EP2677068A1 - Procédé de traitement de surface d'un élément métallique et élément métallique ainsi obtenu - Google Patents
Procédé de traitement de surface d'un élément métallique et élément métallique ainsi obtenu Download PDFInfo
- Publication number
- EP2677068A1 EP2677068A1 EP12747582.0A EP12747582A EP2677068A1 EP 2677068 A1 EP2677068 A1 EP 2677068A1 EP 12747582 A EP12747582 A EP 12747582A EP 2677068 A1 EP2677068 A1 EP 2677068A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- anodic oxidation
- oxidation coating
- fluorine
- based polymer
- metal member
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/24—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/20—Electrolytic after-treatment
- C25D11/22—Electrolytic after-treatment for colouring layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/24—Chemical after-treatment
- C25D11/246—Chemical after-treatment for sealing layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/30—Anodisation of magnesium or alloys based thereon
Definitions
- the present invention relates to a surface treatment method for an anodizable metal member, and a metal member that is obtained by the surface treatment method and exhibits improved surface properties.
- the surface of a metal member produced using aluminum, an aluminum alloy, magnesium, a magnesium alloy, titanium, a titanium alloy, or the like is generally provided with an anodic oxidation coating in order to improve corrosion resistance, design, and the like.
- a metal member provided with only an anodic oxidation coating may exhibit insufficient corrosion resistance during long-term use.
- a metal member provided with only an anodic oxidation coating may also be easily contaminated.
- a coloring step e.g., secondary electrolytic coloring
- significant discoloration may occur due to insufficient corrosion resistance of the anodic oxidation coating.
- a clear coating has a thickness as large as 10 to 20 ⁇ m, the metal surface texture may be impaired.
- a transparent fluororesin coating that can provide corrosion resistance with a reduced thickness as compared with an acrylic clear coating or a urethane clear coating has been proposed.
- Patent Document 1 that aims at dealing with a wax remover discloses a technique that forms a polytetrafluoroethylene (PTFE) coating layer on the surface of an alumite coating.
- PTFE polytetrafluoroethylene
- Patent Document 1 states that it is appropriate that the thickness of the PTFE coating layer is 3 ⁇ m, a film-like surface texture is necessarily observed. Moreover, since Patent Document 1 states that it is necessary to apply a primer or enlarge the pores formed in the anodic oxidation coating, the process is complex, and the treatment cost increases.
- Patent Document 2 discloses immersing a metal material provided with an anodic oxidation coating in a solution that contains a hydrophilic amorphous fluororesin so that the amorphous fluororesin enters the pores formed in the anodic oxidation coating.
- a preliminary heat treatment it is necessary to perform a preliminary heat treatment in order to improve the quality, and polymerize the fluororesin layer on the anodic oxidation coating by heating at 200°C for 30 minutes.
- the coating layer disclosed in Patent Document 2 has a large thickness, and a film-like surface texture is necessarily observed. Moreover, cracks may occur in the anodic oxidation coating when the anodic oxidation coating is heated at a high temperature of 200°C.
- An object of the invention is to provide a surface treatment method that improves the surface properties of a metal member while maintaining the metal surface texture, and a metal member that is obtained by the surface treatment method.
- a surface-treated metal member that is obtained by bringing a solution of a fluorine-based polymer (hereinafter may be referred to as "fluorine-based polymer solution”) into contact with a surface of an anodic oxidation coating that is formed on a surface of a metal and has not been subjected to a sealing treatment, and subjecting the anodic oxidation coating to a steam sealing treatment, the surface-treated metal member comprising:
- An electrolytic coloring step may be performed after forming the anodic oxidation coating as long as the fluorine-based polymer solution is brought into contact with the anodic oxidation coating that has not been subjected to a sealing treatment, and the anodic oxidation coating is then subjected to the steam sealing treatment.
