EP2626464B1 - Composition de désacidification de papier, procédé permettant de l'obtenir et son procédé d'application - Google Patents

Composition de désacidification de papier, procédé permettant de l'obtenir et son procédé d'application Download PDF

Info

Publication number
EP2626464B1
EP2626464B1 EP11464027.9A EP11464027A EP2626464B1 EP 2626464 B1 EP2626464 B1 EP 2626464B1 EP 11464027 A EP11464027 A EP 11464027A EP 2626464 B1 EP2626464 B1 EP 2626464B1
Authority
EP
European Patent Office
Prior art keywords
paper
composition
deacidification
cmc
hap
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP11464027.9A
Other languages
German (de)
English (en)
Other versions
EP2626464A1 (fr
Inventor
Rodica-Mariana Ion
Sanda Maria Doncea
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institutul National de Cercetare Dezvoltare Pentru Chimie si Petrochimie - Icechim
Original Assignee
Institutul National de Cercetare Dezvoltare Pentru Chimie si Petrochimie - Icechim
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institutul National de Cercetare Dezvoltare Pentru Chimie si Petrochimie - Icechim filed Critical Institutul National de Cercetare Dezvoltare Pentru Chimie si Petrochimie - Icechim
Priority to EP11464027.9A priority Critical patent/EP2626464B1/fr
Publication of EP2626464A1 publication Critical patent/EP2626464A1/fr
Application granted granted Critical
Publication of EP2626464B1 publication Critical patent/EP2626464B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/18—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00 of old paper as in books, documents, e.g. restoring

Definitions

  • the present invention relates to a new chemical composition based on a suspension of hydroxyapatite nanoparticles (HAp) in carboxymethyl-cellulose (CMC) in alcoholic solution (isopropylic alcohol), used for paper deacidification, by acidity anihilation from 4.5 to 7.2.
  • HAp hydroxyapatite nanoparticles
  • CMC carboxymethyl-cellulose
  • alcoholic solution isopropylic alcohol
  • the paper degradation due to an excessive acidity (due to chemical or biological action), is reflected by the yellow tonalities appearance accompanied by an increased brittlement of the paper, which is transformed into a very fragile substance that is destroyed at the slightest touch.
  • the acid hydrolysis of cellulose that occurs during aging represents about 95% of the paper damages, and is considered as the most significant cause of deterioration of cellulosic materials.
  • Acid attack causes a random attack on hemi-acetal bonds between different constituents of cellulose molecules. This reaction will weaken the molecules, leading to the brittlement of cellulosic materials.
  • the present invention is to provide a new method for paper safeguard and conservation, by using nanosized hydroxyapatite (30 nm), mixed with carboxymethyl cellulose (the last compound being a compound with similar structure with the structure of the paper) in isopropanol solvent (solvent environment friendly and non-toxic), and prevent the destruction or impairment of the recognized printed or printed paper.
  • HA hydroxyapatite
  • CMC carboxymethyl-cellulose
  • HAp carboxymethyl-cellulose
  • CMC carboxymethyl-cellulose
  • HAp hidroxyapatite
  • the functional groups that contain pairs of positive charged ions of calcium and clusters of six atoms of oxygen negative charge associated with phosphate crystal triplets, generating hexagonal crystals with a columnar shape with Ca: P 1.67.
  • the ions Ca, P and hydroxyl groups, are located on the HA surface.
  • the two components of the composition HAp are interacting only by weak hydrogen bonds.
  • the interaction between CMC with HAp in this composition is visible in FTIR spectra through the widening of OH group bands (3500-3000 cm -1 ).
  • the electrostatic binding of the two components will be favored, too, forasmuch due to acidic pH, Ca 2+ ions located on the surface of HAp come into contact with the -COO 2- anions from the CMC surface.
  • the electrostatic link between these two components is stabilizing and neutralizing the paper pH where it is sprayed (visible at 1460 cm -1 band of the FTIR spectrum, attributed to ionic pair -Ca 2+ COO 2- ).
  • the atmospheric CO 2 has the ability to react with none of these two components, the risk of transformation of pH paper from the basic range to acidic one, is practically null.
  • composition hidroxyapatite carboxymethyl cellulose prepared by us, has the following advantages:

