EP2780664A1 - Capteur extensométrique à réseau de bragg sur fibre pour surfaces courbes - Google Patents
Capteur extensométrique à réseau de bragg sur fibre pour surfaces courbesInfo
- Publication number
- EP2780664A1 EP2780664A1 EP12805923.5A EP12805923A EP2780664A1 EP 2780664 A1 EP2780664 A1 EP 2780664A1 EP 12805923 A EP12805923 A EP 12805923A EP 2780664 A1 EP2780664 A1 EP 2780664A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fbg
- plastic
- fastening elements
- sliding
- teflon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004033 plastic Substances 0.000 claims abstract description 23
- 229920003023 plastic Polymers 0.000 claims abstract description 23
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 239000013307 optical fiber Substances 0.000 claims abstract description 18
- 230000001681 protective effect Effects 0.000 claims abstract description 13
- 239000004809 Teflon Substances 0.000 claims abstract description 12
- 229920006362 Teflon® Polymers 0.000 claims abstract description 12
- 239000000853 adhesive Substances 0.000 claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 claims abstract description 11
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 10
- 239000004945 silicone rubber Substances 0.000 claims abstract description 10
- MEKOFIRRDATTAG-UHFFFAOYSA-N 2,2,5,8-tetramethyl-3,4-dihydrochromen-6-ol Chemical compound C1CC(C)(C)OC2=C1C(C)=C(O)C=C2C MEKOFIRRDATTAG-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000011888 foil Substances 0.000 claims description 26
- 239000000463 material Substances 0.000 description 42
- 238000005259 measurement Methods 0.000 description 17
- 239000002184 metal Substances 0.000 description 17
- 239000003365 glass fiber Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000012791 sliding layer Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L1/00—Measuring force or stress, in general
- G01L1/24—Measuring force or stress, in general by measuring variations of optical properties of material when it is stressed, e.g. by photoelastic stress analysis using infrared, visible light, ultraviolet
- G01L1/242—Measuring force or stress, in general by measuring variations of optical properties of material when it is stressed, e.g. by photoelastic stress analysis using infrared, visible light, ultraviolet the material being an optical fibre
- G01L1/246—Measuring force or stress, in general by measuring variations of optical properties of material when it is stressed, e.g. by photoelastic stress analysis using infrared, visible light, ultraviolet the material being an optical fibre using integrated gratings, e.g. Bragg gratings
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B11/00—Measuring arrangements characterised by the use of optical techniques
- G01B11/16—Measuring arrangements characterised by the use of optical techniques for measuring the deformation in a solid, e.g. optical strain gauge
- G01B11/18—Measuring arrangements characterised by the use of optical techniques for measuring the deformation in a solid, e.g. optical strain gauge using photoelastic elements
Definitions
- the present invention relates to an optical fiber strain sensor comprising a fiber Bragg grating, hereinafter called an FBG strain sensor.
- the invention is suitable for precisely measuring an elongation even on curved surfaces.
- a metal foil DMS consists essentially of a plastic carrier foil on which at least one thin meander-shaped metal foil strip over its entire area, i. H. with its entire surface, is attached. To detect the elongation, the plastic carrier film is glued to the material surface to be examined.
- the use of a plastic film as a sensor carrier is required because only with such an arrangement DMS can be applied defined. The electrically isolated application of the very thin metal foil without the relatively stable plastic film is impractical outside of laboratory conditions.
- FBG sensors Analogous to these metal foil DMS, FBG sensors have been developed, which have as an essential component a glass fiber with a fiber Bragg grating, hereinafter referred to as FBG.
- This glass fiber must also be attached to the material surface to be examined. This also causes problems in handling, because the glass fiber is thin and fragile. Therefore, a sensor carrier had to be developed to make the FBG sensor less sensitive to harsh field conditions. In documents JP 2003 279760 A and WO 2008/101657 A1, such sensory described. By embedding the sensitive fiber with the FBG in a soft plastic mass, the sensor has become manageable and thus practical.
