EP2669395A2 - Alliage d'aluminium pour coulée sous pression - Google Patents

Alliage d'aluminium pour coulée sous pression Download PDF

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Publication number
EP2669395A2
EP2669395A2 EP11857105.8A EP11857105A EP2669395A2 EP 2669395 A2 EP2669395 A2 EP 2669395A2 EP 11857105 A EP11857105 A EP 11857105A EP 2669395 A2 EP2669395 A2 EP 2669395A2
Authority
EP
European Patent Office
Prior art keywords
aluminum alloy
weight
present
die
casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11857105.8A
Other languages
German (de)
English (en)
Other versions
EP2669395B1 (fr
EP2669395A4 (fr
Inventor
Jung Taek Lee
Myeong Hyeon Nam
Kab Yong Park
Jong Hoon Jeong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GK CORP Ltd
Original Assignee
GK CORP Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GK CORP Ltd filed Critical GK CORP Ltd
Publication of EP2669395A2 publication Critical patent/EP2669395A2/fr
Publication of EP2669395A4 publication Critical patent/EP2669395A4/fr
Application granted granted Critical
Publication of EP2669395B1 publication Critical patent/EP2669395B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/026—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/03—Making non-ferrous alloys by melting using master alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/10—Alloys based on aluminium with zinc as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/12—Alloys based on aluminium with copper as the next major constituent

