EP2600996A2 - Verfahren zum pulvermetallurgischen herstellen eines cu-cr-werkstoffs - Google Patents
Verfahren zum pulvermetallurgischen herstellen eines cu-cr-werkstoffsInfo
- Publication number
- EP2600996A2 EP2600996A2 EP11751787.0A EP11751787A EP2600996A2 EP 2600996 A2 EP2600996 A2 EP 2600996A2 EP 11751787 A EP11751787 A EP 11751787A EP 2600996 A2 EP2600996 A2 EP 2600996A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- powder
- grains
- maximum
- switching contact
- temperature limit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/052—Metallic powder characterised by the size or surface area of the particles characterised by a mixture of particles of different sizes or by the particle size distribution
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1017—Multiple heating or additional steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/16—Both compacting and sintering in successive or repeated steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/0425—Copper-based alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/045—Alloys based on refractory metals
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/06—Alloys based on chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/0203—Contacts characterised by the material thereof specially adapted for vacuum switches
- H01H1/0206—Contacts characterised by the material thereof specially adapted for vacuum switches containing as major components Cu and Cr
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H11/00—Apparatus or processes specially adapted for the manufacture of electric switches
- H01H11/04—Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
- H01H11/048—Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by powder-metallurgical processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
- B22F2003/248—Thermal after-treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2301/00—Metallic composition of the powder or its coating
- B22F2301/10—Copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2301/00—Metallic composition of the powder or its coating
- B22F2301/20—Refractory metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2304/00—Physical aspects of the powder
- B22F2304/10—Micron size particles, i.e. above 1 micrometer up to 500 micrometer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
Definitions
- the present invention relates to a method for powder metallurgy
- Vacuum switch and a powder metallurgically produced Cu-Cr switching contact, in particular for vacuum switch. It involves the production of a high-performance Cu-Cr material. It is known to use Cu-Cr materials as material for switching contacts, in particular in the field of application of the vacuum switching principle.
- the vacuum switching principle has been found in the range of medium voltage, i. in the range of approx. 7.2 kV to 40 kV, already established as the leading switching principle worldwide, and there is also a trend towards use at higher voltages.
- Such switching contacts come here, e.g. used in both vacuum medium-voltage circuit breakers and vacuum contactors.
- the switching contacts require a switching capacity that is as constant as possible over the service life, a high dielectric strength and the lowest possible burnup. It is desired, a high erosion resistance, a good electrical and thermal conductivity, the lowest possible
- DE 10 2006 021 772 A1 describes a method for producing copper-chrome contacts for vacuum switches. Copper-chrome contacts for vacuum switches are thereby produced by producing a thin copper-chromium sheet as the starting material for the contacts by means of a casting or spraying process with subsequent rapid cooling. In this case, concentration profiles set in a direction perpendicular to the belt direction. A state diagram of the Cu-Cr system is also shown and described.
- Vacuum switching technology are purely powder metallurgical processes
- Cu-Cr materials have not yet satisfactorily exhibit the desired properties. It is an object of the present invention to provide a method for powder metallurgy producing a Cu-Cr material for a switching contact and a
- the method for powder metallurgy producing a Cu-Cr material for a switching contact comprises the following steps: pressing a Cu-Cr powder mixture formed from Cu powder and Cr powder, sintering the pressed Cu-Cr powder mixture to the material of the
- Treatment process is carried out with an alternating temperature profile in which the Cu-Cr powder mixture or the Cu-Cr material is heated at least twice alternately above an upper temperature limit and cooled again below a lower temperature limit. All steps are performed at temperatures that do not form a molten phase. The entire manufacturing process of the Cu-Cr material is thus pure
- molten phase comes. It will either be sintering or a
- Temperature increase and a decrease in temperature take place, with a Temperature increase and a temperature decrease in each case at least twice.
- the temperature increase and the temperature reduction preferably take place at least three times.
- the alternating temperature profile can be traversed, for example, during the sintering of the pressed Cu-Cr green body.
- the upper temperature limit can preferably be chosen so that the greatest possible solubility of Cr in Cu is given in solid solution.
- the lower temperature limit may preferably be chosen to provide a significantly lower solubility of Cr in Cu in solid solution than at the upper temperature limit.
- the production of the Cu-Cr material may be e.g. such that already the finished switching contact is provided in its final form, or e.g. also such that the switching contact is given its final shape only by suitable post-processing.
