EP2920112A4 - PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE - Google Patents

PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE

Info

Publication number
EP2920112A4
EP2920112A4 EP13855440.7A EP13855440A EP2920112A4 EP 2920112 A4 EP2920112 A4 EP 2920112A4 EP 13855440 A EP13855440 A EP 13855440A EP 2920112 A4 EP2920112 A4 EP 2920112A4
Authority
EP
European Patent Office
Prior art keywords
olefins
conversion
production
zeolitic material
oxygenated compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP13855440.7A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2920112A1 (en
Inventor
Manuela Gaab
Ulrich Mueller
Milan Kostur
Kirsten Braunsmann
Kerem Bay
Andrei-Nicolae Parvulescu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP13855440.7A priority Critical patent/EP2920112A4/en
Publication of EP2920112A1 publication Critical patent/EP2920112A1/en
Publication of EP2920112A4 publication Critical patent/EP2920112A4/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
EP13855440.7A 2012-11-13 2013-11-11 PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE Pending EP2920112A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP13855440.7A EP2920112A4 (en) 2012-11-13 2013-11-11 PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12192407 2012-11-13
EP13855440.7A EP2920112A4 (en) 2012-11-13 2013-11-11 PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE
PCT/IB2013/060057 WO2014076625A1 (en) 2012-11-13 2013-11-11 Production and Use of a Zeolitic Material in a Process for the Conversion of Oxygenates to Olefins

Publications (2)

Publication Number Publication Date
EP2920112A1 EP2920112A1 (en) 2015-09-23
EP2920112A4 true EP2920112A4 (en) 2016-12-07

Family

ID=47143770

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13855440.7A Pending EP2920112A4 (en) 2012-11-13 2013-11-11 PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE

Country Status (6)

Country Link
EP (1) EP2920112A4 (OSRAM)
JP (1) JP6461807B2 (OSRAM)
KR (1) KR102171666B1 (OSRAM)
CN (1) CN104918886B (OSRAM)
WO (1) WO2014076625A1 (OSRAM)
ZA (1) ZA201504215B (OSRAM)

Families Citing this family (19)

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BR112016007918B1 (pt) 2013-10-23 2020-12-29 Basf Se processo para a produção de um corpo de moldagem, corpo de moldagem e uso de um corpo de moldagem
JP6519943B2 (ja) * 2015-03-25 2019-05-29 株式会社豊田中央研究所 球状シリカ系メソ多孔体及びその製造方法
BR112018003685A2 (pt) * 2015-08-27 2018-09-25 Chevron Usa Inc peneira molecular ssz-91, métodos para preparar ssz-91, e usos para ssz-91
JP2017114755A (ja) * 2015-12-25 2017-06-29 ユニオン昭和株式会社 ゼオライト、及びその製造方法
CN108697997B (zh) * 2016-02-19 2021-05-14 日立造船株式会社 沸石分离膜及其制造方法
CN106064822B (zh) * 2016-05-30 2018-03-23 中国科学院大连化学物理研究所 一种mww/mel共结晶分子筛及其合成方法
EP3472100A1 (en) * 2016-06-17 2019-04-24 Basf Se Process for a continuous synthesis of zeolitic materials
KR102470492B1 (ko) * 2016-09-06 2022-11-23 바스프 에스이 Mww 골격 구조를 갖는 붕소 함유 제올라이트의 고체열 합성
WO2018064273A1 (en) 2016-09-30 2018-04-05 Johnson Matthey Public Limited Company A novel zeolite synthesis with a fluoride source
KR102343528B1 (ko) * 2017-03-29 2021-12-29 엑손모빌 케미칼 패턴츠 인코포레이티드 촉매 조성물 및 방향족 알킬화 공정에서의 이의 용도
US20200368734A1 (en) * 2017-08-08 2020-11-26 Basf Se A composition comprising a mixed metal oxide and a molding comprising a zeolitic material having framework type cha and an alkaline earth metal
CN108946762B (zh) * 2018-08-20 2020-02-14 中触媒新材料股份有限公司 一种多级孔eu-1分子筛及其制备方法
CN108751219B (zh) * 2018-08-20 2020-02-14 中触媒新材料股份有限公司 一种多级孔eu-1分子筛及其合成方法
WO2020221683A1 (en) * 2019-04-29 2020-11-05 Basf Se Molding comprising a type mfi zeolitic titanosilicate and a silica binder, its preparation process and use as catalyst
EP4072727A1 (en) * 2019-12-11 2022-10-19 Basf Se Process for preparing a molding comprising a zeolite catalyst and method for converting oxygenates to olefins using the catalytic molding
CN111573694B (zh) * 2020-06-17 2021-10-15 浙江大学 以有机模板剂一步合成富铝*mre沸石分子筛的方法
CN116422362B (zh) * 2021-12-30 2024-12-20 卓悦环保新材料（上海）有限公司 一种抗破碎的甲醇制丙烯催化剂及其制备方法和应用
JP2023138070A (ja) * 2022-03-18 2023-09-29 三菱ケミカル株式会社 ゼオライトの製造方法
CN120476099A (zh) * 2023-01-30 2025-08-12 旭化成株式会社 醇的转换方法、含沸石的催化剂、含沸石的催化剂的制造方法、及烃等的制造方法

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US20070135637A1 (en) * 2003-12-02 2007-06-14 Basf Aktiengesellschaft Pentasil-structuer zeolithic material the production and use thereof
WO2011089263A1 (en) * 2010-01-25 2011-07-28 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process

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EP0178687A2 (en) * 1984-07-13 1986-04-23 Exxon Research And Engineering Company Zeolite catalyst preparation
US20070135637A1 (en) * 2003-12-02 2007-06-14 Basf Aktiengesellschaft Pentasil-structuer zeolithic material the production and use thereof
WO2011089263A1 (en) * 2010-01-25 2011-07-28 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process

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Title
ALI A ROWNAGHI ET AL: "Yield of gasoline-range hydrocarbons as a function of uniform ZSM-5 crystal size", CATALYSIS COMMUNICATIONS, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 14, no. 1, 12 July 2011 (2011-07-12), pages 37 - 41, XP028286827, ISSN: 1566-7367, [retrieved on 20110723], DOI: 10.1016/J.CATCOM.2011.07.015 *
AOKI K ET AL: "Gas permeation properties of ion-exchanged ZSM-5 zeolite membranes", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, vol. 39, no. 3, 1 October 2000 (2000-10-01), pages 485 - 492, XP004217701, ISSN: 1387-1811, DOI: 10.1016/S1387-1811(00)00224-9 *
MCINTOSH R J ET AL: "THE PROPERTIES OF MAGNESIUM AND ZINC-OXIDE TREATED ZSM-5 CATALYSTS FOR CONVERSION OF METHANOL INTO OLEFIN-RICH PRODUCTS", APPLIED CATALYSIS, AMSTERDAM, NL, vol. 6, no. 3, 1 January 1983 (1983-01-01), pages 307 - 314, XP002717328, ISSN: 0166-9834 *
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See also references of WO2014076625A1 *

Also Published As

Publication number Publication date
WO2014076625A1 (en) 2014-05-22
ZA201504215B (en) 2017-11-29
JP2016502487A (ja) 2016-01-28
KR20150086300A (ko) 2015-07-27
CN104918886B (zh) 2018-08-10
JP6461807B2 (ja) 2019-01-30
CN104918886A (zh) 2015-09-16
EP2920112A1 (en) 2015-09-23
KR102171666B1 (ko) 2020-10-29

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