EP2652560A1 - Blindage magnetique pour spiral de piece d'horlogerie - Google Patents
Blindage magnetique pour spiral de piece d'horlogerieInfo
- Publication number
- EP2652560A1 EP2652560A1 EP11793747.4A EP11793747A EP2652560A1 EP 2652560 A1 EP2652560 A1 EP 2652560A1 EP 11793747 A EP11793747 A EP 11793747A EP 2652560 A1 EP2652560 A1 EP 2652560A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- arms
- spiral
- magnetic
- hairspring
- rocker
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 37
- 238000012216 screening Methods 0.000 title 1
- 229910045601 alloy Inorganic materials 0.000 claims description 8
- 239000000956 alloy Substances 0.000 claims description 8
- 230000005294 ferromagnetic effect Effects 0.000 claims description 2
- 102100031680 Beta-catenin-interacting protein 1 Human genes 0.000 claims 1
- 101000993469 Homo sapiens Beta-catenin-interacting protein 1 Proteins 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 239000003302 ferromagnetic material Substances 0.000 abstract description 6
- 239000000463 material Substances 0.000 description 7
- 230000005415 magnetization Effects 0.000 description 6
- 230000035699 permeability Effects 0.000 description 5
- 230000010287 polarization Effects 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- 229910000599 Cr alloy Inorganic materials 0.000 description 2
- 239000000788 chromium alloy Substances 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012800 visualization Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 description 1
- 229910000808 amorphous metal alloy Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- GOECOOJIPSGIIV-UHFFFAOYSA-N copper iron nickel Chemical compound [Fe].[Ni].[Cu] GOECOOJIPSGIIV-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 230000000763 evoking effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- VAWNDNOTGRTLLU-UHFFFAOYSA-N iron molybdenum nickel Chemical compound [Fe].[Ni].[Mo] VAWNDNOTGRTLLU-UHFFFAOYSA-N 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B43/00—Protecting clockworks by shields or other means against external influences, e.g. magnetic fields
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/04—Oscillators acting by spring tension
- G04B17/06—Oscillators with hairsprings, e.g. balance
- G04B17/063—Balance construction
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/20—Compensation of mechanisms for stabilising frequency
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/20—Compensation of mechanisms for stabilising frequency
- G04B17/22—Compensation of mechanisms for stabilising frequency for the effect of variations of temperature
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/20—Compensation of mechanisms for stabilising frequency
- G04B17/22—Compensation of mechanisms for stabilising frequency for the effect of variations of temperature
- G04B17/222—Compensation of mechanisms for stabilising frequency for the effect of variations of temperature with balances
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/20—Compensation of mechanisms for stabilising frequency
- G04B17/22—Compensation of mechanisms for stabilising frequency for the effect of variations of temperature
- G04B17/227—Compensation of mechanisms for stabilising frequency for the effect of variations of temperature composition and manufacture of the material used
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B43/00—Protecting clockworks by shields or other means against external influences, e.g. magnetic fields
- G04B43/002—Component shock protection arrangements
Definitions
- the present invention relates to a device for protecting a spiral of a mechanical timepiece against disruptive magnetic fields coming from outside this timepiece.
- the material constituting the hairspring is generally made of a metal alloy such as a steel capable of remanent magnetization if it is subjected to an external magnetic field.
- a metal alloy such as a steel capable of remanent magnetization if it is subjected to an external magnetic field.
- the simplest and most radical solution is to completely shield the movement of the timepiece to allow no disturbing line of fields to penetrate.
- This is the case proposed by document CH 122391 where the movement of the watch is protected by a set of elements formed of a stainless alloy, high permeability and low hysteresis, forming a magnetic screen.
- the elements are a bowl disposed between the movement and the bottom of the watch, a dust cover ring forming a cap disposed between the movement and a casing ring, and an intermediate plate disposed between the watch plate and its dial. This way of doing things is extremely cumbersome and expensive. Indeed it requires three additional pieces that not only weigh down the watch but also increase its volume.
- the device is constituted by a housing element having a sufficient permeance to magnetic fields, the housing element being completed by a casing ring of mild steel with which it forms a bowl enveloping the movement and forming a screen magnetic.
- the housing element is formed by the bottom of the housing, this bottom being made of stainless and polishable alloy having a homogeneous ferritic structure.
- the bottom and the casing ring being directly made of materials with high magnetic permeability.
- no screen is disposed between the movement and the dial of the watch, the protection device being limited to a bowl without lid serving as housing for the movement of the watch.