- the alternating temperature profile ensures that many Cr grains with grain sizes with a cross section between 0.1 pm 2 and 50 pm 2 (measured in the micrograph) are formed in a Cu matrix.
- the Cu-Cr material formed thus has a particle size distribution of the Cr grains measured in the micrograph, which has a first maximum in the range of grain sizes with a cross section between 0.1 pm 2 and 50 pm 2 . The determination of the particle size distribution takes place
- the described advantageous particle size distribution is also easily achieved when relatively coarse Cr powder (eg with particle diameters between 20 pm and 200 pm) is used as the starting material.
- the resulting Cu-Cr material has a microstructure in which the micrograph in a Cu -Matrix next to some smaller Cr-Kömern relatively large Cr grains with a grain diameter in the range between 100 pm and 150 ⁇ are present. This then typically results in a unimodal grain size distribution with a maximum, for example, with grain sizes in the range between 100 pm 2 and 25000 ⁇ m 2 . This suggests that the particle sizes of the Cr powder as the starting material in the resulting Cu-Cr material are substantially maintained unless the alternating temperature profile is traversed.
- Cr powder fractions is higher than in coarse-grained powders. Another difficulty in the processing of fine powders is the handling of the
- the resulting Cu-Cr material is ideal for switching contacts for use in vacuum switching technology, both as a circuit breaker in the high and medium voltage range as well as a vacuum contactor switch in the
- the upper temperature limit is in a range between 1065 ° C and 1025 ° C and the lower temperature limit is at least 50 ° C below the upper temperature limit.
- the lower temperature limit is preferably at least 100 ° C below the upper temperature limit.
- the upper temperature limit is in a temperature range just below the temperature of the eutectic (1075 ° C), that is, a range in which up to about 0.7 at% Cr can be dissolved in the Cu matrix in solid solution. This corresponds to the range in which the maximum solubility of Cr in Cu is given in solid solution.
- the upper temperature limit is far enough below the temperature of the eutectic that the formation of a
- the lower temperature limit is well below the upper temperature limit, ie in a range in which (in thermal equilibrium) a significantly smaller amount of Cr in the Cu matrix can be dissolved in solid solution.
- the upper temperature limit Cr it is enriched in the material of the Cu matrix (up to a maximum of approximately 0.7 at%).
- the method further comprises the step of: mixing Cu powder and Cr powder into a Cu-Cr powder mixture.
- the Cu-Cr powder mixture can be easily provided by using conventional Cr powder and Cu powder.
- the Cu particles in the Cu-Cr powder mixture have a particle size distribution with a maximum particle diameter 80 ⁇ , preferably
- Particle diameter is determined by means of a sieve analysis.
- a sieve with a corresponding mesh size for example 80 ⁇ m or 50 ⁇ m is used and only particles which fall through the sieve are used.
- the Cr particles in the Cu-Cr powder mixture have a particle size distribution with a maximum particle diameter of 200 ⁇ m, preferably
- Sieve analysis determined with a corresponding mesh size of the sieve.
- the value for the maximum particle diameter is small enough so as not to form excessively large Cr grains in the Cu-Cr material.
- the individual particles can also be formed large enough so that no excessive risk of contamination by oxides occurs and in conventional production plants, a high density and a low degree of porosity can be achieved.
- the Cr particles in the Cu-Cr powder mixture have a particle size distribution with a minimum particle diameter of 20 ⁇ m, preferably z 32 ⁇ m.
- the minimum particle diameter is also determined using a sieve analysis (with a mesh size of, for example, 20 ⁇ m or 32 ⁇ m), but in this case only the particles that do not fall through the sieve are used. In this case, the minimum particle diameter is large enough so that there is no undue risk of contamination by oxides and conventional ones Production facilities high density and a low degree of porosity can be achieved.
- the Cu-Cr powder mixture has a Cu content between 30% by weight and 80% by weight and a Cr content between 70% by weight and 20% by weight. In this case it is achieved that both a high
- the object is also achieved by a powder-metallurgically produced Cu-Cr switching contact according to claim 8.
- Advantageous developments are specified in the dependent claims.
- the Cu-Cr switch contact can for
- Vacuum switch be formed.
- the powder-metallurgically produced Cu-Cr switch contact has a Cu content between 30 wt .-% and 80 wt .-% and a Cr content between 70 wt .-% and 20 wt .-%.