- the FBG sensor described in the document WO 2008/101657 A1 has a two-point force introduction and thereby a substantially greater measurement accuracy than FBG sensors which are applied over the whole area. With this type of sensor, strains on flat surfaces can be precisely measured. In contrast to the metal foil DMS, however, problems occur in the measurement with FBG sensors on curved surfaces, which are explained with reference to FIGS. 1a to 1g.
- FIGS. 1a-1c show a conventional metal foil DMS adhered to a curved material surface, wherein FIG. 1a shows a perspective view of the curved material surface with a DMS application. 1 b shows the side view of FIG. 1 a, and FIG. 1 c shows an enlarged detail of FIG. 1 b.
- FIGS. 1d and 1e show, in longitudinal section and in cross-section, an FBG sensor mounted on a material according to the document WO 2008/101657 A1, which is constructed as follows: A glass fiber with an FBG is held between two rigid fastening elements and into a soft Plastic, z. As a silicone rubber, embedded. The two rigid fasteners are glued to the material surface to be examined. The soft plastic serves For example, to protect the provided with the FBG section of the glass fiber from disturbing forces, ie lateral forces and to improve the handling of the FBG sensor in the application as a whole. If an FBG sensor with this design is used to measure strain on a curved surface, however, effects occur that lead to larger measurement errors. The reasons for this will be explained below with reference to FIGS. 1f-1g.
- FIG. 1f shows the sensor applied on a curved material surface according to document WO 2008/101657 A1
- FIG. 1g shows how the glass fiber follows an expansion of the material surface.
- the elongation of the material surface is indicated by the double arrow in the material to be monitored.
- the distance between the two fasteners is increased by the lengths a + a, d. H.
- the fiber is stretched by the length 2a. Since the fiber is only clamped in the two fasteners, it is pulled towards the material surface, i. H. the plastic presses undefined on the FBG.
- this movement of the fiber the actual strain of the material surface is distorted transferred to the FBG, thereby a measurement error occurs, which is dependent on the radius of curvature of the material surface.
- an FBG sensor with an optical fiber having an FBG, fixed between two fastening elements The undersides of the fastening elements are designed as adhesive surfaces, which are glued to the material surface to be examined. Furthermore, the optical fiber and the fasteners are embedded in a protective compound of a soft silicone rubber or a plastic having comparable mechanical properties. The fiber is embedded between an upper and a lower thin sliding foil made of Teflon or a plastic with a comparable low coefficient of friction such as Teflon, wherein the underside of the lower sliding foil lies in a plane with the adhesive surfaces.
- the FBG sensor is fixed with an optical fiber having an FBG, between two fastening elements.
- the undersides of the fastening elements are designed as adhesive surfaces, which are glued to the material surface to be examined.
- the optical fiber and the fasteners are embedded in a protective composition of a soft silicone rubber or a plastic having comparable mechanical properties.
- the fiber is enclosed with a thin sliding tube of Teflon or a plastic with a comparable low coefficient of friction such as Teflon, wherein the outer lower surface line of the sliding tube is in a plane with the adhesive surfaces.
- An FBG sensor having the structure according to claim 1 or claim 2 also has a significantly lower measurement error on a curved surface than a sensor arrangement according to JP 2003 279760 A or WO 2008/101657 A1. This is due to two effects:
- the sliding tube is glued to the protective compound according to claim 4.
- the welding or bonding of the films together and the bonding of the films and the sliding tube with the protective compound prevent the films and the sliding tube can migrate by micro-movements. Such shifts can cause strains within the protective mass, which worsen the accuracy of measurement of the FBG. Such micro-movements occur both with periodically occurring mechanical forces and with temperature fluctuations.
- Fig. 1a shows a conventional metal foil DMS on a curved material surface.
- Fig. 1 b shows the side view of Fig. 1a.
