EP2877346B1 - Procédés de décoration de carreaux de céramique - Google Patents

Procédés de décoration de carreaux de céramique Download PDF

Info

Publication number
EP2877346B1
EP2877346B1 EP13759316.6A EP13759316A EP2877346B1 EP 2877346 B1 EP2877346 B1 EP 2877346B1 EP 13759316 A EP13759316 A EP 13759316A EP 2877346 B1 EP2877346 B1 EP 2877346B1
Authority
EP
European Patent Office
Prior art keywords
adhesive
ceramic
decoration
layer
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP13759316.6A
Other languages
German (de)
English (en)
Other versions
EP2877346A1 (fr
Inventor
Hagai Peled
Marek LASMAN
Gregory Nakhmanovich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lasman Marek
Nakhmanovich Gregory
Peled Hagai
Original Assignee
Lasman Marek
Nakhmanovich Gregory
Peled Hagai
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lasman Marek, Nakhmanovich Gregory, Peled Hagai filed Critical Lasman Marek
Publication of EP2877346A1 publication Critical patent/EP2877346A1/fr
Application granted granted Critical
Publication of EP2877346B1 publication Critical patent/EP2877346B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/006—Patterns of chemical products used for a specific purpose, e.g. pesticides, perfumes, adhesive patterns; use of microencapsulated material; Printing on smoking articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock

Definitions

  • the present invention relates to a method of decorating ceramic or glass materials, which method offers ease of production and in particular to such a method involving printing more than one color onto a ceramic substrate.
  • UK patent application published GB 2 289 866 A discloses a method suitable for decorating a ceramic article.
  • the method comprises the steps of (1) printing a liquid material by an ink jet printer on to the article to form the required pattern of an adhesive material, (2) supplying particulate decorative material on to the adhesive pattern, and (3) removing the excess of particulate material which has not adhered to the pattern.
  • the present invention relates to a method for applying at least a two-color decoration material having a particular shape or boundaries to a ceramic substrate, in accordance with appended independent claim 1 and appended dependent claims 2-9.
  • the present invention in some embodiments thereof, relates to methods for printing or otherwise applying decoration materials having a particular shape(s) and/or boundary/boundaries, determined by forming an adhesive layer through a process having more than one stage, followed by applying the decoration material by means of dry silk screen, dry gravure or spray-gun.
  • the decoration material remains only at the location(s) determined by the adhesive layer (or substantially only at these location(s)).
  • “remains” it is meant that the decoration layer may optionally be applied specifically to the adhesive layer or alternatively may optionally be applied to at least one location other than that determined by the adhesive layer, followed by removal of any decoration material not specifically adhered to the adhesive layer, for example and without limiting, by washing, brushing, tilting, air blowing or air suction.
  • Non-limiting examples of the decoration material include but are not limited to metal oxides, metals, precious metals, glass frits, lusters and special color effects pigments, organo-clay pigments, glazes, salts flux, mineralizers and pigment stains.
  • the adhesive layer is formed through a process comprising a plurality of stages.
  • a plurality of adhesive layer components are applied during the plurality of stages, such that only when all such components have been applied, the adhesive layer becomes functionally adhesive to receive and adhere to the decoration layer.
  • functionally adhesive it is meant that the adhesive layer adheres to the decoration material.
  • At least one adhesive layer-forming component(s) are applied, followed by activation of the adhesive layer such that it becomes functionally adhesive.
  • the adhesive layer is formed through a process comprising a plurality of stages.
  • a plurality of adhesive layer components are applied during the plurality of stages, such that only when all such components have been applied, the adhesive layer becomes functionally adhesive to receive and adhere to the decoration layer.
  • functionally adhesive it is meant that the adhesive layer adheres to the decoration material.
  • At least one adhesive layer-forming component(s) are applied, followed by activation of the adhesive layer such that it becomes functionally adhesive.
  • any suitable application process may optionally be used, referred to herein as "printing".
  • a second, adhesive activator component is applied and establishes the pattern by creating the activated adhesive upon which the pigment is deposited.
  • the adhesive layer may optionally be applied through digital patterning of the adhesive in any possible way (any of the above, ink-jet printing of the adhesive and alike).
  • the adhesive layer may optionally be spread in a non-patterned manner atop the surface and only then is it patterned e.g., by reacting with another component and/or electromagnetic irradiation (photo curing) and/or thermally activated curing.
  • At least one adhesive forming component is optionally reacted on the surface with at least one printable adhesive- activating component in a way to form the adhesive only at the desired locations.
  • said substrate is selected from the group consisting of. unfired tiles ("green” tiles), fired tiles and unfired glaze (bisque), glazed and fired tiles (third fire), decal (ceramic transfer paper), glass and metal enamel.
  • a method for applying at least a two color decoration material having a particular shape or boundaries on a ceramic substrate comprising:
  • a method for applying at least a three color decoration material having a particular shape or boundaries on a ceramic substrate as defined above wherein in step f, said further ceramic pigment, in particulate form ,is applied together with a yet further amount of at least one adhesive-layer-forming component, and steps d,e,f,and g are repeated with a third ceramic pigment whereby a ceramic substrate, decorated with at least three colors, is formed.
  • a method for applying a multiple color decoration material having a particular shape or boundaries on a ceramic substrate as defined above wherein in step f, said further ceramic pigment, in particulate form ,is applied together with a yet further amount of at least one adhesive-layer-forming component, and steps d,e,f,and g are repeatedly repeated with as many separate ceramic pigments respectively as determined for completing the multicolor decoration.
  • said patent is directed to a method of providing a recording medium and all three of the examples in said patent teach the use of a recording paper which was provided with an adhesive to which was then applied a pigment and the printed surface of the recording paper was contacted with the surface of a white tile.
  • said patent does not teach or suggest a process for directly printing on "green" tiles and similar surfaces and does not teach or suggest the especially efficient process of the present invention for applying multi-color decorations to ceramic tiles.
  • Said patent does mention in column 4 lines 1-7 thafalso, it is possible to use a one-pass type multicolor printing apparatus that does not involve plate making and comprises a plurality of units, each performing therein the steps of selectively giving tackiness to a substrate, developing with powder, and removing unnecessary powder so that development with different color powder can be carried out in a different unit.