- a first disadvantage of this latter solution is that the hairspring proper is not protected against a disturbing field whatever the orientation of this field prevailing in the plane of the hairspring. Indeed, as the hairspring is off-center with respect to the center of the movement and if omnidirectional protection is desired, it is a question of proposing a device centered with respect to said hairspring and not with respect to the movement as a whole as it is the case of the document cited above.
- Another disadvantage of this solution is to completely mask the movement, which is detrimental from an aesthetic point of view, especially for high-end watches.
- Pendulums made of ferromagnetic materials are also known in the context of electronic watches, for example in the watches described in patent documents FR2063101 or CH361247.
- the ferromagnetic material used for the balance does not constitute a magnetic shielding to improve the isochronism of the spiral, but is intended to cooperate with an electromagnetic circuit sustaining the oscillations.
- FR2000706 is an example of a similar solution of an electronic watch comprising a ferromagnetic balance-regulator which is even totally devoid of spiral.
- document CH689106 discloses spirals made with particular alloys having advantageous elasticity and thermoelastic properties for attachment with a nickel balance. No particular property of magnetic shielding is however mentioned for the balance relative to the balance spring.
- the protection device comprises a rocker made of amorphous ferromagnetic material .
- An advantage of the proposed solution is to achieve a powerful magnetic shielding, due to the advantageous magnetic and anticorrosive properties of amorphous metals, while advantageously reusing certain elements of the movement as a shielding element, and thus not requiring the use of no additional parts or special surface treatments. Congestion is thus reduced to the maximum, as well as production costs.
- Another advantage of the proposed solution is to allow the visualization of the movement elements by the bottom of the watch, thus improving the overall aesthetics of the timepiece produced.
- FIGS. 1A and 1B show a spiral perspective in the plane and a portion of this spiral
- FIG. 2 is a schematic perspective view of a preferred embodiment of the invention.
- FIG. 3 is a schematic perspective view of an alternative embodiment of the invention.
- the watchmaker faces a space problem to house the shield on the plate and in the housing. Therefore, it has been sought to find optimal solutions that combine minimal footprint and effective attenuation of the magnetic field.
- the regulating organ of a mechanical watch is generally constituted by a spiral spring, as illustrated in FIG. 1 A.
- the spiral is mounted around an axis of rotation Z and is wound in a plane perpendicular to this axis.
- the diameter of the spiral in this plane is noted d, while the height of the spiral along the Z axis is denoted h.
- Figure 1 B shows a portion of the spiral 1 which is a very long ribbon wound on itself, this ribbon preferably having a reduced height h and a very small thickness e. It follows from this that if it is polarized in the direction of the Z or orthogonally height, or in the direction of the thickness R or radially, little or no remanent magnetization will remain.
- the casing ring 4 makes it possible to effectively protect the hairspring 1 against the disturbing magnetic fields, because the latter are deflected in greater numbers in the vertical direction of the Z axis of rotation, which is a direction of polarization according to which the hairspring is less sensitive. It will be noted however that the concentration of the field at the periphery of the arms 3 and at the level of the circle 4 always tends to locally increase this field, hence the need to provide a casing ring 4 of diameter D which is relatively large compared with the diameter. d spiral 1, preferably at least twice so that no part of the spiral, even at the outermost level, can suffer this undesirable effect of concentration.
- the process of producing movement parts made of ferromagnetic material that is to say having a magnetic susceptibility (generally noted by the Greek letter ⁇ ) very high, had until now never been considered by the man of the watchmaking business because of the strong tendency to oxidation of the usual ferromagnetic materials, in particular by the presence of iron and the deficiency of chromium in these alloys.
- the high magnetic saturation material used to make the casing ring 4 and the arms 3 is an amorphous iron-based alloy, for example an iron-nickel, iron-cobalt or iron-chromium alloy, or alloys of the same type.
- iron-nickel-molybdenum, iron-nickel-copper This type of alloy is recognized for its low coercivity properties and high magnetic permeability, that is to say with very narrow hysteresis cycles, and with a very high slope, are also very resistant to corrosion and thus particularly suitable for the implementation of the invention.
- the chemical nature of the alloy is chosen so that the magnetic behavior of the material has a high magnetic permeability and saturation level, such as a Permenorm iron-nickel alloy with a nickel content of 45 to 50%.
- the rocker 2 comprises at least four flattened arms which extend in the winding plane of the spiral.
- the balance is constantly rotated and a substantially flat surface is emulated to form a magnetic shield in this plane.
- the attenuation is of the order of half between an external field and the field where the hairspring 1 is located, whose diameter / and height h preferably respect the ratios stated above in relation to those D, H of the casing circle 4.
