EP2851455B1 - Procédé de fabrication d'un revêtement anti-usure - Google Patents

Procédé de fabrication d'un revêtement anti-usure Download PDF

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Publication number
EP2851455B1
EP2851455B1 EP14179103.8A EP14179103A EP2851455B1 EP 2851455 B1 EP2851455 B1 EP 2851455B1 EP 14179103 A EP14179103 A EP 14179103A EP 2851455 B1 EP2851455 B1 EP 2851455B1
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EP
European Patent Office
Prior art keywords
particles
electrolyte
component
metal alloy
material particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP14179103.8A
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German (de)
English (en)
Other versions
EP2851455A1 (fr
Inventor
André Werner
Josef Linska
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MTU Aero Engines AG
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MTU Aero Engines AG
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Publication date
Application filed by MTU Aero Engines AG filed Critical MTU Aero Engines AG
Publication of EP2851455A1 publication Critical patent/EP2851455A1/fr
Application granted granted Critical
Publication of EP2851455B1 publication Critical patent/EP2851455B1/fr
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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/09Mixtures of metallic powders
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/058Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/07Alloys based on nickel or cobalt based on cobalt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C27/00Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/06Alloys based on chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/12Electroplating: Baths therefor from solutions of nickel or cobalt
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/56Electroplating: Baths therefor from solutions of alloys
    • C25D3/562Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces
    • C25D5/50After-treatment of electroplated surfaces by heat-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/05Light metals
    • B22F2301/052Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/15Nickel or cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/20Refractory metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12014All metal or with adjacent metals having metal particles
    • Y10T428/12028Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y10T428/12049Nonmetal component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12014All metal or with adjacent metals having metal particles
    • Y10T428/12028Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y10T428/12049Nonmetal component
    • Y10T428/12056Entirely inorganic

Definitions

  • the heat treatment is carried out under vacuum, wherein component and electrodeposited layer can be homogeneously exposed to the corresponding temperature together.
  • a local heating of the electrodeposited layer by a surface heating can be made.
  • the invention provides the possibility of creating a wear protection coating which is suitable in particular for turbomachinery and has an MCrAl matrix with embedded hard material particles and lubricant particles, which can be applied uniformly to a component even in hard-to-reach places without undue, in particular inhomogeneous temperature loads.
  • the electrolyte is brought to a temperature of 30 ° C to 70 ° C and kept in motion by suitable stirrers or the like, so that the dispersed first and second particles 1, 2 are uniformly distributed in the electrolyte 3.
  • the Fig. 2 shows the electrolyte bath Fig. 1 in a galvanic deposition of a wear protection coating according to the invention on a component 4.
  • the component is connected as a cathode to a power supply 6, while an additional anode 5 is arranged in the electrolyte bath.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Coating By Spraying Or Casting (AREA)

Claims (10)

