EP2871161A4 - Précurseur pour la préparation d'un oxyde de métal de transition composite de lithium, procédé de préparation correspondant et oxyde de métal de transition composite de lithium - Google Patents
Précurseur pour la préparation d'un oxyde de métal de transition composite de lithium, procédé de préparation correspondant et oxyde de métal de transition composite de lithiumInfo
- Publication number
- EP2871161A4 EP2871161A4 EP13816829.9A EP13816829A EP2871161A4 EP 2871161 A4 EP2871161 A4 EP 2871161A4 EP 13816829 A EP13816829 A EP 13816829A EP 2871161 A4 EP2871161 A4 EP 2871161A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal oxide
- transition metal
- lithium composite
- composite transition
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title 2
- 239000002131 composite material Substances 0.000 title 2
- 229910052744 lithium Inorganic materials 0.000 title 2
- 229910000314 transition metal oxide Inorganic materials 0.000 title 2
- 239000002243 precursor Substances 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Nickelates
- C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
- C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/54—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [Mn2O4]-, e.g. Li(NixMn2-x)O4, Li(MyNixMn2-x-y)O4
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13816829T PL2871161T3 (pl) | 2012-07-09 | 2013-07-03 | Prekursor do wytwarzania litowego kompozytu tlenku metalu przejściowego, sposób jego wytwarzania oraz sposób wytwarzania litowego kompozytu tlenku metalu przejściowego |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20120074278 | 2012-07-09 | ||
PCT/KR2013/005903 WO2014010862A1 (fr) | 2012-07-09 | 2013-07-03 | Précurseur pour la préparation d'un oxyde de métal de transition composite de lithium, procédé de préparation correspondant et oxyde de métal de transition composite de lithium |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2871161A1 EP2871161A1 (fr) | 2015-05-13 |
EP2871161A4 true EP2871161A4 (fr) | 2016-01-27 |
EP2871161B1 EP2871161B1 (fr) | 2019-03-13 |
Family
ID=49916261
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13816829.9A Active EP2871161B1 (fr) | 2012-07-09 | 2013-07-03 | Précurseur pour la préparation d'un oxyde de métal de transition composite de lithium, procédé de préparation correspondant et procédé de préparation d'un oxyde de métal de transition composite de lithium |
Country Status (10)
Country | Link |
---|---|
US (1) | US9966600B2 (fr) |
EP (1) | EP2871161B1 (fr) |
JP (1) | JP6072235B2 (fr) |
KR (2) | KR101490852B1 (fr) |
CN (1) | CN104364201B (fr) |
BR (1) | BR112014031358B8 (fr) |
IN (1) | IN2014DN10250A (fr) |
PL (1) | PL2871161T3 (fr) |
TW (1) | TWI464948B (fr) |
WO (1) | WO2014010862A1 (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101497909B1 (ko) * | 2012-05-04 | 2015-03-03 | 주식회사 엘지화학 | 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법 |
KR20140007742A (ko) * | 2012-07-09 | 2014-01-20 | 주식회사 엘지화학 | 리튬 복합 전이금속 산화물 제조용 전구체 |
KR101506640B1 (ko) * | 2014-02-11 | 2015-03-27 | 한국화학연구원 | 이종 복합 소재를 이용한 전극 활물질 및 이의 제조방법 |