- the plurality of arms 3 covers an area equal to more than a quarter of the virtual disk delimited by the casing ring 4 in the arm rotation plane 3, an attenuation of the disturbances relative to the operating gaps which can reach ratios higher than 3, in particular for induction values greater than 10 millitesla (mT), ie approximately 8kA / m for a three-armed balance with the ratio of area evoked with respect to the virtual disk delimited by the casing circle .
- mT millitesla
- the amorphous metal alloy used in the context of the invention is here again particularly advantageous because of the elastic deformation properties and mechanical strength conferred, which make it easy to obtain a very flattened shape for a given mass.
- This flattened shape makes it possible to orient the lines of an external magnetic field more effectively without requiring increasing the weight of the balance, and consequently its moment of inertia, which would be detrimental to the performance of the regulating system for a given spiral spring. .
- the device according to the invention may comprise a second series of arms 3 surmounted on said casing ring 4, as illustrated in FIG. 3.
- the series of arms 3 ' can be preferably angularly offset, or of a different or complementary but symmetrical geometrical shape.
- the two sets of arms are identical to that of the lower arms 3, so that the two series of arms 3 and 3 'are superimposed.
- the advantage of covering the magnetic shield on the top by rotating arms makes it possible on the one hand to constitute a symmetrical and totally closed space inside which the spiral 1 is arranged, which makes the shielding effective both in terms of attenuation and isotropy; on the other hand, similar to the attenuation values measured with the only arms 3 the mass efficiency of the shielding is greatly improved compared to a solid surface such as a disk.
- the piece forming the balance with two sets of arms 3,3 ' may be formed integrally for example by a LIGA type process, or by interlocking a rib in a groove of male-female parts each having a series of arms and each forming part of the casing ring 4.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Electric Clocks (AREA)
- Springs (AREA)
- Magnetic Treatment Devices (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11793747.4A EP2652560B1 (fr) | 2010-12-15 | 2011-12-05 | Blindage magnetique pour spiral de piece d'horlogerie |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10195192A EP2466396A1 (fr) | 2010-12-15 | 2010-12-15 | Blindage magnétique pour spiral de pièce d'horlogerie |
EP11793747.4A EP2652560B1 (fr) | 2010-12-15 | 2011-12-05 | Blindage magnetique pour spiral de piece d'horlogerie |
PCT/EP2011/071753 WO2012080021A1 (fr) | 2010-12-15 | 2011-12-05 | Blindage magnetique pour spiral de piece d'horlogerie |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2652560A1 true EP2652560A1 (fr) | 2013-10-23 |
EP2652560B1 EP2652560B1 (fr) | 2019-11-13 |
Family
ID=44123366
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10195192A Withdrawn EP2466396A1 (fr) | 2010-12-15 | 2010-12-15 | Blindage magnétique pour spiral de pièce d'horlogerie |
EP11793747.4A Active EP2652560B1 (fr) | 2010-12-15 | 2011-12-05 | Blindage magnetique pour spiral de piece d'horlogerie |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10195192A Withdrawn EP2466396A1 (fr) | 2010-12-15 | 2010-12-15 | Blindage magnétique pour spiral de pièce d'horlogerie |
Country Status (7)
Country | Link |
---|---|
US (1) | US9494921B2 (fr) |
EP (2) | EP2466396A1 (fr) |
JP (1) | JP5815043B2 (fr) |
CN (1) | CN103261976B (fr) |
HK (1) | HK1188488A1 (fr) |
RU (1) | RU2545488C2 (fr) |
WO (1) | WO2012080021A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3502786A1 (fr) | 2017-12-22 | 2019-06-26 | The Swatch Group Research and Development Ltd | Balancier pour pièce d'horlogerie et procédé de fabrication d'un tel balancier |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US965506A (en) * | 1908-10-22 | 1910-07-26 | Frederic Ecaubert | Compensating balance for timepieces. |
