EP2417840B1 - Kühlrohre, elektrodenaufnahmen und elektrode für einen lichtbogenplasmabrenner sowie anordnungen aus denselben und lichtbogenplasmabrenner mit denselben - Google Patents

Kühlrohre, elektrodenaufnahmen und elektrode für einen lichtbogenplasmabrenner sowie anordnungen aus denselben und lichtbogenplasmabrenner mit denselben Download PDF

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Publication number
EP2417840B1
EP2417840B1 EP10720245.9A EP10720245A EP2417840B1 EP 2417840 B1 EP2417840 B1 EP 2417840B1 EP 10720245 A EP10720245 A EP 10720245A EP 2417840 B1 EP2417840 B1 EP 2417840B1
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EP
European Patent Office
Prior art keywords
electrode
cooling pipe
electrode holder
face
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP10720245.9A
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German (de)
English (en)
French (fr)
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EP2417840A2 (de
Inventor
Frank Laurisch
Volker Krink
Ralf-Peter Reinke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kjellberg Finsterwalde Plasma und Maschinen GmbH
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Kjellberg Finsterwalde Plasma und Maschinen GmbH
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Priority to PL10720245T priority Critical patent/PL2417840T3/pl
Priority to SI201031660T priority patent/SI2417840T1/en
Publication of EP2417840A2 publication Critical patent/EP2417840A2/de
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Publication of EP2417840B1 publication Critical patent/EP2417840B1/de
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/28Cooling arrangements
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • H05H1/3457Nozzle protection devices
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • H05H1/3436Hollow cathodes with internal coolant flow
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/26Plasma torches
    • H05H1/32Plasma torches using an arc
    • H05H1/34Details, e.g. electrodes, nozzles
    • H05H1/3442Cathodes with inserted tip

