EP2895632A1 - Verfahren zur herstellung von bainitischen schienenstählen, gleisteil und einrichtung zur durchführung des verfahrens - Google Patents
Verfahren zur herstellung von bainitischen schienenstählen, gleisteil und einrichtung zur durchführung des verfahrensInfo
- Publication number
- EP2895632A1 EP2895632A1 EP13739927.5A EP13739927A EP2895632A1 EP 2895632 A1 EP2895632 A1 EP 2895632A1 EP 13739927 A EP13739927 A EP 13739927A EP 2895632 A1 EP2895632 A1 EP 2895632A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- temperature
- rail
- cooling
- cooling medium
- rail head
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01B—PERMANENT WAY; PERMANENT-WAY TOOLS; MACHINES FOR MAKING RAILWAYS OF ALL KINDS
- E01B5/00—Rails; Guard rails; Distance-keeping means for them
- E01B5/02—Rails
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/08—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
- B21B1/085—Rail sections
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/20—Isothermal quenching, e.g. bainitic hardening
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/613—Gases; Liquefied or solidified normally gaseous material
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0006—Details, accessories not peculiar to any of the following furnaces
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0062—Heat-treating apparatus with a cooling or quenching zone
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/04—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rails
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0203—Cooling
- B21B45/0209—Cooling devices, e.g. using gaseous coolants
- B21B45/0215—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes
- B21B2045/0221—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes for structural sections, e.g. H-beams
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B43/00—Cooling beds, whether stationary or moving; Means specially associated with cooling beds, e.g. for braking work or for transferring it to or from the bed
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/63—Quenching devices for bath quenching
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
Definitions
- the invention relates to a rail part, in particular a rail for rail vehicles made of a low-alloy steel.
- the invention further relates to a method for producing a rail part from a hot-rolled profile and to a device for carrying out this method.
- Rail tracks are therefore subject to difficult operating conditions and must therefore be of higher quality to withstand the higher loads. Concrete problems are manifested in a sharp increase in wear, particularly in the rails mounted in arches, and in the occurrence of material fatigue damage, which mainly develops on the running edge, which is the main contact point of the rail with the wheels in the arch. This leads to rolling contact fatigue damage (RCF - rolling-contact-fatigue).
- RCF surface damage examples include head checks (rolling fatigue), spalling (flaking), squats (plastic surface deformations), slip waves and herniation. These damage to the surface results in shortened rail life, increased noise emissions and operational disability. The increased occurrence of errors is also accelerated by the ever-increasing traffic loads. The immediate consequence of this development is an increased need for maintenance of the rails. However, the increasing need for maintenance is in conflict with the ever-decreasing number of maintenance windows. Higher train densities more and more reduce the time during which rails can be machined. Although the above-mentioned damage can be eliminated in the early stages by grinding, but the rail is to be replaced in case of severe damage.
- Bainite is a microstructure that can be produced during the heat treatment of carbon steel by isothermal transformation or continuous cooling. Bainite forms at temperatures and cooling rates that are intermediate to those for perlite or martensite formation. In contrast to the formation of martensite, folding processes in the crystal lattice and diffusion processes are coupled here, which makes various conversion mechanisms possible. Due to the dependence on cooling rate, carbon content, alloying elements and the resulting formation temperature, the bainite has no characteristic structure.
- Bainite like perlite, consists of the phases ferrite and cementite (Fe3C), but differs from pearlite in shape, size and distribution. Basically, bainite is divided into two main structural forms, the upper bainite and the lower bainite.
- a rail material is known in which a structural transformation of austenite is expressly formed only in the lower bainite, so that the profiled rolling a hardness of at least 350 HB, in particular 450-600 HB receives.
- a bainitic ground structure can also be used with higher alloying constituents, such as with a high chromium content of 2.2 to 3.0 wt .-% can be achieved, as described in the publications DE 102006030815 AI and DE 102006030816 AI.
- the high proportion of alloy components leads to undesirably high costs and a complex welding technology.
- DE 202005009259 Ul also describes a bainitic high-strength rail part made of a high-alloy steel, in particular with high alloy contents of Mn, Si and Cr. In such a high-alloyed steel, the bainite formation can be easily obtained by cooling in still air. In contrast, bainite formation is only possible with low-alloyed steels if controlled cooling is used.