KR102273779B1 (ko) * | 2014-04-04 | 2021-07-06 | 삼성에스디아이 주식회사 | 복합양극활물질 제조방법, 복합양극활물질 및 이를 채용한 양극과 리튬전지 |
WO2016068682A1 (fr) * | 2014-10-31 | 2016-05-06 | 주식회사 엘지화학 | Précurseur d'oxyde de métal de transition, oxyde de métal de transition composite au lithium, électrode positive qui comprend celui-ci, et batterie secondaire |
CN104577100A (zh) * | 2014-12-13 | 2015-04-29 | 山东精工电子科技有限公司 | 通过添加高分子糖类作为成形介质制备锂离子二次电池正极材料LiNi0.5Co0.2Mn0.3O2的方法 |
US20180269476A1 (en) * | 2015-09-11 | 2018-09-20 | Umicore | Lithium Metal Oxide Material, the Use Thereof in a Positive Electrode of a Secondary Battery and a Method for Preparing such a Lithium Metal Oxide Material |
EP3281915B1 (fr) | 2016-08-10 | 2019-02-20 | Umicore | Précurseurs de matériaux cathodiques à oxydes ayant comme métal de transition le lithium pour batteries rechargeables |
JP6980053B2 (ja) * | 2020-05-07 | 2021-12-15 | 住友化学株式会社 | リチウム二次電池用正極活物質前駆体、リチウム二次電池用正極活物質前駆体の製造方法及びリチウム二次電池用正極活物質の製造方法 |
KR20230062803A (ko) * | 2021-10-27 | 2023-05-09 | 컨템포러리 엠퍼렉스 테크놀로지 씨오., 리미티드 | 리튬-니켈-망간 복합 산화물 소재, 이차전지 및 전기기기 |
Family Cites Families (23)
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JP4032624B2 (ja) * | 2000-09-26 | 2008-01-16 | 三菱化学株式会社 | リチウム遷移金属複合酸化物の製造方法 |
JP3827545B2 (ja) * | 2001-09-13 | 2006-09-27 | 松下電器産業株式会社 | 正極活物質、その製造方法および非水電解質二次電池 |
JP4475941B2 (ja) * | 2003-12-12 | 2010-06-09 | 日本化学工業株式会社 | リチウムマンガンニッケル複合酸化物の製造方法 |
JP4411157B2 (ja) | 2004-07-27 | 2010-02-10 | 日本化学工業株式会社 | リチウムマンガンニッケル系複合酸化物、その製造方法及びそれを用いたリチウム二次電池 |
KR101455663B1 (ko) * | 2004-12-28 | 2014-11-03 | 보스톤-파워, 인크. | 리튬 이온 2차 배터리 |
JP2006219323A (ja) * | 2005-02-09 | 2006-08-24 | Sumitomo Metal Mining Co Ltd | リチウムマンガンニッケルアルミニウム複合酸化物およびその製造方法 |
KR100633287B1 (ko) * | 2005-07-05 | 2006-10-11 | 한양대학교 산학협력단 | 고용량, 고율특성의 이중층 구조를 가지는 리튬이차전지용양극 활물질, 그 제조 방법 및 그를 사용한 리튬이차전지 |
KR101306532B1 (ko) * | 2005-08-12 | 2013-09-09 | 토다 고교 유럽 게엠베하 | 무기 화합물 |
KR100872370B1 (ko) * | 2007-03-29 | 2008-12-05 | 대정이엠(주) | 리튬 이차전지용 스피넬형 양극 활물질 및 그 제조방법 |
KR100960137B1 (ko) * | 2007-12-12 | 2010-05-27 | 주식회사 에너세라믹 | 리튬 이차 전지용 양극 활물질 및 이를 포함하는 리튬 이차전지 |
KR100999563B1 (ko) * | 2008-01-14 | 2010-12-08 | 한양대학교 산학협력단 | 리튬 이차 전지용 양극 활물질, 이의 제조방법, 및 이를포함하는 리튬 이차 전지 |
KR101110922B1 (ko) * | 2008-02-04 | 2012-03-13 | 파나소닉 주식회사 | 리튬 함유 천이금속 산화물의 제조방법 |
TWI397506B (zh) * | 2008-04-03 | 2013-06-01 | Lg Chemical Ltd | 鋰過渡金屬氧化物製備用之前驅物 |
HUE060257T2 (hu) * | 2008-04-03 | 2023-02-28 | Lg Energy Solution Ltd | Új prekurzor lítium kompozit átmenetifém-oxid elõállítására |
KR100959589B1 (ko) * | 2008-04-03 | 2010-05-27 | 주식회사 엘지화학 | 리튬 복합 전이금속 산화물 제조용 신규 전구체 |
CN102119457A (zh) * | 2008-09-03 | 2011-07-06 | 住友大阪水泥股份有限公司 | 电极材料的制造方法、电极材料及电极、以及电池 |
CN102203988A (zh) * | 2009-04-03 | 2011-09-28 | 松下电器产业株式会社 | 锂离子二次电池用正极活性物质及其制造方法以及锂离子二次电池 |
US20120176097A1 (en) * | 2009-09-18 | 2012-07-12 | Hideharu Takezawa | Method for charging/discharging positive electrode active material in a lithium secondary battery, charging/discharging system provided with lithium secondary battery and vehicle, electronic device, battery module, battery pack |