Definitions

  • the present invention relates to cooling tubes, electrode holders and electrodes for an arc plasma torch, and to arrangements of the same and a plasma arc torch with the same.
  • Plasma is a thermally highly heated electrically conductive gas, which consists of positive and negative ions, electrons and excited and neutral atoms and molecules.
  • the plasma gas used is a variety of gases, for example the monatomic argon and / or the diatomic gases hydrogen, nitrogen, oxygen or air. These gases ionize and dissociate through the energy of an arc. The narrowed by a nozzle arc is then referred to as plasma jet.
  • the plasma jet can be greatly influenced in its parameters by the design of the nozzle and electrode. These parameters of the plasma jet are, for example, the beam diameter, the temperature, the energy density and the flow velocity of the gas.
  • the plasma is constricted through a nozzle, which may be gas or water cooled.
  • a nozzle which may be gas or water cooled.
  • energy densities up to 2x10 6 W / cm 2 can be achieved.
  • Temperatures of up to 30,000 ° C are generated in the plasma jet, which, in combination with the high flow velocity of the gas, produce very high cutting speeds on materials.
  • the nozzle is then inserted into an arc plasma torch, or plasma torch, whose main components are a plasma torch head, a nozzle cap, a plasma gas guide member, a nozzle, a nozzle holder, an electrode insert electrode and, in modern plasma torches, a nozzle cap retainer and nozzle cap.
  • a pointed tungsten electrode insert which is suitable for the use of non-oxidizing gases as plasma gas, for example an argon-hydrogen mixture.
  • a so-called flat electrode whose electrode insert consists for example of hafnium is also suitable for the use of oxidizing gases as plasma gas, for example air or oxygen.
  • the nozzle and the electrode is often cooled with a liquid, for example water, but it can also be cooled with a gas.
  • the electrode consists of a good electrical and heat conductive material, such as copper and silver or their alloys, and an electrode insert made of a temperature-resistant material, eg. As tungsten, zirconium or hafnium. Zirconium can be used for oxygen-containing plasma gases.
  • hafnium is more suitable because its oxide is more temperature resistant.
  • the high-temperature material is introduced as an emission insert in the socket, which is then cooled.
  • the most effective way of cooling is liquid cooling.
  • the electrode has an inwardly extending cylindrical or conical portion over which the cooling tube projects.
  • the coolant flows around this area and is intended to ensure better heat exchange between the electrode and the coolant.
  • the invention is therefore based on the object to avoid overheating of the electrode of arc plasma torches, but at least to reduce.
  • a cooling tube for an arc plasma torch comprising an elongated body having an end which can be arranged in the open end of an electrode and extending therethrough Coolant channel, characterized in that there is a bead-like inward and / or outward thickening of the wall of the cooling tube at said end.
  • this object is achieved by an arrangement of a cooling tube according to one of claims 1 to 3 and an electrode having a hollow elongate body with an open end for arranging the front end of a cooling tube and a closed end, wherein the bottom surface of the open end a protruding portion over which the end of the cooling tube extends, and the thickening extends longitudinally beyond at least the protruding portion.
  • a cooling tube for an arc plasma torch comprising an elongate body with a releasably connectable to an electrode holder of an arc plasma torch rear end and a extending through him coolant channel, characterized in that for releasably connecting the rear end with an electrode receptacle, an external thread is provided, wherein it is followed by a cylindrical outer surface for centering the cooling tube to the electrode holder.
  • an electrode holder for an arc plasma torch comprising an elongate body having an end for receiving an electrode and a hollow interior, characterized in that in the hollow interior, an internal thread for screwing in a rear end of a cooling tube is provided it is followed by a cylindrical inner surface for centering dese cooling tube for electrode recording.
  • this object is achieved by an arrangement of a cooling tube according to one of claims 9 to 13 and an electrode holder according to one of claims 14 to 16, wherein the cooling tube is screwed to the electrode holder via the external thread and the internal thread.
  • a cooling tube for an arc plasma torch comprising an elongated body with a releasably connectable to an electron beam of an arc plasma burner rear end and a coolant channel extending therethrough and an electrode holder for an arc plasma torch having an elongated body with an end for receiving an electrode and a hollow interior comprises, characterized in that on the outer surface of the cooling tube at least one projection for centering the cooling tube is provided in the Elek- trodenage.
  • an electrode for an arc plasma torch comprising a hollow elongate body having an open end for locating the front end of a cooling tube in the same and a closed end, the open end having an external thread for screwing to the internal thread of an electrode holder characterized in that adjoins the external thread to the closed end, a cylindrical outer surface for centering the electrode for electrode recording.
  • an electrode holder for an arc plasma torch comprising an elongated body having an internally threaded end for receiving an electrode and a hollow interior, characterized in that the internal thread has a cylindrical inner surface for centering the electrode for electrode reception followed.
  • the present invention provides an assembly of an electrode according to any one of claims 24 to 28 and an electrode holder according to any one of claims 29 to 31, wherein the electrode is screwed to the electrode holder via the external thread and the internal thread.
  • this object is achieved by an arc plasma torch with a cooling tube according to one of claims 1 to 3 or 9 to 13, an electrode holder according to one of claims 14 to 16 or 29 to 31, an electrode according to one of claims 24 to 28 or an arrangement according to one of claims 4 to 8, 17 to 23 or 32 to 33.
  • the thickening in the longitudinal direction of the cooling tube extends over at least one millimeter.
  • the thickening leads to an increase in the outer diameter by at least 0.2 millimeters and / or a reduction in the inner diameter by at least 0.2 millimeters.
  • an electrode holder which has an elongate body with an end for receiving the electrode and a hollow interior, wherein the cooling tube extends into the hollow interior and on the outer surface of the cooling tube at least one projection for centering the cooling tube is provided in the electrode holder.