  • said publication is a teaching away from the present invention in that it clearly contemplates an extra step for each color application in that it also does not teach or suggest the unique and efficient method of the present invention wherein a further second, third, fourth, etc., ceramic pigment, in particulate form , is applied together with a yet further amount of at least one adhesive-layer-forming component on top of the previously deposited adhesive activator so that while said further ceramic pigment is being attached to the activated adhesive therebelow, the surface is already being primed to receive a further layer of adhesive activator and pigment.
  • said adhesive activator is a solvent which causes the adhesive-layer-forming component to become functionally adhesive to the decoration layer.
  • At least one component of said decoration material and said adhesive layer are applied through digital patterning
  • said solvent is applied via an ink-jet printing print head.
  • said decoration material is applied in solid particulate form.
  • the decoration material relates to metal oxides, metals, precious metals, glass frits, luster and color effects pigments, organo-clay pigments, glazes, salts flux, mineralizers, pigment stains and their combinations and their mixtures in combination with said first adhesive layer forming component.
  • the method is based on forming the shape of a decoration material by producing and/or depositing and/or activating and/or deactivating an adhesive on a surface at the desired shape, following by depositing metal oxides particles and/or metals particles and/or precious metals particles and/or glass frits particles and/or luster particles and/or color effects pigments particles and/or organo-clay pigments particles and/or glazes particles and/or salts flux particles and/or mineralizers particles and/or pigment stains particles in combination with a further adhesive layer forming component, wherein said decoration material adheres to the activated adhesive which totally interacts with and adheres to said decoration material thus forming a decoration layer while said further deposited adhesive layer forming component is ready to receive further adhesive activator,.
  • the system may be further subjected to treatment steps aimed at one or a combination of the following: coating with different layers, pressing, air blowing, air suction, heating, drying, firing, polishing, trimming, cutting and the like.
  • the method is based on forming the decoration layer by forming a patterned adhesive layer on a surface of the desired shape, using one or a combination of printing techniques such as, but not limited to ink-jet, flexography, rotogravure, offset and screen-print.
  • the patterned adhesive layer is formed by contacting two or more components.
  • the patterned adhesive layer is formed by contacting one or more printed components with another component that is pre-deposited atop the printing surface (hereinafter referred to as "substrate").
  • the present invention thus provides a method of decorating ceramic materials which offers ease of production using various decoration materials, and in particular to such a method, involving printing onto a substrate utilizing metal oxides, metals, precious metals, glass frits, luster and color effects pigments, organo-clay pigments, glazes, salts flux, mineralizers and pigment stains in combination with an adhesive layer forming component to produce a decoration layer characterized by high quality, high colour strength, wide colour gamut and conspicuous decoration effects even under harsh conditions.
  • the present invention in some embodiments thereof, relates to methods for decorating ceramic materials, and, more particularly, but not exclusively, to methods for digitally decorating ceramic materials.
  • the basic principle of the new method of the present invention is patterning the desired structures to be formed with adhesives, then contacting the adhesive pattern with one or more decoration materials such as, for example, pigment particles in combination with a further adhesive layer forming component, , wherein the adhesive layer is formed through a process comprising a plurality of stages such that only when all the stages are complete does the adhesive layer becomes functionally adhesive to the decoration layer and further colored layers can be applied without repeating all the steps of the original one color process.
  • the decoration layer containing metal oxides, metals, precious metals, glass frits, luster and color effects pigments, organo-clay pigments, glazes, salts flux, mineralizers, pigment stains bound to the adhesive layer may be further treated by one or more heating techniques, may be covered by a layer of glaze/frit, may serve as a base for further layer construction, and/or may be contacted with yet another one or more decoration materials, such as, for example, pigment particles and the like by the methods described above.
  • the method of the invention may be used, for example, for the production of glazed and non-glazed wall tiles, floor tiles, "green” tiles, decal, glass sheets, glass packaging, dinner ware, sanitary ware, ceramic products, clay slab, metal and metal enamel.
  • the methods of the present invention are adapted to be applied to: unfired tiles ("green” tiles), fired tiles and unfired glaze (bisque), glazed and fired tiles (third fire), decal (ceramic transfer paper), glass and metal enamel.
  • the methods of the present invention for applying multiple layers of multiple colors are especially adapted to be applied to unfired tiles ("green" tiles),which are not readily decorated by prior art processes,
  • the formation of the patterned adhesive layer is achieved by pre-depositing one or more adhesive forming components on the substrate which are reactive to a particular material or solvent. Next one or more additional components are applied that contain such a material or solvent, thereby bringing these components into contact with each other and activating the adhesive.
