EP2823916B1 - Procédé de fabrication d'une pièce moulée composite - Google Patents
Procédé de fabrication d'une pièce moulée composite Download PDFInfo
- Publication number
- EP2823916B1 EP2823916B1 EP13175828.6A EP13175828A EP2823916B1 EP 2823916 B1 EP2823916 B1 EP 2823916B1 EP 13175828 A EP13175828 A EP 13175828A EP 2823916 B1 EP2823916 B1 EP 2823916B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- producing
- casting
- insert
- composite cast
- exothermic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005266 casting Methods 0.000 title claims description 64
- 239000002131 composite material Substances 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title description 7
- 239000000463 material Substances 0.000 claims description 87
- 238000000034 method Methods 0.000 claims description 32
- 229910000831 Steel Inorganic materials 0.000 claims description 22
- 239000010959 steel Substances 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910001018 Cast iron Inorganic materials 0.000 claims description 6
- 229910000838 Al alloy Inorganic materials 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000003466 welding Methods 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 229910001369 Brass Inorganic materials 0.000 claims description 2
- 229910000906 Bronze Inorganic materials 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 2
- 239000010951 brass Substances 0.000 claims description 2
- 239000010974 bronze Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 2
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 2
- 229910052681 coesite Inorganic materials 0.000 claims 1
- 229910052906 cristobalite Inorganic materials 0.000 claims 1
- 238000005538 encapsulation Methods 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 229910052682 stishovite Inorganic materials 0.000 claims 1
- 229910052905 tridymite Inorganic materials 0.000 claims 1
- 239000011248 coating agent Substances 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 229910001208 Crucible steel Inorganic materials 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000012778 molding material Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000007712 rapid solidification Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000677 High-carbon steel Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/04—Casting in, on, or around objects which form part of the product for joining parts
Definitions
- the invention relates to a method for producing a composite casting comprising an insert part and casting material, wherein the insert part is connected in a material-locking manner to the cast material according to the preamble of claim 1.
- the DE 10 2006 041 901 A1 discloses a method for producing metal composite parts from steel and / or cast iron.
- the einzug manende part which is made of steel or cast iron, coated by flux.
- the coating aims at a reduction, that is to say that during the pouring, the oxide skin of the casting is dissolved and washed away, as a result of which the casting material can undergo a metallurgical bond.
- the DE 10 2011 053 858 B3 discloses a method of using a pourable component in a lost mold, wherein a coating agent is applied to a surface of the inflowing component.
- the coating agent forms a separation-active surface, which prevents adhesion of the material to the component as well as corrosion before casting with casting material.
- the DE 100 43 105 B4 discloses a method of forming a tough, resilient and / or at least substantially defect free bond between an insert and a cast metal material having a melting point below that of the feedstock.
- the insert is coated with a thin layer of a metallic material derived from the group of silver, antimony, bismuth, chromium, gold, lead, magnesium, silicon, tin, titanium and zinc. This is followed by casting of the casting material against the coated surface of the insert.
- the thermal expansion coefficient of the coating is greater than that of the insert and less than that of the casting material.
- the coated insert is also maintained at a temperature of at least 100 ° C for a period of at least 5 minutes.
- the EP 0 659 899 A1 finally also discloses a method for producing a composite casting with all the technical features of the preamble of claim 1.
- Object of the present invention is to provide a method and a corresponding composite casting, which achieved over the prior art, an improved bond between an insert and casting material, and ensures economic production.
- the sheathing or embedding of the insert is formed by an exothermic material which ignites by contacting with the inflowing casting material or by reaching the ignition temperature whereby the temperature gradient between solidifying melt and the insert is reduced after casting and demolding, the exothermic material is removed, the surface (s) of the insert covered by the exothermic material being / are free of casting material.
- This energy is released and released to the environment, resulting in a reduced temperature gradient between the solidifying melt and the insert.
- Exothermic materials are used in addition to the use in welding (Thermitsch Stammsgemische) in exothermic feeders in the foundry. Upon contact of the melt with the exothermic mass, a combustion reaction is triggered, which ensures in the feeder that there is the last solidifying melt and so that the changing volume during solidification in the casting can be compensated.
- Such materials are known in the art, which EP 1 050 354 A1 .
- EP 0 888 199 B1 and DE 196 42 838 A1 reveal such.
- such a known material causing an exothermic reaction is used as a sheath for the inflowing insert.
- the material ignites.
- the insert is heated from both sides, which prevents rapid solidification of the casting material in the border region to the insert, since the insert loses its quenching effect for the casting material.
- the temperature gradient between casting material and insert is minimized. This, in turn, promotes carbon diffusion between the casting material and the insert, whereby a cohesive or metallurgical bond can be produced.
- the insert is preferably made of steel, copper, bronze, brass, aluminum or an aluminum alloy.
- the process or the composite casting is versatile due to the wide choice of materials.
- the exothermic material preferably has an easily oxidizable metal, in particular aluminum and / or magnesium.
- the exothermic material has an oxidizing agent for the readily oxidizable metal, in particular iron (III) oxide.