- DE 1533982 describes a method for heat treatment of rails, in which the still rolling temperature having rail is taken after leaving the rolling stand with a lifting device and immersed with the rail head down in a maintained at a constant temperature fluidized bed and cooled there, wherein a bainitic microstructure is achieved by selecting the fluid bed temperature between 380 and 460 ° C and leaving the rail in the fluidized bed for between 300 and 900 seconds depending on its temperature.
- a further production of high-strength rails of low-alloy steels with bainitic structures for achieving a better resistance to fatigue damage due to rolling contact has become known from EP 612852 B1.
- the head of the rail is subjected to accelerated cooling at a rate of 1-10 ° C / sec from the austenite region to a cooling-down temperature of 500-300 ° C. After this rapid cooling, the rail head is further cooled to near room temperature, in which either a natural Cooling with heat recovery or forced cooling at a rate of 1-40 ° C / min is used.
- the invention therefore aims to improve a rail part, in particular a rail, which is to consist of a low-alloy steel for cost reasons and for reasons of welding, to the effect that even with increased wheel loads no RollunterermüdungsSWden and in particular no cracks on the running edge and arise at the tread. Furthermore, the wear resistance should be increased so far that a service life of more than 30 years can be ensured. Finally, the track part should be well weldable and similar other material properties such as e.g. a similar electrical conductivity and a similar coefficient of thermal expansion have been proven in rail construction proven steels.
- the invention aims to provide a simple production process, which is characterized by a short process time (avoiding incandescent phases), high reproducibility and high cost-effectiveness.
- the method is intended to produce long rails of e.g. be suitable over 100 m in length, over the entire rail length constant material properties are to be ensured.
- the invention according to a first aspect provides a rail part of the type mentioned, which is developed such that the steel in the rail head of the Rail part has a ferrite content of 5-15 vol.% And a multi-phase bainite structure consisting of upper and lower bainite parts.
- a ferritic structure By combining a ferritic structure with a bainitic structure, excellent toughness properties and a sufficiently high hardness are achieved.
- the ferrite microstructure component serves as plasticity carrier and leads to the fact that any cracks which may have occurred can not run into the material as head checks.
- the ferrite content gives the entire structure a continuous network in which the bainite is embedded.
- the ferrite is an acicular ferrite.
- the acicular structure is characterized by a higher tensile strength and wear resistance compared to a non-acicular structure and also to a pearlitic structure.
- the acicular ferrite has a microstructure characterized by needle-like shaped crystallites or grains, wherein the crystallites are not uniformly aligned, but are completely unoriented, which positively influences the toughness of the steel.
- the unoriented arrangement of the grains leads to a mutual entanglement of the individual grains, which in combination with the multiphase bainite effectively prevents cracking or propagation.
- the texture often has a grainy appearance, so the upper bainite is sometimes referred to as granular bainite.
- the lower bainite is formed during isothermal and continuous cooling in the lower temperature range of bainite formation. Ferritation causes the austenite to accumulate in carbon, and on further cooling, the austenite areas are transformed into ferrite, cementite, needle-like bainite and martensite. Bainitizing reduces residual stresses and increases toughness.
- the mixing ratio between lower and upper bainite can basically be varied within wide limits according to the respective requirements.
- the choice of mixing ratio determines the hardness of the steel. It is particularly preferred in the context of the invention that the proportion of the upper bainite 5-75 vol .-%, in particular 20-60 vol .-% and the proportion of the lower bainite 15-90 vol .-%, in particular 40-85 vol .-%, is.
- the ferrite content is preferably 8-13% by volume.
- Precondition for a complete bainitic transformation is the carbide formation from the austenite. Because carbides absorb large amounts of carbon, they are carbon sinks that extract carbon from austenite. Will the Carbide formation, for example, prevented or delayed by silicon as an alloying element, so larger Austenitmen- gene are not converted. After quenching to room temperature, they are then completely or partially present as retained austenite. The amount of retained austenite depends on how much the martensite temperature in the remaining austenite has dropped. In the context of the invention, it is advantageous if the smallest possible proportions of austenite and / or martensite remain. The invention therefore preferably provides in this connection for the steel in the rail head of the rail part to have a Re martensite / austenite content of ⁇ 2 vol. -% having.
- low-alloy steels are used according to the invention in order to minimize costs and to improve weldability.