Definitions

  • the present invention relate to an aluminum alloy for die-casting. More particularly, the present invention relate to an aluminum alloy being usable for die-casting and including 1.0% to 5.0% by weight of Mn, 0.5% to 1.5% by weight of Zn, 1.0% to 2.0% by weight of Zr, 0.5% to 1.5% by weight of Cu and 85% to 97% by weight of aluminum.
  • An aluminum alloy has a light weight and a high strength so that an aluminum alloy is used for durable goods. Especially, an aluminum alloy is recently being for parts of a motor vehicle or for a case of an electronic device such as a mobile phone.
  • Two methods are generally used for manufacturing an aluminum alloy product.
  • an aluminum board is processed through a press-forming method to form a case, and the case is covered with an anodic oxidation coat.
  • the case covered with the anodic oxidation coat can be used for a long time without damage, and can have a surface having a clear color.
  • it is difficult to form a rib for reinforcement of the case, a space for parts disposed in the case, and a boss for screw combination.
  • a design of the case is limited.
  • a case of an electronic device may be formed from an aluminum alloy through a die-casting method.
  • an aluminum alloy for a die-casting method includes various metallic or non-metallic additives such as silicon or the like to improve flexibility.
  • the additives migrate to near a surface.
  • a method of forming an additional coating layer on the die-casting-formed cover may be used. However, when the cover is used for a long time, the additional coating layer may be stripped.
  • the present invention provides an aluminum alloy such that surface smut due from silicon smutting is not caused after a molding process so that a product can have a clear color. Furthermore, the aluminum alloy can increase an adhesion strength of a coating layer thereby increasing a durability of a die-casting product. Furthermore, because the aluminum alloy does not include a heavy metal harmful to human being, the aluminum alloy may be non-toxic and environment-friendly.
  • the present invention provides an aluminum alloy for die-casting including 1.0% to 5.0% by weight of Mn, 0.5% to 1.5% by weight of Zn, 1.0% to 2.0% by weight of Zr, 0.5% to 1.5% by weight of Cu and 85% to 97% by weight of aluminum.
  • the present invention provides an aluminum alloy for die-casting further including 0.1% to 0.6% by weight of Si.
  • the present invention provides an aluminum alloy for die-casting further including 0.5% to 1.5% by weight of Fe.
  • the present invention provides an aluminum alloy for die-casting further including equal to or less than 0.1% by weight of Ni.
  • the present invention provides an aluminum alloy for die-casting further including 0.5% to 1.0% by weight of Mg.
  • the present invention provides an aluminum alloy for die-casting further including 0.3% to 0.7% by weight of Ti.
  • the present invention provides an aluminum alloy for die-casting having a tensile strength of 180 Mpa to 250 Mpa, and an elongation of 5% to 10%.
  • FIG. 1 is a flow chart for explaining a method of preparing an aluminum alloy of the present invention.
  • An aluminum alloy of the present invention includes 1.0% to 5.0% by weight of Mn, 0.5% to 1.5% by weight of Zn, 1.0% to 2.0% by weight of Zr, 0.5% to 1.5% by weight of Cu and 85% to 97% by weight of aluminum.
  • the aluminum alloy of the present invention essentially includes 1.0% to 5.0% by weight of Mn.
  • Mn precipitates a MnA16 phase thereby causing solid-solution strengthening and dispersion of fine precipitates to increase mechanical characteristics of the aluminum alloy.
  • the content of Mn in the aluminum alloy is 1.0% to 5.0% by weight based on the total weight of the aluminum alloy.
  • the content of Mn is less than 1% by weight based on the total weight of the aluminum alloy, mechanical characteristics of the aluminum alloy are hardly increased.
  • the content of Mn is more than 5% by weight based on the total weight of the aluminum alloy, surface smut appears after anodizing,
  • the aluminum alloy of the present invention includes 0.5% to 1.5% by weight of Zn.
  • Zn serves to increase mechanical characteristics.
  • the aluminum alloy of the present invention includes 0.5% to 1.5% by weight of Zn based on the total weight of the aluminum alloy.
  • the aluminum alloy of the present invention includes 1.0% to 2.0% by weight of Zr so that the aluminum alloy can be anodized. Furthermore, Zr serves to increase grain refinement and mechanical characteristics. Preferably, the aluminum alloy of the present invention includes 1.0% to 2.0% by weight of Zr based on the total weight of the aluminum alloy.
  • the aluminum alloy of the present invention includes 0.5% to 1.5% by weight of Cu.
  • Cu forms solid solution in the aluminum alloy to reinforce a substrate to prevent seizure of a mold.
  • Cu may increase precipitation hardening thereby increasing a strength.
  • the aluminum alloy of the present invention includes 0.5% to 1.5% by weight of Cu based on the total weight of the aluminum alloy.
  • the aluminum alloy of the present invention may further include 0.1% to 0.6% by weight of Si.
  • Si increases a flexibility of the aluminum alloy to improve a formability of the aluminum alloy.
  • an excessive amount of Si causes smut on a surface of the aluminum alloy at an anodizing process thereby making coloring difficult and decreasing a strength of an anodic oxidation coat.
  • the aluminum alloy of the present invention preferably includes less than or equal to 0.6% by weight of Si based on the total weight of the aluminum alloy. More than 0.6% by weight of Si may cause smut thereby making coloring the aluminum alloy difficult.
  • the aluminum alloy of the present invention may further include 0.5% to 1.5% by weight of Fe.
  • Fe reduces adhesion of the aluminum alloy in a mold and prevents erosion of the mold.
  • the aluminum alloy of the present invention includes 0.5% to 1.5% by weight of Fe based on the total weight of the aluminum alloy.
  • the content of Fe is less than 0.5% by weight based on the total weight of the aluminum alloy, the aluminum alloy may be seized in the mold.
  • the content of Fe is more than 1.5% by weight based on the total weight of the aluminum alloy, a corrosion resistance and an anodizability of the aluminum alloy may be reduced.
  • the aluminum alloy of the present invention may further include equal to or less than 0.1% by weight of Ni.
  • Ni induces grain refinement to increase elongation of the aluminum alloy.
  • the aluminum alloy of the present invention includes equal to or less than 0.1% of Ni based on the total weight of the aluminum alloy.
  • the aluminum alloy of the present invention may further include 0.5% to 1.0% by weight of Mg.
  • Mg increases a corrosion resistance and an anodizability of the aluminum alloy. Equal to or less than 1.0% by weight of Mg may increases a strength of the aluminum alloy. However, more than 1.0% by weight of Mg may cause smut on a surface after anodizing.
  • the aluminum alloy of the present invention preferably includes 0.5% to 1.0% by weight of Mg.
  • the aluminum alloy of the present invention may further include equal to or less than 0.5% by weight of Ti.
  • Ti induces grain refinement in the aluminum alloy.
  • the aluminum alloy of the present invention includes equal to or less than 0.5% of Ti based on the total weight of the aluminum alloy. More than 0.5% by weight of Ti may reduce a strength of the aluminum alloy.
  • the aluminum alloy for die-casting of the present invention may be prepared through a general method of preparing an aluminum alloy. For example, pure aluminum is dissolved (or melted), and a mother alloy is dissolved in a molten metal of the dissolved pure aluminum. Thereafter, the molten metal is stirred and degasified to obtain an aluminum ingot.
  • FIG. 3 is a flow chart for explaining a method of preparing an aluminum alloy of the present invention.
  • the aluminum alloy prepared according to the above has a tensile strength of 180 Mpa to 250 Mpa, and an elongation of 5% to 10%.
  • the present invention provides an aluminum alloy such that surface smut due from silicon smutting is not caused after a molding process so that a product can have a clear color. Furthermore, the aluminum alloy can increase an adhesion strength of a coating layer thereby increasing a durability of a die-casting product. Furthermore, because the aluminum alloy does not include a heavy metal harmful to human being, the aluminum alloy may be non-toxic and environment-friendly.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Prevention Of Electric Corrosion (AREA)
EP11857105.8A 2011-01-27 2011-12-20 Alliage d'aluminium pour coulée sous pression Not-in-force EP2669395B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020110008077A KR101055373B1 (ko) 2011-01-27 2011-01-27 다이캐스팅용 알루미늄합금
PCT/KR2011/009846 WO2012102485A2 (fr) 2011-01-27 2011-12-20 Alliage d'aluminium pour coulée sous pression

Publications (3)

Publication Number Publication Date
EP2669395A2 true EP2669395A2 (fr) 2013-12-04
EP2669395A4 EP2669395A4 (fr) 2014-09-03
EP2669395B1 EP2669395B1 (fr) 2015-08-12