- Fig. 1c shows an enlarged detail of Fig. 1 b.
- FIGS. 1d-1e show an FBG sensor in longitudinal and cross-section.
- Fig. 1f shows the FBG sensor according to Fig. 1d on a curved
- FIG. 1g shows the FBG sensor according to FIG. 1f expanding.
- FIG. 2a shows the longitudinal section of an FBG sensor according to FIG.
- FIG. 2b shows a first embodiment of the FBG sensor according to the invention in cross section.
- Fig. 2c shows a second embodiment of the FBG sensor according to the invention in cross section.
- Fig. 2d shows a third embodiment of the FBG sensor according to the invention in cross section.
- Fig. 2e shows a fourth embodiment of the FBG sensor according to the invention in cross section.
- Fig. 1a shows a perspective view of a conventional metal foil DMS 1 on a curved material surface 2, z.
- a metal foil strain gage 1 consists essentially of a plastic carrier foil 1a, on which at least one thin meander-shaped metal foil strip 1b is secured over its entire surface. To detect the elongation, the plastic carrier film 1a is adhered to the material surface 2.
- FIG. 1 b shows the side view of FIG. 1 a
- FIG. 1 c shows an enlarged detail of FIG. 1 b.
- the material expands, as shown in FIG. 1c with the expansion arrow A1
- this elongation is uniformly transferred to the carrier foil 1a due to the full-area adhesion
- the metal foil 1b is combined with the carrier foil 1a over the entire surface. 1b stretched.
- the material expansion of the material surface 2 is transferred to the metal foil strip 1b almost without any errors, which is illustrated by the extension arrow A2 of the same size. This almost error-free strain transfer applies to even surfaces as well as to curved surfaces.
- FIGS. 1d and 1e show in longitudinal and cross-section an FBG sensor 3 according to the document WO 2008/101657 A1, which is constructed as follows: A glass fiber 4 with an FBG 4a is held between two rigid fastening elements 5a, 5b and a soft plastic 6, z. As a silicone rubber, embedded. The two rigid fastening elements 5a, 5b are glued to the material surface 2 to be examined and may consist of interconnected phenol resin-impregnated glass fiber sheets. The soft silicone rubber 6 serves to expose the portion of the optical fiber 4 to the FBG 4a from disturbing forces, i. H. z. As lateral forces to protect and improve the handling of the FBG sensor 3 in the application. If forces F act on the material to be examined and the material and thus the flat material surface 2 expand by the lengths a + a, this elongation is likewise transmitted to the FBG sensor 3 almost error-free, as in the case of the metal foil strain gauge.
- forces F act on the material to be examined and the material and thus the flat material
- FIG. 1f shows the FBG sensor 3 applied on a curved material surface 2. Since the optical fiber 4 is very thin and thus very flexible and the silicone rubber 6 likewise adapts well to the radius of curvature of the material surface 2, FBG sensors 3 can be used with this structure in principle also apply well on strongly curved surfaces.
- Fig. 1g shows the situation when this material surface 2 expands, which is symbolized by the arrows below the curved material wall.
- the double arrow shows the elongation of the material surface.
- the fiber 4 is clamped only in the two fastening elements 5a, 5b, it moves towards the material surface and presses into the silicone rubber. This movement is symbolized by the little arrows.
- the transverse forces acting on the FBG 4a falsify the measurement result.
- this movement does not completely transfer the actual stretch of the material surface to the FBG 4a, thereby causing another measurement error that depends on the radius of curvature of the material surface. Therefore, it has been found that neither with a sensor according to JP 2003 279760 A, nor with a sensor according to WO 2008/101657 A1 accurate strain measurements on curved surfaces are possible.
- FIG. 2a shows the longitudinal section of the FBG sensor 3 according to the invention.
- the basic construction and the function of the FBG sensor 3 are described in conjunction with the cross-sectional illustration of FIG. 2b.