  • the pre-deposited component may optionally comprise one or more of water soluble and/or water swellable polymers, or one or more organic solvent soluble or swellable polymers, or one or more alkali soluble or swellable polymers; such that the additional adhesive-activating component(s)) contain the relevant material or solvent (water, organic solvent and/or alkali, respectfully) and can be printed thereon.
  • the component that is pre-deposited atop the substrate may contain one or more water soluble or water swellable polymers including, but not limited to, gelatin, arabic gum, polyvinyl alcohol and its derivatives, polyvinylpyrrolidone and its derivatives, carboxymethyl cellulose and alike.
  • the printed adhesive activator component may contain, optionally in addition to other components, a mixture of water and/or one or more water soluble alcohols, and/or one or more water soluble mono- glycols, and/or one or more water soluble glycol oligomers, and/or one or more water soluble glycol polymers and/or one or more water soluble glycol esters and/or one or more water soluble polymers and/or one or more surfactants.
  • the component that is pre-deposited atop the substrate may contain, optionally in addition to other components, one or more alkali soluble or alkali swellable polymers while the printed component may contain one or more alkali compounds and water.
  • the component that is pre-deposited atop the substrate may contain, optionally in addition to other components, one or more alkali soluble or alkali swellable polymers such as, but not limited to, polyacrylic acid, copolymers of acrylic acid with epoxy acrylates, alkyl acrylates, aryl acrylates, polyacrylic esters, polyacrylic amides, copolymers of the above.
  • the printed adhesive activator component may contain, optionally in addition to other components, a mixture of water and/or one or more alkali compound and/or one or more water soluble alcohols, and/or one or more water soluble mono- glycols, and/or one or more water soluble glycol oligomers, and/or one or more water soluble glycol polymers and/or one or more water soluble glycol esters and/or one or more alkali soluble polymers and/or one or more surfactants.
  • the printed adhesive activator component may contain, optionally in addition to other components, one or more alkali compound such as, but not limited to, ammonia, animoalcohols, alkyl amines, aryl amines, hydroxides of alkaline metals and alike.
  • alkali compound such as, but not limited to, ammonia, animoalcohols, alkyl amines, aryl amines, hydroxides of alkaline metals and alike.
  • the adhesive forming component that is pre-deposited atop the substrate may contain, optionally in addition to other components, one or more polymers that are soluble or swellable in organic solvents while the printed adhesive activator component may contain, optionally in addition to other components, one or more organic solvents that may dissolve or swell the pre-deposited component, thus forming the adhesive.
  • the adhesive forming component that is pre-deposited atop the substrate may contain one or more polymers such as, but not limited to, polyacrylates and their derivatives, polystyrenes and their derivatives, polyurethanes and their derivatives, polyesters and their derivatives, polyvinyl chloride and its derivative.
  • the printed adhesive activator component may contain, optionally in addition to other components, a mixture of one or more organic solvents, one or more solvent soluble polymers, one or more surfactants.
  • the printed adhesive activator component may contain, optionally in addition to other components, one or more organic solvents such as but not limited to alcohols, glycols, esters, amides, glycol esters and ketones.
  • the printed adhesive activator component may be deposited by ink-jet printing, using commercially available and/or especially designed ink-jet printers.
  • the printers may be based on thermal (bubble) jet principle.
  • the printers may be based on piezzo jet principle.
  • the printers may be based on continuous ink jet principle.
  • the first adhesive layer forming component is dispersed and/or formed homogeneously on the printing surface and said desired shape is achieved by photo-irradiation of the surface through a mask, rendering the exposed parts of the adhesive non adhesive by means of a photo-curing process.
  • said first adhesive layer forming component, dispersed homogeneously on the printing surface may contain, optionally, in addition to other components, one or more free-radical and/or cationic UV-curable resins and/or one or more photo-initiators and/or one or more surfactants.
  • said first adhesive layer forming component may contain, optionally in addition to other components, one or more UV-curable resins such as, but not limited to, urethane acrylates, epoxyacrylates, aminoacrylates, poly ester acrylates, oligo ester acrylates, poly amide acrylates, oligo amide acrylates, epoxy derivatives, oxetane derivatives and the like
  • one or more UV-curable resins such as, but not limited to, urethane acrylates, epoxyacrylates, aminoacrylates, poly ester acrylates, oligo ester acrylates, poly amide acrylates, oligo amide acrylates, epoxy derivatives, oxetane derivatives and the like
  • said first adhesive layer forming component that is dispersed homogeneously on the printing surface may contain, optionally in addition to other components, one or more photo-initiators such as, but not limited to, alfa-hydroxyketons, alfa-animoketons, Bis-Acyl-Phosphine Oxide (BAPO), Mono-Acyl-Phosphine Oxide (MAPO), 2-lsopropylthioxanthone (ITX), Ethyl-4-Dimethyl amino benzoate (EDB), sulphonium derivatives, iodonium derivatives and alike.
  • one or more photo-initiators such as, but not limited to, alfa-hydroxyketons, alfa-animoketons, Bis-Acyl-Phosphine Oxide (BAPO), Mono-Acyl-Phosphine Oxide (MAPO), 2-lsopropylthioxanthone (ITX), Ethyl-4-Dimethyl amino benzoate (EDB
  • said first adhesive layer forming component in its desired shape, is achieved by photo-irradiation of a coated surface through a mask, rendering the exposed parts of the coated surface adhesive by means of a photo-reaction process.
  • said first adhesive layer forming component is patterned on a non- planar object such as a rugged surface, a surface that contains steps, surfaces at a different height, rectangles, cubes, curved objects, bent surfaces and the like.
  • the substrate is exposed to a decoration material in combination with components of a further adhesive layer forming component.