- a surface treatment method for a metal member comprising:
- the surface treatment method may further include subjecting the anodic oxidation coating to electrolytic coloring after forming the anodic oxidation coating, but before bringing the fluorine-based polymer solution into contact with the anodic oxidation coating.
- the surface-treated metal member according to one aspect of the invention is characterized by including the composite sealed layer that is formed by subjecting the anodic oxidation coating to the steam sealing treatment in a state in which the fluorine-based polymer is present inside the pores formed in the anodic oxidation coating from the viewpoint of maintaining the metal surface texture. It suffices that the fluorine-based polymer layer that is formed continuously over the composite sealed layer have a small thickness.
- the thickness of the fluorine-based polymer layer is adjusted to 100 nm or less, and preferably 10 nm or less, in order to prevent a situation in which the surface of the anodic oxidation coating has a film-like texture.
- the aspects of the invention are applied to a metal member on which a porous anodic oxidation coating can be formed.
- the aspects of the invention are mainly applied to a metal member formed of aluminum, magnesium, titanium, or an alloy thereof.
- the type of the anodic oxidation coating is not particularly limited as long as the anodic oxidation coating is porous.
- the metal member is anodized using a known electrolytic solution such as sulfuric acid or an organic acid.
- the expression "has not been subjected to a sealing treatment" used herein in connection with the anodic oxidation coating means that the anodic oxidation coating has not been subjected to the steam sealing treatment, and means that the anodic oxidation coating may have been washed with water, washed with hot water, or semi-sealed using hot water at 60 to 90°C.
- the anodic oxidation coating may have been washed with water, subjected to electrolytic coloring, and washed with water or hot water.
- electrolytic coloring refers to subjecting the anodic oxidation coating that has not been subjected to a sealing treatment to a DC electrolysis, AC electrolysis, or the like in an aqueous solution that includes metal ions (e.g., nickel ions or tin ions) to deposit the metal ions inside the pores formed in the anodic oxidation coating.
- metal ions e.g., nickel ions or tin ions
- steam sealing treatment refers to a sealing treatment that utilizes normal-pressure steam or pressurized steam.
- the fluorine-based polymer used in connection with the aspects of the invention is a fluorine-based polymer that has such a molecular weight that the fluorine-based polymer can be dissolved in a solvent to prepare a solution.
- fluorine-based polymer examples include polytetrafluoroethylene, a polytetrafluoroethylene copolymer such as an ethylene-tetrafluoroethylene copolymer, polyvinyl fluoride, a copolymer thereof, polyvinylidene fluoride, a copolymer thereof, polychlorotrifluoroethylene, a copolymer thereof, and the like.
- perfluoroalkyl group-containing fluorine-based polymer examples include a polyperfluoroalkyl (meth)acrylate, a poly(2-(perfluoroalkyl)ethyl (meth)acrylate), a tetrafluoroethylene-perfluoroalkyl vinyl ether, a poly(perfluoroalkyl vinyl ether), a poly(2-(perfluoro(alkyl)ethyl vinyl ether), and the like.
- the perfluoroalkyl group is preferably represented by C n F 2n+1 (wherein n is an integer from 1 to 6).
- the solvent used in connection with the aspects of the invention may be an organic solvent such as a ketone (e.g., acetone, MEK, or MIBK), ethyl acetate, butyl acetate, diethyl ether, dioxane, ethanol, or isopropyl alcohol. It is preferable to use a fluorine-based solvent that exhibits high affinity to the fluorine-based polymer.
- a ketone e.g., acetone, MEK, or MIBK
- ethyl acetate e.g., acetone, MEK, or MIBK
- ethyl acetate e.g., acetone, MEK, or MIBK
- ethyl acetate e.g., acetone, MEK, or MIBK
- ethyl acetate e.g., acetone, MEK, or MIBK
- ethyl acetate e
- the fluorine-based solvent also has an advantage in that it is unnecessary to use special ventilation/explosion-proof equipment.