  • a first group of projections is provided, which are arranged circumferentially at a distance from each other.
  • the second group of protrusions is circumferentially offset from the first group of protrusions.
  • a stop surface may be provided for axially fixing the cooling tube in the electrode holder.
  • the cylindrical outer surface has a circumferential groove.
  • a round ring can be arranged for sealing in the groove.
  • the cylindrical outer surface has an outer diameter which is equal to or greater than the outer diameter of the external thread.
  • a stop surface for axially fixing the cooling tube is advantageously provided in the electrode holder.
  • the cylindrical inner surface has an inner diameter which is equal to or greater than the inner diameter of the inner thread.
  • D6.1 (D.61a - D6.1i) / 2.
  • the cooling tube and the electrode holder are designed so that there is an annular gap to the front end between them.
  • cylindrical outer surface of the cooling tube and the cylindrical inner surface of the electrode holder are closely tolerated each other.
  • a first group of projections is advantageously provided, which are arranged circumferentially at a distance from each other.
  • exactly three projections can be provided, which are preferably arranged offset by 120 ° to each other.
  • a second group of projections may be provided, which are arranged circumferentially spaced from each other, wherein the second group is axially offset from the first group.
  • the second group of projections may also consist of exactly three projections, which are preferably offset by 120 ° to each other.
  • the second group of projections is circumferentially offset from the first group of projections.
  • the offset may be 60 °.
  • an abutment surface for axially fixing the electrode in the electrode receptacle may conveniently be provided.
  • the cylindrical outer surface may have a circumferential groove, in which a round ring is preferably arranged for sealing.
  • the cylindrical outer surface has an outer diameter which is equal to or greater than the outer diameter of the external thread.
  • a stop surface for axially fixing an electrode may be provided in the electrode holder.
  • the cylindrical inner surface has an inner diameter which is equal to or greater than the inner diameter of the inner thread.
  • D6.4 (D6.4a + D6.4i) / 2.
  • the cylindrical outer surface of the electrode and the cylindrical inner surface of the electrode holder are closely tolerated each other.
  • a so-called transition fit is used, that means for example tolerance outside: 0 to -0.01 mm, inside tolerance: 0 to +0.01 mm.
  • the invention is based on the surprising finding that the gaps between the cooling tube and the electrode become narrower due to the thickening, but without a cross-sectional reduction in the rear region of the arc plasma burner head.
  • a high flow velocity of the coolant is achieved in front between the cooling tube and electrode, which improves the heat transfer.
  • the heat transfer is additionally or alternatively improved by suitable centering of components of the plasma burner head.
  • the invention is based on the finding that the heat transfer between the electrode and the coolant is not optimal.
  • the pressure, the flow velocity, the volume flow and / or the pressure difference of the coolant in the flow path in the front region, in which the cooling tube protrudes beyond the inwardly extending region of the electrode may not be sufficient.
  • the problem has been recognized that the annular gap between the electrode and cooling tube can be different in size due to a non-centric position on its circumference. This results in uneven distribution of the coolant around the inwardly extending portion of the electrode. This worsens the cooling.
  • FIG. 1 shows a first particular embodiment of a plasma burner head 1 according to the present invention.
  • Said plasma burner head has an electrode 7, an electrode holder 6, a cooling tube 10, a nozzle 4, a nozzle cap 2 and a gas guide 3.
  • the nozzle 4 is fixed by the nozzle cap 2 and a nozzle holder 5.
  • the electrode holder 6 receives the electrode 7 and the cooling tube 10 in each case via a thread, namely internal thread 6.4 and internal thread 6.1, on.
  • the gas guide 3 is located between the electrode 7 and the nozzle 4 and sets a plasma gas PG in rotation.
  • the plasma burner head 1 has a secondary gas protection cap 9, which is screwed onto a nozzle protection cap holder 8 in this exemplary embodiment. Between the secondary gas protection cap 9 and the nozzle cap 2 flows a secondary gas SG, which protects the nozzle 4, in particular the nozzle tip.
  • the cooling tube 10 (see also FIG. 2 ) is attached to the rear part of the electrode holder 6, and the electrode 7 is fixed to the front part of the electrode holder 6.
  • the cooling tube 10 projects beyond an area 7.5 extending inwards, ie away from the nozzle tip (see also FIG Figures 3 and 8th In this area, the inner diameter D10.8 along the length L10.8 of the cooling tube 10 is smaller than the inner diameter D10.9 of the rearward inner portion 10.9 of the cooling tube 10 and the outer diameter D10.10 is on the length L10 .10 of the cooling tube 10 is greater than the outer diameter D10.11 of the rearwardly directed outer portion 10.11 of the cooling tube 10.
  • a coolant first flows in the flow path through WV1 (water supply 1) the interior of the cooling tube 10, strikes the inwardly extending portion 7.5 of the electrode 7, before it via the flow path WR1 (water return 1) in the space between the cooling tube 10 and the Elek-trode 7 and the electrode holder 6 flows back.
  • WV1 water supply 1
  • WR1 water return 1
  • the plasma jet (not shown) has its starting point on the outer surface of an electrode insert 7.8. There, most of the heat that must be dissipated to achieve a long life of the electrode 7. The heat is conducted via the electrode 7 made of copper or silver to the coolant in the electrode interior.
  • the distance between the opposing surfaces of the front inner portion 10.8 of the cooling tube and the electrode portion 7.5 of the electrode 7 and the front outer portion 10.10 and the inner surface 7.10 of the electrode very small. It is in the range of 0.1 to 0.5 mm.
  • coolant flows in the space between the nozzle 4 and the nozzle cap 2 via a flow path WV2 (water supply 2) and WR2 (water return 2).
  • the cooling tube 10 is screwed to the electrode holder 6 via the external thread 10.1 and the internal thread 6.1.
  • the cooling tube 10 and the electrode holder 6 are formed by the cylindrical outer surface 10.3 of the cooling tube 10 and the cylindrical inner surface 6.3 of the electrode holder. 6 centered on each other. These are closely tolerated to each other to achieve a good centering.