- the Cu-Cr switch contact has Cr grains in a Cu matrix.
- a particle size distribution of Cr grains measured in the micrograph has a first
- a Cu matrix is understood to mean a material which mainly consists of Cu but may also have a small proportion of Cr in solid solution. There may also be traces of impurities.
- Cr grains are formed.
- the grain size distribution of the Cr grains is determined as follows: A micrograph of the Cu-Cr material of the switch contact is made and analyzed microscopically. The micrograph identifies the Cr grains and the Cross-sectional areas of the Cr grains are measured. The evaluation takes place over a sufficiently large surface area or different
- the evaluation can be done eg by hand or supported by a suitable software.
- the particle size distribution is seen.
- the particle size distribution has a maximum in a range of grain sizes with a measured cross-sectional area between 0.1 ⁇ 2 and 50 ⁇ 2 .
- the powder-metallurgically produced Cu-Cr switch contact achieves the advantages described above with respect to the method of powder metallurgy producing a Cu-Cr material for a switch contact. Due to the pure powder metallurgical production a particularly economical production is possible. Due to the grain size distribution with the maximum in the range of grain sizes with a cross-sectional area between 0.1 pm 2 and 50 pm 2 , the Cu-Cr switch contact has a large number of fine Cr grains. The fine ones
- powder metallurgical process is available, is carried out in the sintering or a subsequent thermal treatment process with an alternating temperature profile in which a Cu-Cr powder mixture or the material of the
- Temperature limit is heated and cooled again below a lower temperature limit and wherein all steps are carried out at temperatures at which no molten phase is formed.
- the production in a purely powder metallurgical process can be seen on the Cu-Cr switch contact.
- the grain size distribution of the Cr grains has a second maximum in the range of grain sizes with a cross-sectional area between 100 pm 2 and 10000 pm 2 .
- a bimodal Cr phase distribution having two maxima, a first maximum at grain sizes with one measured cross-sectional area between 0.1 ⁇ 2 and 50 pm 2 and a second maximum at grain sizes with a measured cross-sectional area between 100 pm 2 and 10,000 pm 2 .
- This particle size distribution results from the pure powder metallurgical production process using coarse Cr powder, for example with particle diameters between 20 pm and 200 pm.
- the number of Cr grains corresponding to the first maximum is greater than the number of the second maximum
- the Cu-Cr switch contact has a relative density> 90%.
- good electrical and thermal conductivity and high mechanical strength are reliably provided.
- Such a high relative density can be reliably achieved by using relatively coarse
- relative density is meant the ratio between the density achieved and the theoretically achievable density for the composition.
- the combination of this high density and the high proportion of fine Cr grains in the Cu matrix can be achieved by combining a use of coarse Cr powder (with particle diameters between 20 pm and 200 pm) and using a
- Fig. 1 shows a grain size distribution of the Cr grains in a powder metallurgically produced Cu-Cr material in the initial state (solid line) and after passing through an alternating temperature profile (dashed line).
- Fig. 2 shows a light microscopic micrograph of a powder metallurgical
- Fig. 3 shows a light microscopic micrograph of a powder metallurgy
- Fig. 4 shows schematically the method steps of a method for
- a first step -S1- is Cu powder with a maximum
- Cu-Cr powder mixture having a Cr content of 43 wt .-% and a Cu content of 57 wt .-% produced.
- a second step -S2- the Cu-Cr powder mixture is pressed.
- the Cu-Cr powder mixture is compacted by cold pressing at a compression pressure in a range between 400 MPa and 850 MPa.
- a subsequent step -S3- the green compact thus formed in a sintering process at temperatures in a temperature range well below the temperature of the eutectic (ie, well below 1075 ° C) sintered.
- Steps -S1- to -S3- a molten phase in the Cu-Cr powder mixture or in the pressed green compact from.
- the sintering process can be used, for example, in
- the temperatures must be high enough so that the sintering process proceeds sufficiently and with sufficient speed, and low enough that even in unavoidable
- FIG. 2 An exemplary light microscopic micrograph of a powder-metallurgically produced Cu-Cr material after step -S3- is shown in FIG. In Fig. 2 it can be seen that in a Cu matrix Cr grains with different
- Fig. 1 An evaluation of the grain size distribution of the Cr grains in the thus prepared Cu-Cr material is shown in Fig. 1 by a solid line. A micrograph of the Cu-Cr material was prepared and the size of the Cr grains was examined microscopically and measured. There were 10 different
- Fig. 1 the measured cross-sectional area of the Cr grains in pm 2 is plotted on a logarithmic scale on the horizontal axis. On the vertical axis, the corresponding number of grains normalized to a unit area of 1 mm 2 is also shown in a logarithmic representation.