Family

ID=44933037

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11857105.8A Not-in-force EP2669395B1 (fr) 2011-01-27 2011-12-20 Alliage d'aluminium pour coulée sous pression

Country Status (6)

Country Link
US (1) US9045815B2 (fr)
EP (1) EP2669395B1 (fr)
JP (1) JP5719939B2 (fr)
KR (1) KR101055373B1 (fr)
CN (1) CN103298962B (fr)
WO (1) WO2012102485A2 (fr)

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CN103614596B (zh) * 2013-07-16 2016-03-02 深圳市欣茂鑫精密五金制品有限公司 一种用于电子产品结构件的高强度铝合金及其制备方法
KR20150040631A (ko) * 2013-10-07 2015-04-15 지케이 주식회사 다이캐스트용 알루미늄 합금과 휴대용 전기장치의 메탈 케이스 및 그 제조방법
EP2887150A1 (fr) * 2013-12-20 2015-06-24 ETA SA Manufacture Horlogère Suisse Barillet d'horlogerie optimisé
CN105316533B (zh) * 2014-08-27 2017-09-08 深圳市欣茂鑫精密五金制品有限公司 一种铝合金
US10494702B2 (en) 2014-08-27 2019-12-03 Arconic Inc. Aluminum casting alloys having manganese, zinc and zirconium
DE212014000273U1 (de) 2014-08-29 2017-04-26 Apple Inc. Prozess zur Minderung der Spallation anodischer Oxidschichten von hochfesten Substratlegierungen
WO2016111693A1 (fr) 2015-01-09 2016-07-14 Apple Inc. Procédés de réduction de l'enrichissement interfacial d'éléments d'alliage sous des films d'oxyde anodique et aspect anodisé amélioré d'alliages pouvant être traités à chaud
US9869623B2 (en) 2015-04-03 2018-01-16 Apple Inc. Process for evaluation of delamination-resistance of hard coatings on metal substrates
US10760176B2 (en) 2015-07-09 2020-09-01 Apple Inc. Process for reducing nickel leach rates for nickel acetate sealed anodic oxide coatings
CN105177376A (zh) * 2015-07-30 2015-12-23 东莞市晋益电子科技有限公司 一种新型铝合金材料及双金属压铸方法
CN105063431A (zh) * 2015-07-31 2015-11-18 广东欧珀移动通信有限公司 一种压铸铝合金、结构件以及电子装置
US10767678B2 (en) * 2015-08-28 2020-09-08 Nhk Spring Co., Ltd. Fastening member and rod-shaped member for fastening member
US9970080B2 (en) 2015-09-24 2018-05-15 Apple Inc. Micro-alloying to mitigate the slight discoloration resulting from entrained metal in anodized aluminum surface finishes
US10711363B2 (en) 2015-09-24 2020-07-14 Apple Inc. Anodic oxide based composite coatings of augmented thermal expansivity to eliminate thermally induced crazing
KR101743234B1 (ko) 2016-02-16 2017-06-02 (주)제이에스루미 다이캐스팅용 알루미늄 합금
CN107177761A (zh) * 2016-03-09 2017-09-19 金利合金制造工业（宁波）有限公司 一种可压铸可阳极氧化的铝合金
US10174436B2 (en) 2016-04-06 2019-01-08 Apple Inc. Process for enhanced corrosion protection of anodized aluminum
US11352708B2 (en) 2016-08-10 2022-06-07 Apple Inc. Colored multilayer oxide coatings
CN106191550B (zh) * 2016-09-27 2019-04-09 广州致远新材料科技有限公司 一种可阳极氧化压铸铝合金
CN106191551B (zh) * 2016-09-27 2019-04-09 广州致远新材料科技有限公司 一种可阳极氧化压铸铝合金
US11242614B2 (en) 2017-02-17 2022-02-08 Apple Inc. Oxide coatings for providing corrosion resistance on parts with edges and convex features
KR101965418B1 (ko) 2017-08-10 2019-04-03 (주)삼기오토모티브 알루미늄 합금의 열처리 방법
US11549191B2 (en) 2018-09-10 2023-01-10 Apple Inc. Corrosion resistance for anodized parts having convex surface features
KR20210042639A (ko) 2019-10-10 2021-04-20 주식회사 삼기 알루미늄 다이캐스팅 제품의 제조방법 및 이 방법에 의해 제조된 알루미늄 다이캐스팅 제품

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JPS57169073A (en) * 1981-04-13 1982-10-18 Mitsubishi Alum Co Ltd Manufacture of brazing sheet for material of fin of heat exchanger showing superior sagging resistance during brazing

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Also Published As

Publication number Publication date
JP5719939B2 (ja) 2015-05-20
JP2014501853A (ja) 2014-01-23
CN103298962A (zh) 2013-09-11
EP2669395B1 (fr) 2015-08-12
US20130156635A1 (en) 2013-06-20
US9045815B2 (en) 2015-06-02
KR101055373B1 (ko) 2011-08-08
CN103298962B (zh) 2016-02-10
EP2669395A4 (fr) 2014-09-03
WO2012102485A3 (fr) 2012-09-27
WO2012102485A2 (fr) 2012-08-02

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