- fluorine-based solvent examples include a perfluorocarbon, a hydrofluorocarbon, a hydrochlorofluorocarbon, a hydrofluoroether, a perfluoropolyether, a hydrofluoropolyether, and the like.
- the fluorine-based polymer solution may be brought into contact with the anodic oxidation coating using an arbitrary means such as dipping, spraying, or brush coating.
- the surface-treated metal member according to one aspect of the invention includes the composite sealed layer in which the fluorine-based polymer is present inside the pores formed in the anodic oxidation coating, the surface-treated metal member exhibits excellent adhesion. Since the fluorine-based polymer layer that is formed continuously over the composite sealed layer has a thickness as small as 100 nm or less, the surface-treated metal member does not show a film-like texture.
- the surface-treated metal member exhibits excellent long-term corrosion resistance, is not easily contaminated, and can be easily cleaned by wiping the surface-treated metal member due to the water repellency and the oil repellency of the fluorine-based polymer.
- T5 material The surface of an extruded shape (T5 material) produced by extrusion using a JIS A 6063 alloy was subjected to a pretreatment (buffing and chemical polishing).
- the extruded shape was anodized using a 15% sulfuric acid electrolytic solution at a current density of 1 A/dm 2 and a bath temperature of 20°C to form an anodic oxidation coating having a thickness of 10 ⁇ m on the surface of the extruded shape (metal).
- Example 1 the anodic oxidation coating was washed with water.
- Example 2 the anodic oxidation coating was subjected to a semi-sealing treatment (washing) at 80°C for 10 minutes using purified water.
- the anodic oxidation coating was then dipped in a fluorine-based polymer solution prepared by dissolving a fluorine-based polymer in a fluorine-based solvent ("OPC-800" manufactured by Noda Screen Co., Ltd.), and removed from the solution.
- a fluorine-based polymer solution prepared by dissolving a fluorine-based polymer in a fluorine-based solvent ("OPC-800" manufactured by Noda Screen Co., Ltd.
- Example 3 the fluorine-based polymer solution was sprayed onto the surface of the anodic oxidation coating.
- the thickness of the fluorine-based polymer that adhered to the surface of the anodic oxidation coating removed from the fluorine-based polymer solution after dipping was estimated to be about 10 nm.
- Example 1 the anodic oxidation coating was then subjected to a sealing treatment for 20 minutes using steam at 150°C.
- the steam sealing treatment may be performed under normal pressure. In this case, however, the sealing time may relatively increase. Therefore, it is preferable to perform the steam sealing treatment using pressurized steam at 130 to 180°C (for 10 to 30 minutes).
- Comparative Example 1 the anodic oxidation coating was subjected to a boiling water sealing treatment at 100°C for 20 minutes using purified water.
- Comparative Example 2 a fluororesin primer was applied to the anodic oxidation coating subjected to a boiling water sealing treatment in the same manner as in Comparative Example 1, and the anodic oxidation coating was then dipped in the fluorine-based polymer solution, and dried.
- Comparative Example 3 the anodic oxidation coating was treated, and dipped in the fluorine-based polymer solution in the same manner as in Example 2, but was then dried without subjecting the anodic oxidation coating to the steam sealing treatment.
- Comparative Example 4 the anodic oxidation coating was treated, and dipped in the fluorine-based polymer solution in the same manner as in Example 2, but was then subjected to a boiling water sealing treatment at 100°C for 20 minutes using purified water.
- FIG. 1 shows the sample production conditions
- FIG. 2 shows the evaluation results
- DIP in FIG. 1 refers to "dipping".
- the sample obtained in Comparative Example 3 was not subjected to the steam sealing treatment after dipping the anodic oxidation coating in the fluorine-based polymer solution. As a result, the sample obtained in Comparative Example 3 showed whitening (discoloration) when subjected to the salt spray test.
- the sample obtained in Comparative Example 4 was subjected to the boiling water sealing treatment after dipping the anodic oxidation coating in the fluorine-based polymer solution. As a result, the sample obtained in Comparative Example 4 showed slight surface whitening.