- the Cu-Cr material in this process stage has a monomodal particle size distribution with particle sizes in a range between approximately 10 ⁇ m 2 and 25000 ⁇ m 2 .
- the particle size distribution has a maximum, which is in the range of> 100 pm 2 for particle sizes.
- the Cu-Cr material is then subjected to a thermal treatment process with an alternating temperature profile, as described below becomes.
- the Cu-Cr material is alternately heated to a temperature above an upper temperature limit and cooled to a temperature below a lower temperature limit.
- the alternating heating and cooling take place at least twice. In these process steps, too, care is taken to ensure that no molten phase is formed, ie
- Cu-Cr material is kept at temperatures below the temperature of the eutectic (1075 ° C) of the Cu-Cr system. This will be described in more detail below.
- the Cu-Cr material is heated to a temperature above the upper temperature limit.
- the upper temperature limit is preferably relatively close below the temperature of the eutectic of the Cu-Cr system, so that the Cu-Cr material is brought to a temperature just below the temperature of the eutectic, but far enough from the
- the upper temperature limit value is thus preferably in a range between 1025 ° C and 1065 ° C.
- the lower temperature limit value is preferably in a range which is at least 50 ° C. below the upper temperature limit value, more preferably in a range of more than 100 ° C. below the upper temperature limit value.
- the lower temperature limit is preferably at most 250 ° C below the upper temperature limit, more preferably at most 180 ° C below the upper temperature limit.
- the lower temperature limit should be chosen so that there is a much lower solubility of Cr in solid solution in Cu than at the upper temperature limit. The reason for this choice will be explained in more detail. For example, can the Cu-Cr material on
- the step -S5- is repeated, i. the Cu-Cr material is again cooled to a temperature below the lower temperature limit.
- the steps -S4- and -S5- are repeated a total of n times, but a total of at least twice, preferably at least three times. It has been shown that at 2 times to about 6 times (2: £ n £ 6) go through the steps -S4- and
- Cu-Cr material is therefore exposed to a pendulum annealing. At least the
- Steps -S4- and -S5- are performed in a protective gas oven under reducing
- Fig. 3 shows a light microscopic micrograph of a powder metallurgy
- Fig. 1 is shown as a dashed line, the determined particle size distribution after passing through the alternating temperature profile.
- Grain size distribution was determined in the same manner as described above with reference to the solid line of FIG. It can be seen that after the pendulum annealing instead of the previously existing monomodal
- Grain size distribution (solid line) is a bimodal grain size distribution.
- the particle size distribution has a first maximum in a range of grain sizes with a cross-sectional area between 0.1 pm 2 and 50 pm 2 .
- the particle size distribution has a second maximum in the range of grain sizes a cross-sectional area between 100 ⁇ 2 and 10000 ⁇ 2 on.
- the number of Cr grains corresponding to the first maximum is greater than the number of Cr grains corresponding to the second maximum.
- the number of Cr grains corresponding to the first maximum is larger than the number of Cr grains corresponding to the second maximum by a factor> 5. Furthermore, there is a very homogeneous distribution of the Cr grains in the Cu matrix.
- the proportion of Cr grains with a cross-sectional area ⁇ 10 ⁇ 2 measured in the microsection is thus very high.
- the thermal treatment with the alternating temperature profile thus achieves a shift to a high proportion of very small finely divided Cr grain precipitates in the Cu matrix.
- the described starting materials having a relatively coarse particle size of the Cr powder, it is possible to produce very dense Cu-Cr materials with low porosity in a purely powder metallurgical process with conventional production plants, which also have a low level of impurities.
- the pure powder metallurgy production is recognizable on the Cu-Cr material. Due to the very finely distributed Cr grains, the purely powder-metallurgically produced Cu-Cr material has a high erosion resistance, a high dielectric strength and a sufficient mechanical strength of the switching contact.
- the temperature change between the high and the low temperature level in the pendulum annealing should be chosen to be sufficiently slow that Cr is reliably precipitated from the Cu matrix on cooling, but not too slow so that larger Cr grains are not produced again by grain coarsening.