- the optical fiber 4 is bonded between the fastening elements 5a, 5b, and each fastening element is glued with its underside with the material surface 2. Furthermore, the optical fiber 4 is embedded between two sliding films 7 and 8. These two slides are z. B. Teflon, are welded together at their edges and form a plain bearing for the fiber 4.
- the in this case 0.15 mm thin sliding film 7 is located directly on the material surface 2, ie the bottom of the sliding film 7 is in the same plane as the adhesive surfaces of the fastening elements 5a, 5b. Since the sliding film 7 due to their nature and their small thickness compresses only negligibly when the fiber 4 is tensioned, the measurement error described in Fig. 1g does not occur or is negligible. Furthermore, since the fiber 4 Covered from above with a sliding film, no slip-stick effects occur due to the influence of the soft plastic 6.
- FIG. 2c shows that the soft plastic 6 projects beyond the edges of the sliding films 7, 8 and thus provides a very good seal against moisture, which could penetrate by capillary action under the sensor, which would lead to measurement errors in frost.
- a flexible tube 9 is used instead of the foils 7, 8. This is a preferred embodiment of the invention because it is easy and reliable to manufacture.
- plastics As a film and tubing all plastics come into question, which can be described as soft elastic and have a very smooth surface, such. As Teflon or silicones.
- two optical fibers 4 are glued in between the fastening elements 5a, 5b and embedded in the plastic 6.
- Such multiple sensors are used to z. B. to reduce the probability of failure of measuring chains.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Length Measuring Devices By Optical Means (AREA)
- Optical Transform (AREA)
Abstract
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011118526A DE102011118526A1 (de) | 2011-11-15 | 2011-11-15 | FBG-Dehnungssensor |
DE102011118525 | 2011-11-15 | ||
DE201110118527 DE102011118527A1 (de) | 2011-11-15 | 2011-11-15 | FBG-Dehnungssensor mit erweitertem Temperaturbereich |
PCT/DE2012/001095 WO2013071914A1 (fr) | 2011-11-15 | 2012-11-15 | Capteur extensométrique à réseau de bragg sur fibre pour surfaces courbes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2780664A1 true EP2780664A1 (fr) | 2014-09-24 |
EP2780664B1 EP2780664B1 (fr) | 2017-09-27 |
Family
ID=47429480
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12805923.5A Not-in-force EP2780664B1 (fr) | 2011-11-15 | 2012-11-15 | Capteur extensométrique à réseau de bragg sur fibre pour surfaces courbes |
Country Status (9)
Country | Link |
---|---|
US (1) | US10132700B2 (fr) |
EP (1) | EP2780664B1 (fr) |
JP (2) | JP6258860B2 (fr) |
KR (1) | KR102007058B1 (fr) |
CN (1) | CN104185772B (fr) |
DK (1) | DK2780664T3 (fr) |
ES (1) | ES2651674T3 (fr) |
PT (1) | PT2780664T (fr) |