  • the decoration materials may consist of metal oxides, metals, precious metals, glass frits, luster and special color effects pigments, organo-clay pigments, glazes, salts flux, mineralizers and pigment stains material in combination with components of an adhesive layer forming component.
  • the decoration materials may be organic materials. In some embodiments of the invention, the decoration materials may be inorganic materials.
  • the decoration materials may exist in the form of small particles, preferably, but not limited to, having a mean size of between 10 nanometers and hundreds of micrometers.
  • the decoration materials may exist as a powder of dry small particles without any liquid medium.
  • the decoration materials may exist as small particles dispersed in a carrier liquid medium.
  • the liquid carrier medium may contain, optionally in addition to other components, water, organic solvents, resins, surfactants, acids, bases, ions.
  • the decoration materials comprise metal oxides, metals, precious metals, glass frits, luster and special color effects pigments, organo-clay pigments, glazes, salts flux, mineralizers and pigment stains in combination with components of said first adhesive layer forming component when a further decorative layer is to be applied, otherwise the decoration materials simply comprise metal oxides, metals, precious metals, glass frits, luster and special color effects pigments, organo-clay pigments, glazes, salts flux, mineralizers and pigment stains .
  • the decoration material may contain one or more water soluble or water swellable polymers including, but not limited to, gelatin, arabic gum, polyvinyl alcohol and its derivatives, polyvinylpyrrolidone and its derivatives, carboxymethyl cellulose and alike.
  • the decoration material may contain in addition to other components, one or more alkali soluble or alkali swellable polymers such as, but not limited to, polyacrylic acid, copolymers of acrylic acid with epoxy acrylates, alkyl acrylates, aryl acrylates, polyacrylic esters, polyacrylic amides, copolymers of the above.
  • the decoration material may contain in addition to other components one or more polymers such as, but not limited to, polyacrylates and their derivatives, polystyrenes and their derivatives, polyurethanes and their derivatives, polyesters and their derivatives, polyvinyl chloride and its derivative.
  • the decoration materials may be deposited on the substrate using screens, brushes, rollers, spray techniques.
  • the excess of the particles that were not adhered to the adhesive layer may be removed from the substrate.
  • the excess of the decoration material particles may be removed by the use of one or any combination of the following techniques: gravitation, air flow (air gun), brushes, vacuum cleaning, electrostatic cleaning, ultrasound cleaning, washing, evaporation, exposure to heat, exposure to ultrasonic waves, exposure to electromagnetic irradiation such as infrared and/or microwaves.
  • the excess of the decoration materials particles that were removed may be used again in the deposition process.
  • the substrate may be glazed- and non-glazed, fired- and not fired-, wall tiles, floor tiles, decal, glass sheets, glass packaging, dinnerware, sanitary ware, ceramic products, clay slab, metal and metal enamel.
  • At least one of said decoration material and said adhesive layer are applied through digital patterning.
  • said ceramic substrates comprise "green” ceramic tiles.
  • said ceramic substrates comprise burned ceramic tiles.
  • said ceramic substrates comprise glass sheets.
  • said ceramic substrates comprise decal sheets.
  • the present invention further comprises treating the substrate, after application of the adhesive layer and the decoration material, with heat.
  • a method for applying a decoration material having a particular shape or boundaries on a ceramic substrate comprising applying at least one adhesive-layer-forming component on a ceramic substrate, followed by applying thereto an adhesive activating component which renders said component functionally adhesive, said adhesive activating component being applied in accordance with pattern parameters of a chosen first color to appear in said decoration, applying a ceramic pigment in particulate form, as a first decoration material, in combination with components of a further adhesive layer forming component, such that said first pigment material remains at the location on the substrate determined by the activated adhesive layer, subsequently applying thereto a further adhesive activating component which once again renders said component functionally adhesive, said further adhesive activating component being applied in accordance with pattern parameters of a chosen second color to appear in said decoration, and applying a different ceramic pigment, in particulate form, as a second decoration material in combination with components of yet a further adhesive layer forming component, such that said second pigment material remains at the location on the substrate determined by the further activated adhesive layer,
  • the decoration image may be produced on an intermediate substrate such as decals and then transferred to the substrate by conventional methods usable in ceramic or glass industry.
  • the coated shapes may be further subjected to one or more and/or combinations of additional processes aimed at:
  • Example 1 Decoration of a ceramic tile suitable for "Third fire", decoration on the surface of a previously glazed and fired tile.
  • Example 2 Decoration of a "first fire” (non fired “green”) ceramic floor tile.
  • a “green” tile is manufactured by pressing ceramic powder in a mold.
  • Example 3 Decoration of a ceramic tile suitable for "third fire” using special effect pigments. "Third fire” is decoration on the surface of a previously glazed and fired tile.
  • Example 4 Decoration of a "third fire” ceramic tile by printing on a decal and transfer to the tile.
  • Example 5 Decoration of a ceramic tile suitable for "third fire” using standard CMYK and bronze pigments. "Third fire” is a decoration of the surface of a previously glazed and fired tile.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Finishing Walls (AREA)
  • Printing Methods (AREA)