- the backfill material used is preferably an oxide, in particular SiO 2 .
- the backfill material serves as a filling material, which is mixed with the other substances such as aluminum and / or magnesium and an oxidizing agent.
- the exothermic material preferably comprises a binder which serves the cohesion of the exothermic material.
- the preferred binder is an alkali silicate in use.
- a preferred embodiment is that a cast iron is used as the casting material, preferably GJS, GJL and / or GJV.
- a cast iron is used as the casting material, preferably GJS, GJL and / or GJV.
- a high strength and elongation at break can be achieved at designated locations in the cast component, or additional, positive properties for a subsequent further treatment can be given to the composite cast component.
- an aluminum alloy is used as the casting material, thereby, for example, aluminum components can be combined with various metallic materials, whereby the advantage of the weight reduction can be used by the light aluminum.
- the inventive method is used with lost molds.
- a hollow body is used as an insert.
- the cavity fills with the casting material and connects cohesively with the insert.
- the outer surface of the insert is coated with the exothermic material or embedded in the material. Due to the exothermic reaction of the mass after contact with the melt, the mass also gives off heat to the insert, resulting in a unified temperature gradient between the solidifying melt and the insert.
- the insert can also be unilaterally, or in hollow execution from the inside with the exothermic material in combination.
- the exothermic material can be easily removed and the outer surface or inner surface of the insert emerges.
- Post-processing is then possible, but in some cases not necessary because the dimensional accuracy and the surface finish are already of good quality.
- the inventive method is economically highly interesting. Furthermore, these methods provide extended possibilities to after-treat the cast component, such as e.g. Welding or heat treatment (even partially on the insert).
- Such composite castings produced by the method according to the invention are particularly suitable for general mechanical engineering, construction machinery and vehicle construction. It can thereby different materials economically combined with each other and the preferred properties of the individual materials are combined with each other, without the problem of insufficient connection of the materials by early solidification of the casting material occurs.
- Fig. 1 shows a partial section of a mold in which a composite casting 1 was shed.
- the casting material 2 flows into the casting mold formed by the molding material 5 in which an insert 3 is inserted in order to form a cohesive or metallurgical bond with the casting material 2.
- the casting material 2 preferably GJS, GJL or GJV, flows into the casting mold formed by the molding material 5.
- the exothermic material 4 At the points where the casting material 2 touches the exothermic material 4, this ignites, whereby heat is released to the environment.
- the insert is thereby heated and the temperature gradient between the solidifying melt and the insert is reduced.
- the carbon diffusion between casting material 2, which directly touches the insert 3, and the insert 3 is driven forward.
- a cohesive or metallurgical connection at the direct contact points between insert 3 and casting material 2 is achieved.
- the exothermic material 4 can be easily removed from the insert 3.
- the area covered by the exothermic material 4 / n of the insert 3 is free of casting material, thus a reworking of the surface of the insert is not necessarily necessary, which in turn makes the inventive method economically very interesting.
- FIG. 2-4 Another embodiment is by the Fig. 2-4 demonstrated.
- a cylindrical steel tube made of a high-carbon steel with wall thicknesses of 5 mm is used and molded into exothermic material 4 with a defined wall thickness.
- This steel pipe 3 with surrounding exothermic material 4 is inserted into the mold 5 to be cast as from Fig. 2 seen.
- the closed mold 5 is filled with melt 2 for producing a GJS, wherein the interior of the steel pipe 3 is flowed through by melt 2 and a Part of the exothermic material has 4 direct melt contact. After the ignition temperature of the exothermic material 4 is reached, this gives off heat to the environment and the steel pipe 3. This is greatly heated and the temperature gradient between the steel pipe 3 and solidifying melt 2 is reduced.
Claims (12)
- Procédé de fabrication d'une pièce coulée composite (1), contenant un insert (3) et un matériau de coulée (2), l'insert (3) étant relié par accouplement de matière avec le matériau de coulée (2) et le procédé comprenant les étapes suivantes :la fabrication de l'insert (3),l'habillage ou l'enrobage de l'insert,l'insertion de l'insert habillé/enrobé dans le moule pour la coulée,le remplissage du moule avec une masse fondue,caractérisé en ce que l'habillage/l'enrobage de l'insert est formé par un matériau exothermique (4) qui s'allume au contact avec le matériau de coulée affluent ou lorsque la température d'allumage de la masse exothermique est atteinte, le gradient de température entre la masse fondue qui se solidifie et l'insert (3) étant ainsi réduit, le matériau exothermique (4) étant éliminé après la coulée et le démoulage, la ou les surfaces de l'insert recouvertes par le matériau exothermique (4) étant exemptes du matériau de coulée (2).
- Procédé de fabrication d'une pièce coulée composite (1) selon la revendication 1, caractérisé en ce que l'insert (3) est constitué par de l'acier, du cuivre, du bronze, du laiton, de l'aluminium ou un alliage d'aluminium.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications 1 ou 2, caractérisé en ce que le matériau exothermique (4) comprend un métal facilement oxydable, notamment l'aluminium et/ou le magnésium.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que le matériau exothermique (4) comprend un oxydant pour le métal facilement oxydable, notamment l'oxyde de fer (III).