WO (1) | WO2013071914A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3812646A1 (fr) * | 2019-10-21 | 2021-04-28 | Audi AG | Réservoir sous pression, système de surveillance d'un réservoir sous pression et véhicule automobile |
Families Citing this family (16)
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US9546689B2 (en) * | 2012-06-14 | 2017-01-17 | Aktiebolaget Skf | Machine arrangement |
CN105143853B (zh) * | 2013-05-14 | 2019-01-04 | 三菱重工业株式会社 | 粘接构造体及粘接状态检测方法 |
CN103453844A (zh) * | 2013-09-25 | 2013-12-18 | 天津亿利科能源科技发展股份有限公司 | 一种基于光纤光栅的柔性管道变形在线监测方法 |
KR101465156B1 (ko) * | 2013-10-01 | 2014-11-26 | 한국표준과학연구원 | 최대 변형률 측정을 위한 fbg 센서, 제조방법 및 사용방법 |
CN103867793B (zh) * | 2014-03-20 | 2015-10-28 | 大连理工大学 | 一种可控预张拉的光纤光栅应变箍夹持器系统 |
JP6272716B2 (ja) * | 2014-03-31 | 2018-01-31 | 株式会社熊谷組 | 成型型枠、及び、当該成型型枠を用いた光ファイバセンサの曲面取付部の形成方法 |
CN104848798B (zh) | 2015-06-08 | 2018-09-11 | 京东方科技集团股份有限公司 | 一种柔性显示器及柔性显示屏的弯曲状态检测方法 |
CN105179406B (zh) * | 2015-08-20 | 2017-06-16 | 哈尔滨工业大学 | 一种高温光纤传感器的胶封方法及装置 |
US10416004B2 (en) * | 2016-05-02 | 2019-09-17 | Mitsubishi Electric Corporation | Resin impregnation detection device, coil for rotating machine, and method for impregnating and molding resin of coil for rotating machine |
DE102016011610B3 (de) * | 2016-09-26 | 2018-08-09 | Hottinger Baldwin Messtechnik Gmbh | Anschweißbarer Dehnungssensor für gekrümmte Oberflächen |
DE102016014280B4 (de) * | 2016-11-30 | 2018-07-12 | Hottinger Baldwin Messtechnik Gmbh | Anschweißbare FBG-Dehnungssensoranordnung |
CN107941389A (zh) * | 2017-06-22 | 2018-04-20 | 南京纳铠生物医药科技有限公司 | 一种用于任意曲率表面的应力测量和可视化的系统及方法 |
CN108225207A (zh) * | 2017-12-27 | 2018-06-29 | 武汉华星光电半导体显示技术有限公司 | 柔性显示装置及柔性显示面板的弯曲状态量的获取方法 |
US10989865B2 (en) * | 2018-02-05 | 2021-04-27 | University Of Georgia Research Foundation, Inc | Stretchable fiber optic sensor |
GB2576167A (en) * | 2018-08-07 | 2020-02-12 | S360 Group B V | Sensing assembly for bearing and mounting method |
CN113359225B (zh) * | 2021-05-21 | 2022-10-25 | 西安交通大学 | 一种测量柱状材料外曲率的光纤传感器的制备与贴敷方法 |
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DE19724528B4 (de) * | 1997-06-11 | 2005-09-15 | Institut für Physikalische Hochtechnologie e.V. | Temperaturkompensiertes faseroptisches Bragg-Gitter |
US6768825B2 (en) * | 1998-05-06 | 2004-07-27 | Weatherford/Lamb, Inc. | Optical sensor device having creep-resistant optical fiber attachments |
US6317555B1 (en) * | 1998-05-06 | 2001-11-13 | Cidra Corporation | Creep-resistant optical fiber attachment |
KR20010080687A (ko) * | 1998-12-04 | 2001-08-22 | 추후제출 | 관으로 싸인 섬유 격자 |
JP2000193427A (ja) * | 1998-12-25 | 2000-07-14 | Ntt-Telecom Engineering Tokai Co Ltd | 光ファイバ構造体 |
JP2001296110A (ja) * | 2000-04-17 | 2001-10-26 | Ntt Advanced Technology Corp | 貼り付け型光ファイバセンサ |
DE10035538A1 (de) * | 2000-07-21 | 2002-02-07 | Bosch Gmbh Robert | Sensor |
US7369729B2 (en) * | 2001-09-13 | 2008-05-06 | Fujikura Ltd. | Optical fiber sheet and optical fiber sheet production method |