- the low-alloyed steel in the context of the invention preferably contains silicon, manganese and chromium as alloy constituents, as well as possibly vanadium, molybdenum, phosphorus, sulfur and / or nickel.
- a steel is in the context of the invention then to be referred to as low-alloy steel, if no alloying ingredient in a proportion of greater than 1.5 Ge. -% is available.
- a particularly good suitability for heavily loaded road sections is preferably given when the rail part in the head region has a tensile strength R m of greater than 1150 N / mm 2 . Furthermore, the track part in the head area preferably has a hardness greater than 340 HB.
- the invention provides a method for producing the track part described above, wherein the track part is produced from a hot-rolled profile, wherein the rail head of the rolled profile is subjected to controlled cooling immediately after leaving the rolling stand with the rolling heat, wherein the controlled cooling in a first step is an accelerated cooling until reaching a first temperature permitting ferrite formation, in a second step holding the first temperature to effect ferrite formation, in a third step further cooling in one of the poly phases - Bainit Bear permitting temperature range up to a second temperature and in a fourth step comprises holding the second temperature.
- the controlled cooling is preferably carried out, as known per se, by immersing at least the rail head in a liquid cooling medium.
- the first step in this case preferably begins at a temperature of 740-850 ° C, in particular about 790 ° C and ends preferably at a temperature of 450-525 ° C.
- the cooling which takes place during the first step must be controlled in such a way that in the time-temperature conversion diagram one arrives in the area of ferrite and subsequent bainite formation, in particular no conversion in the pearlite stage.
- the accelerated cooling takes place in the first Step preferably with a cooling rate of 2-5 ° C / sec.
- the preferred procedure is that the rail part is completely immersed in the cooling medium during the first step.
- the temperature of preferably 450-525 ° C is maintained and it produces the important for the property property ferrite, in particular the acicular ferrite, with a volume fraction of 5-15%, in particular 8-13%, in particular about 10%. Maintaining the temperature is preferably achieved by holding the splice member in a position taken out of the cooling medium during the second step.
- a further controlled cooling is carried out for the required limitation of the ferrite content, so that a mixture of upper and lower bainite structure is formed (multiphase bainite).
- the temperature range in which bainitization occurs is preferably between 450-525 ° C and 280-350 ° C, i. that the rail head of the rail part in the bainite phase from 450-525 ° C to 280-350 ° C is cooled.
- This third step preferably extends over a period of 50-100 sec, in particular about 70 sec. In the bainite formation phase, it is sufficient if the rail part is preferably immersed in the cooling medium only with the rail head.
- the hardness of the rail part in the fourth step is then finally fixed depending on the temperature position, falling below the martensite start temperature (usually about 280 ° C) is to be avoided since can form too many martensitic, brittle microstructural constituents in the temperature range.
- the temperature hold during the fourth step is preferably carried out by cyclic head diving, ie that the track part is dipped cyclically in the cooling medium and taken out of the cooling medium. Since the temperature range of the bainite phase formation and the Martensitstarttemperatur depends on the alloying elements of the respective steel and their proportions, the value of the first temperature and the value of the second temperature must be determined in advance for each steel exactly.
- the temperature of the rail is then continuously measured during the controlled cooling, wherein the cooling and holding sections are started or terminated upon reaching the respective temperature thresholds. Since the surface temperature of the rail can vary over the entire length of the rail part, but the cooling is carried out uniformly for the entire rail part, it is preferred that the temperature is detected at a plurality of measuring points distributed over the length of the rail part and a mean temperature is formed, which is used for the control of the controlled cooling.
- austenite transforms to bainite as completely as possible. This occurs at temperatures below the perlite formation up to the martensite start temperature both isothermally and with continuous cooling.
- By slowly folding the austenite out, starting from the grain boundaries or impurities strongly carbon-supersaturated ferrite crystals with cubic-body-centered crystal lattice are formed.
- the carbon precipitates within the ferrite grain due to the higher diffusion rate in the cubic body centered lattice in the form of spherical or ellipsoidal cementite crystals.
- the carbon can diffuse into the austenite area and form carbides.
- cooling and temperature maintenance are carried out in such a way that a multiphase bainite is formed.
- a continuous cooling takes place at a lower cooling rate than in a second substep, in which the temperature is lowered abruptly until the second temperature is reached.
- predominantly upper bainite is formed.