  • the internal thread 6.1 of the electrode-receiving 6 and the external thread 10.1 of the cooling tube 10 have sufficient clearance to each other, so that the cooling tube 10 can be easily screwed into the electrode holder 6. Only shortly before tightening, the centering is done by the closely tolerated, opposite in the screwed state cylindrical inner surface 6.3 and cylindrical outer surface 10.3.
  • the outer diameter D10.3 of the cylindrical outer surface 10.3 of the cooling tube 10 is at least as large as or larger than the outer diameter D10.1 of the external thread 10.1.
  • the centering described above ensures the parallel alignment of the cooling tube 10 to the axis M of the plasma burner head 1, a uniform annular gap between the cooling tube 10 and electrode region 7.5 and thus a uniform distribution of the coolant flow in the electrode interior, in particular in the region of the front section 10.8 of the cooling tube 20 and the inwardly extending electrode area 7.5.
  • the stop surfaces are 10.2 and 6.2 to each other. This results in an axial fixation of the cooling tube 10 in the electrode holder. 6
  • the electrode 7 is screwed to the electrode holder 6 via the external thread 7.4 and the internal thread 6.4.
  • the electrode 7 and the electrode holder 6 are formed by the cylindrical outer surface 7.6 of the electrode 7 and the cylindrical inner surface of the electrode 6.6 6.6 centered to each other.
  • the outer surfaces are closely tolerated to each other to achieve a good centering.
  • the tolerance of the cylindrical outer surface may be the nominal dimension of the outer diameter D7.6 from 0 to -0.01 mm and the tolerance of the cylindrical inner surface the nominal dimension of the inner diameter D6.6 from 0 to +0.01 mm.
  • the internal thread 6.4 of the electrode holder 6 and the external thread 7.4 of the electrode 7 have enough clearance to each other so that the electrode 7 can be easily screwed into the electrode holder 6. Only shortly before tightening the centering is done by the closely tolerated, opposite in the screwed state cylindrical surfaces 6.6 and cylindrical outer surface 7.6.
  • the outer diameter D7.6 of the cylindrical outer surface 7.6 of the electrode 7 is at least equal to or greater than the maximum outer diameter D7.4 of the external thread 7.4 (see FIG. 8 ).
  • the centering described above is necessary for the parallel alignment of the electrode 6 to the axis M of the plasma burner head 1, which in turn for a uniform distribution of the coolant flow in the electrode interior, in particular in the region of the front inner portion 10.8 of the cooling tube 10 and the inwardly extending portion 7.5 of Electrode 7 provides.
  • the centering of the electrode 7 to the electrode holder 6 serves to secure the centricity to the other components of the plasma burner head, in particular the nozzle 4. This is used for uniform formation of the plasma jet, which is determined by positioning the electrode insert 7.8 of the electrode 7 to the nozzle bore 4.1 of the nozzle 4 ,
  • the cylindrical outer surface 7.6 has a groove 7.3, in which a round ring 7.2 is arranged for sealing. In the bolted state lie the stop surfaces 7.7 and 6.7 each other. This results in an axial fixation of the electrode 7 in the electrode holder. 6
  • the projections 10.6 are offset in this case to the projections 10.7 offset by 60 °. This offset improves the radial centering.
  • the projections 10.7 can be used as a counterpart for a tool (not shown) for screwing in and out of the cooling tube 10.
  • the projections 10.6 and 10.7 have seen from the front portion 10.8 of rectangular cross-section.
  • only the corners of the rectangular cross sections are on the cylindrical inner surface 6.11 of the electrode holder 6.
  • a high degree of centricity is achieved at the same time smooth assembly.
  • FIG. 9 shows a further particular embodiment of a plasma burner head 1 according to the invention, which differs from the in the FIGS. 1 to 8 shown embodiment in the design of the front inner portion 10.8 of the cooling tube 10 (see also FIG. 10 ) is different.
  • the length L10.8 of the inner section 10.8 is shorter, whereby the flow cross section is greatly increased only in the foremost area.
  • the lengths of the front inner section 10.8 and the front outer section 10.10. are the same size here.
  • a groove 10.4 in which a circular ring 10.5 is arranged for sealing (see also FIG. 11 ).
  • FIG. 12 shows a further particular embodiment of the plasma burner head according to the invention, which differs from the two embodiments according to the FIGS. 1 to 11 in the design of the front inner portion 10.8 of the cooling tube 10 (see also FIG. 13 ) is different.
  • the length L10.8 of the inner section 10.8 is shorter than in the FIG. 1
  • the length L10.10 of the front outer section 10.10 is larger than in FIG. 9 .
  • the centering between cooling tube 10 and electrode holder 6 also takes place via a cylindrical inner surface 6.3 and a cylindrical outer surface 10.3. But these are different than in the FIGS. 1 and 9 arranged.
  • the cylindrical centering surfaces are increased. This further improves the centering and is achieved by changing the order of the threaded centering surface stop surface to the threaded stop surface centering surface. Another advantage is that the size does not increase. With maintained order, the stop surface should have a larger diameter than the centering.
  • FIG. 15 shows a further particular embodiment of the plasma burner head according to the invention. This differs from the embodiment according to FIG. 1 in the design of the front inner portion 10.8 of the cooling tube 10 (see also FIG. 16 ).
  • the lengths of the front inner section 10.8 and the front outer section 10.10. are the same size here. Said sections correspond in their length to the area 7.5 of the electrode 7.
  • cooling tube 10 and electrode holder 6 takes place as in FIG. 12 , in the cylindrical outer surface 10.3 of the cooling tube 10, a groove 10.4, in which a round ring is arranged 10.5 for sealing. This is in FIG. 17 shown.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Plasma Technology (AREA)
  • Arc Welding In General (AREA)
  • Discharge Heating (AREA)
EP10720245.9A 2009-04-08 2010-03-24 Kühlrohre, elektrodenaufnahmen und elektrode für einen lichtbogenplasmabrenner sowie anordnungen aus denselben und lichtbogenplasmabrenner mit denselben Active EP2417840B1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL10720245T PL2417840T3 (pl) 2009-04-08 2010-03-24 Rury chłodzące, uchwyty do elektrod i elektroda do łukowego palnika plazmowego oraz złożone z nich układy i zawierające je łukowy palnik plazmowy
SI201031660T SI2417840T1 (en) 2009-04-08 2010-03-24 Cooling tubes, electrode and electrode holders for an arc plasma torch and assemblies thereof, and an arc plasma burner comprising these elements