- Experiments were also carried out with Cu-Cr powder mixtures with other ratios between Cr and Cu, which also led to comparable results.
- experiments with a Cr content of 70 wt .-% and a Cu content of 30 wt .-% resulted in respect to the fine Cr precipitates to a comparable result.
- Temperature profile takes place after the step -S3- of sintering in the Cu-Cr material, it is e.g. also possible already to carry out the sintering process itself with an alternating temperature profile.
- the pressed Cu-Cr green compact is already subjected to the steps -S4- and -SS- repeatedly during the sintering process.
- the separate step -S3- is omitted and the sintering takes place during the steps -S4- and -S5-.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
- High-Tension Arc-Extinguishing Switches Without Spraying Means (AREA)
- Contacts (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0048410U AT11814U1 (de) | 2010-08-03 | 2010-08-03 | Verfahren zum pulvermetallurgischen herstellen eines cu-cr-werkstoffs |
PCT/AT2011/000319 WO2012016257A2 (de) | 2010-08-03 | 2011-08-01 | Verfahren zum pulvermetallurgischen herstellen eines cu-cr-werkstoffs |
Publications (2)
Publication Number | Publication Date |
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EP2600996A2 true EP2600996A2 (de) | 2013-06-12 |
EP2600996B1 EP2600996B1 (de) | 2018-06-06 |
Family
ID=43646247
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP11751787.0A Active EP2600996B1 (de) | 2010-08-03 | 2011-08-01 | Verfahren zum pulvermetallurgischen herstellen eines cu-cr-werkstoffs |
Country Status (6)
Country | Link |
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US (2) | US20130140159A1 (de) |
EP (1) | EP2600996B1 (de) |
CN (1) | CN103201059B (de) |
AT (1) | AT11814U1 (de) |
ES (1) | ES2686421T3 (de) |
WO (1) | WO2012016257A2 (de) |
Families Citing this family (16)
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WO2014084315A1 (ja) * | 2012-11-28 | 2014-06-05 | 古河機械金属株式会社 | 熱電変換モジュール |
US9992917B2 (en) | 2014-03-10 | 2018-06-05 | Vulcan GMS | 3-D printing method for producing tungsten-based shielding parts |
CN104232961B (zh) * | 2014-09-10 | 2016-09-21 | 华南理工大学 | 一种高强高硬Cu-Cr复合材料及其制备方法和应用 |
CN105018815B (zh) * | 2015-07-31 | 2017-03-08 | 陕西斯瑞新材料股份有限公司 | 一种高Cr含量、高耐压性铜铬触头材料及其制备方法 |
RU2645855C2 (ru) * | 2016-06-28 | 2018-02-28 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Способ получения электроконтактного композитного материала на основе меди, содержащего кластеры на основе частиц тугоплавкого металла |
US10468205B2 (en) * | 2016-12-13 | 2019-11-05 | Eaton Intelligent Power Limited | Electrical contact alloy for vacuum contactors |
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CN112391556B (zh) * | 2020-11-17 | 2022-02-11 | 中南大学 | 一种双峰晶粒尺寸、双尺度纳米相强化的高强高导Cu-Cr-Nb合金 |
CN112553500B (zh) * | 2020-12-11 | 2022-04-05 | 中南大学 | 一种同时提高Cu-Cr-Nb合金强度和导电率的方法 |
CN112985052A (zh) * | 2021-04-09 | 2021-06-18 | 江西科技学院 | 一种隧道式连续烧结炉及其烧结方法 |
CN114769585B (zh) * | 2022-04-20 | 2024-01-05 | 中铝科学技术研究院有限公司 | 一种Cu-Cr-Nb系合金的冷喷涂成形方法 |
CN114951665B (zh) * | 2022-05-17 | 2024-04-16 | 浙江省冶金研究院有限公司 | 一种低成本高致密高导电铜铬触头的制备方法 |