- a holding at the second temperature takes place, in which case lower bainite is formed. The duration of holding the second temperature during the fourth step determines the extent of lower bainite formation.
- the upper bainite consists of needle-shaped ferrite, which is arranged in packets. Between the individual Ferritnadeln more or less continuous films of 'carbides are parallel prior to the needle axis.
- lower bainite is composed of ferrite ⁇ plates, within which the carbides form an angle of 60 ° to the needle axis.
- the cooling medium passes through three phases of the quenching process.
- the first phase the vapor film phase
- the temperature at the surface of the rail head is so high that the cooling medium evaporates rapidly and forms a thin insulating vapor film (Leidenfrost effect).
- This steam film phase is, inter alia, very much dependent on the vapor formation heat of the cooling medium, the surface condition of the rail part, such as scale, or the chemical composition and design of the cooling pool.
- the cooling medium comes into direct contact with the hot surface of the rail head and comes immediately to boiling, resulting in a high cooling rate.
- the third phase the Convection phase, begins when the surface temperature of the rail part has dropped to the boiling point of the cooling medium. In this area, the cooling speed is essentially influenced by the flow velocity of the cooling medium.
- the cooling medium is preferably in the vapor film phase during the first step. Preference is also given to proceeding so that the cooling is controlled during the third step so that the cooling medium first forms a vapor film on the surface of the rail head and then boils on the surface. There is thus a transition from the vapor film phase into the cooking phase.
- the vapor film phase extends over the length of the above-mentioned first substep, in which predominantly upper bainite is produced.
- the temperature Upon reaching the boiling phase, the temperature abruptly drops to the second temperature, i. to preferably 280-350 ° C from.
- the transition from the vapor film phase to the cooking phase is usually relatively uncontrolled and spontaneous. Since the rail temperature over the entire length of the rail part is subject to certain production-related temperature fluctuations, there is the problem that the transition from the vapor film phase into the cooking phase occurs in different lengths of the rail part at different times. This would lead to a non-uniform microstructure over the length of the rail part and consequently to uneven material properties.
- a preferred procedure provides that during the third step, a film breaking, gaseous printing medium, such as nitrogen, is fed along the entire length of the rail part to the rail head to the steam film along the entire length of the rail part to break and initiate the cooking phase.
- the film-breaking, gaseous pressure medium is brought to the rail head approximately 20-100 seconds, in particular approximately 50 seconds after the beginning of the third step.
- a device for carrying out the method described above comprising a coolant tank which can be filled with cooling medium, a lifting and lowering device for the rail part in order to dip and lift the rail part into the cooling tank
- Temperature measuring means for measuring the temperature of the rail part Pressure medium generating means, by which the pressure medium is introduced into the cooling medium, means for controlling the temperature of the cooling medium and a control device, which are supplied with the measured values of the temperature measuring device and which with the raising and lowering device for controlling the Heb - and lowering operations and with the means for controlling the temperature of the cooling medium in dependence on the temperature readings and further cooperates with the pressure medium generating means.
- sensors are provided for detecting cooling medium boiling on the surface of the rail head, the sensor measured values of which are fed to the control device in order to increase the pressure measurement. diumer Wegungsmittel depending on the sensor measured values to control.
- a plurality of sensors may be provided for detecting cooling medium cooking on the surface of the rail head, which are distributed over the length of the cooling pool.
- the sensor measured values of the plurality of sensors are fed to the control device, wherein the control device controls the pressure medium generating means as soon as at least one sensor detects boiling cooling medium on the surface of the rail head.
- control means is adapted to perform a controlled cooling, in a first step, an accelerated cooling until reaching a ferrite permitting first temperature, in a second step, holding the first temperature to effect ferrite formation, in a third Step includes further cooling in a temperature range allowing the multiphase bainite formation to a second temperature and in a fourth step comprising holding the second temperature.
- the controller may be configured to reduce the temperature of the rail head in the first step at a cooling rate of 2-5 ° C / sec to a first temperature of 450-525 ° C, the temperature of the rail head in the second step on the to maintain the first temperature and the temperature of the rail head during the third step, preferably over a period of 50-100 sec, in particular about 70 sec, to a second temperature of 280-350 ° C to reduce.
- the control means is adapted to drive the print medium generating means during the third step.