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009016932A DE102009016932B4 (de) 2009-04-08 2009-04-08 Kühlrohre und Elektrodenaufnahme für einen Lichtbogenplasmabrenner sowie Anordnungen aus denselben und Lichtbogenplasmabrenner mit denselben
PCT/DE2010/000325 WO2010115397A2 (de) 2009-04-08 2010-03-24 Kühlrohre, elektrodenaufnahmen und elektrode für einen lichtbogenplasmabrenner sowie anordnungen aus denselben und lichtbogenplasmabrenner mit denselben

Publications (2)

Publication Number Publication Date
EP2417840A2 EP2417840A2 (de) 2012-02-15
EP2417840B1 true EP2417840B1 (de) 2018-02-21

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EP10720245.9A Active EP2417840B1 (de) 2009-04-08 2010-03-24 Kühlrohre, elektrodenaufnahmen und elektrode für einen lichtbogenplasmabrenner sowie anordnungen aus denselben und lichtbogenplasmabrenner mit denselben

Country Status (12)

Country Link
US (2) US9204526B2 (enExample)
EP (1) EP2417840B1 (enExample)
JP (1) JP2012523651A (enExample)
KR (1) KR101650605B1 (enExample)
CN (2) CN102388681A (enExample)
BR (1) BRPI1016021B1 (enExample)
DE (1) DE102009016932B4 (enExample)
ES (1) ES2669644T3 (enExample)
PL (1) PL2417840T3 (enExample)
RU (1) RU2524919C2 (enExample)
SI (1) SI2417840T1 (enExample)
WO (1) WO2010115397A2 (enExample)

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EP4122299A1 (en) * 2020-03-16 2023-01-25 Hypertherm, Inc. Liquid coolant tube for a plasma arc cutting system
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KR102594269B1 (ko) * 2022-11-17 2023-10-26 (주)한국진공야금 플라즈마 토치
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CN102388681A (zh) 2012-03-21
US9204526B2 (en) 2015-12-01
US9743504B2 (en) 2017-08-22
SI2417840T1 (en) 2018-04-30
DE102009016932B4 (de) 2013-06-20
KR20110136852A (ko) 2011-12-21
JP2012523651A (ja) 2012-10-04
WO2010115397A3 (de) 2011-03-03
PL2417840T3 (pl) 2018-07-31
BRPI1016021B1 (pt) 2019-11-19
DE102009016932A1 (de) 2010-10-21
US20150083695A1 (en) 2015-03-26
RU2011145039A (ru) 2013-05-20
US20120132626A1 (en) 2012-05-31
RU2524919C2 (ru) 2014-08-10
BRPI1016021A2 (pt) 2016-04-26
CN107018618A (zh) 2017-08-04
KR101650605B1 (ko) 2016-08-23
ES2669644T3 (es) 2018-05-28
EP2417840A2 (de) 2012-02-15
WO2010115397A2 (de) 2010-10-14

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