KR101217453B1 (ko) * | 2009-12-24 | 2013-01-02 | 제이에이치화학공업(주) | 리튬이차전지 양극활물질용 전구체인 니켈계 복합금속수산화물 및 그 제조방법 |
CN102306776A (zh) * | 2011-08-26 | 2012-01-04 | 北大先行科技产业有限公司 | 一种锂离子电池正极材料的制备方法 |
JP5863065B2 (ja) * | 2011-12-09 | 2016-02-16 | 株式会社Gsユアサ | 非水電解質二次電池用活物質、非水電解質二次電池用電極及び非水電解質二次電池 |
KR101497909B1 (ko) * | 2012-05-04 | 2015-03-03 | 주식회사 엘지화학 | 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법 |
KR20130125124A (ko) * | 2012-05-08 | 2013-11-18 | 한국과학기술연구원 | 리튬이차전지용 나노복합체 양극 활물질을 제조하는 방법 |
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2013
- 2013-07-03 WO PCT/KR2013/005903 patent/WO2014010862A1/fr active Application Filing
- 2013-07-03 BR BR112014031358A patent/BR112014031358B8/pt active IP Right Grant
- 2013-07-03 KR KR20130077800A patent/KR101490852B1/ko active IP Right Grant
- 2013-07-03 JP JP2015515958A patent/JP6072235B2/ja active Active
- 2013-07-03 PL PL13816829T patent/PL2871161T3/pl unknown
- 2013-07-03 IN IN10250DEN2014 patent/IN2014DN10250A/en unknown
- 2013-07-03 CN CN201380031477.XA patent/CN104364201B/zh active Active
- 2013-07-03 EP EP13816829.9A patent/EP2871161B1/fr active Active
- 2013-07-05 TW TW102124125A patent/TWI464948B/zh active
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2014
- 2014-09-16 KR KR1020140122747A patent/KR20140130376A/ko active Search and Examination
- 2014-12-03 US US14/559,155 patent/US9966600B2/en active Active
Non-Patent Citations (14)
Title |
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ALCANTARA R ET AL: "STRUCTURAL AND ELECTROCHEMICAL STUDY OF NEW LINI0.5TIXMN1.5-XO4 SPINEL OXIDES FOR 5-V CATHODE MATERIALS", CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, US, vol. 15, no. 12, 17 June 2003 (2003-06-17), pages 2376 - 2382, XP001233332, ISSN: 0897-4756, DOI: 10.1021/CM034080S * |
B. LEON ET AL: "Structure and Lithium Extraction Mechanism in LiNi0.5Mn1.5O4 after Double Substitution with Iron and Titanium", ELECTROCHEMICAL AND SOLID-STATE LETTERS., vol. 9, no. 2, 1 February 2006 (2006-02-01), US, pages A96 - A100, XP055237467, ISSN: 1099-0062, DOI: 10.1149/1.2154374 * |
DONG WOOK SHIN ET AL: "Role of Cation Ordering and Surface Segregation in High-Voltage Spinel LiMn 1.5 Ni 0.5- x M x O 4 (M = Cr, Fe, and Ga) Cathodes for Lithium-Ion Batteries", CHEMISTRY OF MATERIALS, vol. 24, no. 19, 6 July 2012 (2012-07-06), US, pages 3720 - 3731, XP055237342, ISSN: 0897-4756, DOI: 10.1021/cm301844w * |
FEY G T-K ET AL: "Preparation and electrochemical properties of high-voltage cathode materials, LiMyNi0.5-yMn1.5O4 (M=Fe, Cu, Al, Mg; y=0.0-0.4)", JOURNAL OF POWER SOURCES, ELSEVIER SA, CH, vol. 115, no. 2, 10 April 2003 (2003-04-10), pages 332 - 345, XP004416034, ISSN: 0378-7753, DOI: 10.1016/S0378-7753(03)00010-7 * |
G.B. ZHONG ET AL: "Structural, electrochemical and thermal stability investigations on LiNi0.5-xAl2xMn1.5-xO4 (0 <= 2x <= 1.0) as 5 V cathode materials", JOURNAL OF POWER SOURCES, vol. 216, 6 June 2012 (2012-06-06), pages 368 - 375, XP055210071, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2012.05.108 * |