- a low-alloy steel with the following directional analysis was formed by hot rolling into a rail with a rail profile:
- the rail was subjected to controlled cooling with the rolling heat.
- the controlled cooling is explained below with reference to the time-temperature conversion diagram shown in FIG. 1, wherein the line designated by 1 represents the cooling curve.
- the cooling process starts at a temperature of 790 ° C.
- the rail is dipped via its ge ⁇ entire length and with its entire cross section in a cooling bath of water and it was a cooling rate of 4 ° C / sec is set. After about 75 seconds, a surface temperature of the rail head of 490 ° C was measured, where point 2 was reached and the rail was taken out of the cooling bath was maintained to hold the temperature for a period of about 30 seconds, whereby the formation of acicular ferrite was achieved.
- the rail was again immersed in the cooling bath and cooled to point 4.
- the initial boiling of the cooling water at the surface of the rail head was detected and compressed air was applied to the rail head to break the vapor film surrounding the rail head and initiate the cooking phase over the entire length of the rail.
- the initiation of the cooking phase led to an abrupt drop in the temperature of the rail head, wherein this cooling was stopped when reaching a temperature of 315 ° C (item 5). By cyclic head diving this temperature was maintained for a certain time.
- the length of the hold time determines the composition of the multiphase bainite structure, as shown in the following examples.
- Example 1 In a first embodiment was. a low-alloyed steel with the following guideline analysis by means of hot rolling to form a rail with rail profile:
- the microstructure is shown in FIG. 2.
- Example 2 In the second embodiment, the same low alloy steel was used as in Example 1 and formed by hot rolling into a rail with a rail profile. The controlled cooling was carried out the same as in Example 1, but the temperature was kept longer in the fourth step than in Example 1. The following structure was achieved in the rail head: about 10 vol. -% acicular ferrite,
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- Organic Chemistry (AREA)
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- Crystallography & Structural Chemistry (AREA)
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Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA990/2012A AT512792B1 (de) | 2012-09-11 | 2012-09-11 | Verfahren zur Herstellung von bainitischen Schienenstählen |
PCT/AT2013/000107 WO2014040093A1 (de) | 2012-09-11 | 2013-06-27 | Verfahren zur herstellung von bainitischen schienenstählen, gleisteil und einrichtung zur durchführung des verfahrens |
Publications (1)
Publication Number | Publication Date |
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EP2895632A1 true EP2895632A1 (de) | 2015-07-22 |
Family
ID=48856470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13739927.5A Withdrawn EP2895632A1 (de) | 2012-09-11 | 2013-06-27 | Verfahren zur herstellung von bainitischen schienenstählen, gleisteil und einrichtung zur durchführung des verfahrens |
Country Status (14)
Country | Link |
---|---|
US (1) | US20150218759A1 (zh) |
EP (1) | EP2895632A1 (zh) |
JP (1) | JP2015532946A (zh) |
CN (1) | CN104812918A (zh) |
AR (1) | AR091760A1 (zh) |
AT (1) | AT512792B1 (zh) |
AU (1) | AU2013315331A1 (zh) |
BR (1) | BR112015005189A2 (zh) |
CA (1) | CA2883523A1 (zh) |
RU (1) | RU2608254C2 (zh) |
TW (1) | TWI496897B (zh) |
UA (1) | UA110312C2 (zh) |
WO (1) | WO2014040093A1 (zh) |
ZA (1) | ZA201502151B (zh) |
Cited By (1)
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CN110102581A (zh) * | 2019-04-03 | 2019-08-09 | 姚国辉 | 一种基于物联网的冷轧线材堆钢检测方法 |