Claims (9)

  1. Procédé pour l'application d'au moins un matériau de décoration bicolore possédant une configuration particulière ou des limites particulières sur un substrat en céramique, comprenant le fait de :
    a. appliquer au moins un composant de formation d'une couche adhésive sur un substrat en céramique ;
    b. appliquer de manière sélective un activateur de l'adhésif qui rend adhésif ledit composant de formation d'une couche adhésive pour former une couche adhésive, en fonction d'un motif de couleur sélectionné de ladite décoration ;
    c. appliquer un pigment céramique, sous forme particulaire, à titre de matériau de décoration conjointement avec une quantité supplémentaire d'au moins un composant de formation d'une couche adhésive ;
    d. éliminer l'excès dudit pigment céramique d'une manière telle que ladite matière pigmentaire subsiste uniquement à l'endroit sur le substrat déterminé par ladite couche adhésive activée ;
    e. appliquer de manière sélective un activateur supplémentaire de l'adhésif qui rend adhésive ladite quantité supplémentaire d'au moins un composant de formation d'une couche adhésive, pour former une couche adhésive davantage activée, en fonction d'un motif de couleur sélectionné de ladite décoration ;
    f. appliquer un pigment céramique supplémentaire différent, sous forme particulaire, à titre de matériau de décoration supplémentaire ; et
    g. éliminer l'excès du pigment supplémentaire d'une manière telle que ladite matière pigmentaire supplémentaire subsiste uniquement à l'endroit sur le substrat déterminé par la couche adhésive davantage activée ;
    par lequel on obtient la formation d'un substrat en céramique décoré avec au moins deux couleurs.
  2. Procédé selon la revendication 1, dans lequel ledit matériau de décoration comprend un ou plusieurs matériaux choisis parmi des oxydes métalliques, des métaux, des métaux précieux, des frittes de verre, des pigments possédant des effets spéciaux de brillant et de couleurs, des pigments d'organoargile, des émaux, des flux salins, des minéralisateurs, des pigments de teintures pigmentées, des oxydes métalliques, des silicates, des émaux, des teintures ou leurs combinaisons.
  3. Procédé selon la revendication 1, dans lequel ledit activateur de l'adhésif est un solvant qui fait en sorte que le composant de formation d'une couche adhésive dispose d'une fonctionnalité adhésive par rapport à la couche de décoration appliquée.
  4. Procédé selon la revendication 1, dans lequel ledit activateur de l'adhésif est déposé via une impression par jet d'encre.
  5. Procédé selon la revendication 1, dans lequel ledit substrat en céramique comprend des carreaux de céramique « à l'état vert ».
  6. Procédé selon la revendication 1, dans lequel ledit substrat en céramique comprend des carreaux de céramique à l'état cuit.
  7. Procédé selon la revendication 1, dans lequel ledit substrat en céramique comprend des plaques de verre.
  8. Procédé selon la revendication 1, dans lequel ledit substrat en céramique comprend des feuilles de décalcomanie.
  9. Procédé selon la revendication 1, comprenant en outre le fait de soumettre le substrat, après l'application de la couche adhésive et du matériau de décoration, à un traitement thermique.
EP13759316.6A 2012-07-25 2013-07-21 Procédés de décoration de carreaux de céramique Not-in-force EP2877346B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261675348P 2012-07-25 2012-07-25
PCT/IL2013/050616 WO2014016828A1 (fr) 2012-07-25 2013-07-21 Procédés de décoration de carreaux de céramique