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que le matériau exothermique (4) comprend un matériau de garnissage, de préférence un oxyde.
- Procédé de fabrication d'une pièce coulée composite (1) selon la revendication 5, caractérisé en ce que l'oxyde est de préférence SiO2.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que le matériau exothermique (4) comprend un liant, de préférence un silicate alcalin.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que le matériau de coulée (2) est une fonte, notamment GJS, GJL et/ou GJV.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que le matériau de coulée (2) est un alliage d'aluminium.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que le moule pour la coulée (5) est un moule pour la coulée perdu.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que la pièce coulée composite (1) peut être soumise au moins au niveau de l'insert (3) à un traitement thermique ou à un procédé de soudage.
- Procédé de fabrication d'une pièce coulée composite (1) selon l'une quelconque des revendications précédentes, caractérisé en ce que l'insert (3) est un corps creux ou une pièce de forme libre.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13175828.6A EP2823916B1 (fr) | 2013-07-10 | 2013-07-10 | Procédé de fabrication d'une pièce moulée composite |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13175828.6A EP2823916B1 (fr) | 2013-07-10 | 2013-07-10 | Procédé de fabrication d'une pièce moulée composite |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2823916A1 EP2823916A1 (fr) | 2015-01-14 |
EP2823916B1 true EP2823916B1 (fr) | 2018-12-26 |
Family
ID=48748015
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP13175828.6A Active EP2823916B1 (fr) | 2013-07-10 | 2013-07-10 | Procédé de fabrication d'une pièce moulée composite |
Country Status (1)
Country | Link |
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EP (1) | EP2823916B1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102016104351B4 (de) | 2016-03-10 | 2018-08-23 | Knorr-Bremse Systeme für Nutzfahrzeuge GmbH | Aus Gusseisen bestehender Bremssattel einer Scheibenbremse sowie Verfahren zur Herstellung eines Bremssattels |
CN108262466A (zh) * | 2017-12-13 | 2018-07-10 | 浙江灿根智能科技有限公司 | 一种双金属铸造工艺 |
CN114029450A (zh) * | 2021-11-10 | 2022-02-11 | 北京星航机电装备有限公司 | 一种轻合金铸造内嵌管路组件及其制备方法和带内嵌管路的轻合金件的铸造方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3433282A (en) * | 1965-12-14 | 1969-03-18 | Us Army | Method for eliminating hot tear cracks in castings |
JPS57187159A (en) * | 1981-05-13 | 1982-11-17 | Mitsubishi Heavy Ind Ltd | Formation of surface coating layer |
JPS5953641A (ja) * | 1982-09-20 | 1984-03-28 | Toyota Motor Corp | 発熱反応を利用した複合材料の製造方法 |
JPS60174244A (ja) * | 1984-02-21 | 1985-09-07 | Mitsubishi Heavy Ind Ltd | 複合鋳物の製造法 |
US5429173A (en) * | 1993-12-20 | 1995-07-04 | General Motors Corporation | Metallurgical bonding of metals and/or ceramics |
BR9601454C1 (pt) | 1996-03-25 | 2000-01-18 | Paulo Roberto Menon | Processo para produção de luvas exotérmicas e isolantes. |
DE19642838A1 (de) | 1996-10-17 | 1997-07-31 | Daimler Benz Ag | Speiser für ein metallisches Gußwerkstück |
DE19650056A1 (de) * | 1996-12-03 | 1998-06-04 | Thyssen Guss Ag | Verfahren zur Herstellung einer Bremsscheibe, insbesondere als Achs- oder Radbremsscheibe für Schienenfahrzeuge |
DE19920570B4 (de) | 1999-05-04 | 2008-01-10 | Chemex Gmbh | Formbare exotherme Zusammensetzungen und Speiser daraus |
DE19920802A1 (de) * | 1999-05-06 | 2000-11-09 | Ks Aluminium Technologie Ag | Giessverfahren unter Verwendung eines Precursorkörpers |
US6484790B1 (en) | 1999-08-31 | 2002-11-26 | Cummins Inc. | Metallurgical bonding of coated inserts within metal castings |
DE102006041901A1 (de) | 2006-09-07 | 2008-03-27 | Daimler Ag | Eingussverfahren zur Herstellung von metallischen Verbundbauteilen |
DE102007059771A1 (de) * | 2007-12-12 | 2009-06-18 | Daimler Ag | Eingussteile mit Konditionierungsschicht zum Eingießen in Leichtmetalle |
DE102011053858B3 (de) | 2011-09-22 | 2013-03-14 | Preiss Metallwaren Gmbh & Co. Kg | Verfahren zur Anwendung eines eingießbaren Bauteils |
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2013
- 2013-07-10 EP EP13175828.6A patent/EP2823916B1/fr active Active
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EP2823916A1 (fr) | 2015-01-14 |
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