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CN107326302B (zh) * | 2017-05-26 | 2018-10-19 | 北京交通大学 | 一种耐蚀贝氏体钢、钢轨及制备方法 |
AT519669B1 (de) * | 2017-06-07 | 2018-09-15 | Voestalpine Schienen Gmbh | Gleisteil und Verfahren zur Herstellung eines Gleisteils |
WO2019102258A1 (en) * | 2017-11-27 | 2019-05-31 | Arcelormittal | Method for manufacturing a rail and corresponding rail |
FR3101888B1 (fr) * | 2019-10-14 | 2024-02-09 | Fives Stein | Refroidissement rapide des tôles d’acier à haute limite élastique |
CN110904311B (zh) * | 2019-12-06 | 2021-08-03 | 马鞍山钢铁股份有限公司 | 一种抗失圆车轮钢、车轮及车轮的制备方法 |
CN110714377B (zh) * | 2019-12-10 | 2021-08-13 | 安徽浦进轨道装备有限公司 | 一种易于装配的磁悬浮车辆轨道的支撑结构 |
CN112159940A (zh) * | 2020-10-27 | 2021-01-01 | 攀钢集团攀枝花钢铁研究院有限公司 | 大过冷度深硬化层道岔钢轨及其制备方法 |
CN112962029B (zh) * | 2021-02-01 | 2021-12-21 | 广东鑫发精密金属科技有限公司 | 一种拉链纽扣用低硬度易加工的不锈钢材料及其制备方法 |
CN114317918B (zh) * | 2021-12-28 | 2023-09-22 | 内蒙古科技大学 | 一种高强韧组织定量化控制的贝马复相重轨钢及其制备方法 |
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AU663023B2 (en) * | 1993-02-26 | 1995-09-21 | Nippon Steel Corporation | Process for manufacturing high-strength bainitic steel rails with excellent rolling-contact fatigue resistance |
GB9313060D0 (en) * | 1993-06-24 | 1993-08-11 | British Steel Plc | Rails |
US5759299A (en) * | 1994-05-10 | 1998-06-02 | Nkk Corporation | Rail having excellent resistance to rolling fatigue damage and rail having excellent toughness and wear resistance and method of manufacturing the same |
GB2297094B (en) * | 1995-01-20 | 1998-09-23 | British Steel Plc | Improvements in and relating to Carbide-Free Bainitic Steels |
JPH0971844A (ja) * | 1995-09-04 | 1997-03-18 | Nkk Corp | 耐損傷性に優れた高強度ベイナイト鋼レ−ル |
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AT410549B (de) * | 2001-09-13 | 2003-05-26 | Voest Alpine Schienen Gmbh & C | Vorrichtung zum vergüten von walzgut mit grosser länge |
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2012
- 2012-09-11 AT ATA990/2012A patent/AT512792B1/de not_active IP Right Cessation
-
2013
- 2013-06-27 EP EP13739927.5A patent/EP2895632A1/de not_active Withdrawn
- 2013-06-27 TW TW102122931A patent/TWI496897B/zh not_active IP Right Cessation
- 2013-06-27 US US14/427,525 patent/US20150218759A1/en not_active Abandoned
- 2013-06-27 AU AU2013315331A patent/AU2013315331A1/en not_active Abandoned
- 2013-06-27 CA CA2883523A patent/CA2883523A1/en not_active Abandoned
- 2013-06-27 RU RU2015113360A patent/RU2608254C2/ru not_active IP Right Cessation
- 2013-06-27 BR BR112015005189A patent/BR112015005189A2/pt not_active IP Right Cessation
- 2013-06-27 JP JP2015530236A patent/JP2015532946A/ja active Pending
- 2013-06-27 WO PCT/AT2013/000107 patent/WO2014040093A1/de active Application Filing
- 2013-06-27 CN CN201380047032.0A patent/CN104812918A/zh active Pending
- 2013-06-27 UA UAA201503380A patent/UA110312C2/uk unknown
- 2013-07-12 AR ARP130102503 patent/AR091760A1/es unknown
-
2015
- 2015-03-27 ZA ZA2015/02151A patent/ZA201502151B/en unknown
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Also Published As
Publication number | Publication date |
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UA110312C2 (uk) | 2015-12-10 |
CA2883523A1 (en) | 2014-03-20 |
RU2608254C2 (ru) | 2017-01-17 |
TW201410877A (zh) | 2014-03-16 |
TWI496897B (zh) | 2015-08-21 |
ZA201502151B (en) | 2016-01-27 |
WO2014040093A1 (de) | 2014-03-20 |
AT512792B1 (de) | 2013-11-15 |
AU2013315331A1 (en) | 2015-04-16 |
AR091760A1 (es) | 2015-02-25 |
BR112015005189A2 (pt) | 2017-07-04 |
US20150218759A1 (en) | 2015-08-06 |
CN104812918A (zh) | 2015-07-29 |
AT512792A4 (de) | 2013-11-15 |
RU2015113360A (ru) | 2016-11-10 |
JP2015532946A (ja) | 2015-11-16 |
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