CN115323217A (zh) * | 2022-08-23 | 2022-11-11 | 陕西斯瑞新材料股份有限公司 | 一种低成本CuCr25触头材料的制备方法 |
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DE3363383D1 (en) * | 1982-07-16 | 1986-06-12 | Siemens Ag | Process for manufacturing a composite article from chromium and copper |
EP0172411B1 (de) * | 1984-07-30 | 1988-10-26 | Siemens Aktiengesellschaft | Vakuumschütz mit Kontaktstücken aus CuCr und Verfahren zur Herstellung dieser Kontaktstücke |
JPH0760623B2 (ja) * | 1986-01-21 | 1995-06-28 | 株式会社東芝 | 真空バルブ用接点合金 |
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JPH04505985A (ja) * | 1989-05-31 | 1992-10-15 | シーメンス アクチエンゲゼルシヤフト | 真空スイツチ用CuCr接触片の製法並びに付属接触片 |
JP2705998B2 (ja) * | 1990-08-02 | 1998-01-28 | 株式会社明電舎 | 電気接点材料の製造方法 |
CN1016185B (zh) * | 1990-11-03 | 1992-04-08 | 冶金工业部钢铁研究总院 | 铜铬铁真空触头材料 |
JP2908073B2 (ja) * | 1991-07-05 | 1999-06-21 | 株式会社東芝 | 真空バルブ用接点合金の製造方法 |
US5561834A (en) * | 1995-05-02 | 1996-10-01 | General Motors Corporation | Pneumatic isostatic compaction of sintered compacts |
DE10010723B4 (de) * | 2000-03-04 | 2005-04-07 | Metalor Technologies International Sa | Verfahren zum Herstellen eines Kontaktwerkstoff-Halbzeuges für Kontaktstücke für Vakuumschaltgeräte sowie Kontaktwerkstoff-Halbzeuge und Kontaktstücke für Vakuumschaltgeräte |
KR100400356B1 (ko) * | 2000-12-06 | 2003-10-04 | 한국과학기술연구원 | 진공개폐기용 구리-크롬계 접점 소재의 조직 제어 방법 |
KR100400354B1 (ko) * | 2000-12-07 | 2003-10-04 | 한국과학기술연구원 | 진공개폐기용 구리-크롬계 접점 소재 제조 방법 |
CN1233492C (zh) * | 2003-06-30 | 2005-12-28 | 哈尔滨工业大学 | W-Cu或Cu-Cr粉末形变复合电极材料制备方法 |
EP1875481A1 (de) * | 2005-04-16 | 2008-01-09 | ABB Technology AG | Verfahren zur herstellung von kontaktstücken für vakuumschaltkammern |
DE102006021772B4 (de) | 2006-05-10 | 2009-02-05 | Siemens Ag | Verfahren zur Herstellung von Kupfer-Chrom-Kontakten für Vakuumschalter und zugehörige Schaltkontakte |
JP5124734B2 (ja) * | 2008-10-31 | 2013-01-23 | 明電T&D株式会社 | 真空遮断器用電極材料及びその製造方法 |
ATE515343T1 (de) * | 2008-12-08 | 2011-07-15 | Umicore Ag & Co Kg | Verwendung von cucr-abfallspänen für die herstellung von cucr-kontaktrohlingen |
CN101540238B (zh) * | 2009-04-30 | 2011-06-22 | 西安交通大学 | 一种合金化的铜铬触头材料制备工艺 |
CN101786164A (zh) * | 2010-03-05 | 2010-07-28 | 陕西斯瑞工业有限责任公司 | 采用CrMo合金粉制备CuCrMo触头材料的方法 |
-
2010
- 2010-08-03 AT AT0048410U patent/AT11814U1/de not_active IP Right Cessation
-
2011
- 2011-08-01 WO PCT/AT2011/000319 patent/WO2012016257A2/de active Application Filing
- 2011-08-01 US US13/813,996 patent/US20130140159A1/en not_active Abandoned
- 2011-08-01 EP EP11751787.0A patent/EP2600996B1/de active Active
- 2011-08-01 ES ES11751787.0T patent/ES2686421T3/es active Active
- 2011-08-01 CN CN201180038423.7A patent/CN103201059B/zh active Active
-
2015
- 2015-12-21 US US14/976,553 patent/US20160107237A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
AT11814U1 (de) | 2011-05-15 |
EP2600996B1 (de) | 2018-06-06 |
CN103201059A (zh) | 2013-07-10 |
WO2012016257A2 (de) | 2012-02-09 |
US20130140159A1 (en) | 2013-06-06 |
CN103201059B (zh) | 2016-06-29 |
US20160107237A1 (en) | 2016-04-21 |
WO2012016257A3 (de) | 2012-11-01 |
ES2686421T3 (es) | 2018-10-17 |
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