins une paroi (20b) qui est une partie d'un dispositif de refroidissement.
  14. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dont la plaque (50) présente au moins une ouverture qui est traversée par une barre (70) s'étendant en direction axiale (A-A) d'élément, dans lequel l'ouverture présente une section transversale légèrement plus grande que la section transversale de la barre.
  15. Elément réfractaire céramique pour l'apport de gaz selon la revendication 1, dans lequel la barre (70) est une partie constitutive d'un afficheur du niveau résiduel d'élément.
EP14167036.4A 2014-05-05 2014-05-05 Élément de barboteur céramique résistant au feu Active EP2942406B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
PL14167036T PL2942406T3 (pl) 2014-05-05 2014-05-05 Ognioodporny ceramiczny element do przedmuchiwania gazem
EP14167036.4A EP2942406B1 (fr) 2014-05-05 2014-05-05 Élément de barboteur céramique résistant au feu
ES14167036.4T ES2572686T3 (es) 2014-05-05 2014-05-05 Elemento cerámico refractario de barrido con gas
JP2017510732A JP6526794B2 (ja) 2014-05-05 2015-03-02 耐火性セラミックガスパージ要素
US14/913,625 US9863708B2 (en) 2014-05-05 2015-03-02 Refractory ceramic gas purging element
CN201580001824.3A CN105517728B (zh) 2014-05-05 2015-03-02 耐火陶瓷气体吹扫元件
CA2923382A CA2923382C (fr) 2014-05-05 2015-03-02 Element de lavage des gaz en ceramique resistant au feu
PCT/EP2015/054285 WO2015169466A1 (fr) 2014-05-05 2015-03-02 Élément de lavage des gaz en céramique résistant au feu
CL2016000588A CL2016000588A1 (es) 2014-05-05 2016-03-11 Elemento de purga de gas de cerámica refractaria

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14167036.4A EP2942406B1 (fr) 2014-05-05 2014-05-05 Élément de barboteur céramique résistant au feu

Publications (2)

Publication Number Publication Date
EP2942406A1 EP2942406A1 (fr) 2015-11-11
EP2942406B1 true EP2942406B1 (fr) 2016-04-13

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EP14167036.4A Active EP2942406B1 (fr) 2014-05-05 2014-05-05 Élément de barboteur céramique résistant au feu

Country Status (9)

Country Link
US (1) US9863708B2 (fr)
EP (1) EP2942406B1 (fr)
JP (1) JP6526794B2 (fr)
CN (1) CN105517728B (fr)
CA (1) CA2923382C (fr)
CL (1) CL2016000588A1 (fr)
ES (1) ES2572686T3 (fr)
PL (1) PL2942406T3 (fr)
WO (1) WO2015169466A1 (fr)

Cited By (1)

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RU2769101C1 (ru) * 2018-01-29 2022-03-28 Рефрактори Интеллектуал Проперти Гмбх & Ко. Кг Газопродувочная пробка, газопродувочная система, способ исследования газопродувочной пробки и способ продувки расплавленного металла

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JP5640123B1 (ja) * 2013-08-09 2014-12-10 株式会社超高温材料研究センター 加熱機器の熱効率改善方法及び加熱機器の熱効率改善装置
EP2942406B1 (fr) 2014-05-05 2016-04-13 Refractory Intellectual Property GmbH & Co. KG Élément de barboteur céramique résistant au feu
CN113502369A (zh) * 2021-06-18 2021-10-15 西安理工大学 连铸铸铁型材生产变质处理新方法
TW202417144A (zh) * 2022-10-27 2024-05-01 奧地利商瑞法克托瑞智產股份有限公司 耐火氣體淨化塞體

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DE10305232B3 (de) * 2003-02-08 2004-08-05 Refractory Intellectual Property Gmbh & Co.Kg Feuerfester keramischer Gasspülstein
RU2235135C1 (ru) * 2003-06-16 2004-08-27 Хлопонин Виктор Николаевич Фурменное устройство для введения газовых сред под уровень жидкого металла
JP2010189687A (ja) * 2009-02-17 2010-09-02 Tokyo Yogyo Co Ltd ガス吹き込みプラグ
DE102010007126B3 (de) * 2010-02-05 2011-07-07 Refractory Intellectual Property Gmbh & Co. Kg Gasspüleinrichtung
EP2942406B1 (fr) 2014-05-05 2016-04-13 Refractory Intellectual Property GmbH & Co. KG Élément de barboteur céramique résistant au feu

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2769101C1 (ru) * 2018-01-29 2022-03-28 Рефрактори Интеллектуал Проперти Гмбх & Ко. Кг Газопродувочная пробка, газопродувочная система, способ исследования газопродувочной пробки и способ продувки расплавленного металла

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WO2015169466A1 (fr) 2015-11-12
JP2017515984A (ja) 2017-06-15
US9863708B2 (en) 2018-01-09
JP6526794B2 (ja) 2019-06-05
EP2942406A1 (fr) 2015-11-11
CN105517728B (zh) 2017-11-14
PL2942406T3 (pl) 2016-08-31
CL2016000588A1 (es) 2016-09-16
US20160209117A1 (en) 2016-07-21
CN105517728A (zh) 2016-04-20
ES2572686T3 (es) 2016-06-01
CA2923382C (fr) 2018-02-13
CA2923382A1 (fr) 2015-11-12

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