- Example 2 The cross section of the sample obtained in Example 2 was observed using a scanning electron microscope (SEM), and the elements were semi-quantitatively analyzed.
- SEM scanning electron microscope
- JSM-7000FZ A scanning electron microscope "JSM-7000FZ” (manufactured by JEOL Ltd.) was used for cross-sectional observation, and an EDS analyzer “EX-2300 ⁇ BU” (manufactured by JEOL Ltd.) was used for semi-quantitative elemental analysis.
- FIG. 3 shows the resulting SEM photograph.
- FIG. 4 shows the elemental analysis results for the surface, the upper part of the cross section, and the lower part of the cross section (see FIG. 3 ).
- the thickness of the fluorine-based polymer layer formed on the surface could not be measured since the thickness of the fluorine-based polymer layer was very small. Since fluorine was detected (deposited) in the upper part of the cross section of the anodic oxidation coating, it was confirmed that a composite sealed layer was formed in which fluorine was present inside the pores formed in the anodic oxidation coating.
- Example 4 In order to check the effects of electrolytic coloring, a sample of Example 4 was obtained in the same manner as in Example 1, and subjected to the salt spray test, except that the anodic oxidation coating was washed with water, and subjected to secondary electrolytic coloring (black) using a nickel-tin mixed bath.
- Comparative Example 5 the anodic oxidation coating was subjected to secondary electrolytic coloring in the same manner as in Example 4, and then subjected to the boiling water sealing treatment in the same manner as in Comparative Example 1 without bringing the fluorine-based polymer solution into contact with the anodic oxidation coating.
- FIG. 5 shows the measurement results for the color difference due to the salt spray test.
- FIG. 6 shows photographs of the samples obtained in Example 4 and Comparative Example 5 after the salt spray test.
- the anodic oxidation coating subjected to secondary electrolytic coloring maintained its metal surface texture, and exhibited improved corrosion resistance as a result of forming the fluorine-based polymer layer on the anodic oxidation coating, and subjecting the anodic oxidation coating to the steam sealing treatment.
- the surface treatment method according to the embodiments of the invention is suitable for a metal member on which a porous anodic oxidation coating can be formed, and may be applied to various fields (e.g., automotive parts) that utilize such a metal member.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
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- Application Of Or Painting With Fluid Materials (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2011033126 | 2011-02-18 | ||
PCT/JP2012/053635 WO2012111739A1 (fr) | 2011-02-18 | 2012-02-16 | Procédé de traitement de surface d'un élément métallique et élément métallique ainsi obtenu |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2677068A1 true EP2677068A1 (fr) | 2013-12-25 |
EP2677068A4 EP2677068A4 (fr) | 2016-10-05 |
Family
ID=46672651
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12747582.0A Withdrawn EP2677068A4 (fr) | 2011-02-18 | 2012-02-16 | Procédé de traitement de surface d'un élément métallique et élément métallique ainsi obtenu |
Country Status (5)
Country | Link |
---|---|
US (1) | US20130319868A1 (fr) |
EP (1) | EP2677068A4 (fr) |
JP (1) | JP5878133B2 (fr) |
CN (1) | CN103392030B (fr) |
WO (1) | WO2012111739A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106191961A (zh) * | 2014-05-22 | 2016-12-07 | 江苏理工学院 | 一种铝合金表面处理中的封闭处理方法 |