JP3811761B2 (ja) * | 2002-03-26 | 2006-08-23 | エヌ・ティ・ティ・アドバンステクノロジ株式会社 | ファイバ型ブラッググレーティング素子及びその製造方法 |
JP2005134199A (ja) * | 2003-10-29 | 2005-05-26 | Kyocera Corp | ファイバ型センサ及びそれを用いたセンシングシステム |
US7496247B2 (en) | 2004-05-20 | 2009-02-24 | National University Of Singapore | Plastic optical fiber sensor |
KR100724998B1 (ko) * | 2004-10-27 | 2007-06-04 | 가부시키가이샤 도모에가와 세이시쇼 | 광섬유 구조체 |
DE102007008464B4 (de) * | 2007-02-19 | 2012-01-05 | Hottinger Baldwin Messtechnik Gmbh | Optischer Dehnungsmessstreifen |
DE102009009367B4 (de) * | 2009-02-18 | 2018-01-11 | Schott Ag | Lichtleiter zur Übertragung von Strahlung sowie Herstellverfahren |
EP2412310A4 (fr) * | 2009-03-25 | 2013-04-24 | Seiko Mitachi | Feuille de fibre optique et capteur de mouvement corporel |
JP5433883B2 (ja) * | 2009-04-06 | 2014-03-05 | 学校法人 創価大学 | 光ファイバセンサ及びこれを備えた検出装置 |
DE102009016834A1 (de) | 2009-04-10 | 2010-10-14 | Hottinger Baldwin Messtechnik Gmbh | Optische Festader |
CN102597727B (zh) | 2009-04-22 | 2015-04-01 | 霍廷格·鲍德温测量技术有限责任公司 | 具有光纤布拉格光栅的光学应变仪 |
DE102009018300A1 (de) | 2009-04-22 | 2010-10-28 | Hottinger Baldwin Messtechnik Gmbh | Optische Dehnungsmessvorrichtung |
JP5300077B2 (ja) * | 2009-10-15 | 2013-09-25 | 日鐵住金溶接工業株式会社 | センサ及びそのセンサを用いた地震計 |
-
2012
- 2012-11-15 EP EP12805923.5A patent/EP2780664B1/fr not_active Not-in-force
- 2012-11-15 PT PT128059235T patent/PT2780664T/pt unknown
- 2012-11-15 DK DK12805923.5T patent/DK2780664T3/en active
- 2012-11-15 WO PCT/DE2012/001095 patent/WO2013071914A1/fr active Application Filing
- 2012-11-15 JP JP2014541536A patent/JP6258860B2/ja not_active Expired - Fee Related
- 2012-11-15 CN CN201280056371.0A patent/CN104185772B/zh not_active Expired - Fee Related
- 2012-11-15 KR KR1020147015858A patent/KR102007058B1/ko active IP Right Grant
- 2012-11-15 US US14/358,314 patent/US10132700B2/en not_active Expired - Fee Related
- 2012-11-15 ES ES12805923.5T patent/ES2651674T3/es active Active
-
2017
- 2017-09-22 JP JP2017182533A patent/JP6388990B2/ja not_active Expired - Fee Related
Non-Patent Citations (2)
Title |
---|
None * |
See also references of WO2013071914A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3812646A1 (fr) * | 2019-10-21 | 2021-04-28 | Audi AG | Réservoir sous pression, système de surveillance d'un réservoir sous pression et véhicule automobile |
Also Published As
Publication number | Publication date |
---|---|
KR102007058B1 (ko) | 2019-08-02 |
DK2780664T3 (en) | 2018-01-08 |
JP6388990B2 (ja) | 2018-09-12 |
WO2013071914A1 (fr) | 2013-05-23 |
ES2651674T3 (es) | 2018-01-29 |
JP2018021927A (ja) | 2018-02-08 |
CN104185772B (zh) | 2017-07-11 |
US20140311250A1 (en) | 2014-10-23 |
KR20140089434A (ko) | 2014-07-14 |
JP2014533366A (ja) | 2014-12-11 |
JP6258860B2 (ja) | 2018-01-10 |
EP2780664B1 (fr) | 2017-09-27 |
US10132700B2 (en) | 2018-11-20 |
PT2780664T (pt) | 2018-01-02 |
CN104185772A (zh) | 2014-12-03 |
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