Landscapes

  • Paper (AREA)

Claims (3)

  1. Une composition constituée par: hydroxyapatite et carboxyméthyl cellulose (50% - 50%) dans 100 ml d'alcool Isopropylique.
  2. Une procédé d'obtenir d'une composition selon la revendication 1 caractérisé en ce qu'il consiste à les étapes suivantes: la production d'une suspension du carboxyméthyl cellulose dans l'alcool isopropylique, la production des nanoparticules d'hydroxyapatite, combinant les components obtenus dans les proportions suivantes: 0,2 g de HA CMC, 100 ml d'alcool isopropylique en agitant vigoureusement.
  3. Utilisation de la composition selon la revendication 1, pour la désacidification de papier, comprenant les étapes consistant à: enlever la poussière, le polissage avec des dispositifs mécaniques, nettoyage mécanique, l'enlèvement des dépôts de cire sèche, et en appliquant du cette composition par la pulvérisation sur la surface du papier endommagée, ce qui induit la désacidification de papier, en annihilation de l'acidité du papier à partir d'une pH 4,5 jusqu'a le domaine alcalin pH = 7,2, puis séchage pendant 24 heures à température ambiante.
EP11464027.9A 2011-12-15 2011-12-15 Composition de désacidification de papier, procédé permettant de l'obtenir et son procédé d'application Active EP2626464B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11464027.9A EP2626464B1 (fr) 2011-12-15 2011-12-15 Composition de désacidification de papier, procédé permettant de l'obtenir et son procédé d'application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP11464027.9A EP2626464B1 (fr) 2011-12-15 2011-12-15 Composition de désacidification de papier, procédé permettant de l'obtenir et son procédé d'application

Publications (2)

Publication Number Publication Date
EP2626464A1 EP2626464A1 (fr) 2013-08-14
EP2626464B1 true EP2626464B1 (fr) 2017-03-22

Family

ID=45524317

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11464027.9A Active EP2626464B1 (fr) 2011-12-15 2011-12-15 Composition de désacidification de papier, procédé permettant de l'obtenir et son procédé d'application

Country Status (1)

Country Link
EP (1) EP2626464B1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109028229B (zh) * 2018-09-29 2020-10-02 佛山市云米电器科技有限公司 一种带视觉检测模块油烟机的换档方法
CN109342382B (zh) * 2018-11-23 2022-11-15 复旦大学 一种带有pH响应荧光探针的脱酸功能纸的制备方法
CN112206585A (zh) * 2020-10-23 2021-01-12 徐少佐 空调过滤网自动清洗装置
CN113074379B (zh) * 2021-03-30 2021-12-31 龙南鑫坤无机新材料有限公司 一种高温去除氮氧化物设备
CN113430863B (zh) * 2021-07-21 2022-05-03 杭州众材科技股份有限公司 一种避免纸张水性脱酸后发生褶皱变形的干燥方法
CN114411446A (zh) * 2022-02-17 2022-04-29 复旦大学 一种脱酸加固抑菌复合功能保护剂及其制备方法与应用
CN116334955B (zh) * 2023-02-17 2024-05-03 甘继东 一种纸张修复装置
ES2943162A1 (es) * 2023-03-30 2023-06-09 Univ Pablo De Olavide Composicion para la desacidificacion de materiales celulosicos, metodo y usos