Publications (2)

Publication Number Publication Date
EP2877346A1 EP2877346A1 (fr) 2015-06-03
EP2877346B1 true EP2877346B1 (fr) 2018-01-31

Family

ID=49118583

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13759316.6A Not-in-force EP2877346B1 (fr) 2012-07-25 2013-07-21 Procédés de décoration de carreaux de céramique

Country Status (2)

Country Link
EP (1) EP2877346B1 (fr)
WO (1) WO2014016828A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017146741A1 (fr) * 2016-02-26 2017-08-31 Hewlett-Packard Development Company, L.P. Impression couleur et impression en trois dimensions (3d)
EP3433096A1 (fr) * 2016-03-24 2019-01-30 Qutone Ceramic Pvt. Ltd. Carreau fusionné multi-couche, et procédé pour sa fabrication
CN109608207A (zh) * 2019-01-24 2019-04-12 信益陶瓷(中国)有限公司 一种通体无釉大理石瓷砖及其制造方法
CN110091423B (zh) * 2019-04-11 2020-11-10 佛山市乐陶工艺陶瓷有限公司 一种瓷片造型工艺

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB623973A (en) * 1947-06-12 1949-05-25 Leslie Hulsom Bradley A new or improved method relating to decoration of ceramic articles
JP2969541B2 (ja) 1993-08-05 1999-11-02 憲一 古川 画像記録方法
GB9324740D0 (en) 1993-12-02 1994-01-19 Johnson Matthey Plc Transfer manufacture
GB2289866A (en) * 1994-06-03 1995-12-06 British Ceramic Res Ass Method for forming curable decal
GB9810213D0 (en) * 1998-05-14 1998-07-08 Decoglas Limited Providing decoration on a substrate
FR2788457B1 (fr) * 1999-01-15 2001-02-16 Saint Gobain Vitrage Procede d'obtention d'un motif sur un substrat en materiau verrier

Also Published As

Publication number Publication date
EP2877346A1 (fr) 2015-06-03
WO2014016828A1 (fr) 2014-01-30

Similar Documents

Publication Publication Date Title
KR101798885B1 (ko) 잉크젯프린팅 인쇄적성이 우수한 도자타일용 유약 조성물 및 이를 이용한 잉크젯프린팅 도자타일의 제조방법
EP2877346B1 (fr) Procédés de décoration de carreaux de céramique
CN104011151B (zh) 数字釉墨
JPH07257097A (ja) 転写の作成
JP2015505794A (ja) 基板上顔料パターン形成
CZ293603B6 (cs) Způsob výroby skleněného substrátu, obsahujícího nejméně jeden motiv na bázi nejméně jedné barvy
JP6159173B2 (ja) 絵付耐熱部材の製造方法及び印刷装置
EP2497647A1 (fr) Procédé de décoration de carreaux de céramique vernis
KR20160094392A (ko) 플렉소그래피에 의해 열 안정성 코팅을 포함하는 물품을 장식하기 위한 방법
JP2007044614A (ja) 意匠性建材の製造方法
EP0703863B1 (fr) Procede de realisation de motifs sur des objets, notamment en ceramique
GB2289866A (en) Method for forming curable decal
US20040094260A1 (en) Ceramic powder transfer process
JPH08253358A (ja) 陶磁器などの絵付け方法
JP2005013939A (ja) 無機質化粧板の製造方法
JP2006335609A (ja) 窯業製品の加飾方法、及び窯業製品
KR200390569Y1 (ko) 축광 전사 문양이 형성된 도자기
JP4108504B2 (ja) 耐熱性素材の絵付又は彩色方法
CA2946358A1 (fr) Papier d'impression de decalque destine a la ceramique
JPH09278566A (ja) セラミックスの金装飾方法
JPH1148694A (ja) 熱転写紙およびこれを使用した装飾セラミック体の製造方法
JP2002068863A (ja) 絵付け陶磁器の製造方法
JP2790422B2 (ja) 描画方法
JP3125482B2 (ja) 陶磁器の製造方法
JP2005281072A (ja) 転写紙およびそれを用いる模様加飾方法

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20150127

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20160317

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20170629

GRAJ Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted

Free format text: ORIGINAL CODE: EPIDOSDIGR1

INTC Intention to grant announced (deleted)
GRAR Information related to intention to grant a patent recorded

Free format text: ORIGINAL CODE: EPIDOSNIGR71

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

INTG Intention to grant announced

Effective date: 20171218

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 966986

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180215

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602013032642

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20180131

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 966986

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180430

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180531

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180430

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180501

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602013032642

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20181102

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20180721

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180721

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20180731

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180721

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180731

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180731

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180721

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180721

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20130721

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180131

Ref country code: MK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180131

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20200728

Year of fee payment: 8

Ref country code: DE

Payment date: 20200728

Year of fee payment: 8

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602013032642

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210731