J.-H. KIM ET AL: "Effect of Ti Substitution for Mn on the Structure of LiNi[sub 0.5]Mn[sub 1.5-x]Ti[sub x]O[sub 4] and Their Electrochemical Properties as Lithium Insertion Material", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 151, no. 11, 22 October 2004 (2004-10-22), pages A1911, XP055210067, ISSN: 0013-4651, DOI: 10.1149/1.1805524 * |
M-H LEE ET AL: "Synthetic optimization of Li[Ni1/3Co1/3Mn1/3]O2 via co-precipitation", ELECTROCHIMICA ACTA, ELSEVIER SCIENCE PUBLISHERS, BARKING, GB, vol. 50, 1 January 2004 (2004-01-01), pages 939 - 948, XP002633595, ISSN: 0013-4686, [retrieved on 20040911], DOI: 10.1016/J.ELECTACTA.2004.07.038 * |
MING-CHE YANG ET AL: "Electronic, Structural, and Electrochemical Properties of LiNi x Cu y Mn 2- x - y O 4 (0 < x < 0.5, 0 < y < 0.5) High-Voltage Spinel Materials", CHEMISTRY OF MATERIALS, vol. 23, no. 11, 14 June 2011 (2011-06-14), US, pages 2832 - 2841, XP055237343, ISSN: 0897-4756, DOI: 10.1021/cm200042z * |
NOGUCHI T ET AL: "Effect of Bi oxide surface treatment on 5V spinel LiNi0.5Mn1.5-xTixO4", JOURNAL OF POWER SOURCES, ELSEVIER SA, CH, vol. 174, no. 2, 6 December 2007 (2007-12-06), pages 359 - 365, XP025917567, ISSN: 0378-7753, [retrieved on 20071206], DOI: 10.1016/J.JPOWSOUR.2007.06.139 * |
See also references of WO2014010862A1 * |
T. A. ARUNKUMAR ET AL: "Influence of Lattice Parameter Differences on the Electrochemical Performance of the 5 V Spinel LiMn[sub 1.5-y]Ni[sub 0.5-z]M[sub y+z]O[sub 4] (M=Li, Mg, Fe, Co, and Zn)", ELECTROCHEMICAL AND SOLID-STATE LETTERS., vol. 8, no. 8, 1 January 2005 (2005-01-01), US, pages A403, XP055237501, ISSN: 1099-0062, DOI: 10.1149/1.1945369 * |
YAIR EIN-ELI ET AL: "LiNi x Cu0.5?-?x Mn1.5?O?4 Spinel Electrodes, Superior High-Potential Cathode Materials for Li Batteries: I. Electrochemical and Structural Studies", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 146, 1 January 1999 (1999-01-01), pages 908 - 913, XP055237334, DOI: 10.1149/1.1391699 * |
ZHONG G B ET AL: "Effects of Al substitution for Ni and Mn on the electrochemical properties of LiNiMnO", ELECTROCHIMICA ACTA, ELSEVIER SCIENCE PUBLISHERS, BARKING, GB, vol. 56, no. 18, 27 March 2011 (2011-03-27), pages 6554 - 6561, XP028230382, ISSN: 0013-4686, [retrieved on 20110401], DOI: 10.1016/J.ELECTACTA.2011.03.093 * |
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Publication number | Publication date |
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EP2871161B1 (fr) | 2019-03-13 |
JP2015523955A (ja) | 2015-08-20 |
IN2014DN10250A (fr) | 2015-08-07 |
JP6072235B2 (ja) | 2017-02-01 |
KR20140130376A (ko) | 2014-11-10 |
KR20140007748A (ko) | 2014-01-20 |
EP2871161A1 (fr) | 2015-05-13 |
PL2871161T3 (pl) | 2019-08-30 |
WO2014010862A1 (fr) | 2014-01-16 |
KR101490852B1 (ko) | 2015-02-09 |
US20150090926A1 (en) | 2015-04-02 |
TWI464948B (zh) | 2014-12-11 |
BR112014031358B8 (pt) | 2023-01-17 |
US9966600B2 (en) | 2018-05-08 |
BR112014031358A2 (pt) | 2017-06-27 |
CN104364201B (zh) | 2017-04-12 |
CN104364201A (zh) | 2015-02-18 |
TW201419638A (zh) | 2014-05-16 |
BR112014031358B1 (pt) | 2021-08-24 |
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