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676182A (en) * 1970-08-31 1972-07-11 Richard Daniel Smith Treatment of cellulosic materials
US5208072A (en) 1988-09-30 1993-05-04 Fmc Corporation Mass treatment of cellulosic materials
US5091111A (en) 1990-09-19 1992-02-25 S. C. Johnson & Son, Inc. Aqueous emulsion and aersol delivery system using same
US5770148A (en) 1996-01-16 1998-06-23 Preservation Technologies, L.P. Method and apparatus for the deacidification of library materials
US6676856B1 (en) 1998-01-09 2004-01-13 Richard Daniel Smith Deacidification treatment of printed cellulosic materials
US6593408B1 (en) * 1998-11-13 2003-07-15 Mitsui Chemicals, Inc. Organic polymer/inorganic fine particle-dispersed aqueous solution having excellent stability and uses thereof
DE19921616B4 (de) 1998-11-16 2007-06-28 Zfb Project-Management Gmbh Entsäuerungsmittel und Verfahren zur Entsäuerung von organischem Material
EP1468143A1 (fr) 2002-01-15 2004-10-20 Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase, C.S.G.I Suspension basique, elaboration de cette suspension, et procede de desacidification du papier
ITFI20020052A1 (it) 2002-03-28 2003-09-29 Consorzio Interuniversitario P Processo per la preparazione di nano - e micro-particelle di ossidi eidrossidi di metalli del secondo gruppo e di transizione, nano-e micro
US20080017336A1 (en) * 2004-02-27 2008-01-24 Wolfgang Wachter Process For Preservation Of Cellulosic Materials
JP2008520459A (ja) * 2004-11-17 2008-06-19 ビーエーエスエフ ソシエタス・ヨーロピア マイクロカプセルを有するコーティングを有する包装材料
RO126570B1 (ro) 2010-02-23 2014-08-29 Institutul Naţional De Cercetare-Dezvoltare Pentru Chimie Şi Petrochimie - Icechim Compoziţie şi procedeu de tratare, restaurare chimică şi dezinfecţie biologică a suprafeţei hârtiei documentelor din arhive şi biblioteci

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
EP2626464A1 (fr) 2013-08-14

Similar Documents

Publication Publication Date Title
EP2626464B1 (fr) Composition de désacidification de papier, procédé permettant de l'obtenir et son procédé d'application
US11718759B2 (en) Surface-reacted calcium carbonate with functional cations
EP1052225B1 (fr) Sol colloidal d'oxyde de titane et procede de preparation associe
CN102268842B (zh) 可溶性四硼酸盐作为纸张脱酸剂用于纸张脱酸的方法
US20200291235A1 (en) Post treatment of surface-reacted calcium carbonate with different functional cations
US10689520B2 (en) Modified mineral-based filler comprising copper salts
ES2352541T3 (es) Composición acuosa que contiene un carbonato de zirconio y de una sal de metal alcalino y un haluro de amonio, así como su uso.
KR20090108590A (ko) 광촉매 활성을 나타내는 코팅제의 제조방법 및 이것에 의해 얻어지는 코팅제
EP2139815B1 (fr) Procédé de préparation d'une composition aqueuse de carbonate de zirconium et d'un sel métallique alcalin et son utilisation
CA2473407A1 (fr) Suspension basique, elaboration de cette suspension, et procede de desacidification du papier
JP2012096133A (ja) 消臭性ルチル型酸化チタン微粒子および該微粒子を含む消臭性塗膜形成用塗布液、消臭性塗膜付基材
EP1111128B1 (fr) Produit de desacidification de matiere cellulosique, son obtention et utilisation
JP2019199574A (ja) 塗布液および塗布物
Musino et al. CNC/AgNP hybrids as safer-by-design biocides in paints
RO128766A2 (ro) Compoziţie pentru dezacidificarea hârtiei, procedeu de obţinere a acesteia şi procedeu de aplicare
JP2781865B2 (ja) 消臭性シート
US6743336B1 (en) Composition for de-acidification of cellulose material
KR20240000468A (ko) 제1 및 제2 완충제 성분을 포함하는 완충제 조성물
WO2023057314A1 (fr) Composition comprenant un carbonate de calcium ayant réagi en surface et un tanin
JP2003246967A (ja) 居住性向上スラリー状分散液
US20040194902A1 (en) Method for the de-acidification of celluso material
KR20230085162A (ko) 낮은 함량의 수용성 마그네슘 이온을 갖는 탄산칼슘 미립자 물질
JPH05132900A (ja) シート状ガス処理材
JP2004210930A (ja) ボールペン用水性インキ組成物

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20130128

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

RAX Requested extension states of the european patent have changed

Extension state: BA

Payment date: 20130925

Extension state: ME

17Q First examination report despatched

Effective date: 20160404

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20161209

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 877917

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170415

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602011036172

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170622

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170623

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 877917

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170622

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170722

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170724

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602011036172

Country of ref document: DE

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

26N No opposition filed

Effective date: 20180102

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602011036172

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20171215

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171215

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171215

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20180831

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20171231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171215

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180703

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180102

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171231

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171215

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171231

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20111215

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170322