  1. Procédé de fabrication d'un revêtement anti-usure (10) sur un composant, en particulier un composant de turbomachine, le procédé comprenant les étapes suivantes :
    - la fourniture d'un électrolyte (3) contenant du Co et/ou du Ni,
    - la dispersion de premières particules (1) dans les électrolytes, les premières particules comprenant des particules de matériau dur et des particules de lubrifiant et possédant une enveloppe métallique, en particulier une enveloppe comprenant ou formée de Ni et/ou de Co,
    - la dispersion de secondes particules (2) dans les électrolytes, les secondes particules comprenant des particules d'alliage métallique dans lesquelles l'alliage métallique possède du chrome et de l'aluminium,
    - la fourniture du composant (4) devant faire l'objet d'un revêtement dans un bain d'électrolyte qui est dispersé avec des première et seconde particules,
    - le dépôt galvanique d'une matrice de Co et/ou de Ni avec des particules d'alliage métallique incorporées (2) et des particules de matériau dur incorporées et des particules de lubrifiant (1) sur le composant, et
    - le traitement thermique du composant sous vide.
  2. Procédé selon la revendication 1, caractérisé en ce que le traitement thermique est effectué à une température de 950 °C à 1 200 °C, en particulier de 1 000 °C à 1 150 °C, pendant 2 à 20 heures, en particulier pendant 5 à 15 heures.
  3. Procédé selon la revendication 1 ou 2, caractérisé en ce que l'électrolyte (3) comprend du NiSO4 et/ou du CoSO4.
  4. Procédé selon l'une des revendications précédentes, caractérisé en ce que l'électrolyte (3) comprend du NaCl et/ou du H3BO3.
  5. Procédé selon l'une des revendications précédentes, caractérisé en ce que l'alliage métallique des particules d'alliage métallique (2) possède une composition qui est choisie dans le groupe comprenant CrAl, CrAlY, CrAlHf, CrAlYHf, CrAlTa, CrAlYTa, CrAlSi, MoCrSiAl, CrCoAl, CrNiAl et les alliages avec Cr et Al, comprenant au moins un ou plusieurs éléments choisis parmi Y, Hf, Ta, Si, Mo, Ni et Co.
  6. Procédé selon l'une des revendications précédentes, caractérisé en ce que les première et seconde particules (1, 2) sont chacune pourvues d'une proportion de 50 g/l à 300 g/l dans l'électrolyte.
  7. Procédé selon l'une des revendications précédentes, caractérisé en ce que les premières particules (1) ont une granulométrie maximale ou moyenne inférieure ou égale à 10 µm, en particulier comprise entre 1 µm et 5 µm.
  8. Procédé selon l'une des revendications précédentes, caractérisé en ce que les secondes particules (2) ont une granulométrie maximale ou moyenne inférieure ou égale à 15 µm, en particulier comprise entre 1 µm et 5 µm.
  9. Procédé selon l'une des revendications précédentes, caractérisé en ce que les particules de lubrifiant (1) comprennent un lubrifiant solide, en particulier du nitrure de bore hexagonal.
  10. Procédé selon l'une des revendications précédentes, caractérisé en ce que les particules de matériau dur (1) comprennent des oxydes, en particulier de l'oxyde de chrome ou de l'oxyde de zirconium.
EP14179103.8A 2013-09-18 2014-07-30 Procédé de fabrication d'un revêtement anti-usure Active EP2851455B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102013218687.8A DE102013218687A1 (de) 2013-09-18 2013-09-18 Galvanisch hergestellte Verschleißschutzbeschichtung und Verfahren hierfür

Publications (2)

Publication Number Publication Date
EP2851455A1 EP2851455A1 (fr) 2015-03-25
EP2851455B1 true EP2851455B1 (fr) 2019-03-13

Family

ID=51292808

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14179103.8A Active EP2851455B1 (fr) 2013-09-18 2014-07-30 Procédé de fabrication d'un revêtement anti-usure

Country Status (3)

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US (1) US10428437B2 (fr)
EP (1) EP2851455B1 (fr)
DE (1) DE102013218687A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11859499B2 (en) 2015-11-10 2024-01-02 Oerlikon Surface Solutions Ag, Pfäffikon Turbine clearance control coatings and method
EP3385406B1 (fr) * 2015-12-01 2021-01-20 IHI Corporation Composant coulissant pourvu d'un revêtement résistant à l'usure et procédé de formation d'un revêtement résistant à l'usure
DE102016221871A1 (de) * 2016-11-08 2018-05-09 Siemens Aktiengesellschaft Gasturbinenbauteil und Verfahren zum Herstellen eines erosionsgeschützten Gasturbinenbauteils
FR3085172B1 (fr) * 2018-08-22 2021-03-05 Safran Aircraft Engines Revetement abradable pour aubes tournantes d'une turbomachine
CN110396710B (zh) * 2019-08-08 2020-10-09 温州中牙模具有限公司 一种耐磨搓丝板及其生产工艺

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US20070227299A1 (en) * 2005-12-22 2007-10-04 Momentive Performance Materials Inc. Wear Resistant Low Friction Coating Composition, Coated Components, and Method for Coating Thereof
US20120099971A1 (en) * 2010-10-25 2012-04-26 United Technologies Corporation Self dressing, mildly abrasive coating for clearance control

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US20120099971A1 (en) * 2010-10-25 2012-04-26 United Technologies Corporation Self dressing, mildly abrasive coating for clearance control

Also Published As

Publication number Publication date
DE102013218687A1 (de) 2015-04-02
US10428437B2 (en) 2019-10-01
US20150075327A1 (en) 2015-03-19
EP2851455A1 (fr) 2015-03-25

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