GB2541756A (en) * | 2015-08-28 | 2017-03-01 | Tata Motors European Technical Ct Plc | Coated substrate and method of fabrication thereof |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012005308B4 (de) | 2011-12-23 | 2022-03-17 | Wabco Gmbh | Druckluftversorgungsanlage, Druckluftversorgungssystem und Fahrzeug, insbesondere PKW, mit einer Druckluftversorgungsanlage |
GB2509335A (en) * | 2012-12-31 | 2014-07-02 | Univ Tartu | Double-structured corrosion resistant coatings and methods of application |
WO2016111693A1 (fr) | 2015-01-09 | 2016-07-14 | Apple Inc. | Procédés de réduction de l'enrichissement interfacial d'éléments d'alliage sous des films d'oxyde anodique et aspect anodisé amélioré d'alliages pouvant être traités à chaud |
US20160289858A1 (en) * | 2015-04-03 | 2016-10-06 | Apple Inc. | Process to mitigate grain texture differential growth rates in mirror-finish anodized aluminum |
US9970080B2 (en) | 2015-09-24 | 2018-05-15 | Apple Inc. | Micro-alloying to mitigate the slight discoloration resulting from entrained metal in anodized aluminum surface finishes |
WO2017165634A1 (fr) * | 2016-03-23 | 2017-09-28 | Maxterial, Inc. | Articles contenant des revêtements améliorant l'adhérence et leurs procédés de production |
US10174436B2 (en) | 2016-04-06 | 2019-01-08 | Apple Inc. | Process for enhanced corrosion protection of anodized aluminum |
US11352708B2 (en) | 2016-08-10 | 2022-06-07 | Apple Inc. | Colored multilayer oxide coatings |
US11242614B2 (en) | 2017-02-17 | 2022-02-08 | Apple Inc. | Oxide coatings for providing corrosion resistance on parts with edges and convex features |
US20200277707A1 (en) * | 2017-09-15 | 2020-09-03 | Oerlikon Surface Solutions Ag, Pfäffikon | Method for producing coating with colored surface |
US11549191B2 (en) | 2018-09-10 | 2023-01-10 | Apple Inc. | Corrosion resistance for anodized parts having convex surface features |
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US3012917A (en) * | 1957-03-26 | 1961-12-12 | Pechiney Prod Chimiques Sa | Method of protecting metal surfaces |
US2949411A (en) * | 1957-05-13 | 1960-08-16 | Titanium Metals Corp | Titanium anodizing process |
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US3664888A (en) * | 1965-10-09 | 1972-05-23 | Sumitomo Electric Industries | Method of resin coating a metal and resin-coated metal product thereof |
US3652342A (en) * | 1967-06-07 | 1972-03-28 | Gillette Co | Razor blades and processes for the preparation thereof |
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2012
- 2012-02-16 CN CN201280008871.7A patent/CN103392030B/zh not_active Expired - Fee Related
- 2012-02-16 US US14/000,123 patent/US20130319868A1/en not_active Abandoned
- 2012-02-16 WO PCT/JP2012/053635 patent/WO2012111739A1/fr active Application Filing
- 2012-02-16 EP EP12747582.0A patent/EP2677068A4/fr not_active Withdrawn
- 2012-02-16 JP JP2012558003A patent/JP5878133B2/ja not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
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See references of WO2012111739A1 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106191961A (zh) * | 2014-05-22 | 2016-12-07 | 江苏理工学院 | 一种铝合金表面处理中的封闭处理方法 |
CN106191961B (zh) * | 2014-05-22 | 2017-11-21 | 江苏理工学院 | 一种铝合金表面处理中的封闭处理方法 |
GB2541756A (en) * | 2015-08-28 | 2017-03-01 | Tata Motors European Technical Ct Plc | Coated substrate and method of fabrication thereof |
GB2541756B (en) * | 2015-08-28 | 2018-06-27 | Tata Motors European Technical Ct Plc | Coated substrate and method of fabrication thereof |
Also Published As
Publication number | Publication date |
---|---|
US20130319868A1 (en) | 2013-12-05 |
EP2677068A4 (fr) | 2016-10-05 |
WO2012111739A1 (fr) | 2012-08-23 |
JPWO2012111739A1 (ja) | 2014-07-07 |
CN103392030B (zh) | 2017-02-15 |
JP5878133B2 (ja) | 2016-03-08 |
CN103392030A (zh) | 2013-11-13 |
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