CH122391A (fr) | 1926-10-22 | 1927-09-16 | Ditisheim Paul | Montre. |
CH289106A (fr) | 1949-06-20 | 1953-02-28 | Dubois Ernest | Spiral compensateur. |
US3002138A (en) * | 1958-06-24 | 1961-09-26 | Gen Time Corp | Electrically powered oscillatory balance |
CH361247A (fr) * | 1958-08-08 | 1962-03-31 | Lip Societe Anonyme D Horloger | Montre électrique |
US3335561A (en) * | 1964-05-18 | 1967-08-15 | Seiko Instr & Electronics | Contactless battery timepiece |
FR1408872A (fr) | 1964-07-08 | 1965-08-20 | Lip Sa | Dispositif de protection des montres contre les champs magnétiques |
DE1673762B2 (de) * | 1968-01-25 | 1976-09-30 | Gebrüder Junghans GmbH, 7230 Schramberg | Schaltungsanordnung fuer den kontaktlosen antrieb eines schwingenden oder umlaufenden gliedes, vorzugsweise eines gangordnerschwingers fuer zeithaltende geraete |
FR2063101A1 (fr) * | 1969-09-15 | 1971-07-09 | Lip Horlogerie | |
US3943701A (en) * | 1975-01-08 | 1976-03-16 | Timex Corporation | Regulator and balance bridge arrangement for a horological device |
JPH04124246A (ja) * | 1990-09-13 | 1992-04-24 | Alps Electric Co Ltd | 時計の文字盤 |
CH689106A5 (de) | 1994-09-15 | 1998-10-15 | Erich M Durrer | Befestigungsvorrichtung fuer Schmuck. |
DE19651320B4 (de) * | 1996-12-11 | 2004-06-03 | Schmidt, Lothar | Schwingsystem |
DE19651321C2 (de) * | 1996-12-11 | 2002-08-14 | Lothar Schmidt | Unruh |
WO2001065318A1 (fr) * | 2000-02-29 | 2001-09-07 | Seiko Instruments Inc. | Piece d'horlogerie mecanique a element de detection optique et element de freinage |
JP2003043166A (ja) * | 2001-07-30 | 2003-02-13 | Seiko Epson Corp | 時 計 |
ATE363676T1 (de) * | 2003-10-01 | 2007-06-15 | Asulab Sa | Uhr mit einem mechanischen uhrwerk, das mit einem elektronischen regulator gekoppelt ist |
JP4595901B2 (ja) * | 2006-07-27 | 2010-12-08 | カシオ計算機株式会社 | 機器ケース、腕時計ケースおよび電波時計 |
JP2010513886A (ja) * | 2006-12-21 | 2010-04-30 | コンプリタイム エスアー | 時計用メカニカル振動子 |
EP2104005A1 (fr) * | 2008-03-20 | 2009-09-23 | Nivarox-FAR S.A. | Balancier composite et son procédé de fabrication |
CH700640B1 (fr) * | 2009-03-19 | 2014-09-30 | Mhvj Manufacture Horlogère Vallée De Joux | Pièce d'horlogerie allegée et renforcée. |
EP2287683B1 (fr) * | 2009-08-17 | 2012-10-31 | The Swatch Group Research and Development Ltd. | Protection magnétique d'un spiral de pièce d'horlogerie |
EP2410387B1 (fr) * | 2010-07-19 | 2016-07-06 | Nivarox-FAR S.A. | Balancier à réglage d'inertie sans insert |
EP2596406B1 (fr) * | 2010-07-19 | 2019-03-27 | Nivarox-FAR S.A. | Mecanisme oscillant a pivot elastique et mobile de transmission d'energie |
-
2010
- 2010-12-15 EP EP10195192A patent/EP2466396A1/fr not_active Withdrawn
-
2011
- 2011-12-05 RU RU2013132473/28A patent/RU2545488C2/ru not_active IP Right Cessation
- 2011-12-05 WO PCT/EP2011/071753 patent/WO2012080021A1/fr active Application Filing
- 2011-12-05 US US13/993,645 patent/US9494921B2/en active Active
- 2011-12-05 EP EP11793747.4A patent/EP2652560B1/fr active Active
- 2011-12-05 CN CN201180060137.0A patent/CN103261976B/zh active Active
- 2011-12-05 JP JP2013543637A patent/JP5815043B2/ja active Active
-
2014
- 2014-02-18 HK HK14101518.5A patent/HK1188488A1/zh unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2012080021A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP5815043B2 (ja) | 2015-11-17 |
US20130265859A1 (en) | 2013-10-10 |
HK1188488A1 (zh) | 2014-05-02 |
EP2652560B1 (fr) | 2019-11-13 |
RU2545488C2 (ru) | 2015-04-10 |
JP2014508918A (ja) | 2014-04-10 |
EP2466396A1 (fr) | 2012-06-20 |
US9494921B2 (en) | 2016-11-15 |
RU2013132473A (ru) | 2015-01-20 |
WO2012080021A1 (fr) | 2012-06-21 |
CN103261976A (zh) | 2013-08-21 |
CN103261976B (zh) | 2016-05-11 |
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