EP2496734A1 - Gleitelement, insbesondere kolbenring, und kombination eines gleitelements mit einem laufpartner - Google Patents

Gleitelement, insbesondere kolbenring, und kombination eines gleitelements mit einem laufpartner

Info

Publication number
EP2496734A1
EP2496734A1 EP10744595A EP10744595A EP2496734A1 EP 2496734 A1 EP2496734 A1 EP 2496734A1 EP 10744595 A EP10744595 A EP 10744595A EP 10744595 A EP10744595 A EP 10744595A EP 2496734 A1 EP2496734 A1 EP 2496734A1
Authority
EP
European Patent Office
Prior art keywords
layer
metal
sliding element
dlc
free
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP10744595A
Other languages
German (de)
English (en)
French (fr)
Inventor
Marcus Kennedy
Michael Zinnabold
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
H-O-T Harte- und Oberflachentechnik & Co KG GmbH
Federal Mogul Burscheid GmbH
Original Assignee
H-O-T Harte- und Oberflachentechnik & Co KG GmbH
Federal Mogul Burscheid GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by H-O-T Harte- und Oberflachentechnik & Co KG GmbH, Federal Mogul Burscheid GmbH filed Critical H-O-T Harte- und Oberflachentechnik & Co KG GmbH
Publication of EP2496734A1 publication Critical patent/EP2496734A1/de
Ceased legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16JPISTONS; CYLINDERS; SEALINGS
    • F16J9/00Piston-rings, e.g. non-metallic piston-rings, seats therefor; Ring sealings of similar construction
    • F16J9/26Piston-rings, e.g. non-metallic piston-rings, seats therefor; Ring sealings of similar construction characterised by the use of particular materials
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/26Deposition of carbon only
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/02Pretreatment of the material to be coated
    • C23C16/0272Deposition of sub-layers, e.g. to promote the adhesion of the main coating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/02Pretreatment of the material to be coated
    • C23C16/0272Deposition of sub-layers, e.g. to promote the adhesion of the main coating
    • C23C16/029Graded interfaces
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/044Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material coatings specially adapted for cutting tools or wear applications
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • C23C28/046Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material with at least one amorphous inorganic material layer, e.g. DLC, a-C:H, a-C:Me, the layer being doped or not
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F5/00Piston rings, e.g. associated with piston crown

Definitions

  • the invention relates to a sliding element, in particular a piston ring, with a coating and a combination of a sliding element with a running partner.
  • Piston ring can be seen with a cylinder liner.
  • the cylinders or cylinder liners are made of, for example, aluminum-silicon alloys, which is the case in particular for gasoline engines, DLC (diamond iike carbon) coating systems have proven to be effective in terms of wear and friction.
  • DLC diamond iike carbon
  • the known DLC layer systems are diesel or high in terms of service life as well as their applicability
  • Layer thicknesses are also known PVD coatings, in particular based on CrN, the layer thicknesses in the range of 10-30 ⁇ have. Although this results in an improved life, but deteriorates the
  • Friction loss and wear resistance especially in case of insufficient lubrication, as well as fire safety.
  • DLC layer systems offer the advantage of exhibiting a largely chemical inactivity with metallic surfaces and thus an extremely low adhesive tendency towards the iron on the track.
  • DE 296 05 666 Ul relates to a component in the region of an internal combustion engine, which is coated with a metal-free, amorphous carbon layer whose hardness profile over the layer thickness is graduated.
  • DE 10 2008 016 864 B3 discloses a piston ring which has, from the inside to the outside, an adhesive layer, a metal-containing, amorphous carbon splint and a metal-free, amorphous carbon layer.
  • WO 2009/106201 AI relates to a component of a
  • WO 2006/125683 A1 shows a piston ring which has, from the inside to the outside, a layer with an element of groups IVB, VB or VIB, an intermediate layer with a diamond-like nanocomposite composition and a DLC layer. Presentation of the invention
  • the invention has for its object to provide a sliding element, in particular a piston ring, which in particular when used in diesel or highly charged petrol engines with, for example, iron-based running partners the
  • Frictional performance met. Furthermore, a suitable combination of a sliding element with a running partner should be specified.
  • the DLC layer is either metal-free or has one
  • the DLC layer is at least partially metal-free and in particular has a metal-free DLC layer on the outer surface. Furthermore, extensive tests have shown that a particularly good behavior of the coating described occurs when an intermediate layer is provided between the CrN and the DLC layer as Me (C x Ny) layer. For this layer structure was found in experiments that the
  • the CrN layer is preferably applied to the piston base material without an adhesive layer, for example by metallic vapor deposition or sputtering.
  • the CrN layer may be special Applications be attached by means of an adhesive layer to the base material of the sliding element.
  • Me stands for metal and, for example, tungsten, chromium, titanium or silicon can be used for this purpose.
  • carbon and nitrogen may be present in almost any proportion in the described layer, i. H. both x and y can range from 0-99 atomic percent.
  • the coating can be provided, in particular at least partially, on at least one running surface. Further, the coating may extend into the transition to surfaces and to surfaces adjacent the treads. This concerns, for example, the running flanks of a piston ring.
  • the metal-containing DLC layer may also advantageously nanocrystalline Metallcarbarbscheidiens, such as. WC, CrC, SIC, GeC or Tic.
  • the top layer forming the surface has a roughness Rz of ⁇ 5 ⁇ m and / or Rpk of ⁇ 0.8 ⁇ m.
  • the invention further relates to a combination of at least one sliding element described above with a
  • Running partner in particular a cylinder or a
  • Figure 1 shows a Schichtier au invention
  • Figure 2 shows the relative wear of a piston ring
  • a CrN layer 12 is applied to the base material 10 of the sliding element.
  • the adhesive layer 14 shown in FIG. 1 does not necessarily have to be provided. In particular, it is preferred to omit them.
  • a Me (C x Ny) intermediate layer 16 of the outside of a DLC layer 18 is provided, the
  • the "Series DLC” system is a standard DLC coating system without CrN
  • the percentages shown indicate what percentage of the original DLC layer is still present after the end of the experiment, and if this value is greater than 100 percent, the CrN resp CrO layer at least
  • Cylinder liner in an acceptable range.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Physical Vapour Deposition (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Carbon And Carbon Compounds (AREA)
EP10744595A 2009-11-02 2010-08-19 Gleitelement, insbesondere kolbenring, und kombination eines gleitelements mit einem laufpartner Ceased EP2496734A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009046281A DE102009046281B3 (de) 2009-11-02 2009-11-02 Gleitelement, insbesondere Kolbenring, und Kombination eines Gleitelements mit einem Laufpartner
PCT/EP2010/062096 WO2011051008A1 (de) 2009-11-02 2010-08-19 Gleitelement, insbesondere kolbenring, und kombination eines gleitelements mit einem laufpartner

Publications (1)

Publication Number Publication Date
EP2496734A1 true EP2496734A1 (de) 2012-09-12

Family

ID=42831604

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10744595A Ceased EP2496734A1 (de) 2009-11-02 2010-08-19 Gleitelement, insbesondere kolbenring, und kombination eines gleitelements mit einem laufpartner

Country Status (9)

Country Link
US (1) US10131988B2 (pt)
EP (1) EP2496734A1 (pt)
JP (1) JP5678075B2 (pt)
KR (1) KR101703962B1 (pt)
CN (1) CN102666925B (pt)
BR (1) BR112012010336B1 (pt)
DE (1) DE102009046281B3 (pt)
RU (1) RU2531220C2 (pt)
WO (1) WO2011051008A1 (pt)

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DE102010062114B4 (de) * 2010-11-29 2014-12-11 Federal-Mogul Burscheid Gmbh Gleitelement, insbesondere Kolbenring, mit einer Beschichtung
BRPI1009955A2 (pt) * 2010-12-27 2013-06-11 Whirlpool Sa conjunto pistço - cilindro para compressor alternativo
JP2012202522A (ja) * 2011-03-28 2012-10-22 Tpr Co Ltd ピストンリング
BRPI1105714B1 (pt) 2011-12-07 2021-01-05 Mahle Metal Leve S/A componente deslizante para uso em motores de combustão interna
BR102012003607A2 (pt) 2012-02-16 2013-10-29 Mahle Metal Leve Sa Componente deslizante para uso em motores de combustão interna
FR2990246B1 (fr) 2012-05-03 2014-05-02 Hydromecanique & Frottement Chemise de moteur a combustion interne
BR102012012636B1 (pt) 2012-05-25 2022-01-04 Mahle Metal Leve S/A Cilindro para aplicação em um motor de combustão interna
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DE102012214284B4 (de) 2012-08-10 2014-03-13 Federal-Mogul Burscheid Gmbh Gleitelement, insbesondere Kolbenring, mit einer widerstandsfähigen Beschichtung
BR102012022941A2 (pt) * 2012-09-11 2014-07-01 Mahle Metal Leve Sa Pistão de motor e processo de fabricação de um pistão de motor
DE102012219930A1 (de) * 2012-10-31 2014-04-30 Federal-Mogul Burscheid Gmbh Gleitelement, insbesondere Kolbenring, mit einer Beschichtung
US20140137831A1 (en) * 2012-11-21 2014-05-22 RZR Corporation Cylinder Bore Coating System
US9617654B2 (en) * 2012-12-21 2017-04-11 Exxonmobil Research And Engineering Company Low friction coatings with improved abrasion and wear properties and methods of making
JP5564099B2 (ja) * 2012-12-28 2014-07-30 株式会社リケン シリンダとピストンリングの組合せ
DE102013200846A1 (de) * 2013-01-21 2014-07-24 Federal-Mogul Burscheid Gmbh Gleitelement, insbesondere Kolbenring, mit einer Beschichtung
GB201304340D0 (en) * 2013-03-11 2013-04-24 Element Six Gmbh Roller bearing assembly and elements thereof, and method of making a roller element
FR3008905B1 (fr) * 2013-07-25 2017-01-13 Hydromecanique & Frottement Piece mecanique revetue d'une couche de carbone amorphe en vue de son glissement vis-a-vis d'un autre composant moins dur
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DE102014200607A1 (de) * 2014-01-15 2015-07-16 Federal-Mogul Burscheid Gmbh Gleitelement, insbesondere Kolbenring
TR201902064T4 (tr) * 2015-02-24 2019-03-21 Oerlikon Surface Solutions Ag Pfaeffikon Yüksek mukavemetli çeliği soğuk metal biçimlendirmeye yönelik yüksek performanslı kaplama.
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US10030773B2 (en) 2016-03-04 2018-07-24 Mahle International Gmbh Piston ring
BR102016015392A2 (pt) * 2016-06-30 2018-01-16 Mahle Metal Leve S.A. Sliding element for internal combustion engines
BR102017007599B1 (pt) * 2017-04-12 2022-07-26 Mahle Metal Leve S.A. Anel de pistão para motores de combustão interna
EP3828309A1 (de) * 2019-11-28 2021-06-02 Winterthur Gas & Diesel AG Kolbenring für einen grossmotor sowie grossmotor
CN114686829A (zh) * 2020-12-29 2022-07-01 苏州吉恒纳米科技有限公司 一种耐磨耐疲劳和反复冲击的涂层及生产工艺
DE102022209916A1 (de) 2022-09-21 2024-03-21 Robert Bosch Gesellschaft mit beschränkter Haftung Werkstück mit DLC-Beschichtung, beispielsweise Pumpenkolben einer Kraftstoff-Hochdruckpumpe

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Also Published As

Publication number Publication date
JP5678075B2 (ja) 2015-02-25
KR101703962B1 (ko) 2017-02-07
CN102666925A (zh) 2012-09-12
KR20120091212A (ko) 2012-08-17
US20130042845A1 (en) 2013-02-21
RU2531220C2 (ru) 2014-10-20
WO2011051008A1 (de) 2011-05-05
JP2013509497A (ja) 2013-03-14
BR112012010336B1 (pt) 2019-09-03
RU2012122808A (ru) 2013-12-10
DE102009046281B3 (de) 2010-11-25
CN102666925B (zh) 2016-08-03
BR112012010336A2 (pt) 2016-11-29
US10131988B2 (en) 2018-11-20

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